51. Spectroscopy of Nafion in terahertz frequency range.
- Author
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Yurchenko, Stanislav O. and Zaytsev, Kirill I.
- Subjects
- *
NAFION , *TERAHERTZ spectroscopy , *POLYMERS , *PERMITTIVITY , *DEBYE'S theory - Abstract
We report results on the terahertz (THz) spectroscopy of polymer Nafion. Using THz pulse spectroscopy and refined post-processing algorithms based on the ill-posed spectroscopic inverse problem analysis, we find the complex dielectric permittivity of Nafion to be in the range 0.15-1.5 THz. The results in the low-frequency (gigahertz) range agree well with known measurements. We find that the complex dielectric permittivity can be described well using the double-Debye model with relaxation times of 7.20×0.05 ps and 0.12×0.05 ps. This result is discussed briefly from the viewpoint of the appearance of a segregated structure in the "Nafion-water" system. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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