2,876 results
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102. Evaluation of pulp and paper properties produced from two new bleaching sequences.
- Author
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Rodrigues de Oliveira, Cláudia, Ventorim, Gustavo, Rodrigues de Oliveira, Iliane, Ferraz, Ana Paula Almeida, Silva, Luana Cristal Lirya, and Nunes dos Santos, André Luis
- Subjects
- *
BLEACHING (Chemistry) , *PAPER pulp , *SULFATE pulping process , *WATER consumption , *WASTE minimization , *PAPER industry - Abstract
The pulp and paper industry is increasingly seeking a sustainable and conscientious development, minimizing the environmental impacts caused by it. Therefore, reducing efficiently the number of stages used in the bleaching process can mean less consumption of water and chemical reagents, contributing to the reduction of harmful waste to the environment. Thus, this study sought to evaluate the pulp quality and some physical-mechanical properties (smoothness, tear and tensile indexes) of two new bleaching sequences A*DP and A*E*DP and compare them with the reference D0(E+P)D1P. To do so, industrial eucalyptus Kraft pulp pre-delignified with oxygen was used. The bleached pulp was refined to 1200, 1800 and 2400, in PFI mill and tested according to TAPPI standards to determine smoothness, tear and tensile indexes. Based on the results obtained, it was verified that the sequences studied are viable for using in bleaching plants, which allowed a reduction in the chlorine dioxide consumption and presented satisfactory smoothness, tear and tensile indexes for paper. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
103. The Map of Pomerania by Eilhardus Lubinus (1618)—Two Editions or Three?
- Author
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Skrycki, Radosław
- Subjects
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PAPER mills , *MAPS , *CARTOGRAPHY , *COPYING , *CARTOGRAPHERS , *WATERMARKS - Abstract
Up to now the literature dealing with the cartography of the former Duchy of Pomerania has assumed that wall map of the region by Eilhardus Lubinus (Eilhard Lubin) had two editions: the first dating from 1618 and the second from 1758. Detailed analysis of correspondence between the mapmaker and his patron, the Pomeranian Duke Philip II, and later letters relating to arguments over payment and paper supplies as well as of a recently discovered copy of the map (now at the University of Szczecin), however, point to the existence of a third edition. This, it is suggested, dates from 1619–1620 and was financed by Lubin himself. Research has also revealed that the paper on which this new exemplar was printed came neither from the Pomeranian dukes' paper mill (as for the 1618 edition) nor from the Unold paper mill in Wolfegg (as for the 1758 edition). [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
104. A Solvent-Free Approach to Crosslinked Hydrophobic Polymeric Coatings on Paper Using Vegetable Oil.
- Author
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Loesch-Zhang, Amelia, Cordt, Cynthia, Geissler, Andreas, and Biesalski, Markus
- Subjects
- *
VEGETABLE oils , *OLIVE oil , *FOURIER transform infrared spectroscopy , *SURFACE coatings , *CONTACT angle , *CHEMICAL reactions , *CLICK chemistry , *SOLVENTS - Abstract
Hydrophobic coatings are of utmost importance for many applications of paper-based materials. However, to date, most coating methods demand vast amounts of chemicals and solvents. Frequently, fossil-based coating materials are being used and multiple derivatization reactions are often required to obtain desired performances. In this work, we present a solvent-free paper-coating process, where olive oil as the main biogenic component is being used to obtain a hydrophobic barrier on paper. UV-induced thiol-ene photocrosslinking of olive oil was pursued in a solvent-free state at a wavelength of 254 nm without addition of photoinitiator. Optimum reaction conditions were determined in advance using oleic acid as a model compound. Paper coatings based on olive oil crosslinked by thiol-ene reaction reach water contact angles of up to 120°. By means of Fourier transform infrared spectroscopy and differential scanning calorimetry, a successful reaction and the formation of a polymer network within the coating can be proven. These results show that click-chemistry strategies can be used to achieve hydrophobic polymeric paper coatings while keeping the amount of non-biobased chemicals and reaction steps at a minimum. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
105. Human Acellular Dermal Allograft Patch on Traumatic Tympanic Membrane Perforation.
- Author
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Dong-Han Lee, Cha-Dong Yeo, and Young Ho Kim
- Subjects
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TYMPANIC membrane perforation , *HOMOGRAFTS , *COMPUTED tomography - Abstract
BACKGROUND: This study aimed to investigate the outcome of using the human acellular dermal allograft patch compared with the conventional paper patch in traumatic tympanic membrane perforation. METHODS: This was a retrospective study including 41 patients (42 ears) treated with 22 human acellular dermal allografts and 20 paper patches for acute traumatic tympanic membrane perforation from April 2013 to June 2020. The procedure was performed by applying human acellular dermal allograft or paper patches after trimming of perforation margins under local anesthesia. Patient's age, sex, cause, duration, side, location, size of perforation, and the result of healing was analyzed. The audiologic or computed tomography data were also investigated when available. RESULTS: There was no significant difference in sex, age, affected side ratio, size and duration of perforation, recovery confirmation time, and audiogram results between the two groups. There was no significant difference in the size or duration of perforation between the success and failure groups. The human acellular dermal allograft and paper-patch groups showed no significant difference in the recovery confirmation time (70.7 ± 42.3 vs. 89.9 ± 119.4 days, P = .486) and recovery rate (95.5% vs. 85.0%, P = .333). However, the patch maintenance time of the human acellular dermal allograft group was statistically longer than the paper-patch group (32.9 ± 14.9 vs. 15.6 ± 19.9 days, P = .001). On multivariable regression analysis, patch material was the only parameter associated with patch maintenance time (P = .002). CONCLUSION: Treatment outcomes of traumatic tympanic membrane perforation using human acellular dermal allograft showed better or similar therapeutic efficacy compared to paper patch. The important advantage of this material is to stay in situ for a sufficient time without being detached until successful healing. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
106. PHMG-KH560 as antifungal and reinforcement media for paper materials.
- Author
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Jia, Minghao, Huang, Xiaoxia, Zhang, Xiaogang, and Hu, Gang
- Abstract
Improving the strength decrease caused by fungal metabolites is still an arduous task in the field of paper materials protection. A set of damaged Kangxi Dictionary from Qing Dynasty was chosen as samples in this work. The main goal of this work is to develop high-efficiency and eco-friendly media with the characteristics of antifungal and reinforcement, to preserve paper materials and continue the historical and scientific research value of cultural heritage. PHMG as an efficient antifungal was used in this work. For better behavior, the epoxy group of KH560 can be induced by the amino group in PHMG by ring opening reaction to form PHMG-KH560 colloidal complex. Spraying PHMG-KH560 on paper could establish Si-O-C bonding and increased the hydrogen bond between polymeric material and paper fibers, which simultaneously inhibited fungi and improved mechanical strength of the original paper, even after the artificial aging. PHMG-KH560 had certain antifungal activity against five fungi, such as Aspergillus versicolor, and Aspergillus Niger , and had better inhibitory effect on Cladosporium herbarum, Trichoderma viride , and Penicillium expansum. The ancient writing ink on the paper sprayed with PHMG-KH560 did not affect its visual beauty, which also indicated that the complex reagent was expected to be applied to the antifungal and reinforcement of paper materials. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
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107. Role of nanocellulose in colored paper preparation.
- Author
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Dai, Lei, Wang, Xiaowan, Jiang, Xue, Han, Qing, Jiang, Feng, Zhu, Xianqi, Xiong, Chuanyin, and Ni, Yonghao
- Subjects
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CELLULOSE , *MANUFACTURING processes , *NANOFIBERS , *FUNCTIONAL groups , *REACTIVE dyes , *CARBON nanofibers , *SURFACE area - Abstract
Colored paper is an important industrial paper grade that has applications in various industrial sectors. The increase in coloring efficiency is a key in decreasing the use of dyes, thus can be considered as a "green" process concept; the coloring efficiency depends on the dye retention and dispersion. This work explores the use of nanocellulose, specifically, TEMPO-oxidized cellulose nanofibers (TOCNF), on the coloring efficiency of the preparation of colored paper. Two dyes (i.e. direct blue GL and reactive red 195 (RR195)) were used. Thanks to the large specific surface area and abundant active sites of TOCNF, its use largely improves the direct blue GL retention during the process. The coloring difference (∆E* ab) reached 5.334 with the addition of 13.6 wt% TOCNF and 1.8 wt% direct blue GL in the pulp furnish. The functional group in the dye is a vital factor in determining the dye retention when one chooses TOCNF to enhance the coloring efficiency in the production of colored paper. Furthermore, TOCNF significantly improved the strength properties of both direct blue GL and RR 195 dyed papers. This work demonstrates the potential of nanocellulose in the production of colored paper in improving the coloring efficiency, thus decreasing the environmental impact of the manufacturing process. [Display omitted] • Nanocellulose (i.e. TOCNF) adopted for colored paper preparation • Coloring efficiency improved by TOCNF due to the dye retention improvement • -COO− in TOCNF deteriorating its combination with negatively-charged dye [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
108. A case study on Hoeamsa Temple, Korea: technical examination and identification of pigments and paper unearthed from the temple site.
- Author
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Go, InHee, Mun, SeongWoo, Lee, JangJon, and Jeong, HyeYoung
- Subjects
- *
CHOSON dynasty, Korea, 1392-1910 , *PIGMENTS , *RADIOCARBON dating , *ANALYSIS of colors , *MECHANICAL properties of condensed matter , *TEMPLES - Abstract
This study applied various scientific analyses to one fragment of paper and three pigments excavated from earthenware found in the Hoeamsa Temple site at Yangju, Korea, which is believed to have been built in the early twelfth century. Radiocarbon dating of the paper fragment suggests a manufacture date between 1460 and 1646 (at a 95% confidence interval). It was estimated to have been used during the early and middle period of the Joseon dynasty (1391–1776), when the Hoeamsa Temple site was rebuilt. In addition, by staining the fiber of the paper fragment with Graff "C" stain, the paper's raw material was identified as paper mulberry through dislocation, cross-marking, and transparent membrane, which are characteristics of the bast fiber. Efforts were made to identify their material properties and manufacturing techniques of the three types of pigments. Color difference analysis was performed by distributing the pigments in large areas to reveal characteristic differences according to the color difference of the pigment. We found that green-type pigments are malachite and atacamite, red-type pigments are hematite based on the element Fe, and white-type pigments are quartz and muscovite based on the elements Si and Al. In addition, as the size distribution of the three types of pigments is wide and has a multi-peak distribution curve, it was concluded that the pigments were used without purification. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
109. Hydrophobic Molecular Treatments of Cellulose-based or Other Polysaccharide Barrier Layers for Sustainable Food Packaging: A Review.
- Author
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Szlek, Dorota B., Reynolds, Autumn M., and Hubbe, Martin A.
- Subjects
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FOOD packaging , *COVALENT bonds , *WATER vapor , *POLYSACCHARIDES , *MONOMERS - Abstract
Paper, nanocellulose, and other polysaccharide-based materials can be excellent candidates for food packaging barrier layers, except that they tend to be vulnerable to moisture. This article reviews published research describing various chemical treatments having the potential to render hydrophobic character to such layers. Emphasis is placed on systems in which hydrophobic monomers are used to treat either particles or sheets comprised largely of polysaccharides. A goal of this review is to identify combinations of materials and procedures having promise for scale-up to industrial production, while providing effective resistance to moisture. The idea is to protect the underlying polysaccharide-based barrier layers such that they can continue to impede the transfer of such permeants as oxygen, greases, flavor compounds, and water vapor. A further goal is to minimize any adverse environmental impacts associated with the treatments. Based on the research articles considered in this review, promising hydrophobic treatments can be achieved involving silanes, ester formation, other covalent interactions, plasma treatments, and to some extent by various treatments that do not require formation of covalent bonds. The article is designed such that readers can skip ahead to items of particular interest to them. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
110. Evaluation of environmental conditions as a decontamination approach for SARS‐CoV‐2 when applied to common library, archive and museum‐related materials.
- Author
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Richter, William R., Sunderman, Michelle M., Mera, Tom O., O'Brien, Kim A., Morgan, Kendra, and Streams, Sharon
- Subjects
- *
SARS-CoV-2 , *POROUS materials , *ARCHIVES , *HUMIDITY , *LIBRARY materials - Abstract
Aims: The purpose of this study was to evaluate the effects of ambient or altered environmental conditions on the inactivation of SARS‐CoV‐2 applied to materials common in libraries, archives and museums. Methods and Results: Porous and non‐porous materials (e.g. paper, plastic protective book cover) were inoculated with approximately 1 × 105 TCID50 SARS CoV‐2 (USA‐WA1/2020), dried, placed within test chamber in either a stacked or unstacked configuration, and exposed to environmental conditions ranging from 4 to 29°C at 40 ± 10% relative humidity. The amount of infectious SARS‐CoV‐2 was then assessed at various timepoints from 0 to 10 days. Ambient conditions resulted in varying inactivation rates per material type. Virus inactivation rate decreased when materials were stacked or at colder temperatures. Virus inactivation rate increased when materials were unstacked or at warmer temperatures. Conclusions: SARS‐CoV‐2 at ambient conditions resulted in the inactivation of virus below limit of quantitation (LOQ) for all materials by Day 8. Warmer temperatures, for a subset of materials, increased SARS‐CoV‐2 inactivation, and all were
- Published
- 2022
- Full Text
- View/download PDF
111. A case study on Hoeamsa Temple, Korea: technical examination and identification of pigments and paper unearthed from the temple site.
- Author
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Go, InHee, Mun, SeongWoo, Lee, JangJon, and Jeong, HyeYoung
- Subjects
- *
CHOSON dynasty, Korea, 1392-1910 , *PIGMENTS , *RADIOCARBON dating , *ANALYSIS of colors , *MECHANICAL properties of condensed matter , *TEMPLES - Abstract
This study applied various scientific analyses to one fragment of paper and three pigments excavated from earthenware found in the Hoeamsa Temple site at Yangju, Korea, which is believed to have been built in the early twelfth century. Radiocarbon dating of the paper fragment suggests a manufacture date between 1460 and 1646 (at a 95% confidence interval). It was estimated to have been used during the early and middle period of the Joseon dynasty (1391–1776), when the Hoeamsa Temple site was rebuilt. In addition, by staining the fiber of the paper fragment with Graff "C" stain, the paper's raw material was identified as paper mulberry through dislocation, cross-marking, and transparent membrane, which are characteristics of the bast fiber. Efforts were made to identify their material properties and manufacturing techniques of the three types of pigments. Color difference analysis was performed by distributing the pigments in large areas to reveal characteristic differences according to the color difference of the pigment. We found that green-type pigments are malachite and atacamite, red-type pigments are hematite based on the element Fe, and white-type pigments are quartz and muscovite based on the elements Si and Al. In addition, as the size distribution of the three types of pigments is wide and has a multi-peak distribution curve, it was concluded that the pigments were used without purification. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
112. CARACTERIZACIÓN DE FIBRAS VEGETALES EN PAPELES USADOS EN RESTAURACIÓN: ABACÁ Y PAPEL JAPÓN.
- Author
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Alcaraz, Élida, Nitiu, Daniela, and Mallo, Andrea
- Subjects
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PLANT species , *REFERENCE sources , *CHEMICAL properties , *BANANAS , *COINCIDENCE - Abstract
Background and aims: The excellent physical and chemical properties of Abacá and Japan papers make them one of the most used materials in restoration of cultural assets on paper. The objective of this work is to characterize the fibers that compose them and identify plant genera or species that were used in their manufacture. M&M: Fibers from samples of each paper and previously collected reference plant material were disintegrated. The diagnostic characters of the fibers were observed with a photomicroscope and photomicrographs were taken. Subsequently, the homologous characters were compared by relating the Abacá paper fiber samples with those of Musa sp. and the Japan paper samples with Broussonetia sp. and Euonymus sp. Results: There were coincidences between the diagnostic characters of the paper fibers of Abacá and Musa sp. Regarding the Japan paper samples, there were results consistent with Broussonetia sp. but not with Euonymus sp. Conclusions: According to the results observed between the Abacá paper fibers and the samples of the collected living material, we infer that the Abacá paper contains fibers of Musa sp. In the Japan paper samples, the similarities observed between the diagnostic characters of the fibers with respect to the reference plant samples indicate the presence of Broussonetia sp. fibers. There is no evidence of fibers of Euonymus sp. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
113. Influence of oil–paper configuration on electric field distribution of main insulation structure on valve‐side winding of UHV‐DC converter transformer.
- Author
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Yang, Lijun, Cheng, Zhidong, Cheng, Li, and Liao, Ruijin
- Subjects
- *
ELECTRIC windings , *ELECTRIC insulators & insulation , *ELECTRIC fields , *CARDBOARD , *PAPER - Abstract
The main insulation structure of the valve‐side winding of converter transformer bears the effect of AC and DC superimposed voltage during operation. The electric field intensity in the pressboard is much higher than that in the pressboard in the AC transformer. This condition increases the probability of failure of insulation structure. Therefore, the design and optimization of the main insulation structure of the valve‐side winding are keys to ensure the stable operation of converter transformer. This study establishes a model of the main insulation structure of the valve‐side winding of the ±1100 kV converter transformer. The influence of the insulating oil–paper configuration on the electric field distribution of the main insulation structure of the valve‐side winding is analysed, and then, an optimization idea is proposed. The oil–paper configuration includes two aspects: oil–paper insulation structural design and combination selection, that is, the influence of typical oil–paper structural design parameters and the aging state of different oil–paper combinations on the electric field distribution. Finally, the optimization idea of the oil–paper configuration for valve‐side winding of converter transformer is obtained, and the established model is optimized. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
114. Building blocks for developing a research question: The ABC‐model.
- Author
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Wisse, Maarten and Roeland, Johan
- Subjects
- *
PAPER , *ACADEMIC dissertations , *STUDENTS , *HUMANITIES - Abstract
A precisely formulated research question is becoming increasingly important within the humanities. This applies not only to research funding applications, but also to articles, papers, and student theses. This article presents a tool allowing students to develop research questions on their own, which is open enough to allow for a wide variety of research questions, while still giving users sufficient guidance to formulate a precise question. It also offers a concrete roadmap for students to use in developing their research question. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
115. Application of carbon paste concurrent with investigation of water electrolysis in paper-based closed bipolar electrochemistry.
- Author
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Rafatmah, Elmira and Hemmateenejad, Bahram
- Subjects
- *
CONDUCTIVITY of electrolytes , *ELECTROCHEMISTRY , *BIPOLAR cells , *CARBON , *CARBON electrodes - Abstract
The effect of bipolar and driving electrodes materials and also the electrolyte conductivity on the required potential for the beginning of the water electrolysis in the paper-based closed cell bipolar electrochemistry is investigated. The importance of the electrode material is studied by placement of various carbon paste mixtures as an electrode on the paper. Carbon paste mixtures are prepared with different carbon allotropes and various binders such as paraffin and ionic liquids. The effect of hydrophobicity, conductivity, and presence of common additives such as gold nanoparticle is discussed in detail. The role of electrolyte conductivity on the needed ∆E for water electrolysis initialization is investigated. It has been proved that even in the absence of ionic current in the closed bipolar setups, electrolyte conductivity can be effective. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
116. A case study on Hoeamsa Temple, Korea: technical examination and identification of pigments and paper unearthed from the temple site.
- Author
-
Go, InHee, Mun, SeongWoo, Lee, JangJon, and Jeong, HyeYoung
- Subjects
- *
CHOSON dynasty, Korea, 1392-1910 , *PIGMENTS , *RADIOCARBON dating , *TEMPLES , *ANALYSIS of colors , *MECHANICAL properties of condensed matter - Abstract
This study applied various scientific analyses to one fragment of paper and three pigments excavated from earthenware found in the Hoeamsa Temple site at Yangju, Korea, which is believed to have been built in the early twelfth century. Radiocarbon dating of the paper fragment suggests a manufacture date between 1460 and 1646 (at a 95% confidence interval). It was estimated to have been used during the early and middle period of the Joseon dynasty (1391–1776), when the Hoeamsa Temple site was rebuilt. In addition, by staining the fiber of the paper fragment with Graff "C" stain, the paper's raw material was identified as paper mulberry through dislocation, cross-marking, and transparent membrane, which are characteristics of the bast fiber. Efforts were made to identify their material properties and manufacturing techniques of the three types of pigments. Color difference analysis was performed by distributing the pigments in large areas to reveal characteristic differences according to the color difference of the pigment. We found that green-type pigments are malachite and atacamite, red-type pigments are hematite based on the element Fe, and white-type pigments are quartz and muscovite based on the elements Si and Al. In addition, as the size distribution of the three types of pigments is wide and has a multi-peak distribution curve, it was concluded that the pigments were used without purification. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
117. Mustard oil thermosets using N-vinyl-2-pyrrolidone as crosslinking agent for scrap paper composites.
- Author
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Jadhav, Nilesh C. and Kale, Ravindra D.
- Subjects
- *
MUSTARD , *DYNAMIC mechanical analysis , *EDIBLE fats & oils , *INTERFACIAL bonding , *FLEXURAL modulus , *DENTAL materials - Abstract
Presently synthesis of edible oil for resin formation and using scrap paper as reinforcement for composite fabrication is still not carried out. In this work, acrylate epoxidized mustard oil (AEMO) was used after blending with a crosslinker N-Vinyl-2-Pyrrolidone (NVP) to fabricate scrap paper reinforced green composites. Mustard oil (MO), Epoxidized mustard oil (EMO) and acrylate epoxidized mustard oil (AEMO) were characterized using iodine value, oxirane content, acid value, FTIR, NMR and viscosity properties. The composites were fabricated using 50:50 ratio of AEMO: NVP and paper loading of 15%, 30% and 60% along with the neat sample. With an increase in paper loading, there was a significant improvement in mechanical properties giving 158.9, 150, 233, 566.66 and 140% improvement in tensile, young's, flexural strength, flexural moduli and impact strength at 60% loading. The elongation at break showed a value of 20% due to the stiff nature of composite. Biodegradability testing proved an increase in weight loss of composite with time, recording the highest weight loss of 7% for 60% composite sample. Dimensional stability showed excellent result for the neat and lower loaded composite samples. Thermogravimetric and differential scanning colorimetry analysis indicated improvement in thermal stability with higher loading %. Morphological analysis confirmed excellent interfacial adhesion and bonding with higher paper loading %. Dynamic mechanical analysis demonstrated a significant rise in storage modulus (E') and loss modulus (E'') and decline in tan δ with broadening of the peak for maximum loading. Chemical resistance was poor for the highest loaded samples with respect to acids and bases. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
118. Analytical investigation of the original painted canvas of Santa Irene, by Giuseppe Verrio (Church of Sant'Irene, Lecce, Italy)*.
- Author
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Rizzo, Daniela and Casciaro, Raffaele
- Subjects
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CANVAS , *OIL paint , *VARNISH & varnishing , *GAS chromatography/Mass spectrometry (GC-MS) , *ACRYLIC paint , *MONASTICISM & religious orders , *ORGANIC dyes , *PAINT - Abstract
The object of this study is unusual for both its material and technique. It is an oil painting on sheets of paper glued to a canvas made of linen fibres, thereby showing some execution peculiarities. It depicts the Virgin of Thessalonica in a hieratic attitude. The painting is attributed to the Salento‐born artist Giuseppe Verrio (1639) for the church of the Theatine religious Order in Lecce, Italy, in which it is still placed, on the left altar of the transept. To truly understand and appreciate a work of art, it is important to have a basic knowledge of the materials and techniques used by the artist. For a better understanding of the execution techniques and to study the original materials and those that have been added over time, the painting was examined using the following analytical techniques: microscopic examination of cross‐sections, μ‐Raman spectroscopy and pyrolysis gas chromatography‐mass spectrometry (Py‐GC‐MS). The data indicate that Verrio used different earthy, mineral and manufactured pigments, an organic dye used only on the paper, oil as a binder, and varnish as a protectant. The results demonstrate that the latter are both original and due to a subsequent restoration. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
119. 含芴基Cardo环水性聚氨酯的制备 及其热性能研究.
- Author
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赵艳娜, 薛瑜瑜, 叶智, and 张 婷
- Abstract
以聚己内酯二元醇(PCL)为软段,二羟甲基丙酸(DMPA)为扩链剂,异佛尔酮二异氰 酸酯(IPDI)为硬段,合成了水性聚氨酯预聚体.通过进一步添加双酚芴(BPFL)反应合成一系 列含 Cardo环水性聚氨酯(WPUS).利用傅里叶变换红外光谱、粒径、热重、力学、X灢射线衍射、 水接触角测定和纸张表面施胶等方法对制备的 WPUS的结构和性能进行表征.结果表明,当 WPUS的 BPFL含量为3%时,WPUS乳液的粒径增大至95.21nm;膜的耐热性最大提高 31.36%;水接触角提升32.13%.不同乳液对纸张表面施胶后与未施胶纸张相比,WPUS3纸 张水接触角提升887.6%;抗张强度最大可达57.1N/mm2,提升46.41%;纸张耐折度最大可 达74次,比未施胶原纸高出60次. [ABSTRACT FROM AUTHOR]
- Published
- 2022
120. Stability of SARS-CoV-2 and influenza virus varies across different paper types.
- Author
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Hirose, Ryohei, Miyazaki, Hajime, Bandou, Risa, Watanabe, Naoto, Yoshida, Takuma, Daidoji, Tomo, Itoh, Yoshito, and Nakaya, Takaaki
- Subjects
- *
INFLUENZA viruses , *INFLUENZA A virus , *SARS-CoV-2 , *VIRAL transmission , *SURFACE structure - Abstract
The assessment of the risk of virus transmission through papers, such as postcards, is important. However, the stability of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) and influenza A virus (IAV) on different types of papers is currently unknown. Investigation of the survival time of these viruses on different types of papers will provide insights into their risk of long-distance transport by postal items. We evaluated the stability of SARS-CoV-2 and IAV, mixed with a culture medium, on the surface of postcards with various coatings, including plain paper (PP), inkjet paper (IP), and inkjet photo paper (IPP). The surface structure of each paper was microscopically assessed. The surface structures of PP, IP, and IPP varied greatly depending on the presence or absence, and type, of coat layer, regardless of the base material. IP and IPP surfaces were less conducive to virus survival than PP surfaces, because of the difference in surface shapes. The survival times of SARS-CoV-2 on each paper were approximately 59.8 (PP), 6.5 (IP), and 9.8 h (IPP), and significantly longer than those of IAV (10.3, 1.8, and 3.3 h, respectively). The risk of SARS-CoV-2 transmission via paper, such as postcards, is significantly higher than that of IAV transmission. While PP, IP, and IPP have the same base material, their surface structures differ, which affects viral stability. The IP and IPP surfaces are less suitable for virus survival. This study provides novel insights into the risks of viral transmission via paper. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
121. LC-HRMS screening of per- and polyfluorinated alkyl substances (PFAS) in impregnated paper samples and contaminated soils.
- Author
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Bugsel, Boris, Bauer, Rebecca, Herrmann, Florian, Maier, Martin E., and Zwiener, Christian
- Subjects
- *
SOIL pollution , *SOIL sampling , *SLUDGE composting , *PHOSPHATE esters , *SOIL horizons - Abstract
High per- and polyfluorinated alkyl substance (PFAS) concentrations have been detected in agricultural soils in Southwest Germany. Discharges of PFAS-contaminated paper sludge and compost are suspected to be the cause of the contamination. Perfluorinated carboxylic acids (PFCAs) have been detected also in groundwater, drinking water, and plants in this area. Recently, previously unknown compounds have been identified by high-resolution mass spectrometry (HRMS). Major contaminants were polyfluorinated dialkylated phosphate esters (diPAPs) and N-ethyl perfluorooctane sulfonamide ethanol–based phosphate diester (diSAmPAP). In this study, HRMS screening for PFAS was applied to 14 soil samples from the contaminated area and 14 impregnated paper samples which were from a similar period than the contamination. The paper samples were characterized by diPAPs (from 4:2/6:2 to 12:2/12:2), fluorotelomer mercapto alkyl phosphates (FTMAPs; 6:2/6:2 to 10:2/10:2), and diSAmPAP. In soil samples, diPAPs and their transformation products (TPs) were the major contaminants, but also FTMAPs, diSAmPAP, and their TPs occurred. The distribution patterns of the carbon chain lengths of the precursor PFAS in soil samples were shown to resemble those in paper samples. This supports the hypothesis that paper sludge is a major source of contamination. The presence of major degradation products like PFCAs, FTSAs, or PFOS and their distribution of carbon chain lengths indicate the activity of biotic or abiotic degradation processes and selective leaching processes from the upper soil horizons. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
122. Paper and thread as media for the frugal detection of urinary tract infections (UTIs).
- Author
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Hasandka, Amrutha, Singh, Ankita Ramchandran, Prabhu, Anusha, Singhal, Hardik Ramesh, Nandagopal, M. S. Giri, and Mani, Naresh Kumar
- Subjects
- *
URINARY tract infections , *GLOBAL burden of disease , *AT-risk people , *THREAD - Abstract
Urinary tract infections (UTIs) make up a significant proportion of the global burden of disease in vulnerable groups and tend to substantially impair the quality of life of those affected, making timely detection of UTIs a priority for public health. However, economic and societal barriers drastically reduce accessibility of traditional lab-based testing methods for critical patient groups in low-resource areas, negatively affecting their overall healthcare outcomes. As a result, cellulose-based materials such as paper and thread have garnered significant interest among researchers as substrates for so-called frugal analytical devices which leverage the material's portability and adaptability for facile and reproducible diagnoses of UTIs. Although the field may be only in its infancy, strategies aimed at commercial penetration can appreciably increase access to more healthcare options for at-risk people. In this review, we catalogue recent advances in devices that use cellulose-based materials as the primary housing or medium for UTI detection and chart out trends in the field. We also explore different modalities employed for detection, with particular emphasis on their ability to be ported onto discreet casings such as sanitary products. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
123. Barrier properties, migration into the food simulants and antimicrobial activity of paper-based materials with functionalized surface.
- Author
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Peter, Anca, Cozmuta, Leonard M, Nicula, Camelia, Cozmuta, Anca M, Apjok, Robert, Talasman, Catalina M, Drazic, Goran, Peñas, Antonio, Calahorro, Antonio J, Kamgang Nzekoue, Franks, Huang, Xiaohui, Sagratini, Gianni, and Silvi, Stefania
- Subjects
- *
SURFACES (Technology) , *ANTI-infective agents , *ESCHERICHIA coli , *CONTACT angle , *FOOD pathogens , *SALMONELLA enterica - Abstract
The study investigates four paper-based materials designed for short-time wrapping of meat products by determining morpho-structure, capillary-hydroscopic, barrier and antibacterial properties, wettability and migration into food simulants. The paper-based materials are coded as RO, SP, IT and SLO. RO and SLO samples exhibit the best barrier properties against water vapors. The low solubility and contact angles of RO, IT and SLO in A simulant (distilled water) make them suitable for aqueous food storage. The extremely high solubility of SP and SLO in simulant B (acetic acid) shows that wax and hydrophobized starch, respectively are carried by the acidic media, thus these agents are unlikely to coat the paper designed to package acidic food. SLO inhibits E. coli, Salmonella enterica, Lysteria monocytogenes, Pseudomonas aeruginosa and fluorescens. Polyethylene coated on RO and IT surface and wax impregnated on SP have a lower antimicrobial activity in comparison with hydrophobized starch coated on SLO. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
124. Imaging Rough Paper to Evaluate Methods for Soot Removal.
- Author
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Duncan, Teresa T., Vicenzi, Edward P., and Brogdon-Grantham, Shannon A.
- Subjects
- *
SOOT , *CULTURAL property , *SCANNING electron microscopy , *CLEANING , *PAPER - Abstract
Here, we use a variety of microscopic imaging techniques, including scanning electron microscopy, 3D visible light microscopy, and portable microscopy to capture the topography of rough paper. Paper coated with a model soot was cleaned with either a firm vinyl eraser or softer, putty-like kneaded eraser and reimaged to characterize the disposition of remaining soot. Although both methods remove soot from the upper-most surface of the paper, only the kneaded eraser can conform to the complex topography to remove soot from the interstices between paper fibers. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
125. Bir prototip kağıt kesme makinesi tasarımı.
- Author
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Demirtaş, Hasan
- Abstract
A4 paper is the most widely used paper type that is produced by using wood-free writing & printing paper with the least amount of wood in its structure. A4 size paper is produced by cutting large and long rolls in width and length directions. The construction of this machine is not made in Turkey. In this study, a prototype designed for a paper cutting machine is presented. For this prototype, step motors are used that can be set at different speeds and polyamide rollers are used to transfer the paper from one line to another without tearing. Some problems that is encountered for the designed paper cutting machine are discussed and some analyses are made to solve these problems. It has been found that the misalignment of the shaft axes during the transfer of the paper and the not suitable construction of the shafts causes the non-uniform cutting of the paper. It is also observed that the speed of the motor must the paper adjusted at an appropriate rate, to avoid the stretch and break of paper. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
126. Fabrication of Eco-friendly Time Indicator Using Cellulose-Based Materials.
- Author
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Hae Min Jo, Yeon Hui Lee, and Ji Young Lee
- Subjects
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FILTER paper , *TIME management , *CORPORATE bonds , *IMMIGRATION enforcement - Abstract
An eco-friendly time indicator (TI) was developed using cellulose-based materials. The TI comprises a dye, copy paper, nanofibrillated cellulose (NFC) film, and filter papers coated with NFC slurry and/or paraffin-free biowax. A suitable dye and its conditions were determined by observing the dye solutions and the migration pattern at the different concentrations. Commercial filter papers were prepared, and the dye migration rate, depending on physical properties, was evaluated. NFC was coated to control the dye migration rate of filter paper. In addition, biowax was used to impart hydrophobicity to filter papers used for supporting NFC films, storing the dye, and allowing the migration of dye. Finally, a TI was fabricated using those components. Methylene blue was selected as a dye for the TI due to its deep color and high solubility. The results showed that the key property of filter paper affecting the dye migration rate was the pore size. The migration rate could be reduced when NFC was coated on both sides of the filter paper. Since biowax modified the hydrophobicity of filter paper surface, it was used to make the NFC film-supporting paper, location for dye storage, and bottom-layer. In conclusion, a multilayered TI could be assembled using cellulose-based materials. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
127. BitConduite: Exploratory Visual Analysis of Entity Activity on the Bitcoin Network.
- Author
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Kinkeldey, Christoph, Fekete, Jean-Daniel, Blascheck, Tanja, and Isenberg, Petra
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- *
BITCOIN , *VISUAL analytics , *CORPORATE finance , *WEBSITES - Abstract
We present BitConduite, a visual analytics approach for explorative analysis of financial activity within the Bitcoin network, offering a view on transactions aggregated by entities, i.e., by individuals, companies, or other groups actively using Bitcoin. BitConduite makes Bitcoin data accessible to nontechnical experts through a guided workflow around entities analyzed according to several activity metrics. Analyses can be conducted at different scales, from large groups of entities down to single entities. BitConduite also enables analysts to cluster entities to identify groups of similar activities as well as to explore characteristics and temporal patterns of transactions. To assess the value of our approach, we collected feedback from domain experts. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
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128. Moisture in Textiles.
- Author
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Duprat, C.
- Abstract
The interactions of textiles with moisture have been thoroughly studied in textile research, while fluid mechanists and soft matter physicists have partially investigated the underlying physics phenomena. A description of liquid morphologies in fibrous assemblies allows one to characterize the associated capillary forces and their impact on textiles, and to organize their complex moisture transport dynamics. This review gathers some of the common features and fundamental mechanisms at play in textile–liquid interactions, with selected examples ranging from knitted fabrics to nonwoven paper sheets, associated with experiments on model systems. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
129. SPECTROSCOPIC TECHNIQUE FOR STUDYING THE CHARACTERISTICS OF PAPER, PIGMENTS AND INKS IN THE AGING PROCESS (REVIEW).
- Author
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Ivanova, Iordanka, Spiridonov, Iskren, and Lasheva, Veska
- Subjects
- *
PIGMENTS , *INDUCTIVELY coupled plasma mass spectrometry , *X-ray spectroscopy , *DOCUMENT imaging systems , *FOURIER transform infrared spectroscopy , *LIPOFUSCINS , *RAMAN spectroscopy - Abstract
For many centuries paper has been the mainstay material for recording cultural achievements around the world. Paper is produced mainly from cellulose with small amounts of organic and inorganic additives, which allow its identification and characterization and can contribute to the decomposition of the paper. Spectroscopic technique is a powerful tool for examining the constituent elements of paper documents to establish their identification and their state of degradation. This review describes the application of selected spectroscopic technique used to characterize paper and inks. Spectroscopic technique that has been reviewed include: Infrared spectroscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray fluorescence analysis, Inductively Coupled Plasma Mass Spectrometry, SEM-EDX, energy dispersion X-ray fluorescence. [ABSTRACT FROM AUTHOR]
- Published
- 2022
130. Carta cartucho.
- Author
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MELO, LAURA
- Abstract
Paper was fundamental in the American wars of independence, it had transcendental military and communication functions for both the patriot and royalist armies. In the parish archive of Paipa Boyacá, there are a series of handwritten citations that allude to the passage of the war of 1819 through this town. From five of these citations I develop an interpretation and reconstruction of their historical context, using paper as a vehicle for a multi-sense story. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
131. THREE PAPERS.
- Author
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GORHAM, SARAH
- Subjects
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PAPER , *MATERIALITY & art , *THEORY of knowledge , *MEMORY , *INTERPERSONAL relations - Abstract
The article presents a memoir of the author's experience, interwoven with reflections on the history and materiality of paper. It delves into themes of neglect, memory, and the enduring value of knowledge. It further discusses cultural and historical contexts, offering insights into the fragility of both physical objects and human connections.
- Published
- 2024
132. Fusion of cellulose microspheres with pulp fibers: Creating an unconventional type of paper.
- Author
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Scheer, Alexa, Fischer, Johanna, Bakhshi, Adelheid, Bauer, Wolfgang, Fischer, Steffen, and Spirk, Stefan
- Subjects
- *
CELLULOSE , *MICROSPHERES , *SURFACE roughness , *SCANNING electron microscopy , *PAPER products , *NANOFIBERS - Abstract
Cellulose microspheres (CMS) are a type of spherical regenerated cellulose particles with versatile properties which have been used as carrier materials in medical and technical applications. The integration of CMS into paper products opens up novel application scenarios for paper products in a wide range of fields. However, the incorporation of CMS carriers into paper products is challenging and hitherto no reports do exist in literature. Here, we present a feasibility study to incorporate up to 50 w.% CMS in paper hand sheets using retention aids. Our primary observations highlight the successful formation of uniform paper hand sheets retaining its tensile strengths at elevated CMS concentrations. Sheets with high CMS contents exhibit an increase in density and display enhanced surface smoothness — an outcome of a CMS layer forming atop the fiber base — which effectively bridges voids and rectifies surface irregularities as supported by Gurley testing, infinite focus microscopy and scanning electron microscopy. While our primary objective centered on the general feasibility to manufacture CMS-containing papers, the resulting composite scaffold carries significant potential as a platform for innovative, functional paper-based materials. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
133. Hygroscopic paper enhanced using hydroxyapatite coating for wearable TENG sensors.
- Author
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Liu, Songling, Tong, Wangshu, Gao, Caixia, Wang, Xuemei, Liu, Yulun, and Zhang, Yihe
- Subjects
- *
NANOGENERATORS , *WEARABLE technology , *OPEN-circuit voltage , *SHORT-circuit currents , *HYDROXYAPATITE coating , *RANGE of motion of joints , *SURFACE coatings - Abstract
• Hydroxyapatite (HAP) composite paper with biocompatibility and hygroscopicity was prepared. • HAP composite paper has better hygroscopic and triboelectric properties than pure paper, making it more suitable for wearable sensing applications. • The HAP composite paper-based triboelectric nanogenerator can detect and distinguish different joint movements. • Hemostatic and disposable HAP composite paper can be degraded in the natural environment without harm. Wearable triboelectric nanogenerators (TENGs) have attracted considerable attention in the field of self-powered sensors that can be worn on the skin directly without packaging because of their breathability, conformability, and sensitivity to collect biomechanical energy. However, high humidity on the skin can affect the wearable TENG output performance, substantially affecting the sensor performance and stability. When worn for a long time, humidity can even cause skin inflammation. Thus, for a wearable TENG, moisture control and biocompatibility are also key factors that need to be addressed. Herein, we report a hygroscopic and biocompatible paper-based TENG using a hydroxyapatite (HAP) mineral coating to enhance the paper fiber. The mineral coating can maintain the surface of the paper fiber, which will not cause large external deformation of the paper fiber under a force, avoid squeezing out excess water, and keep the friction surface dry, avoiding humidity affecting the output performance. Without interfering with the performance of the TENG, the maximum water absorption of the HAP composite paper is ∼8 μL. The HAP composite paper–based TENG (4 cm2) has an open-circuit voltage and short-circuit current 5.8 times and 4.2 times that of pure paper, respectively, and can obtain 80.4 mW/m2 output and directly light 117 LEDs. At relative humidity values of 25.7 %, 43.1 %, and 58.8 %, the performance retained the peak values of 80.2 %, 68 %, and 63.7 %, respectively. Even at a high relative humidity of 71.7 %, the triboelectric performance of HAP composite paper is retained 59.3 %, and the stability under humidity is better than that of pure paper (45.6 %). In addition, the mineral paper can even work with tissue fluid and output performance decreases by 43.8 %. The mineral-enhanced paper TENG with high power generation performance, hygroscopicity, biocompatibility, and degradability provides a new perspective for disposable wearable sensors, even in medical treatment. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
134. Preparation of high-solid PLA waterborne dispersions with PEG-PLA-PEG block copolymer as surfactant and their use as hydrophobic coating on paper.
- Author
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Calosi, Matteo, D'Iorio, Andrea, Buratti, Elena, Cortesi, Rita, Franco, Silvia, Angelini, Roberta, and Bertoldo, Monica
- Subjects
- *
XANTHAN gum , *DISPERSION (Chemistry) , *SURFACE energy , *GEL permeation chromatography , *SURFACE coatings , *SURFACE active agents - Abstract
Paper-based packaging is experiencing a resurgence due to its inherent biodegradability and recyclability. To meet the barrier properties required for certain applications, a coating is necessary. This coating must enhance functionality without compromising the environmental sustainability of the substrate. With this goal in mind, we prepared waterborne dispersions of biodegradable poly(lactic acid) (PLA) using a PEG-PLA-PEG triblock copolymer as the main surfactant. We achieved formulations with good stability over a 6-month period and high solids content (∼40 wt%). The waterborne dispersions underwent analysis by dynamic light scattering (DLS), size exclusion chromatography (SEC), gravimetric tests, and rotational rheology with and without xanthan gum (0.2–0.8 wt%) as a thickener. Subsequently, the thickened dispersions were coated at 60 °C onto a paper substrate. SEM analyses revealed the formation of a polymer layer on the paper surface with thickness and morphology dependent on the processing conditions. Partial interpenetration between the coating and the paper fibers was observed, resulting in excellent adhesion between the layers. The coated paper exhibited good barriers to liquid and water vapor, with Cobb60 < 5 g/m2 and water vapor transmission rate (WVTR) < 100 g/(m2∙day) for coating weights ≤15 g/m2, comparable to the performance of solvent-based PLA paper coatings. The surface energy of the coating was approximately 50 dyne/cm, higher than that of neat PLA, making it suitable for printing with common inks. Furthermore, the coated paper can be fully pulped in water, indicating that it can still be recycled in the paper stream, albeit with potentially increased processing time due to the coating weight. [Display omitted] • A PEG-PLA-PEG block copolymer was proven to stabilize waterborne PLA dispersions. • Dispersions with 40 % solid content were obtained. • The dispersions thickened with xanthan gum were successfully coated on paper at 60 °C. • PLA-coated paper had similar water barrier properties to its oil-based counterpart. • Repulping of PLA-coated paper is possible but slower than for uncoated paper. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
135. Paper-based optical sensor arrays for simultaneous detection of multi-targets in aqueous media: A review.
- Author
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Mohan, Binduja, Sasaki, Yui, and Minami, Tsuyoshi
- Subjects
- *
SENSOR arrays , *OPTICAL sensors , *ELECTRONIC noses , *ENVIRONMENTAL monitoring , *IMAGE analysis , *FOOD safety , *SPECTROPHOTOMETERS - Abstract
Sensor arrays, which draw inspiration from the mammalian olfactory system, are fundamental concepts in high-throughput analysis based on pattern recognition. Although numerous optical sensor arrays for various targets in aqueous media have demonstrated their diverse applications in a wide range of research fields, practical device platforms for on-site analysis have not been satisfactorily established. The significant limitations of these sensor arrays lie in their solution-based platforms, which require stationary spectrophotometers to record the optical responses in chemical sensing. To address this, this review focuses on paper substrates as device components for solid-state sensor arrays. Paper-based sensor arrays (PSADs) embedded with multiple detection sites having cross-reactivity allow rapid and simultaneous chemical sensing using portable recording apparatuses and powerful data-processing techniques. The applicability of office printing technologies has promoted the realization of PSADs in real-world scenarios, including environmental monitoring, healthcare diagnostics, food safety, and other relevant fields. In this review, we discuss the methodologies of device fabrication and imaging analysis technologies for pattern recognition-driven chemical sensing in aqueous media. [Display omitted] • Cross-reactive sensors are applied to paper-based arrays for simultaneous detection. • Portable digital recorders can be used for detecting various responses. • Imaging analysis techniques can accelerate accurate data processing. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
136. Polyvinyl chloride coated paper postmodified by nucleophilic substitution with diphenylamine to enhance cation-π interactions with opioids in saliva samples.
- Author
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Pedraza-Soto, Ana M., Calero-Cañuelo, Carlos, Lucena, Rafael, and Cárdenas, Soledad
- Subjects
- *
DIPHENYLAMINE , *OPIOIDS , *POLYVINYL chloride , *SALIVA , *REFLECTANCE spectroscopy , *MASS spectrometry , *ALKALOIDS - Abstract
[Display omitted] • PVC-diphenylamine modified cellulose was proposed as sorptive phase. • The synthesis, using the dip-coating technique, is simple and cost-effective. • Opioids interact with the membrane by a mixed-mode interaction. • Direct infusion mass spectrometry allows to reduce the time of analysis. • The approach was successfully applied to real saliva samples containing codeine and tramadol. This article evaluates the potential of cellulose paper as a substrate for preparing a polyvinylchloride (PVC)-diphenylamine sorptive phase that can be used under the thin film microextraction (TFME) format. This phase was easily synthesized using the dip-coating technique to coat the filter paper with PVC, followed by the covalent bonding of diphenylamine. As a result, aromatics rings are available on paper surface to isolate the target analytes by a mixed-mode interaction at physiological pH. The resulting material was characterized by infrared spectroscopy, UV–Vis diffuse reflection spectroscopy, and scanning electron microscopy. As analytical problem, three opioids (methadone, codeine, and tramadol) were determined in saliva samples by direct infusion mass spectrometry. Different variables involved in the extraction procedure have been optimized (e.g. sample pH, extraction time, and sample dilution). The proposed method provides good linearity (R2 > 0.9817) and sensitivity (detection limits in the range from 1.5 µg L−1 to 15 µg L−1). The intra-day and inter-day precision, expressed as relative standard deviation, were better than 16.4 % and 18.5 % respectively. The accuracy, expressed as relative recovery, provides values in the interval from 82 % to 105 %. Finally, the proposed approach has been successfully applied to real saliva samples of patients under codeine and tramadol medical prescription. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
137. Porous lignin-based composites for oil/water separation: A review.
- Author
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He, Zhiwei, Wang, Mingkun, and Ma, Shiyu
- Subjects
- *
LIGNINS , *ETHANOL as fuel , *OIL spills , *FOOD chains , *OIL fields , *INDUSTRIAL wastes , *HUMAN beings - Abstract
Frequent oceanic oil spill incidents and the discharge of industrial oily wastewaters have caused serious threats to environments, food chains and human beings. Lignin wastes with many reactive groups exist as the byproducts from bioethanol and pulping processing industries, and they are either discarded as wastes or directly consumed as a fuel. To make full use of lignin wastes and simultaneously deal with oily wastewaters, porous lignin-based composites have been rationally designed and prepared. In this review, recent advances in the preparation of porous lignin-based composites are summarized in terms of aerogels, sponges, foams, papers, and membranes, respectively. Then, the mechanisms and the application of porous lignin-based adsorbents and filtration materials for oil/water separation are discussed. Finally, the challenges and perspectives of porous lignin-based composites are proposed in the field of oil/water separation. The utilization of abundant lignin wastes can replace fossil resources, and meanwhile porous lignin-based composites can be used to efficiently treat with oily wastewaters. The above utilization strategy opens an avenue to the rational design and preparation of lignin wastes with high-added value, and gives a possible solution to use lignin wastes in a sustainable and environmentally friendly way. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
138. Physics informed neural networks reveal valid models for reactive diffusion of volatiles through paper.
- Author
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Serebrennikova, Alexandra, Teubler, Raimund, Hoffellner, Lisa, Leitner, Erich, Hirn, Ulrich, and Zojer, Karin
- Subjects
- *
DIFFUSION , *PARTIAL differential equations , *CHEMICAL reactions , *POROUS materials , *PHYSICS , *VOLATILE organic compounds - Abstract
Predictive models for the transport of volatile organic compounds in paper need to consider the complex interplay of diffusion, adsorption, desorption, or chemical reactions. The relative importance of each of these processes is determined by the polarity of the volatile. Hence, it is challenging to pick a valid theoretical model that correctly predicts transport regardless of the polarity. Here, physics-informed neural networks (PINNs) assess which of five different models correctly describe transport of DMSO as polar and n-tetradecane as apolar model compound: (i) a pseudo first-order adsorption model for an irreversible sorption process, (ii) a first-order kinetics model allowing reversible sorption, (iii) a second-order model with a reversible process, and an effective diffusion model accounting for a constant (iv) and for a variable effective diffusivity (v). Each tested model is given as set of partial differential equations (PDE). Considering the model under testing and experimentally obtained spatially and temporally resolved concentration profiles through stacks of paper sheets, PINNs predict concentration of the volatiles and associated material constants such as sorption constants and effective diffusion coefficients by solving the inverse problem. Our PINNs revealed two models, pseudo first-order sorption and second-order reversible sorption, that correctly predict concentration profiles and polarity-driven differences in sorption times. While a PINN-based picking of valid transport models has important implications for the development of effective methods for controlling emission of volatiles from paper materials, PINNs represent a versatile mathematical tool to validate or refute the capability of PDE-based theoretical models to describe experimental data. • PINNs evaluate sorption kinetics in porous materials. • Focus: Transport of organic volatiles in cellulose. • Pseudo first-order model suits organic volatiles. • Predicting transport of volatiles through paper. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
139. Lightweight honeycomb furniture panels with discreetly located strengthening blocks.
- Author
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Smardzewski, Jerzy and Tokarczyk, Maciej
- Abstract
[Display omitted] • Honeycomb panels with discrete arranged block reinforcements were numerically designed. • The elastic moduli of the new honeycomb panels are higher than those of heavier panels with slatted. • Tables with new cellular panels are characterized by a stiffness of 85 % of the stiffness of heavier tables with slats. Furniture manufacturers indicate they know the benefits of lightweight honeycomb panels but still expect their higher mechanical properties. This work presents a numerical and experimental approach to designing new tables manufactured of paper honeycomb panels with discreetly arranged reinforcing blocks in the core. The main goal was to determine whether the discrete arrangement of the blocks affects the strength and amount of energy absorbed by the newly designed tables and stiffness of honeycomb panels. Optimization reduced the weight of the panels by up to 30 %. At the same time, their linear elastic modulus was increased from 1579 MPa to 1771 MPa. After ten load cycles, tables with discrete reinforcements have a stiffness up 86.85–87.20 % of the stiffness of the reference table. After destructive tests up 89.96–91.16 %. Ultimately, the test results demonstrate the effectiveness of replacing wide slats with discreetly placed reinforcing blocks in the core structure. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
140. Love Song.
- Subjects
- *
ACRYLIC painting , *PAPER - Published
- 2024
141. Liquid uptake in porous cellulose sheets studied with UFI-NMR: Penetration, swelling and air displacement.
- Author
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Nicasy, R.J.K., Waldner, C., Erich, S.J.F., Adan, O.C.G., Hirn, U., and Huinink, H.P.
- Subjects
- *
DARCY'S law , *POROUS materials , *FILM flow , *MAGNETIC resonance imaging , *CELLULOSE , *CELLULOSE fibers , *FOAM - Abstract
Liquid penetration in porous cellulosic materials is crucial in many technological fields. The complex geometry, small pore size, and often fast timescale of liquid uptake makes the process hard to capture. Effects such as swelling, vapor transport, film flow and water transport within cellulosic material makes transport deviate from well-known relations such as Lucas-Washburn and Darcy's Law. In this work it is demonstrated how Ultra-Fast Imaging NMR can be used to simultaneously monitor the liquid distribution and swelling during capillary uptake of water with a temporal- and spatial resolution of 10 ms and 14.5–18 μm respectively. The measurements show that in a cellulose fiber sheet, within the first 65 ms, liquid first penetrates the whole sheet before swelling takes place for another 30 s. Furthermore, it was observed that the liquid front traps 15 v% of air which is slowly replaced by water during the final stage of liquid uptake. Our method makes it possible to simultaneously quantify the concentration of all three phases (solid, liquid and air) within porous materials during processes exceeding 50 ms (5 times the temporal resolution). We hence believe that the proposed method should also be useful to study liquid penetration, or water diffusion, into other porous cellulosic materials like foams, membranes, nonwovens, textiles and films. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
142. On the development of a high strain-rate tensile testing method for thin low-impedance materials.
- Author
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Baumann, Georg, Czibula, Caterina, Hirn, Ulrich, and Feist, Florian
- Subjects
- *
TENSILE tests , *DIGITAL twins , *TEST methods , *FINITE element method - Abstract
• An attempt to characterize thin, low impedance paper at various high strain-rates. • The creation of a digital twin of the physical Split Hopkinson Test bench. • To demonstrate that there can be distortions of the transmitted measuring signal. This work deals with the high strain-rate characterization of paper under uniaxial tension using a Split Hopkinson test bench. An aluminum bar system featuring a highly sensitive hollow transmission bar was used. Paper tests were performed in a strain-rate range between approximately 60 s−1 and 210 s−1. The experimental tests showed that the breaking strength appears to decrease with increasing strain-rate. To verify these results, a digital twin of both the paper specimen and the entire test rig was created in an explicit Finite Element method environment. The numerical model was then used to perform a parameter study with different types of transmission bars. It was shown that the system is quite sensitive to additional masses caused by the specimen fixtures, as well as to drastic reductions in the cross section of the transmission bar. As a result, the transmitted measuring signal can be distorted and may need to be corrected using the digital twin. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
143. Paper-based fluorescent materials containing on-demand nanostructured brain-cells-inspired AIE self-assembles for real-time visual monitoring of seafood spoilage.
- Author
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Chen, Lijuan, Luo, Xiaomin, Wang, Xuechuan, Ning, Lulu, Li, Nihao, Zhao, Suqiu, Zhang, Qian, Liu, Xinhua, and Jiang, Huie
- Subjects
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FOOD spoilage , *SEAFOOD , *BIOGENIC amines , *DETECTION limit , *SMARTPHONES , *DAYLIGHT - Abstract
[Display omitted] • Molecular-level light-emitting origins were strategically imparted to paper. • The morphology of AIE self-assembly can be adjusted on demand. • AFP-FP exhibited high selectivity, sensitivity and repeatable recognition of NH 3. • AFP-FP integrated with smartphone realized the visual food spoilage monitoring. Biogenic amines containing NH 3 are important indicators for conducting full-scale appraisal of food spoilage and disease diagnosis. However, the currently-used detection methods of NH 3 have several limitations such as time-consuming high cost, and inability to provide visual real-time monitoring. Therefore, researchers have attempted to explore strategies for quantitative real-time monitoring of NH 3 for food spoilage has attracted widespread attentions. Herein, we developed sustainable, fast response, hypersensitized, user-friendly and molecular-level light-emitting biomass-based materials (AFP-FP) containing on-demand nanostructured brain-cells-inspired aggregation-induced-emission (AIE) self-assembles for real-time visual monitoring of seafood spoilage. The 2-hydroxy-5-methyl-isophthalaldehyde-based AIE probe (AFP) was synthesized using a simple "one-step" route. AFP-FP exhibited high selectivity, sensitivity, repeatable and quantitative recognition (y = 7.292×103x + 7.621×104, R = 0.990) of NH 3 with a low detection limit (246 ppb) and fast response (<1 s). Furthermore, we integrated AFP-FP into a user-friendly smartphone color recognition app, enabling its practical application in visual, real-time daylight monitoring of food spoilage. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
144. Long term curl of printing paper due to ink solvent migration.
- Author
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Maass, Alexander and Hirn, Ulrich
- Subjects
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INK , *HIGH performance liquid chromatography - Abstract
[Display omitted] • For the first time the root cause for paper curl developing over days and weeks is described. • The curl of the paper sheets is caused by migration of co-solvents (e.g., glycerol) from the inkjet ink. • A 2D-laser scanner is utilized to investigate short- and long-term paper curl. • Glycerol migration in paper sheets is monitored using a combination of sheet splitting and subsequent HPLC analysis. The dimensional stability of paper during printing is crucial for ensuring production quality and runnability. However, inkjet printing faces inherent challenges due to the hygroscopic nature of paper and the use of water-based inks. Despite freshly printed sheets are flat, a considerable development of paper curl is often observed during storage. In this study, we establish the link between the migration of ink co-solvents and the long-term curl development of printed paper. A4 paper sheets were sprayed with a water-glycerol model ink and changes in the sheet's curvature were monitored using a 2D-laser sensor. We also investigated glycerol migration by splitting the sheets into layers and determining the glycerol distribution using high-performance liquid chromatography. Our results demonstrate the development of curl during storage as well as glycerol migration in thickness direction of the sheet, both on a comparable timescale. We thus propose that long term curl in inkjet printing can be caused by z-directional migration of the co-solvent (glycerol) over time. This study enhances understanding of the physical mechanisms that drive the long-term curl phenomenon in inkjet-printed sheets. The results can be used to optimize printing processes, allowing for the production of higher quality printed products with greater dimensional stability. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
145. Development of the viscosity biosensor for the detection of DNase I based on the flow distance on the paper with DNA mucus.
- Author
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Li, Xia, Duan, Qing, Khan, Mashooq, Yang, Danhong, Liu, Qian, Yin, Fangchao, Hu, Qiongzheng, and Yu, Li
- Subjects
- *
MUCUS , *VISCOSITY , *DNA , *BIOSENSORS , *DETECTION limit - Abstract
Deoxyribonuclease I (DNase I) is a biomarker which has important applications in various biological processes. Thus, it is highly important to develop a user-friendly method for the detection of DNase I. Here, we present a paper-based distance sensor for the rapid detection of DNase I based on changes in the viscosity of DNA mucus. The viscosity of DNA mucus varies with different concentrations of DNase I, showing different water flow lengths on the pH test papers, this makes the quantification of DNase I possible. This method has a wide linear range (0.01–10 U/mL), excellent sensitivity, remarkable specificity and excellent reproducibility. The detection limit reaches 0.003 U/mL. Additionally, it can be well applied to detection of DNase I inhibitors, assay of DNase I in human serum and quality evaluation of nucleic acid scavengers. In general, this study offers a brief, convenient, label-free, and economical method to construct paper-based distance sensors using DNA mucus, which is very promising in the detection of DNase I in various applications. [Display omitted] • The paper-based sensor detects DNase I by distance signal. • The new method for detecting DNase I based on viscosity changes. • The detection limit for DNase I is 0.003 U/mL. • The sensor shows excellent specificity, remarkable practicality and portability. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
146. Robust, ultrathin and flexible electromagnetic interference shielding paper designed with all-polysaccharide hydrogel and MXene.
- Author
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Wei, Jiasheng, Dai, Lei, Xi, Xiangju, Chen, Zhuo, Zhu, Meng, Dong, Cuihua, Ding, Shujiang, and Lei, Tingzhou
- Subjects
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ELECTROMAGNETIC interference , *ELECTROMAGNETIC shielding , *GUAR gum , *SURFACE preparation , *FILTER paper , *POLYDIMETHYLSILOXANE - Abstract
An effective strategy was demonstrated to design an electromagnetic interference (EMI) shielding paper via a facile surface treatment on paper. TEMPO-oxidized cellulose nanofibers (TOCN) were first integrated with Ti 3 C 2 T x MXene, and subsequently cast onto a filter paper with cationic guar gum (CGG) in a sequential way. TOCN and CGG generated a self-assembling hydrogel and formed a MXene-containing hydrogel film on top of the filter paper. The hydrogel film enhanced the tensile strength (9.49 MPa) of composite paper, and resulted in a 17 % increase as compared to the control. The composite paper containing 80 mg MXene (namely, 2.07 mg·cm−2) showed a conductivity of 3843 S·m−1 and EMI shielding effectiveness (EMI SE) of 49.37 dB. Furthermore, the 2-layer assembled TC-M 80 hydrogel composite paper achieved an EMI SE of 73.99 dB. Importantly, this composite paper showed higher EMI SE and lower thickness than a lot of reported materials. The presence of TOCN and CGG also protected MXene against several solvents and the incorporation of polydimethylsiloxane (PDMS) further improved the durability of the composite paper. This work provides a novel and simple strategy to design robust, ultrathin and flexible EMI shielding materials, and it might also inspire other work in paper-based functional materials. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
147. Role of intrinsic and extrinsic xylan in softwood kraft pulp fiber networks.
- Author
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Schaubeder, Jana B., Spirk, Stefan, Fliri, Lukas, Orzan, Eliott, Biegler, Veronika, Palasingh, Chonnipa, Selinger, Julian, Bakhshi, Adelheid, Bauer, Wolfgang, Hirn, Ulrich, and Nypelö, Tiina
- Subjects
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SULFATE pulping process , *PLANT cell walls , *FIBERS , *SOFTWOOD , *PAPERMAKING - Abstract
Xylan is primarily found in the secondary cell wall of plants providing strength and integrity. To take advantage of the reinforcing effect of xylan in papermaking, it is crucial to understand its role in pulp fibers, as it undergoes substantial changes during pulping. However, the contributions of xylan that is added afterwards (extrinsic) and xylan present after pulping (intrinsic) remain largely unexplored. Here, we partially degraded xylan from refined bleached softwood kraft pulp (BSKP) and adsorbed xylan onto BSKP. Enzymatic degradation of 1 % xylan resulted in an open hand sheet structure, while adsorption of 3 % xylan created a denser fiber network. The mechanical properties improved with adsorbed xylan, but decreased more significantly after enzymatic treatment. We propose that the enhancement in mechanical properties by adsorbed extrinsic xylan is due to increased fiber-fiber bonds and sheet density, while the deterioration in mechanical properties of the enzyme treated pulp is caused by the opposite effect. These findings suggest that xylan is decisive for fiber network strength. However, intrinsic xylan is more critical, and the same properties cannot be achieved by readsorbing xylan onto the fibers. Therefore, pulping parameters should be selected to preserve intrinsic xylan within the fibers to maintain paper strength. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
148. Visual distance-based paper analytical device for on-site detection of Pb(II).
- Author
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Zhang, Yuan, Qian, Lelin, Yu, Zhangli, Yu, Ying, Feng, Chang, Niu, Lili, and Zhang, Juan
- Subjects
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RESOURCE-limited settings , *METAL detectors , *DETECTION limit , *CATALYTIC activity , *DEOXYRIBOZYMES - Abstract
[Display omitted] • An visual distance-based paper analytical device has been developed for on-site detection of Pb(II). • Pb(II) can inhibit the catalytic activity of G4/hemin DNAzyme induced by K+. • The biosensor can sensitively detect Pb(II) with a lowest detection limit of 1 nM. • The biosensor can be applied to detect Pb(II) in real samples. A simple, inexpensive, fast, and visual distance-based paper analytical device has been developed for on-site detection of Pb(II). Pb(II) can inhibit the catalytic activity of G-quadruplex/hemin (G4/hemin) DNAzyme induced by K+, which catalyzes 3,3,5,5-tetramethyl benzidine (TMB) immobilized on paper to produce a visible blue band. The factors affecting Pb(II) detection have been optimized with PS concentration of 3 μM, K+ concentration of 10 mM, and hemin concentration of 10 μM, as well as the straight channel width of 2.0 mm. It can be well found that the formed length correlates with the concentration of Pb(II) with a linear detection range of 0.02 μM − 50 μM. A fitting linear equation of Y = 20.793–5.391Log C (R2 = 0.9788) can be obtained with a lowest detection limit of 1 nM. Additionally, the method is capable of selectively detecting Pb(II) and works well for Pb(II) detection in real samples. Overall, the visual distance-based paper analytical device offers an ideal platform for on-site detection of heavy metal ions, especially in resource-limited areas. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
149. Writing from nothing (or very little).
- Author
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Esaias, Timons
- Subjects
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NARRATIVE art , *TIMER switches , *VOCABULARY , *PAPER - Abstract
The article presents the author's view on one of the methods he uses is to do a 10-minute or 20-minute for writing exercise, he says one needn't have more than 15 or 20 words on paper, but have the essence of a story, a Person in a place with a Problem, than set a timer for the length of the exercise and go.
- Published
- 2022
150. Looted Libraries and Legitimation Policies: Ptolemy, the Library of al-Arawšī and the Translation Movement in Toledo.
- Author
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Bellver, José
- Subjects
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MARGINALIA , *LIBRARIES , *COPYING , *TRANSLATING & interpreting , *FLAX , *CULTURAL transmission - Abstract
MS Tunis, Dār al-kutub al-waṭaniyya, 7116, is the only extant manuscript containing a complete copy of the Isḥāq/Ṯābit version of the Almagest. Paul Kunitzsch has underlined the close similarities between the marginal notes in the Tunis manuscript and those in Gerard of Cremona's Latin translation of the Almagest , so that Kunitzsch has concluded that Gerard of Cremona had a manuscript close to the Tunis manuscript before him during the revision of his translation of the Almagest. A note in MS Tunis, Dār al-kutub al-waṭaniyya, 7116, points out that this manuscript was copied from a model owned by al-Arawšī, a bibliophile living in Valencia famous for the size of his library, a significant part of which was looted by al-Maʾmūn b. Ḏī l-Nūn and sent to Toledo, arguably shortly before Ṣāʿid al-Andalusī wrote his Ṭabaqāt al-umam. Based on MS Tunis, Dār al-kutub al-waṭaniyya, 7116, the present contribution explores the significance of al-Arawšī's looted library as an important link between Umayyad Cordoba and Toledo. It also calls attention to the highly unusual paper of MS Tunis, Dār al-kutub al-waṭaniyya, 7116, made of woven fibers, maybe flax. Résumé: Le manuscrit de Tunis, Dār al-kutub al-waṭaniyya, 7116, est le seul manuscrit existant contenant une copie complète de la version d'Isḥāq/Ṯābit de l' Almageste. Paul Kunitzsch souligna les fortes similitudes entre les notes marginales du manuscrit de Tunis et celles de la traduction latine de l' Almageste par Gérard de Crémone, de sorte qu'il conclut que Gérard de Crémone avait devant lui un manuscrit proche du manuscrit de Tunis lors de la révision de sa traduction de l' Almageste. Une note dans le manuscrit de Tunis, Dār al-kutub al-waṭaniyya, 7116, signale que ce manuscrit a été copié d'après un modèle appartenant à al-Arawšī, un bibliophile vivant à Valence et célèbre pour la taille de sa bibliothèque, dont une importante partie fut pillée par al-Maʾmūn b. Ḏī l-Nūn et envoyée à Tolède, sans doute peu avant que Ṣāʿid al-Andalusī ne rédige ses Ṭabaqāt al-umam. S'appuyant sur le manuscrit de Tunis, Dār al-kutub al-waṭaniyya, 7116, la présente contribution explore l'importance de la bibliothèque pillée d'al-Arawšī comme lien essentiel entre la Cordoue omeyyade et Tolède. Elle porte également une attention particulière au papier très inhabituel du manuscrit de Tunis, Dār al-kutub al-waṭaniyya, 7116, fait de fibres tissées, peut-être du lin. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
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