101. Competitive mechanism of electron transition in Mn-doped ZnS nanoribbons
- Author
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Quantao Liu, Chunxiang Xu, Xinying Zhu, Ming Meng, Jitao Li, Kuili Liu, and Wei Qin
- Subjects
Materials science ,Condensed matter physics ,Dopant ,Mechanical Engineering ,Metals and Alloys ,Mn element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Blueshift ,Emission band ,Mechanics of Materials ,Absorption band ,Atomic electron transition ,Materials Chemistry ,Mn doped ,0210 nano-technology ,Wurtzite crystal structure - Abstract
In this work, ZnS-based one-dimensional nanoribbons were synthesized by a simple thermal evaporation method. The highly crystalline fringes exhibit the wurtzite structure, growing mainly along the [001] or [100] direction. The optical absorption spectra showed that the optical absorption band edge of the pure ZnS nanoribbons exhibit an obvious blue shift compared to that of the Mn-doped ZnS. Strong emission band centered at 343 nm has been found from the PL spectrum of the pure ZnS nanoribbons, while a weak defect-related emission centered at 580 nm also was discovered with the dopant of Mn element. Combined with all the measurements, the growth mechanism and the electron transition process were discussed.
- Published
- 2016
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