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Lamellar structures of transition metal phosphorus trisulfides possess strong intralayer bonding, albeit adjacent layers are held by weak van der Waals interactions. Those compounds received enormous interest due to their unique combination of optical and long-range magnetic properties. Among them, iron phosphorus trisulfide (FePS$_3$) gathered special attention for being a semiconductor with an absorption edge in the near-infrared, as well as showing an Ising-like anti-ferromagnetism. We report a successful growth of centimeter size bulk FePS$_3$ crystals with a chemical yield above 70%, whose crystallographic structure and composition were carefully identified by advanced electron microscopy methodologies, including atomic resolution elemental mapping, along with photoelectron spectroscopy. The knowledge on the optical activity of FePS$_3$ is extended utilizing temperature-dependent absorption and photoacoustic spectroscopies, while measurements were corroborated with density-functional theory calculations. Temperature-dependent experiments showed a small and monotonic band-edge energy shift down to 115 K and exposed the interconnected importance of electron-phonon coupling. Most of all, the correlation between the optical behavior and the magnetic phase transition is revealed, which shows the practical utilization of temperature-dependent optical absorption to investigate magnetic interactions., Comment: 40 pages, 13 figures, 1 table

The electron density ($n_{e^{-}}$) plays an important role in setting the chemistry and physics of the interstellar medium. However, measurements of $n_{e^{-}}$ in neutral clouds have been directly obtained only toward a few lines of sight or they rely on indirect determinations. We use carbon radio recombination lines and the far-infrared lines of C$^{+}$ to directly measure $n_{e^{-}}$ and the gas temperature in the envelope of the integral shaped filament (ISF) in the Orion A molecular cloud. We observed the C$102\alpha$ and C$109\alpha$ carbon radio recombination lines (CRRLs) using the Effelsberg 100m telescope at ~2' resolution toward five positions in OMC-2 and OMC-3. Since the CRRLs have similar line properties, we averaged them to increase the signal-to-noise ratio of the spectra. We compared the intensities of the averaged CRRLs, and the 158 {\mu}m-[CII] and [$^{13}$CII] lines to the predictions of a homogeneous model for the C$^{+}$/C interface in the envelope of a molecular cloud and from this comparison we determined the electron density, temperature and C$^{+}$ column density of the gas. We detect the CRRLs toward four positions, where their velocity and widths (FWHM 2.3 km s$^{-1}$) confirms that they trace the envelope of the ISF. Toward two positions we detect the CRRLs, and the [CII] and [$^{13}$CII] lines with a signal-to-noise ratio >5, and we find $n_{e^{-}}=0.65\pm0.12$ cm$^{-3}$ and $0.95\pm0.02$ cm$^{-3}$, which corresponds to a gas density $n_{H}\approx5\times10^{3}$ cm$^{-3}$ and a thermal pressure of $p_{th}\approx4\times10^{5}$ K cm$^{-3}$. We also constrained the ionization fraction in the denser portions of the molecular cloud using the HCN(1-0) and C$_{2}$H(1-0) lines to $x(e^{-})<3\times10^{-6}$. The derived electron densities and ionization fraction imply that $x(e^{-})$ drops by a factor >100 between the C$^{+}$ layer and the regions probed by HCN(1-0)., Comment: 14 pages, 6 figures, 8 tables, accepted for publication in A&A

Integral field unit (IFU) spectra of face-on star-forming galaxies from the MaNGA survey are stacked in radial bins so as to reach a S/N high enough to measure emission lines and Lick indices out to 2.5-3 R_e. Two thirds of galaxies have stellar populations in the outer disks that are older, more metal poor and less dusty than in the inner disks. Recent bursts of star formation have occurred more frequently in the outer disk, but extinction-corrected Halpha equivalent widths are significantly lower at fixed D_n(4000) in these regions. I examine the properties of a subset of galaxies with the the most H$\alpha$ deficient outer disks. These regions contain young stellar populations that must have formed within the last 0.5 Gyr, but extinction-corrected Halpha values well below the values predicted for a standard Kroupa IMF. The Halpha deficient galaxies have flat D_n(4000) and Hdelta_A profiles with little radial fluctuation, indicating that star formation has occurred extremely uniformly across the entire disk. The H$\alpha$ line profiles indicate that the ionized gas kinematics is also very regular across the disk. The main clue to the origin of the Halpha deficiency is that it sets in at the same radius where the dust extinction abruptly decreases, suggesting a mode of star formation deficient in massive stars in quiescent, HI-dominated gas. Finally, I have carried out a search for galaxies with signatures of unusual Halpha kinematics and find that 15% of the sample exhibit evidence for significant ionized gas that is displaced from the systemic velocity of the disk., Comment: 16 pages, 15 figures, accepted for publication in MNRAS

This paper describes a search for galaxy centers with clear indications of unusual stellar populations with an initial mass function flatter than Salpeter at high stellar masses. Out of a sample of 668 face-on galaxies with stellar masses in the range 10^10- 10^11 M_sol, I identify 15 galaxies with young to intermediate age central stellar populations with unusual stellar population gradients in the inner regions of the galaxy. In these galaxies, the 4000 Angstrom break is either flat or rising towards the center of the galaxy, indicating that the central regions host evolved stars, but the H$\alpha$ equivalent width also rises steeply in the central regions. The ionization parameter [OIII]/[OII] is typically low in these galactic centers, indicating that ionizing sources are stellar rather than AGN. Wolf Rayet features characteristic of hot young stars are often found in the spectra and these also get progressively stronger at smaller galactocentric radii. These outliers are compared to a control sample of galaxies of similar mass with young inner stellar populations, but where the gradients in Halpha equivalent width and 4000 Angstrom break follow each other more closely. The outliers exhibit central Wolf Rayet red bump excesses much more frequently, they have higher central stellar and ionized gas metallicities, and they are also more frequently detected at 20 cm radio wavelengths. I highlight one outlier where the ionized gas is clearly being strongly perturbed and blown out either by massive stars after they explode as supernovae, or by energy injection from matter falling onto a black hole., Comment: 16 pages, 16 figures, accepted for publication in MNRAS

The Central Molecular Zone (CMZ), a $\sim$200 pc sized region around the Galactic Centre, is peculiar in that it shows a star formation rate (SFR) that is suppressed with respect to the available dense gas. To study the SFR in the CMZ, young stellar objects (YSOs) can be investigated. Here we present radio observations of 334 2.2 $\mu$m infrared sources that have been identified as YSO candidates. Our goal is to investigate the presence of centimetre wavelength radio continuum counterparts to this sample of YSO candidates which we use to constrain the current SFR in the CMZ. As part of the GLOSTAR survey, D-configuration VLA data was obtained for the Galactic Centre, covering -2$^{\circ}

We study the radial motions of cold, star-forming gas in the secular evolution phase of a set of 14 magnetohydrodynamical cosmological zoom-in simulations of Milky Way-mass galaxies. We study the radial transport of material within the disc plane in a series of concentric rings. For the gas in each ring at a given time we compute two quantities as a function of time and radius: 1) the radial bulk flow of the gas; and 2) the radial spread of the gas relative to the bulk flow. Averaging the data from all the halos, we find that the radial spread increases with radius in the form of a power law with strong secondary dependencies on the fraction of accreted material and the local radial velocity dispersion of the gas. We find that the bulk motion of gas is well described in the inner disc regions by a radially-independent mean inward flow speed of $-$2.4 km s$^{-1}$. The spread around this value relates to the change in angular momentum of the gas and also the amount of accreted material. These scalings from fully cosmological, MHD simulations of galaxy formation can then be used in semi-analytic models to better parameterise the radial flow of gas in discs., Comment: 17 pages, 13 figures, Accepted for publication in MNRAS

NASA's Great Observatories have opened up the electromagnetic spectrum from space, providing sustained access to wavelengths not accessible from the ground. Together, Hubble, Compton, Chandra, and Spitzer have provided the scientific community with an agile and powerful suite of telescopes with which to attack broad scientific questions, and react to a rapidly changing scientific landscape. As the existing Great Observatories age, or are decommissioned, community access to these wavelengths will diminish, with an accompanying loss of scientific capability. This report, commissioned by the NASA Cosmic Origins, Physics of the Cosmos and Exoplanet Exploration Program Analysis Groups (PAGs), analyzes the importance of multi-wavelength observations from space during the epoch of the Great Observatories, providing examples that span a broad range of astrophysical investigations., Comment: A report by the Great Observatories Science Analysis Group (SAG-10), commissioned by NASA's Cosmic Origins, Physics of the Cosmos, and Exoplanet Exploration Program Analysis Groups. 87 pages, 23 figures

In order to study the circumgalactic medium (CGM) of galaxies we develop an automated pipeline to estimate the optical continuum of quasars and detect intervening metal absorption line systems with a matched kernel convolution technique and adaptive S/N criteria. We process $\sim$ one million quasars in the latest Data Release 16 (DR16) of the Sloan Digital Sky Survey (SDSS) and compile a large sample of $\sim$ 160,000 MgII absorbers, together with $\sim$ 70,000 FeII systems, in the redshift range $0.35

Many approaches, which have been developed to express the potential energy of large systems, exploit the locality of the atomic interactions. A prominent example are fragmentation methods, in which quantum chemical calculations are carried out for overlapping small fragments of a given molecule that are then combined in a second step to yield the system's total energy. Here we compare the accuracy of the systematic molecular fragmentation approach with the performance of high-dimensional neural network (HDNN) potentials introduced by Behler and Parrinello. HDNN potentials are similar in spirit to the fragmentation approach in that the total energy is constructed as a sum of environment-dependent atomic energies, which are derived indirectly from electronic structure calculations. As a benchmark set we use all-trans alkanes containing up to eleven carbon atoms at the coupled cluster level of theory. These molecules have been chosen because they allow to extrapolate reliable reference energies for very long chains, enabling an assessment of the energies obtained by both methods for alkanes including up to 10 000 carbon atoms. We find that both methods predict high-quality energies with the HDNN potentials yielding smaller errors with respect to the coupled cluster reference.

We present the first results from a CARMA high-resolution $^{12}$CO(1-0), $^{13}$CO(1-0), and C$^{18}$O(1-0) molecular line survey of the North America and Pelican (NAP) Nebulae. CARMA observations have been combined with single-dish data from the Purple Mountain 13.7m telescope to add short spacings and produce high-dynamic-range images. We find that the molecular gas is predominantly shaped by the W80 HII bubble that is driven by an O star. Several bright rims are probably remnant molecular clouds heated and stripped by the massive star. Matching these rims in molecular lines and optical images, we construct a model of the three-dimensional structure of the NAP complex. Two groups of molecular clumps/filaments are on the near side of the bubble, one being pushed toward us, whereas the other is moving toward the bubble. Another group is on the far side of the bubble and moving away. The young stellar objects in the Gulf region reside in three different clusters, each hosted by a cloud from one of the three molecular clump groups. Although all gas content in the NAP is impacted by feedback from the central O star, some regions show no signs of star formation, while other areas clearly exhibit star formation activity. Other molecular gas being carved by feedback includes the cometary structures in the Pelican Head region and the boomerang features at the boundary of the Gulf region. The results show that the NAP complex is an ideal place for the study of feedback effects on star formation., Comment: accepted by AJ

Applying dendrogram analysis to the CARMA-NRO C$^{18}$O ($J$=1--0) data having an angular resolution of $\sim$ 8", we identified 692 dense cores in the Orion Nebula Cluster (ONC) region. Using this core sample, we compare the core and initial stellar mass functions in the same area to quantify the step from cores to stars. About 22 \% of the identified cores are gravitationally bound. The derived core mass function (CMF) for starless cores has a slope similar to Salpeter's stellar initial mass function (IMF) for the mass range above 1 $M_\odot$, consistent with previous studies. Our CMF has a peak at a subsolar mass of $\sim$ 0.1 $M_\odot$, which is comparable to the peak mass of the IMF derived in the same area. We also find that the current star formation rate is consistent with the picture in which stars are born only from self-gravitating starless cores. However, the cores must gain additional gas from the surroundings to reproduce the current IMF (e.g., its slope and peak mass), because the core mass cannot be accreted onto the star with a 100\% efficiency. Thus, the mass accretion from the surroundings may play a crucial role in determining the final stellar masses of stars., Comment: 13 pages, 5 figures, accepted by ApJL

G0.253+0.016, aka 'the Brick', is one of the most massive (> 10^5 Msun) and dense (> 10^4 cm-3) molecular clouds in the Milky Way's Central Molecular Zone. Previous observations have detected tentative signs of active star formation, most notably a water maser that is associated with a dust continuum source. We present ALMA Band 6 observations with an angular resolution of 0.13" (1000 AU) towards this 'maser core', and report unambiguous evidence of active star formation within G0.253+0.016. We detect a population of eighteen continuum sources (median mass ~ 2 Msun), nine of which are driving bi-polar molecular outflows as seen via SiO (5-4) emission. At the location of the water maser, we find evidence for a protostellar binary/multiple with multi-directional outflow emission. Despite the high density of G0.253+0.016, we find no evidence for high-mass protostars in our ALMA field. The observed sources are instead consistent with a cluster of low-to-intermediate-mass protostars. However, the measured outflow properties are consistent with those expected for intermediate-to-high-mass star formation. We conclude that the sources are young and rapidly accreting, and may potentially form intermediate and high-mass stars in the future. The masses and projected spatial distribution of the cores are generally consistent with thermal fragmentation, suggesting that the large-scale turbulence and strong magnetic field in the cloud do not dominate on these scales, and that star formation on the scale of individual protostars is similar to that in Galactic disc environments., Comment: Accepted for publication in MNRAS. 23 pages, 13 figures, 4 tables

We observe 1.3~mm spectral lines at 2000~AU resolution toward four massive molecular clouds in the Central Molecular Zone of the Galaxy to investigate their star formation activities. We focus on several potential shock tracers that are usually abundant in protostellar outflows, including SiO, SO, CH$_3$OH, H$_2$CO, HC$_3$N, and HNCO. We identify 43 protostellar outflows, including 37 highly likely ones and 6 candidates. The outflows are found toward both known high-mass star forming cores and less massive, seemingly quiescent cores, while 791 out of the 834 cores identified based on the continuum do not have detected outflows. The outflow masses range from less than 1~$M_\odot$ to a few tens of $M_\odot$, with typical uncertainties of a factor of 70. We do not find evidence of disagreement between relative molecular abundances in these outflows and in nearby analogs such as the well-studied L1157 and NGC7538S outflows. The results suggest that i) protostellar accretion disks driving outflows ubiquitously exist in the CMZ environment, ii) the large fraction of candidate starless cores is expected if these clouds are at very early evolutionary phases, with a caveat on the potential incompleteness of the outflows, iii) high-mass and low-mass star formation is ongoing simultaneously in these clouds, and iv) current data do not show evidence of difference between the shock chemistry in the outflows that determines the molecular abundances in the CMZ environment and in nearby clouds., Comment: 43 pages, 25 figures, 3 tables, accepted for publication in ApJ

The SEDIGISM (Structure, Excitation and Dynamics of the Inner Galactic Interstellar Medium) survey used the APEX telescope to map 84 deg^2 of the Galactic plane between l = -60 deg and l = +31 deg in several molecular transitions, including 13CO(2-1) and C18O(2-1), thus probing the moderately dense (~10^3 cm^-3) component of the interstellar medium. With an angular resolution of 30'' and a typical 1-sigma sensitivity of 0.8-1.0 K at 0.25 km/s velocity resolution, it gives access to a wide range of structures, from individual star-forming clumps to giant molecular clouds and complexes. The coverage includes a good fraction of the first and fourth Galactic quadrants, allowing us to constrain the large scale distribution of cold molecular gas in the inner Galaxy. In this paper we provide an updated overview of the full survey and the data reduction procedures used. We also assess the quality of these data and describe the data products that are being made publicly available as part of this first data release (DR1). We present integrated maps and position-velocity maps of the molecular gas and use these to investigate the correlation between the molecular gas and the large scale structural features of the Milky Way such as the spiral arms, Galactic bar and Galactic centre. We find that approximately 60 per cent of the molecular gas is associated with the spiral arms and these appear as strong intensity peaks in the derived Galactocentric distribution. We also find strong peaks in intensity at specific longitudes that correspond to the Galactic centre and well known star forming complexes, revealing that the 13CO emission is concentrated in a small number of complexes rather than evenly distributed along spiral arms., Comment: MNRAS, in press

We use the 13CO(2-1) emission from the SEDIGISM high-resolution spectral-line survey of the inner Galaxy, to extract the molecular cloud population with a large dynamic range in spatial scales, using the SCIMES algorithm. This work compiles a cloud catalogue with a total of 10663 molecular clouds, 10300 of which we were able to assign distances and compute physical properties. We study some of the global properties of clouds using a science sample, consisting of 6664 well resolved sources and for which the distance estimates are reliable. In particular, we compare the scaling relations retrieved from SEDIGISM to those of other surveys, and we explore the properties of clouds with and without high-mass star formation. Our results suggest that there is no single global property of a cloud that determines its ability to form massive stars, although we find combined trends of increasing mass, size, surface density and velocity dispersion for the sub-sample of clouds with ongoing high-mass star formation. We then isolate the most extreme clouds in the SEDIGISM sample (i.e. clouds in the tails of the distributions) to look at their overall Galactic distribution, in search for hints of environmental effects. We find that, for most properties, the Galactic distribution of the most extreme clouds is only marginally different to that of the global cloud population. The Galactic distribution of the largest clouds, the turbulent clouds and the high-mass star-forming clouds are those that deviate most significantly from the global cloud population. We also find that the least dynamically active clouds (with low velocity dispersion or low virial parameter) are situated further afield, mostly in the least populated areas. However, we suspect that part of these trends may be affected by some observational biases, and thus require further follow up work in order to be confirmed., Comment: 25 pages (+ appendices, 15 pages), 26 figures, MNRAS

By combining two surveys covering a large fraction of the molecular material in the Galactic disk we investigate the role the spiral arms play in the star formation process. We have matched clumps identified by ATLASGAL with their parental GMCs as identified by SEDIGISM, and use these giant molecular cloud (GMC) masses, the bolometric luminosities, and integrated clump masses obtained in a concurrent paper to estimate the dense gas fractions (DGF$_{\rm gmc}=\sum M_{\rm clump}/M_{\rm gmc}$) and the instantaneous star forming efficiencies (i.e., SFE$_{\rm gmc} = \sum L_{\rm clump}/M_{\rm gmc}$). We find that the molecular material associated with ATLASGAL clumps is concentrated in the spiral arms ($\sim$60% found within $\pm$10 km s$^{-1}$ of an arm). We have searched for variations in the values of these physical parameters with respect to their proximity to the spiral arms, but find no evidence for any enhancement that might be attributable to the spiral arms. The combined results from a number of similar studies based on different surveys indicate that, while spiral-arm location plays a role in cloud formation and HI to H$_2$ conversion, the subsequent star formation processes appear to depend more on local environment effects. This leads us to conclude that the enhanced star formation activity seen towards the spiral arms is the result of source crowding rather than the consequence of a any physical process., Comment: 15 pages, 12 figures. Full list of affiliations can be found at the end of the paper