406 results on '"Zeyan Wang"'
Search Results
102. An integrated Si photocathode with lithiation-activated molybdenum oxide nanosheets for efficient ammonia synthesis
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Yuyin Mao, Haona Zhang, Weiyi Jiang, Renna Zhao, Yuanyuan Liu, Zeyan Wang, Peng Wang, Zhaoke Zheng, Kepeng Song, Wei Wei, Ying Dai, Jr-Hau He, Hefeng Cheng, and Baibiao Huang
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Renewable Energy, Sustainability and the Environment ,General Materials Science ,Electrical and Electronic Engineering - Published
- 2022
103. Molten-salt assisted synthesis of Cu clusters modified TiO2 with oxygen vacancies for efficient photocatalytic reduction of CO2 to CO
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Xiaolei Bao, Minghui Zhang, Zeyan Wang, Dujuan Dai, Peng Wang, Hefeng Cheng, Yuanyuan Liu, Zhaoke Zheng, Ying Dai, and Baibiao Huang
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General Chemical Engineering ,Environmental Chemistry ,General Chemistry ,Industrial and Manufacturing Engineering - Published
- 2022
104. Boron containing metal-organic framework for highly selective photocatalytic production of H
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Yujie, Li, Fahao, Ma, Liren, Zheng, Yuanyuan, Liu, Zeyan, Wang, Peng, Wang, Zhaoke, Zheng, Hefeng, Cheng, Ying, Dai, and Baibiao, Huang
- Abstract
A zirconium-based metal-organic framework containing boron (UiO-66-B) is prepared, which displays efficient photocatalytic H
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- 2021
105. Dynamic magnetic resonance imaging evaluation before and after operation for pelvic organ prolapse
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Hongbo Zhang, Zeyan Wang, Xuehong Xiao, Jing Wang, and Beibei Zhou
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Radiological and Ultrasound Technology ,Uterine Prolapse ,Valsalva Maneuver ,Urology ,Gastroenterology ,Humans ,Radiology, Nuclear Medicine and imaging ,Female ,Pelvic Floor ,Magnetic Resonance Imaging ,Pelvic Organ Prolapse - Abstract
This study aimed to explore the value of dynamic magnetic resonance imaging (MRI) before and after operation for pelvic organ prolapse (POP).Twenty-nine patients with POP (POP group) before and one month after surgery and 12 healthy women (control group) underwent static and dynamic MRI at rest and during straining (Valsalva maneuver). The preoperative MRI images of the POP and control groups were analyzed, and various measurements were recorded. Differences in measurements were compared between the POP and control groups; similarly, changes in measurements before and after operation were compared.In the POP group, MRI detected 29 anterior vaginal prolapses, 27 uterine prolapses, 1 rectoceles, and 14 pouch of Douglas hernias. In addition, 27 levator ani muscle defect and 15 pubocervical fascial defect cases were observed. The bladder-pubococcygeal line (B-PCL), uterus-pubococcygeal line (U-PCL), Douglas pouch-pubococcygeal line, the length of the hiatus, the descent of the levator plate, levator hiatus size, levator plate angle, iliococcygeus angle, and urethral inclination angle (UA) were larger in the POP group than in the control group. The pelvic organs' positions returned to normal postoperatively in 9 of 21 cases. The B-PCL, U-PCL, and UA were smaller post-surgery than pre-surgery.Static and dynamic MRI can comprehensively evaluate morphological and functional changes of the pelvic floor postoperatively.
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- 2021
106. Fabrication of ZnO Ceramics with Defects by Spark Plasma Sintering Method and Investigations of Their Photoelectrochemical Properties
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Haipeng Zhang, Zeyan Wang, Liren Zheng, Hefeng Cheng, Baibiao Huang, Peng Wang, Yuanyuan Liu, Zhaoke Zheng, and Mu Liu
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Materials science ,Fabrication ,General Chemical Engineering ,chemistry.chemical_element ,Spark plasma sintering ,Sintering ,Zinc ,Conductivity ,Article ,ZnO ceramic ,law.invention ,oxygen vacancies ,interstitial zinc ,law ,General Materials Science ,Calcination ,Ceramic ,QD1-999 ,equipment and supplies ,Chemistry ,chemistry ,Chemical engineering ,visual_art ,electrical properties ,visual_art.visual_art_medium ,photoelectrochemical properties ,spark plasma sintering ,Visible spectrum - Abstract
ZnO, as an important semiconductor material, has attracted much attention due to its excellent physical properties, which can be widely used in many fields. Notably, the defects concentration and type greatly affect the intrinsic properties of ZnO. Thus, controllable adjustment of ZnO defects is particularly important for studying its photoelectric properties. In this work, we fabricated ZnO ceramics (ZnO(C)) with different defects through spark plasma sintering (SPS) process by varying sintering temperature and using reduction environment. The experimental results indicate that the changes of color and light absorption in as-prepared ZnO originate from the different kinds of defects, i.e., oxygen vacancies (VO), interstitial zinc (Zni), and Zinc vacancies (VZn). Moreover, with the increase in calcination temperature, the concentration of oxygen defects and interstitial zinc defects in the ceramics increases gradually, and the conductivity of the ceramics is also improved. However, too many defects are harmful to the photoelectrochemical properties of the ceramics, and the appropriate oxygen defects can improve the utilization of visible light.
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- 2021
107. BiVO4 Ceramic Photoanode with Enhanced Photoelectrochemical Stability
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Baibiao Huang, Yujie Li, Ying Dai, Hefeng Cheng, Peng Wang, Liren Zheng, Yuanyuan Liu, Zeyan Wang, Zhaoke Zheng, Jiyu Li, Weiyi Jiang, Minrui Wang, Fahao Ma, and Mu Liu
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Photocurrent ,Materials science ,BiVO4 photoanode ,General Chemical Engineering ,Doping ,Oxide ,Spark plasma sintering ,photoelectrochemical stability ,spark plasma sintering (SPS) ,ceramics ,Tin oxide ,Article ,chemistry.chemical_compound ,Chemistry ,chemistry ,Chemical engineering ,visual_art ,Bismuth vanadate ,visual_art.visual_art_medium ,Reversible hydrogen electrode ,General Materials Science ,Ceramic ,QD1-999 - Abstract
Monoclinic bismuth vanadate (BiVO4) is an attractive material with which to fabricate photoanodes due to its suitable band structure and excellent photoelectrochemical (PEC) performance. However, the poor PEC stability originating from its severe photo-corrosion greatly restricts its practical applications. In this paper, pristine and Mo doped BiVO4 ceramics were prepared using the spark plasma sintering (SPS) method, and their photoelectrochemical properties as photoanodes were investigated. The as-prepared 1% Mo doped BiVO4 ceramic (Mo-BVO (C)) photoanode exhibited enhanced PEC stability compared to 1% Mo doped BiVO4 films on fluorine doped Tin Oxide (FTO) coated glass substrates (Mo-BVO). Mo-BVO (C) exhibited a photocurrent density of 0.54 mA/cm2 and remained stable for 10 h at 1.23 V vs. reversible hydrogen electrode (RHE), while the photocurrent density of the Mo-BVO decreased from 0.66 mA/cm2 to 0.11 mA/cm2 at 1.23 V vs. RHE in 4 h. The experimental results indicated that the enhanced PEC stability of the Mo-BVO (C) could be attributed to its higher crystallinity, which could effectively inhibit the dissociation of vanadium in BiVO4 during the PEC process. This work may illustrate a novel ceramic design for the improvement of the stability of BiVO4 photoanodes, and might provide a general strategy for the improvement of the PEC stability of metal oxide photoanodes.
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- 2021
108. Space-confined growth of lead-free halide perovskite Cs3Bi2Br9 in MCM-41 molecular sieve as an efficient photocatalyst for CO2 reduction at the gas−solid condition under visible light
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Zihao Cui, Peng Wang, Yaqiang Wu, Xiaolei Liu, Guoqiang Chen, Peng Gao, Qianqian Zhang, Zeyan Wang, Zhaoke Zheng, Hefeng Cheng, Yuanyuan Liu, Ying Dai, and Baibiao Huang
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Process Chemistry and Technology ,Catalysis ,General Environmental Science - Published
- 2022
109. In-situ-derived self-selective electrocatalysts for solar formate production from simultaneous CO2 reduction and methanol oxidation
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Zaiqi Li, Yugang Gao, Xiao Meng, Bin Sun, Kepeng Song, Zeyan Wang, Yuanyuan Liu, Zhaoke Zheng, Peng Wang, Ying Dai, Hefeng Cheng, and Baibiao Huang
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General Energy ,General Engineering ,General Physics and Astronomy ,General Materials Science ,General Chemistry - Published
- 2022
110. Building a Bridge from Papermaking to Solar Fuels
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Xinhan Zhang, Wei Sun, Zeyan Wang, Jiachuan Chen, Yugang Gao, Tingjiang Yan, Geoffrey A. Ozin, Deren Yang, Paul N. Duchesne, Guihua Yang, Baibiao Huang, Zhimin Yuan, Xingxiang Ji, and Zaiyong Jiang
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Photoluminescence ,Materials science ,010405 organic chemistry ,Graphene ,Papermaking ,Nanotechnology ,General Chemistry ,General Medicine ,Raw material ,010402 general chemistry ,01 natural sciences ,Catalysis ,Industrial waste ,0104 chemical sciences ,law.invention ,law ,Quantum dot ,Energy source ,Black liquor - Abstract
Black liquor, an industrial waste product of papermaking, is primarily used as a low-grade combustible energy source. Despite its high lignin content, the potential utility of black liquor as a feedstock in products manufacturing, remains to be exploited. Demonstrated here in is the use of black liquor as a primary feed-stock for synthesizing graphene quantum dots that exhibit both up-conversion and photoluminescence when excited using visible/near-infrared radiation, thereby enabling the photosensitization of ultraviolet-absorbing TiO2 nanosheets. In addition, these graphene quantum dots can trap photo-generated electrons to realize the effective separation of electron-hole pairs. Together, these two processes facilitate the solar-powered generation of H2 from H2 O, and CO from H2 O-CO2 , using broadband solar radiation.
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- 2019
111. Bi20TiO32 Nanoparticles Doped with Yb3+ and Er3+ as UV, Visible, and Near-Infrared Responsive Photocatalysts
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Yuanyuan Liu, Baibiao Huang, Zhaoke Zheng, Ying Dai, Zeyan Wang, Zhang Xiaoyang, Huining Huang, Xiaoyan Qin, Xizhuang Liang, and Peng Wang
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Materials science ,Band gap ,business.industry ,Doping ,Near-infrared spectroscopy ,Oxide ,Nanoparticle ,Photon upconversion ,Ion ,chemistry.chemical_compound ,chemistry ,Optoelectronics ,General Materials Science ,business - Abstract
In this work, we employed Yb3+ and Er3+ ions doped in a narrow bandgap oxide Bi20TiO32 to fabricate Bi20TiO32:Yb,Er, which can achieve near-infrared (NIR) responsive upconversion (UC) photocatalysi...
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- 2019
112. DFT study of CO2 adsorption across a CaO/Ca12Al14O33 sorbent in the presence of H2O under calcium looping conditions
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Wan Zhang, Xiaotong Ma, Yingjie Li, Jianli Zhao, and Zeyan Wang
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education.field_of_study ,Sorbent ,Materials science ,General Chemical Engineering ,Population ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Industrial and Manufacturing Engineering ,0104 chemical sciences ,Bond length ,Adsorption ,Chemical engineering ,Atom ,Environmental Chemistry ,Density functional theory ,Electron configuration ,0210 nano-technology ,education ,Calcium looping - Abstract
The synthetic CaO/Ca12Al14O33 sorbent has been regarded as an efficient CO2 sorbent during the calcium looping cycles. In this work, the CO2 adsorption performance of the synthetic CaO/Ca12Al14O33 sorbent in the presence of H2O was investigated by density functional theory (DFT) calculations. DFT was used to analyze the adsorption of CO2 and H2O on the synthetic sorbent. Both structural parameters (atomic layout and electronic configuration) and the adsorption parameters (energy, bond lengths, angles, bond population and charge transfer) of CO2 and H2O on the synthetic sorbent were determined. To confirm the feasibility of DFT analysis, the CO2 capture performance of the synthetic sorbent in the presence of steam was examined in a dual fixed bed reactor. The results indicate strong interactions between the C atom and the O atom in CaO and interactions between the H atom and the O atom in CaO. The higher adsorption energy of CO2 than H2O on pristine CaO and Ca12Al14O33-supported CaO suggests that the adsorptions of CO2 and H2O are competitive and that the adsorption of CO2 is stronger than that of H2O. The adsorption of H2O leads to the activation of adjacent O atoms of CaO and thus stronger CO2 adsorption on the O atom with H2O adsorbed. The electrons in the p orbital of the O atom near the Fermi level play important roles in CO2 adsorption by CaO. The presence of Ca12Al14O33 hinders CO2 adsorption by CaO. A low Ca12Al14O33 content in synthetic sorbents should be maintained to ensure high CO2 capture capacity and sintering resistance of synthetic sorbents. DFT calculations can predict the CO2 adsorption performance of CaO-based sorbents with additives under different reaction atmospheres.
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- 2019
113. Photocatalytic hydrogen evolution on P-type tetragonal zircon BiVO4
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Zeyan Wang, Qian Ma, Yu Li, Ping Yang, Yanan Song, Ying Dai, Baibiao Huang, Quande Che, Jing Hu, Junpeng Wang, and Wang Gang
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Materials science ,Hydrogen ,Photoemission spectroscopy ,business.industry ,Process Chemistry and Technology ,Analytical chemistry ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Catalysis ,0104 chemical sciences ,Crystal ,Tetragonal crystal system ,Semiconductor ,chemistry ,Diffuse reflection ,Inductively coupled plasma ,0210 nano-technology ,business ,General Environmental Science ,Zircon - Abstract
Tetragonal zircon BiVO4 (P-BiVO4) were grown on fluorine-doped tin oxide (FTO) glass via hydrothermal method. The cathodic photocurrent and Mott-Schottky analysis indicate that the tetragonal zircon BiVO4 is a p-type semiconductor. Inductively coupled plasma (ICP) analysis and X-ray photoelectron spectrum showed that there are Bi vacancies and interstitial oxygen exist in the crystal, which are the origin of the p-type conductivity. The flat band potential of the P-BiVO4 is about 1.33 V (vs Ag/AgCl) inferred from Mott-Schottky plots. Combining with diffuse reflection spectrum and valence band X-ray photoelectron spectrum, the calculated conduction band value of the P-BiVO4 is about 0.06 V vs RHE, slightly higher than the reduction potential of hydrogen. However, the P-BiVO4 exhibit hydrogen production activity under Xe light irradiation even though its conduction band level is not negative enough. This can be attributed to the hot carrier processes in p-type semiconductors.
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- 2019
114. α‐Fe2O3Film with Highly Photoactivity for Non‐enzymatic Photoelectrochemical Detection of Glucose
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Baibiao Huang, Zhang Qianqian, Xiaoyan Qin, Ying Dai, Zeyan Wang, Fuyan Liu, Xiaoyang Zhang, Peng Wang, Yuanyuan Liu, and Zhaoke Zheng
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Materials science ,Non enzymatic ,Electrochemistry ,Combinatorial chemistry ,Analytical Chemistry - Published
- 2019
115. Polar Molecular Modification onto BiOBr to Regulate Molecular Oxygen Activation
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Jiajia Wang, Zeyan Wang, Guangwei Yu, Xinhua Song, Ying Dai, Ruoqian Zhang, Baibiao Huang, Yuanyuan Liu, Zhaoke Zheng, and Peng Wang
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chemistry.chemical_classification ,Reactive oxygen species ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Photochemistry ,01 natural sciences ,Oxygen ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Ion ,chemistry.chemical_compound ,General Energy ,chemistry ,Molecular modification ,Photocatalysis ,Polar ,Physical and Theoretical Chemistry ,0210 nano-technology - Abstract
In this work, we provide an alternative way to modulate the type of major reactive oxygen species produced during the photocatalytic process. Polar molecular 4-carboxythiophenolate anion (4CBT) mod...
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- 2019
116. Enhanced photocatalytic activity towards H2 evolution over NiO via phosphonic acid surface modification with different functional groups
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Yuanyuan Liu, Peng Wang, Zhaoke Zheng, Xiaoyang Zhang, Baibiao Huang, Jiajia Wang, Zeyan Wang, Ying Dai, and Xiaoyan Qin
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Renewable Energy, Sustainability and the Environment ,Non-blocking I/O ,Energy Engineering and Power Technology ,02 engineering and technology ,respiratory system ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,chemistry.chemical_compound ,Fuel Technology ,chemistry ,Chemical engineering ,X-ray photoelectron spectroscopy ,Chemical bond ,Functional group ,Photocatalysis ,Surface modification ,0210 nano-technology ,Phosphoric acid ,Hydrogen production - Abstract
Enhancing the photocatalytic activity of NiO towards hydrogen generation (6 times) is achieved by phenyl phosphoric acid (PPA) surface modification. The photocatalytic activity can be further improved by changing PPA to 4-aminophenyl phosphonic acid (PPA-NH2), about 10 times, suggesting the functional group plays an important role in improving the activity. A chemical bond (Ni O P) between NiO and organic phosphoric acid was proved by FT-IR spectra. XPS and LSV analysis suggested organic phosphonic acid modification increased the electron density of Ni, which promoted the transformation from Ni2+ to Ni0. Mott-Schottky (M − S) measurement revealed that PPA-NH2 modified NiO processed a larger the space charge layer thickness (dsc), which enhanced ability towards H2 evolution from dynamical aspect.
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- 2019
117. Perovskite photocatalyst CsPbBr3-xIx with a bandgap funnel structure for H2 evolution under visible light
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Zhang Qianqian, Ying Dai, Zeyan Wang, Yaqiang Wu, Yuanyuan Liu, Myung-Hwan Whangbo, Zihan Guan, Baibiao Huang, Zhaoke Zheng, and Peng Wang
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Aqueous solution ,Materials science ,Ion exchange ,Process Chemistry and Technology ,Analytical chemistry ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Catalysis ,0104 chemical sciences ,Photocatalysis ,Particle ,Quantum efficiency ,Irradiation ,0210 nano-technology ,General Environmental Science ,Visible spectrum ,Perovskite (structure) - Abstract
A simple and efficient light-assisted method is employed to prepare powder samples of all-inorganic mixed-perovskite CsPbBr3-xIx from CsPbBr3 by ion exchange in aqueous HBr/KI solution such that the concentration of I in a sample particle decreases on going from the surface to the interior. CsPbBr3-xIx/Pt, namely, CsPbBr3-xIx samples loaded with Pt nanoparticles, shows a high performance for the hydrogen evolution under visible-light irradiation in aqueous HBr solution saturated with CsPbBr3. The H2 evolution rate of the CsPbBr3-xIx/Pt powders (200 mg) is determined to be 224 μmol h−1, under 120 mW cm-2 visible-light (λ ≥ 420 nm) illumination. The CsPbBr3-xIx samples have a high stability, with no apparent decrease in the catalytic activity after 50 h of repeated H2 evolution experiments. The apparent quantum efficiency of CsPbBr3-xIx/Pt is determined to be 2.15% under the irradiation of 450 nm light.
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- 2019
118. Preparation of a morph-genetic CaO-based sorbent using paper fibre as a biotemplate for enhanced CO2 capture
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Zeyan Wang, Wan Zhang, Xiaotong Ma, Jianli Zhao, Xianyao Yan, and Yingjie Li
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Sorbent ,Materials science ,General Chemical Engineering ,Carbonation ,Slag ,Sintering ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Microstructure ,01 natural sciences ,Industrial and Manufacturing Engineering ,0104 chemical sciences ,law.invention ,Carbide ,Chemical engineering ,law ,visual_art ,visual_art.visual_art_medium ,Environmental Chemistry ,Calcination ,0210 nano-technology ,Calcium looping - Abstract
Calcium looping is regarded as an effective and viable way to address CO2 emissions. To overcome the loss-in-capacity problems of calcium-based sorbents with the number of calcium looping cycles, a novel CaO/Ca12Al14O33 sorbent with a microtube-like structure was prepared from carbide slag and Al(NO3)3·9H2O using paper fibre as a biotemplate. The CO2 capture performance and microstructure of the novel synthetic sorbent under calcium looping conditions were investigated. The results show that the utilization of the biotemplate is good to retain the high cyclic CO2 capture reactivity of the synthetic sorbent. Due to the unique hollow porous structure, the CO2 capture capacity of the synthetic sorbent containing 7.5 wt% Al2O3 retains 0.56 and 0.33 g/g after 30 cycles under mild and severe calcination conditions, respectively, which are 2.56 and 2.11 times higher than those of carbide slag under the same respective calcination conditions. With the presence of 10% steam in the carbonation atmosphere, the CO2 capture capacity of the synthetic sorbent retains 0.55 g/g under the severe calcination conditions after 10 cycles. The native hierarchical biostructure of paper fibre is preserved in the synthetic sorbent. CaO and Ca12Al14O33 are uniformly distributed in the synthetic sorbent, resulting in a high sintering resistance during multiple CO2 capture cycles. CO2 can penetrate through the microtube-like structure of the synthetic sorbent from two directions, i.e., from the outer surface and inner surface. This phenomenon effectively enlarges the contact area between CO2 and CaO. The CaO/Ca12Al14O33 sorbent with a hollow porous structure by means of a biotemplate appears promising in the calcium looping technology for CO2 capture.
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- 2019
119. Efficient near-infrared photocatalysts based on NaYF4:Yb3+,Tm3+@NaYF4:Yb3+,Nd3+@TiO2 core@shell nanoparticles
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Baibiao Huang, Huining Huang, Yingjie Li, Ying Dai, Peng Wang, Yuanyuan Liu, Zeyan Wang, Zhaoke Zheng, and Huiliang Li
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Absorption of water ,Materials science ,General Chemical Engineering ,Near-infrared spectroscopy ,Nanoparticle ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Laser ,Photochemistry ,01 natural sciences ,Industrial and Manufacturing Engineering ,Photon upconversion ,0104 chemical sciences ,law.invention ,chemistry.chemical_compound ,chemistry ,law ,Photocatalysis ,Rhodamine B ,Environmental Chemistry ,Irradiation ,0210 nano-technology - Abstract
In this work, we fabricated NaYF4:Yb3+,Tm3+@NaYF4:Yb3+,Nd3+@TiO2 (Tm@Nd@TiO2) core@shell nanoparticles and investigated their near-infrared (NIR) photocatalytic activities. Comparing to traditional TiO2 based upconversion (UC) photocatalysts (i.e., NaYF4:Yb3+,Tm3+@TiO2, named Tm@TiO2), Tm@Nd@TiO2 exhibits enhanced photocatalytic activity under NIR light irradiation. The photocatalytic activity of Tm@Nd@TiO2 under 980, 808, and 980 + 808 nm laser irradiation is 4.40, 5.84, and 9.83 times as high as that of Tm@TiO2 under only 980 nm irradiation, respectively. The ethylene degradation rate of Tm@Nd@TiO2 under 980 + 808 nm laser irradiation is 6.4 times as that of Tm@TiO2. The photocatalytic activity of Tm@Nd@TiO2 under visible + NIR irradiation is even comparable with (∼2/3) that under UV light irradiation during Rhodamine B (RhB) degradation. The enhanced photocatalytic activity of Tm@Nd@TiO2 can be attributed to the stronger light absorption in NIR region ascribed to Nd3+, lower water absorption and the enhanced UC emission of Tm@Nd with unique core@shell nanostructures. This work can provide a possible route to improve the NIR photocatalytic activity and stimulate the applications in many other fields.
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- 2019
120. Carbon nanosheet facilitated charge separation and transfer between molybdenum carbide and graphitic carbon nitride toward efficient photocatalytic H2 production
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Zeyan Wang, Yajun Zou, Jian-Wen Shi, Dandan Ma, Chi He, Siman Mao, Xin Ji, and Diankun Sun
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Materials science ,Graphitic carbon nitride ,General Physics and Astronomy ,chemistry.chemical_element ,Heterojunction ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Photocatalysis ,Water splitting ,Irradiation ,0210 nano-technology ,Carbon nitride ,Carbon ,Nanosheet - Abstract
Interfacial manipulation of nanostructured heterojunction photocatalysts to enhance charge separation and transfer is highly desirable to achieve a high photocatalytic activity. In this work, a well-designed non-noble-metal Mo2C@C/g-C3N4 heterostructure is constructed, in which the intercalated carbon nanosheets serve as a binder to form an excellent interfacial contact between Mo2C and g-C3N4. In addition, large quantities of carbon quantum dotsare found to be homogeneously embedded in the carbon nanosheets. The as-obtained Mo2C@C/g-C3N4 hybrid exhibits a remarkably improved photocatalytic H2 evolution rate of 52.1 μmol h−1 under visible-light irradiation (λ ≥ 420 nm) without co-catalyst, which is up to nearly 260 times higher than that of pristine g-C3N4 (0.2 μmol h−1) under the same conditions. The significant increase in photocatalytic activity mainly results from the fast charge migration and separation between Mo2C and g-C3N4 facilitated by the conducting carbon nanosheets as an efficient electron mediator. Moreover, the carbon quantum dots embedded in the carbon support also promotes solar energy utilization. This work highlights a feasible strategy to explore highly efficient photocatalysts via interfacial engineering on heterojunction composites.
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- 2019
121. The Sol–gel method synthesis of Bi4NbO8Cl with (001) facets exposed for high visible-light activity
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Fengping Li, Yanqing Li, Zeyan Wang, Huimin Chen, Xiaoyang Zhang, Baibiao Huang, Guangda Ni, Xiaoyan Qin, and Hongshuai Liu
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010302 applied physics ,Materials science ,Aqueous solution ,Scanning electron microscope ,Band gap ,Condensed Matter Physics ,Photochemistry ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,0103 physical sciences ,Lattice plane ,Photocatalysis ,Electrical and Electronic Engineering ,Visible spectrum ,Perovskite (structure) ,Sol-gel - Abstract
Layered perovskite oxyhalide Bi4NbO8Cl with exposed (001) lattice plane has been successfully synthesized by Sol–gel method. The obtained products were characterized by X-ray diffraction, diffuse-reflection spectra, scanning electron surface area from Brunauer–Emmitt–Teller analysis. The photocatalytic activity for the decomposition of Rhodamine-B (RhB) aqueous solution can be significantly improved under visible light irradiation. Based on both high charge speration efficiency originated from the large exposed surface areas of (001) facts and high photocatalytic redox ability generated from band gap expansion, sol gel-Bi4NbO8Cl exhibit higher efficiency over solid state-Bi4NbO8Cl during the degradation of organic dyes under visble light irradiation. What’s more, the Sg-Bi4NbO8Cl photocatalyst still kept higher photocatalytic activity after five cycle measurement.
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- 2019
122. A study of the synergistic effects of Mn/steam on CO 2 capture performance of CaO by experiment and DFT calculation
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Zeyan Wang, Wan Zhang, Xiaotong Ma, Jianli Zhao, and Yingjie Li
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Environmental Engineering ,Materials science ,Carbonation ,Doping ,technology, industry, and agriculture ,food and beverages ,02 engineering and technology ,010501 environmental sciences ,Combustion ,complex mixtures ,01 natural sciences ,humanities ,law.invention ,Periodic density functional theory ,020401 chemical engineering ,X-ray photoelectron spectroscopy ,Chemical engineering ,law ,Environmental Chemistry ,Calcination ,0204 chemical engineering ,Porosity ,Calcium looping ,0105 earth and related environmental sciences - Abstract
Novel Mn‐doped CaO was prepared by the combustion method. The CO2 capture performance of Mn‐doped CaO, carbonated in the presence of steam and under severe calcination conditions (950°C and 70% CO2/30% N2) during calcium looping cycles, was investigated in a dual fixed‐bed reactor. The intercoupling effects of Mn and steam on CO2 capture by CaO were also studied. Doping of Mn in CaO by the combustion method greatly improved the CO2 capture capacity of CaO. The carbonation conversions of Mn‐doped CaO increased with increasing steam concentration from 0 to 15%. When the molar ratio of Mn/Ca was 0.75 : 100, Mn‐doped CaO achieved the highest CO2 capture capacity. Under severe calcination conditions, the carbonation conversion of Mn‐doped CaO, where the molar ratio of Mn to Ca = 0.75 : 100 in the presence of 15% steam, was about 0.4 after ten cycles (carbonation for 5 min at 650°C under 15% CO2/15% steam/N2), which was 4.38 times as high as that of the original CaO in the absence of steam. The cyclic CO2 capture capacities of CaO were improved by Mn and steam. Synergistic enhancement effects of Mn and steam on the CO2 capture capacities of CaO were also found. The effect of steam on the carbonation conversion of Mn‐doped CaO was stronger than that of the original CaO. Mn in the presence of steam showed a more positive effect on CO2 capture by CaO. X‐ray photoelectron spectroscopy analysis showed that doping of Mn in CaO enhanced the transport of electrons in the carbonation of CaO, which helped to increase the carbonation rate. When steam was present in the carbonation, Mn‐doped CaO possessed a more porous structure and smaller CaO grains than the original CaO during the cycles. Simulation calculations using periodic density functional theory (DFT) showed that CO2 molecules were easier to absorb on CaO owing to the doping of Mn and the presence of steam. The synergistic enhancement effects of Mn and steam on CO2 captured the performance of CaO. © 2019 Society of Chemical Industry and John Wiley & Sons, Ltd.
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- 2019
123. The synergistic effect of light irradiation and interface engineering of the Co(OH)2/MoS2 heterostructure to realize the efficient alkaline hydrogen evolution reaction
- Author
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Peng Wang, Yuanyuan Liu, Zhaoke Zheng, Baibiao Huang, Zeyan Wang, Ying Dai, Xiaolei Liu, Xingshuai Lv, and Zhang Qianqian
- Subjects
Tafel equation ,Materials science ,Hydrogen ,General Chemical Engineering ,chemistry.chemical_element ,Exchange current density ,02 engineering and technology ,Overpotential ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrocatalyst ,01 natural sciences ,Dissociation (chemistry) ,0104 chemical sciences ,Catalysis ,chemistry ,Chemical engineering ,Electrochemistry ,Water splitting ,0210 nano-technology - Abstract
Photo-electrochemical and electrochemical water splitting are considered as effective ways to realize the efficient hydrogen evolution reaction and solve the increased energy demand. Herein, the photo-responsive MoS2 electrocatalyst modified with Co(OH)2 was synthesized on a carbon cloth (CC) by a facile approach. Benefiting from the heterogeneous interface between MoS2 and Co(OH)2, this hybrid catalyst shows superior HER activity in 1 M KOH aqueous solution with an overpotential of 117 mV at 10 mA cm−2 and a Tafel slope of 59.82 mV dec−1, which are smaller than those of MoS2/CC (an overpotential of 171 mV at 10 mA cm−2 and a Tafel slope of 90.78 mV dec−1) or Co(OH)2/CC (an overpotential of 268 mV at 10 mA cm−2 and a Tafel slope of 99.84 mV dec−1). The HER activity of Co(OH)2/MoS2/CC can be further promoted with an overpotential of 101 mV at 10 mA cm−2 due to the enhanced conductivity and exchange current density under light irradiation. Density functional theory calculations are carried out to gain a deeper insight into the effect of Co(OH)2 MoS2 interface, indicating that the introduction of Co(OH)2 can reduce the energy barrier of the initial water dissociation process and provide the hydroxyl adsorption sites, while MoS2 can promote the adsorption of hydrogen intermediates and H2 release. The synergistic effect of light irradiation and interface engineering strategy can realize efficient hydrogen evolution reaction, which can enlighten and extend to other electrocatalytic system.
- Published
- 2019
124. Post-synthetic platinum complex modification of a triazine based metal organic frameworks for enhanced photocatalytic H2 evolution
- Author
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Ruoqian Zhang, Zeyan Wang, Ying Dai, Xiaoyang Zhang, Xiaoyan Qin, Jiajia Wang, Baibiao Huang, Yuanyuan Liu, Zhaoke Zheng, and Peng Wang
- Subjects
Materials science ,Light irradiation ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Photochemistry ,01 natural sciences ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Inorganic Chemistry ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,Ceramics and Composites ,Photocatalysis ,Platinum complex ,Metal-organic framework ,Charge carrier ,Hydrogen evolution ,Physical and Theoretical Chemistry ,0210 nano-technology ,Triazine - Abstract
A triazine-based MOFs [PCN-9(Co)] was synthesized and its photoelectrical, photophysical properties were studied. As a new photocatalyst, PCN-9(Co) displays photocatalytic hydrogen evolution from water under UV–Visible light irradiation. With the introduction of platinum complex, PCN-9-Pt was obtained and platinum complex was believed to coordinate with the N in triazine. The H2 evolution rate of PCN-9-Pt is greatly improved, about 6.8 times higher than that of PCN-9(Co). The reason is due to the fact that platinum complex plays an important role in improving the separation efficiency of photogenerated charge carriers, as verified by PL and EIS results. This result provides a new kind of idea of modifying MOFs materials with molecular complex to improve the photocatalytic activity.
- Published
- 2019
125. Noble-metal-free Fe2P–Co2P co-catalyst boosting visible-light-driven photocatalytic hydrogen production over graphitic carbon nitride: The synergistic effects between the metal phosphides
- Author
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Zhihui Li, Dandan Ma, Jian-Wen Shi, Zeyan Wang, Linhao Cheng, Yajun Zou, Diankun Sun, and Sanmu Xie
- Subjects
Materials science ,Renewable Energy, Sustainability and the Environment ,Schottky barrier ,Graphitic carbon nitride ,Energy Engineering and Power Technology ,02 engineering and technology ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Catalysis ,chemistry.chemical_compound ,Fuel Technology ,Chemical engineering ,chemistry ,engineering ,Photocatalysis ,Water splitting ,Noble metal ,0210 nano-technology ,Hydrogen production ,Visible spectrum - Abstract
Photocatalytic hydrogen evolution from water splitting driven by visible light is a promising approach to solve energy crisis and environmental problems, and noble-metal-free co-catalysts for boosting the hydrogen evolution reaction are highly desired. Herein, we explore a novel noble-metal-free Fe2P–Co2P co-catalyst for the first time to boost the photocatalytic performance of graphitic carbon nitride (g-C3N4). The resultant Fe2P–Co2P/g-C3N4 with optimum ratio exhibits a hydrogen production rate of 347 μmol h−1 g−1 in the absence of noble-metal co-catalyst, which is 87 times higher than that of pristine g-C3N4 under the same conditions. The significant enhancement in the photocatalytic performance of Fe2P–Co2P/g-C3N4 can be ascribed to the Schottky junction formed between Fe2P–Co2P and g-C3N4, which produces a strong driving force for the transfer of electrons from g-C3N4 to Fe2P–Co2P, promoting the separation and transfer of photogenerated electrons and holes. Furthermore, due to the synergistic effects between the two metal phosphides (Fe2P and Co2P), the Schottky junction in Fe2P–Co2P/g-C3N4 can produce stronger driving force than that in Fe2P/g-C3N4 and Co2P/g-C3N4, resulting in the fact that the hydrogen production rate over Fe2P–Co2P/g-C3N4 is much higher than that over Fe2P/g-C3N4 and Co2P/g-C3N4. This work may shed light on the careful design of co-catalyst by utilizing the synergistic effect of different components.
- Published
- 2019
126. Enhanced photocatalytic hydrogen evolution of CdWO4 through polar organic molecule modification
- Author
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Zeyan Wang, Xiaoyan Qin, Xiaoyang Zhang, Peng Zhou, Danning Xing, Ying Dai, Peng Wang, Baibiao Huang, Yuanyuan Liu, and Zhaoke Zheng
- Subjects
Work (thermodynamics) ,Materials science ,Renewable Energy, Sustainability and the Environment ,Chemical polarity ,Energy Engineering and Power Technology ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Photochemistry ,01 natural sciences ,0104 chemical sciences ,Fuel Technology ,Electric field ,Photocatalysis ,Polar ,Molecule ,Hydrogen evolution ,Steady state (chemistry) ,0210 nano-technology - Abstract
In this work, a polar molecule 4-mercaptobenzoic acid (4-MBA) is anchored on the surface of CdWO4 by forming Cd S and W S bond. Photocatalytic hydrogen evolution is significantly enhanced (about 3.41 times) after the modification. The reason is due to the modification of 4-MBA, which results in a polar surface and built-in electric field. The polar surface is confirmed by the steady state and time-resolved PL spectra, Voc and SHG results.
- Published
- 2019
127. Artificial Second-Order Nonlinear Optics in a Centrosymmetric Optical Material BiVO4: Breaking the Prerequisite for Nonlinear Optical Materials
- Author
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Jiyang Wang, Ying Xie, Bing-hui Ge, Zeyan Wang, Zheshuai Lin, Fei Liang, Bo Zhang, Baibiao Huang, Huaijin Zhang, and Haohai Yu
- Subjects
Materials science ,business.industry ,General Chemical Engineering ,Physics::Optics ,Nonlinear optics ,Second-harmonic generation ,General Chemistry ,Laser ,Polarization (waves) ,Article ,law.invention ,lcsh:Chemistry ,lcsh:QD1-999 ,law ,Molecular symmetry ,Optoelectronics ,Thin film ,Homojunction ,Photonics ,business - Abstract
Second-order nonlinear optics (NLO) is the foundation of frequency conversion for the generation of coherent light at frequencies where lasers have no emissions or operate poorly. The prerequisite for NLO materials is noncentrosymmetric symmetry that can generate an effectively non-counterbalanced spontaneous electronic polarization. Here, we propose that this material restriction can be broadened by controlling the electron distribution with a local internal electrostatic field (IEF), and we demonstrate artificially created and manipulated second harmonic generation (SHG) in a centrosymmetric optical material, a superimposed Co2+- and Mo6+-doped BiVO4 thin film with 2/m point group symmetry, where a homojunction producing tunable effective polarization is formed. The SHG was characterized and tuned by IEF. This work breaks the structural symmetry constraint on NLO materials. Besides, the phase-matching-like condition was realized for the further improvement of the efficient frequency conversion. Because polarization is also a prerequisite for many other functions besides SHG, we believe that this work should provide some inspiration for the further development of optoelectronic, photonic, and electronic materials.
- Published
- 2019
128. Stabilizing the titanium-based metal organic frameworks in water by metal cations with empty or partially-filled d orbitals
- Author
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Myung-Hwan Whangbo, Zeyan Wang, Ying Dai, Baibiao Huang, Yang An, Xiaoyang Zhang, Xiaoyan Qin, Yuanyuan Liu, Zhaoke Zheng, and Peng Wang
- Subjects
Aqueous solution ,Materials science ,Metal ions in aqueous solution ,Inorganic chemistry ,chemistry.chemical_element ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Ion ,Biomaterials ,Metal ,Colloid and Surface Chemistry ,chemistry ,visual_art ,Photocatalysis ,visual_art.visual_art_medium ,Metal-organic framework ,Porosity ,Titanium - Abstract
Though titanium-based metal-organic frameworks (MOFs) are declared to be relatively water stable, their framework gradually collapses in water within days due to the attack of OH− to O Ti O bond. For practical applications of titanium-based MOFs, it is crucial to solve their instability problem in water. We searched for a simple and efficient method to enhance the stability of titanium-based MOFs in water by using Ti-ATA (ATA = 2-aminoterephthallate ion) as a representative titanium-based MOF. Here, we show that the stability of Ti-ATA in water is greatly improved nearly without affecting its porosity and photocatalytic activity by treating it with aqueous solutions containing metal ions of empty d orbitals (Y3+, La3+, Ce3+, Nd3+ and Tm3+) or partially-filled d orbitals (Cr3+).
- Published
- 2019
129. CO2 capture by a novel CaO/MgO sorbent fabricated from industrial waste and dolomite under calcium looping conditions
- Author
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Xiaotong Ma, Xianyao Yan, Yingjie Li, Zeyan Wang, Hantao Liu, and Jianli Zhao
- Subjects
Sorbent ,Chemistry ,Carbonation ,Dolomite ,Slag ,General Chemistry ,Catalysis ,Industrial waste ,Carbide ,law.invention ,Chemical engineering ,law ,visual_art ,Materials Chemistry ,visual_art.visual_art_medium ,Calcination ,Calcium looping - Abstract
Herein, the novel CaO/MgO CO2 sorbent was fabricated from carbide slag and dolomite by the combustion method during the calcium looping process. The carbide slag is a precursor of CaO, and dolomite is a precursor of both MgO and CaO. The effects of the mass ratio of the carbide slag to dolomite, calcination conditions and presence of steam during carbonation on the CO2 capture performance of the novel CaO/MgO sorbent were studied during the calcium looping cycles. When the mass ratio of the carbide slag to dolomite was 74 : 26, the resulting CaO/MgO sorbent having the mass ratio of CaO to MgO = 90 : 10 achieved highest CO2 capture capacity that was retained at 0.52 g g−1 after 20 cycles (carbonation in 15% CO2/85% N2 at 700 °C for 20 min; calcination in 100% N2 at 850 °C for 10 min), which was higher than those of the carbide slag and other reported CaO/MgO sorbents prepared from analytical reagents. Compared with that of the sample calcined under pure CO2 at 950 °C, the CO2 capture capacity of the CaO/MgO sorbent calcined in pure steam at 800 °C is apparently higher. This novel CaO/MgO sorbent fabricated from industrial waste and dolomite exhibits a more porous microstructure, which is promising for the calcium looping process for CO2 capture.
- Published
- 2019
130. A water-stable triazine-based metal-organic framework as an efficient adsorbent of Pb(II) ions
- Author
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Yang An, Xiaoyang Zhang, Ying Dai, Ruoqian Zhang, Yuanyuan Liu, Zhaoke Zheng, Peng Wang, Zeyan Wang, Baibiao Huang, and Xiaoyan Qin
- Subjects
Aqueous solution ,Chemistry ,Metal ions in aqueous solution ,Inorganic chemistry ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Ion ,chemistry.chemical_compound ,Colloid and Surface Chemistry ,Adsorption ,Adsorption kinetics ,Metal-organic framework ,Binding site ,0210 nano-technology ,Triazine - Abstract
Effective and selective removal of Pb(II) from aqueous solution is highly desirable, but it is still a great challenge. We report here a water stable metal-organic frameworks (CAU-7-TATB), and the ligands contain N, which provides binding sites for metal ions. CAU-7-TATB exhibits fast adsorption kinetics, high adsorption capacity towards Pb(II). More importantly, CAU-7-TATB remains high prior adsorption towards Pb(II) in the presence of interfering ions like Cr(III), Co(II), Ni(II), Mn(II), Zn(II), Mg(II) and Ca(II), which is potentially applicable in removing Pb(II) from industrial water.
- Published
- 2019
131. Synthesis of a WO3 photocatalyst with high photocatalytic activity and stability using synergetic internal Fe3+ doping and superficial Pt loading for ethylene degradation under visible-light irradiation
- Author
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Baibiao Huang, Zeyan Wang, Zhang Qianqian, Peng Wang, Xiaolei Liu, Xiaoyan Qin, Ying Dai, Yuanyuan Liu, Huishan Zhai, and Xiaoyang Zhang
- Subjects
Ethylene ,Materials science ,010405 organic chemistry ,Doping ,010402 general chemistry ,01 natural sciences ,Environmentally friendly ,Catalysis ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Photocatalysis ,Degradation (geology) ,Irradiation ,Absorption (electromagnetic radiation) - Abstract
Ethylene (C2H4) is harmful for storage and fresh-keeping of fruits and vegetables. Photocatalytic technology is an effective and environmentally friendly approach for degrading ethylene. Herein, we first report the synthesis of a WO3 photocatalyst with high photocatalytic activity and stability using synergetic internal Fe3+ doping and superficial Pt loading for ethylene degradation under visible-light irradiation. Internal Fe3+ doping not only enhances the visible-light absorption but also improves the stability to some degree due to more positive reduction potential of Fe3+/Fe2+ than that of W6+/W5+ and separation efficiency of the photo-generated carriers. Furthermore, the loading of Pt as a co-catalyst through the photo-reduction of H2PtCl6 on the surface of Fe-doped WO3 promotes the effective transfer of photo-generated electrons and reduces the photo-corrosion of WO3. Due to the synergistic effect, extremely high degradation speed can be achieved by doping 0.25 mol% Fe and loading 0.75 wt% Pt for WO3, which exceeds that of pristine WO3 by about 3.3 times under visible-light irradiation. In addition, due to the excellent stability of Pt@Fe-doped WO3, it has good industrial application prospects in the field of photocatalysis.
- Published
- 2019
132. Enhanced selectivity and activity for electrocatalytic reduction of CO2 to CO on an anodized Zn/carbon/Ag electrode
- Author
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Fengping Li, Ying Dai, Myung-Hwan Whangbo, Zeyan Wang, Peng Zhou, Yugang Gao, Peng Wang, Yuanyuan Liu, Zhaoke Zheng, and Baibiao Huang
- Subjects
Materials science ,Renewable Energy, Sustainability and the Environment ,Anodizing ,chemistry.chemical_element ,Ag electrode ,02 engineering and technology ,General Chemistry ,021001 nanoscience & nanotechnology ,Catalysis ,Metal ,chemistry ,visual_art ,Electrode ,visual_art.visual_art_medium ,General Materials Science ,Density functional theory ,0210 nano-technology ,Selectivity ,Carbon ,Nuclear chemistry - Abstract
We constructed a composite electrode by depositing a C/Ag mixture containing a tiny amount of 20 nm Ag NPs (∼0.5 wt%) on anodized Zn (AZ) metal. The AZ/C/Ag electrode exhibits greatly enhanced CO selectivity (∼86%) and activity (∼7.3 mA cm−2) on comparison with the GCE/C/Ag electrode (∼24% and ∼2.3 mA cm−2). The experimental results show that the enhanced CO2 reduction performance of the AZ/C/Ag electrode is attributed to the synergistic effect of AZ, C and Ag. Density functional theory calculations indicate that the enhanced CO selectivity may originate from the enhanced stabilization of CO2 and COOH* on the AZ/C/Ag electrode surface. This electrode also shows great mass activity and stability for CO2 reduction. Our work provides a new and simple way to fabricate efficient catalysts with high selectivity, activity and stability for electrocatalytic CO2 reduction.
- Published
- 2019
133. Accelerated electrocatalytic hydrogen evolution on non-noble metal containing trinickel nitride by introduction of vanadium nitride
- Author
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Zeyan Wang, Baibiao Huang, Xiaoyang Zhang, Peng Zhou, Ying Dai, Xiaoyan Qin, Peng Wang, Yuanyuan Liu, Zhaoke Zheng, and Danning Xing
- Subjects
Tafel equation ,Materials science ,Renewable Energy, Sustainability and the Environment ,Vanadium nitride ,02 engineering and technology ,General Chemistry ,Nitride ,Overpotential ,021001 nanoscience & nanotechnology ,Electrocatalyst ,Cathode ,Anode ,law.invention ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,law ,Electrode ,General Materials Science ,0210 nano-technology - Abstract
Trinickel nitride as a kind of promising hydrogen evolution reaction (HER) electrocatalyst has attracted much attention in recent years due to its high electrical conductivity and low cost. Herein, we designed and synthesized a novel and efficient Ni3N@VN–NF composite by nitriding treatment of a NiV-LDH precursor. The obtained electrode exhibits superior performances including a much lower overpotential of 56 mV at 10 mA cm−2 and Tafel value of 47 mV dec−1 compared to pure Ni3N–NF and VN–NF electrodes. The Ni3N@VN–NF composite as a cathode and a conventional OER electrode NiFe-LDH–NF as an anode were combined to form a complete water-splitting system. The voltage at 10 mA cm−2 is about 1.55 V, which is superior to the voltage value reported in many literature studies. In addition, the two-electrode system exhibits excellent durability after as long as 50 hours of operation.
- Published
- 2019
134. Ag2ZnSnS4/Mo-mesh photoelectrode prepared by electroplating for efficient photoelectrochemical hydrogen generation
- Author
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Yuanyuan Liu, Zhaoke Zheng, Zeyan Wang, Ying Dai, Xiaoyang Zhang, Peng Wang, Zhang Qianqian, Baibiao Huang, Xiaoyan Qin, and Xizhuang Liang
- Subjects
Photocurrent ,Materials science ,Renewable Energy, Sustainability and the Environment ,02 engineering and technology ,General Chemistry ,Substrate (electronics) ,021001 nanoscience & nanotechnology ,Atomic layer deposition ,Chemical engineering ,Water splitting ,General Materials Science ,Thin film ,0210 nano-technology ,Electroplating ,Faraday efficiency ,Hydrogen production - Abstract
In this paper, n-type Ag2ZnSnS4 (AZTS) thin film was prepared by a simple electrodeposition and in situ sulfurization method on Mo-mesh substrate. Pristine AZTS photoanode yielded a photocurrent density of 4.0 mA cm−2 at 0.6 V vs. RHE. In order to improve the stability of Ag2ZnSnS4 photoanode, TiO2 offering more protection against the photo corrosion was deposited through an atomic layer deposition (ALD) process. IPCE measurements were used to evaluate solar energy utilization efficiencies of AZTS and TiO2/AZTS photoanodes, which showed 25% and 20% IPCE (510–530 nm) in water splitting reaction, respectively. The analysis of gas yield determined that the faradaic efficiency during the H2 evolution process was over 90%. Furthermore, the reasons for the high photoelectrochemical performance of AZTS/Mo-mesh and mechanism of PEC H2 evolution in system are discussed below.
- Published
- 2019
135. ZnO nanorods modified with noble metal-free Co3O4 nanoparticles as a photocatalyst for efficient ethylene degradation under light irradiation
- Author
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Zhang Qianqian, Baibiao Huang, Zihao Cui, Ying Dai, Peng Wang, Xiaolei Liu, Yuanyuan Liu, Zhaoke Zheng, Xizhuang Liang, and Zeyan Wang
- Subjects
Materials science ,Ethylene ,010405 organic chemistry ,Nanoparticle ,Mineralization (soil science) ,engineering.material ,010402 general chemistry ,01 natural sciences ,Catalysis ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Photocatalysis ,engineering ,Molecule ,Nanorod ,Noble metal - Abstract
In this study, we synthesized noble metal-free Co3O4 as a cocatalyst for a modified ZnO nanorod photocatalyst to achieve efficient ethylene degradation under light irradiation. The Co3O4-decorated ZnO nanorods demonstrate photocatalytic activity for ethylene oxidation that is better than that of pure ZnO and even better than that of the noble metal-based RuO2-modified ZnO. Furthermore, Co3O4-modified ZnO exhibits good stability in a six-cycle experiment. Measurement results indicate that the Co3O4 nanoparticles can effectively promote the transfer and inhibit the recombination of photogenerated electrons and holes during the photocatalytic reaction. Therefore, the Co3O4-modified ZnO nanorod photocatalyst displays excellent photocatalytic properties for ethylene degradation and can effectively realize the complete mineralization of ethylene molecules.
- Published
- 2019
136. Boosting H 2 Production from a BiVO 4 Photoelectrochemical Biomass Fuel Cell by the Construction of a Bridge for Charge and Energy Transfer
- Author
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Zhaoqi Wang, Yuhao Guo, Mu Liu, Xiaolei Liu, Haipeng Zhang, Weiyi Jiang, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Hefeng Cheng, Ying Dai, Zeyan Wang, and Baibiao Huang
- Subjects
Mechanics of Materials ,Mechanical Engineering ,General Materials Science - Published
- 2022
137. Photoreforming of plastic waste poly (ethylene terephthalate) via in-situ derived CN-CNTs-NiMo hybrids
- Author
-
Xueqin Gong, Fengxia Tong, Fahao Ma, Yujia Zhang, Peng Zhou, Zeyan Wang, Yuanyuan Liu, Peng Wang, Hefeng Cheng, Ying Dai, Zhaoke Zheng, and Baibiao Huang
- Subjects
Process Chemistry and Technology ,Catalysis ,General Environmental Science - Published
- 2022
138. Highly efficient electrocatalytic hydrogen evolution coupled with upcycling of microplastics in seawater enabled via Ni3N/W5N4 janus nanostructures
- Author
-
Fahao Ma, Shuhua Wang, Xueqin Gong, Xiaolei Liu, Zeyan Wang, Peng Wang, Yuanyuan Liu, Hefeng Cheng, Ying Dai, Zhaoke Zheng, and Baibiao Huang
- Subjects
Process Chemistry and Technology ,Catalysis ,General Environmental Science - Published
- 2022
139. Synergistic effect between boron containing metal-organic frameworks and light leading to enhanced CO2 cycloaddition with epoxides
- Author
-
Yujie Li, Guangyao Zhai, Yuanyuan Liu, Zeyan Wang, Peng Wang, Zhaoke Zheng, Hefeng Cheng, Ying Dai, and Baibiao Huang
- Subjects
History ,Polymers and Plastics ,General Chemical Engineering ,Environmental Chemistry ,General Chemistry ,Business and International Management ,Industrial and Manufacturing Engineering - Published
- 2022
140. Borate-modulated amorphous NiFeB nanocatalysts as highly active and stable electrocatalysts for oxygen evolution reaction
- Author
-
Yunrui Zhao, Fahao Ma, Zeyan Wang, Peng Wang, Yuanyuan Liu, Hefeng Cheng, Ying Dai, Zhaoke Zheng, and Baibiao Huang
- Subjects
Mechanics of Materials ,Mechanical Engineering ,Materials Chemistry ,Metals and Alloys - Published
- 2022
141. Stress-induced BiVO4 photoanode for enhanced photoelectrochemical performance
- Author
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Weiyi Jiang, Yang An, Zeyan Wang, Minrui Wang, Xiaolei Bao, Liren Zheng, Hefeng Cheng, Peng Wang, Yuanyuan Liu, Zhaoke Zheng, Ying Dai, and Baibiao Huang
- Subjects
Process Chemistry and Technology ,Catalysis ,General Environmental Science - Published
- 2022
142. Strain-assisted in-situ formed oxygen defective WO3 film for photothermal-synergistic reverse water gas shift reaction and single-particle study
- Author
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Yayang Xu, Mu Liu, Fengxia Tong, Fahao Ma, Xiangyun He, Zeyan Wang, Peng Wang, Yuanyuan Liu, Hefeng Cheng, Ying Dai, Zhaoke Zheng, and Baibiao Huang
- Subjects
General Chemical Engineering ,Environmental Chemistry ,General Chemistry ,Industrial and Manufacturing Engineering - Published
- 2022
143. g-C3N4/ITO/Co-BiVO4 Z-scheme composite for solar overall water splitting
- Author
-
Dujuan Dai, Peng Wang, Xiaolei Bao, Yayang Xu, Zhaoqi Wang, YuHao Guo, Zeyan Wang, Zhaoke Zheng, Yuanyuan Liu, Hefeng Cheng, and Baibiao Huang
- Subjects
General Chemical Engineering ,Environmental Chemistry ,General Chemistry ,Industrial and Manufacturing Engineering - Published
- 2022
144. Fabrication of BiVO4 photoanode consisted of mesoporous nanoparticles with improved bulk charge separation efficiency
- Author
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Huiliang Li, Xiaoyang Zhang, Yuanyuan Liu, Zhaoke Zheng, Baibiao Huang, Zeyan Wang, Xiaoyan Qin, Peng Wang, Ying Dai, and Haipeng Zhang
- Subjects
Photocurrent ,Nanostructure ,Fabrication ,Materials science ,Process Chemistry and Technology ,Doping ,Nanoparticle ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Catalysis ,0104 chemical sciences ,Ion ,Chemical engineering ,Electrical resistivity and conductivity ,0210 nano-technology ,Mesoporous material ,General Environmental Science - Abstract
In this work, we developed a simple method to fabricate BiVO4 photoanode consisted of mesoporous nanoparticles (meso-BVO) by using P123 as a pore maker. Owing to the unique mesoporous nanostructure, meso-BVO exhibits higher BET surface areas, shorter hole transit distance and higher electrical conductivity than does pristine BiVO4 photoanode (BVO) consisted of solid nanoparticles. As a result, the charge separation efficiency and PEC performances of meso-BVO have been greatly improved. Meso-BVO yields a photocurrent of 2.19 mA/cm2 (1.23 V vs RHE) and IPCE of 39% (420 nm), which is 2.52 and 2 times as high as that of pristine BVO. With the assistance of Mo6+ ions doping and Co-Pi, the PEC performances could be further improved by addressing the inefficient electron transport and slow water oxidation kinetics. Co-Pi/Mo:meso-BVO yields a photocurrent of 4.57 mA/cm2 (1.23 V vs RHE) and IPCE value of 65% (420 nm). The enhanced PEC performance can be mainly ascribed to the perfect charge separation in the bulk of Co-Pi/Mo:meso-BVO photoanode. Our work provides a simple method to fabricate high efficient BiVO4 photoanodes consisted of mesoporous nanoparticles with enhanced bulk charge separation efficiencies.
- Published
- 2018
145. Au Nanoparticle and CdS Quantum Dot Codecoration of In2O3 Nanosheets for Improved H2 Evolution Resulting from Efficient Light Harvesting and Charge Transfer
- Author
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Dandan Ma, Chi He, Jian-Wen Shi, Linhao Cheng, Chunming Niu, Zeyan Wang, Diankun Sun, and Yajun Zou
- Subjects
Materials science ,Renewable Energy, Sustainability and the Environment ,General Chemical Engineering ,Schottky barrier ,Nanoparticle ,Heterojunction ,02 engineering and technology ,General Chemistry ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Chemical engineering ,Quantum dot ,Photocatalysis ,engineering ,Environmental Chemistry ,Charge carrier ,Noble metal ,0210 nano-technology ,Hydrogen production - Abstract
Au nanoparticle (NP)- and CdS quantum dot (QD)-codecorated In2O3 nanosheets, assembled into flowerlike structure (In2O3/Au/CdS), were synthesized to facilitate photocatalytic H2 production. The optimized In2O3/Au4/CdS-12 (4 wt % Au NPs and CdS QDs were deposited for 12 cycles) displays achieved a photocatalytic hydrogen generation ability of 17.23 μmol/h (10 mg of catalyst), which is 22.97, 5.08, and 5.05 times as high as that of pristine In2O3 (0.75 μmol/h), In2O3/Au4 (3.39 μmol/h), and In2O3/CdS-12 (3.41 μmol/h), respectively. This significant improvement of H2 generation rate can be attributed to the following factors: the heterojunction at the In2O3–CdS interface and the Schottky barrier at the interface between In2O3–Au and CdS–Au improves the migration and separation of charge carriers, and the surface plasma resonance (SPR) effect of noble metal Au NPs enhances the light harvesting capacity of In2O3 and boosts the generation of hot electrons, efficiently improving the utilization rate of sunlight.
- Published
- 2018
146. Synthesis of MoS2/Ni3S2 heterostructure for efficient electrocatalytic hydrogen evolution reaction through optimizing the sulfur sources selection
- Author
-
Xiaoyan Qin, Xiaolei Liu, Zhang Qianqian, Zeyan Wang, Ying Dai, Peng Wang, Yuanyuan Liu, Zhaoke Zheng, Baibiao Huang, and Xiaoyang Zhang
- Subjects
Tafel equation ,Materials science ,Active surface area ,General Physics and Astronomy ,chemistry.chemical_element ,Heterojunction ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,Overpotential ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Sulfur ,0104 chemical sciences ,Surfaces, Coatings and Films ,chemistry.chemical_compound ,Thiourea ,chemistry ,Chemical engineering ,Hydrogen evolution ,0210 nano-technology - Abstract
The electrocatalysts with low-cost, good stabilities, rich reserves and efficient activities are required to replace Pt-based materials for the hydrogen evolution reaction. Herein, we synthesize the low-cost MoS2/Ni3S2 heterostructure on Ni foam with efficient HER activity and good stability through optimizing the sulfur sources selection among thioacetamide (TAA), L-cysteine and thiourea. The different sulfur sources have a very important influence on the structures and morphologies of NF-MoS2/Ni3S2 composites, which may attribute to the different selective combining capacities of sulfur sources with Na2MoO4 and Ni foam. By contrast, NF-MoS2/Ni3S2-TAA shows relatively lower overpotential of 91 mV at 10 mA cm−2 and Tafel slope of 48.62 mV dec−1 than those of NF-MoS2/Ni3S2-L-cysteine (overpotential of 148 mV at 10 mA cm−2 and Tafel slope of 68.81 mV dec−1) or NF-MoS2/Ni3S2-thiourea (overpotential of 187 mV at 10 mA cm−2 and Tafel slope of 93.41 mV dec−1). The superior HER activity of NF-MoS2/Ni3S2-TAA is benefit from the higher MoS2 content and larger electrochemically active surface area. Optimizing the sulfur source selection can realize the efficient electrocatalytic hydrogen evolution of MoS2/Ni3S2 heterostructure which has an important guiding significance for the practical application in the future.
- Published
- 2018
147. Simultaneous SO2/NO removal performance of carbide slag pellets by bagasse templating in a bubbling fluidized bed reactor
- Author
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Xin Wang, Jiewen Shi, Yingjie Li, Jianli Zhao, Hantao Liu, Xingang Zhou, and Zeyan Wang
- Subjects
Flue gas ,Materials science ,020209 energy ,General Chemical Engineering ,digestive, oral, and skin physiology ,Metallurgy ,Pellets ,Energy Engineering and Power Technology ,Slag ,02 engineering and technology ,complex mixtures ,Carbide ,Fuel Technology ,020401 chemical engineering ,Volume (thermodynamics) ,visual_art ,0202 electrical engineering, electronic engineering, information engineering ,visual_art.visual_art_medium ,Particle size ,0204 chemical engineering ,Bagasse ,Porosity - Abstract
Carbide slag pellets fabricated by bagasse templating using extrusion-spheronization were proposed to simultaneously remove SO2/NO from flue gas. The effects of the reaction temperature, O2 concentration, mass ratio of bagasse to carbide slag and particle size on the simultaneous SO2/NO removal performance of carbide slag pellets were investigated in a bubbling fluidized bed reactor. CaO in the carbide slag pellets has a significant promotion effect on NO reduction by CO. SO2 and NO are completely removed by the carbide slag pellets at 825–875 °C. The presence of O2 in the reaction gas results in an adverse effect on NO removal by carbide slag pellets, while it leads to a positive effect on SO2 removal. With an increase in the mass of bagasse in the pellets, the duration for the complete NO removal becomes longer and the porosity of the pellets appears higher. Carbide slag pellets with a smaller particle size possess a higher NO removal capacity. The higher mass ratio of bagasse to carbide slag leads to a larger surface area and pore volume of the pellets during SO2/NO removal process but results in a slight decrease in the attrition resistance. Carbide slag pellets by bagasse templating for simultaneous SO2/NO removal seems promising in the industrial application.
- Published
- 2018
148. Sulfuration of NiV-layered double hydroxide towards novel supercapacitor electrode with enhanced performance
- Author
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Ying Dai, Peng Zhou, Xiaoyang Zhang, Xiaoyan Qin, Cong Wang, Myung-Hwan Whangbo, Zeyan Wang, Peng Wang, Yuanyuan Liu, and Baibiao Huang
- Subjects
chemistry.chemical_classification ,Supercapacitor ,Materials science ,Sulfide ,Ion exchange ,General Chemical Engineering ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Capacitance ,Industrial and Manufacturing Engineering ,Energy storage ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Electrode ,Environmental Chemistry ,Hydroxide ,0210 nano-technology ,Power density - Abstract
NiV-LDH as a novel electrode material has rarely been investigated in the energy storage field. Herein, novel ultrathin NiV-LDH was designed and synthesized, which displays high specific capacitance but poor stability. To further improve the stability, NiV-LDH was transformed to the sulfide named NiV-S through an ion exchange reaction (S2− replaces OH−). The obtained NiV-S maintains the ultrathin (5 nm in thickness) and porous structure, and displays higher specific capacitance (2270.4 F g−1 at 2 A g−1), compared to NiV-LDH (1502 F g−1 at 2 A g−1). What is more improtant is that the cycling stability of NiV-S is much higher than NiV-LDH, (91.9% retention after 10,000 cycles for NiV-S vs only 63% retention after 5000 cycles for NiV-LDH). The asymmetric supercapacitor assembled using ultrathin porous NiV-S as the positive electrode and activated carbon (AC) as the negative electrode was found to deliver a maximum energy density of 51 W h kg−1 at a power density of 1600 W kg−1 and 12 kW kg−1 at 23.7 W h kg−1. In addition, 98.5% of the initial capacitance retains after 10,000 continuous cycling.
- Published
- 2018
149. CaO/Ca(OH)2 thermochemical heat storage of carbide slag from calcium looping cycles for CO2 capture
- Author
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Hantao Liu, Lunbo Duan, Zeyan Wang, Yingjie Li, Jianli Zhao, and Yi Yuan
- Subjects
chemistry.chemical_classification ,Materials science ,Renewable Energy, Sustainability and the Environment ,020209 energy ,Carbonation ,Metallurgy ,Energy Engineering and Power Technology ,Slag ,chemistry.chemical_element ,02 engineering and technology ,medicine.disease ,Industrial waste ,Carbide ,Fuel Technology ,Nuclear Energy and Engineering ,chemistry ,visual_art ,0202 electrical engineering, electronic engineering, information engineering ,visual_art.visual_art_medium ,medicine ,Chlorine ,Compounds of carbon ,Dehydration ,Calcium looping - Abstract
Carbide slag is an industrial waste generated from ethylene gas production in chlor-alkali plants. Here, a novel system coupling calcium looping and CaO/Ca(OH)2 thermochemical heat storage using carbide slag were proposed to simultaneously capture CO2 and store heat. For CaO/Ca(OH)2 thermochemical heat storage, the hydration/dehydration performance of original carbide slag and carbide slag that experienced calcium looping cycles for CO2 capture was investigated. The performances of the two types of carbide slag with and without chlorine were compared. The dehydration conversions of carbide slag improved with the increase of dehydration temperature. The chlorine content has no apparent effect on the hydration/dehydration performance of original carbide slag. However, for CO2 capture, carbide slag with high chlorine content shows lower carbonation conversion than that of carbide slag without chlorine. The hydration/dehydration conversions of carbide slag that experienced CO2 capture cycles are lower than those of original carbide slag. For carbide slag with chlorine, the hydration conversion can be improved by more than one CO2 capture cycle. Therefore, carbide slag that experienced various CO2 capture cycles is still suitable to be used in CaO/Ca(OH)2 thermochemical heat storage although calcium looping has an adverse effect on the hydration/dehydration performance of carbide slag.
- Published
- 2018
150. Surface Fluorination Engineering of NiFe Prussian Blue Analogue Derivatives for Highly Efficient Oxygen Evolution Reaction
- Author
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Fahao Ma, Yuchen Fan, Qian Wu, Fengxia Tong, Zeyan Wang, Ying Dai, Mu Liu, Hefeng Cheng, Baibiao Huang, Liren Zheng, Yuanyuan Liu, Zhaoke Zheng, and Peng Wang
- Subjects
Tafel equation ,Prussian blue ,Materials science ,Oxygen evolution ,02 engineering and technology ,Surface engineering ,Overpotential ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Catalysis ,chemistry.chemical_compound ,Adsorption ,Chemical engineering ,chemistry ,General Materials Science ,Density functional theory ,0210 nano-technology - Abstract
Surface engineering is of importance to reduce the reaction barrier of oxygen evolution reaction (OER). Herein, the NiFe Prussian blue analogue (NiFe-PBA)-F catalyst with a multilevel structure was obtained from NiFe-PBAs via a fluorination strategy, which presents an ultralow OER overpotential of 190 mV at 10 mA cm-2 in alkaline solution, with a small Tafel slope of 57 mV dec-1 and excellent stability. Interestingly, surface fluorination engineering could achieve a controllable removal of ligands of the cyan group, contributing to keep the framework structure of NiFe-PBAs. Particularly, NiFe-PBAs-F undergoes a dramatic reconstruction with the dynamic migration of F ions, which creates more active sites of F-doped NiFeOOH and affords more favorable adsorption of oxygen intermediates. Density functional theory calculations suggest that F doping increases the state density of Ni 3d orbital around the Fermi level, thus improving the conductivity of NiFeOOH. Furthermore, based on our experimental results, the lattice oxygen oxidation mechanism for NiFe-PBAs-F was proposed. Our work not only provides a new pathway to realize the controllable pyrolysis of NiFe-PBAs but also gives more insights into the reconstruction and the mechanism for the OER process.
- Published
- 2021
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