101. Synthesis, thermal and magnetic properties of RE-diborides
- Author
-
А.N. Vasil'ev, V. V. Novikov, Olga S. Volkova, and A. V. Matovnikov
- Subjects
010302 applied physics ,Materials science ,Magnetic moment ,Condensed matter physics ,Phonon ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Heat capacity ,Thermal expansion ,Electronic, Optical and Magnetic Materials ,Magnetization ,Ferromagnetism ,Condensed Matter::Superconductivity ,0103 physical sciences ,Magnetic components ,Thermal ,0210 nano-technology - Abstract
Techniques of synthesis of RE diborides (RB 2 ) are developed (R=Tb, Dy, Ho, Er, Lu). Temperature dependence of magnetisation, a heat capacity, a lattice parameters of diborides in the range of 2–300 K are measured. According to joint calorimetric and X-ray research the analysis of a phonon component of a heat capacity and thermal expansion of RE-diborides is carried out by Debye-Einstein's models, the parameters of the model are determined. The change of magnetisation of the ferromagnetic RB 2 compounds with growth of temperature caused by violation of ordering in the system of the atomic magnetic moments is compared with the change of entropy of a magnetic subsystem calculated from calorimetric data. Analytical expansion for calculation of a magnetic component of a heat capacity by RB 2 magnetisation data at the temperatures of 2–300 K is obtained.
- Published
- 2017
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