413 results on '"Kelley, Simon P."'
Search Results
152. Mineralogy and 40Ar/39Ar geochronology of orangeites (Group II kimberlites) from the Damodar Valley, eastern India
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Kent, Ray W., primary, Kelley, Simon P., additional, and Pringle, Malcolm S., additional
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- 1998
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153. Preliminary UVLAMP determinations of argon partition coefficients for olivine and clinopyroxene grown from silicate melts
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Brooker, Richard A, primary, Wartho, J-A, additional, Carroll, Michael R, additional, Kelley, Simon P, additional, and Draper, David S, additional
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- 1998
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154. Exhumation of blueschists along a Tethyan suture in northwest Turkey
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Okay, Aral I., primary, Harris, Nigel B.W., additional, and Kelley, Simon P., additional
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- 1998
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155. A late Triassic age for the Rochechouart impact structure, France
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KELLEY, SIMON P., primary and SPRAY, JOHN G., additional
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- 1997
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156. Laser probe argon-40/argon-39 dating of coesite- and stishovite-bearing pseudotachylytes and the age of the Vredefort impact event
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Spray, John G., primary, Kelley, Simon P., additional, and Reimold, W. Uwe, additional
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- 1995
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157. Metamorphic rocks seek meaningful cooling rate: Interpreting 40Ar/39Ar ages in an exhumed ultra-high pressure terrane
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Warren, Clare J., Kelley, Simon P., Sherlock, Sarah C., and McDonald, Christopher S.
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METAMORPHIC rocks , *HIGH pressure geosciences , *MUSCOVITE , *ARGON , *GNEISS , *COOLING power (Meteorology) , *METAMORPHISM (Geology) - Abstract
Abstract: 40Ar/39Ar dating of metamorphic white mica is commonly used to elucidate the timing of cooling and/or exhumation of metamorphic terranes. In theory, so long as the dated mineral originally crystallised above its closure temperature, the yielded 40Ar/39Ar ages should not vary significantly within or between samples, and should vary only due to grain size (~3Ma variation depending on the estimated cooling rate). Infra-red laser single grain fusion and ultra-violet laser spot muscovite and/or phengite data from mafic eclogite bodies and their host gneisses in the Nordfjord region of the Western Gneiss Complex (WGC), Norway, show that the ages yielded both within and between white micas from the same mafic eclogite sample vary by up to 284Ma. Ages yielded within the same pelitic gneiss sample vary by up to 28Ma. Overall the 40Ar/39Ar phengite dates from mafic eclogites range from ~750 to 440Ma and are significantly older than the previously reported 405–400Ma U–Pb zircon age constraining peak metamorphism in the Nordfjord WGC. The felsic host gneiss samples, which recrystalised during a post-peak, exhumation-related, amphibolite-facies overprint, yield single grain fusion and laser spot 40Ar/39Ar white mica dates spanning ~420 to 385Ma, encompassing previous estimates of the timing of the entire metamorphic cycle. These data suggest that Ar is heterogeneously distributed both within grains and between grains on the cm to sub-mm scale in all samples, and imply restricted Ar transport and inefficient removal during the metamorphic cycle. Open system (zero grain boundary Ar concentration) behaviour is an inherent assumption in the commonly applied closure temperature formulation, but unless this can be demonstrated, linking 40Ar/39Ar ages to temperature is no longer trivial. The high spatial and chronological precision afforded by UV laser ablation mean that intra-grain Ar concentration distributions may be used to assess open vs. closed system behaviour. The data presented here suggest that open system behaviour cannot be assumed in metamorphic systems, even those in which the pressure, temperature and time conditions in theory allow for efficient diffusion during the metamorphic cycle. High spatial resolution 40Ar/39Ar data and robust comparison with numerical models of open system behaviour provide the greatest future potential for unravelling the complexities of metamorphic exhumation timescales. [Copyright &y& Elsevier]
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- 2012
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158. Australian Residential Solar Feed-in Tariffs: Industry Stimulus or Regressive form of Taxation?
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Nelson, Tim, Simshauser, Paul, and Kelley, Simon
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TAXATION ,PHOTOVOLTAIC power systems ,SOLAR technology ,JURISDICTION ,MONETARY incentives ,RENEWABLE energy sources - Abstract
Feed-in Tariffs (FiT) for residential photovoltaic solar technologies are available in most Australian jurisdictions. Financial incentives under FiT are in addition to those provided by the Small-Scale Renewable Energy Scheme which forms part of the national 20% Renewable Energy Target. Little attention has been paid to the welfare impacts of FiT on retail electricity prices and social policy objectives. Our analysis indicates that current FiT are a regressive form of taxation. By providing estimates of household impact by income groupings, we conclude that wealthier households are beneficiaries and the effective taxation rate for low income households is three times higher than that paid by the wealthiest households. [ABSTRACT FROM AUTHOR]
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- 2011
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159. Mineralogy, geochemistry, and 40Ar–39Ar geochronology of lunar granulitic breccia Northwest Africa 3163 and paired stones: Comparisons with Apollo samples
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Hudgins, Jillian A., Kelley, Simon P., Korotev, Randy L., and Spray, John G.
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LUNAR petrology , *MINERALOGY , *GEOCHEMISTRY , *ARGON , *GEOLOGICAL time scales , *METEORITES , *PYROXENE - Abstract
Abstract: The lunar meteorites Northwest Africa (NWA) 3163, 4881, and 4483 are paired stones classified as granulitic breccias. At 2.4kg, these three stones constitute one of the largest known lunar meteorite masses. Here we describe the petrography, mineralogy, and chemistry of NWA 3163, 4881, and 4483, and present 40Ar–39Ar data for two of the meteorites. Two-pyroxene thermometry indicates that the rocks equilibrated at 1050±50°C, which represents the high-temperature, low-pressure event that generated their characteristic recrystallization textures and reset their Ar systematics. Stepped-heating, in situ infrared laser microprobe 40Ar–39Ar geochronology yields a mean age of 3327±29Ma for NWA 3163, and a more disturbed release spectrum for NWA 4881. NWA 4881 shows an upward-trending pattern, suggesting that it may have had a 40Ar–39Ar age of >3.0Ga, but that it was partially reset at ∼2.6Ga. NWA 3163 et al. exhibit shock effects, including maskelynitized plagioclase, shock veins, and melt pockets, which are absent in the Apollo granulitic breccias. Although the Apollo and meteorite samples are texturally similar and have comparable bulk compositions and equilibration temperatures, their trace and siderophile element contents point to distinct parental lithologies derived from different regions of the Moon. Based on mineralogical and geochemical differences between the Apollo and meteorite samples, we conclude that the parent rock(s) of the paired NWA meteorites came from an area outside the Imbrium region and that they underwent high-temperature (granulite event) metamorphism long after the Late Heavy Bombardment. [Copyright &y& Elsevier]
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- 2011
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160. Causes and effects of geochemical variations in late Cenozoic volcanism of the Foca volcanic centre, NW Anatolia, Turkey.
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Altunkaynak, Şafak, Rogers, Nick W., and Kelley, Simon P.
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VOLCANISM ,MIOCENE stratigraphic geology ,VOLCANIC fields ,GRABENS (Geology) ,TRACHYANDESITE ,RHYOLITE ,IGNIMBRITE ,PHONOLITE ,CRYSTALLIZATION - Abstract
The Foca volcanic centre (FVC) occupies a NNE-SSW-oriented highland between two EW-trending structural grabens in western Anatolia, and includes early-middle Miocene mafic and felsic extrusive suites. Its evolutionary history consists of an older volcano stage (16.6-16.1 Ma) and a younger volcano stage (15.2-14.1 Ma), which are characterized by different eruption styles and compositional and geochemical features. The older units include high-K calc-alkaline basalt, andesite, trachyandesite, rhyolite, and associated pyroclastic rocks, which formed during ignimbrite eruptions and plinian-subplinian air-fall episodes. The younger sequences are composed of shoshonitic-alkaline basalt lavas and dikes, trachytes, phonolites, and phonolitic ignimbrites that formed strombolian cones. The Foca volcanic rocks display high initial 87Sr/86Sr ratios (0.7075-0.7082 for the calc-alkaline mafic lavas, 0.7073-0.7064 for calc-alkaline felsic lavas, and 0.7063-0.7075 for the alkaline series) and low 143Nd/144Nd (0.5123-0.5125 in both series with εNd values varying from - 1.3 to - 6.0). These FVC geochemical features are consistent with those of other volcanic centres in western Anatolia (i.e. Bodrum, Urla-Cumaovası) and on the Aegean islands (i.e. Samos, Patmos, Chios). The geochemical and Sr-Nd isotopic compositions of the Foca volcanic units suggest that both lithospheric and asthenospheric mantle melts were involved in their evolution; however, the mantle lithosphere fingerprint was diminished by the middle Miocene, as the asthenospheric mantle melt input became dominant. These findings, combined with the bimodal character of post-collisional volcanism in the study area, suggest that geochemical variations in the nature of volcanism from calc-alkaline to alkaline and the changes in tectonic regimes through time may have been caused by successive thermal relaxations associated with possible 'piecemeal' removal of the base of subcontinental lithospheric mantle beneath western Anatolia. This interpretation is more plausible than a catastrophic collapse or wholesale delamination of the entire lithospheric mantle. Asthenospheric upwelling caused by this inferred convective thinning provided underplating of mantle-derived magmas, which interacted with the previously metasomatized lithospheric mantle and the overlying crust, resulting in their partial melting and in production of high-K calc-alkaline to mildly alkaline, incompatible element enriched magmas in separate magma chambers in which fractional crystallization occurred. [ABSTRACT FROM AUTHOR]
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- 2010
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161. Shock implantation of Martian atmospheric argon in four basaltic shergottites: A laser probe 40Ar/39Ar investigation
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Walton, Erin L., Kelley, Simon P., and Spray, John G.
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ARGON isotopes , *NEUTRON irradiation , *BASALT , *METEORITES - Abstract
Abstract: Spatially resolved argon isotope measurements have been performed on neutron-irradiated samples of two Martian basalts (Los Angeles and Zagami) and two Martian olivine-phyric basalts (Dar al Gani (DaG) 476 and North West Africa (NWA) 1068). With a ∼50μm diameter focused infrared laser beam, it has been possible to distinguish between argon isotopic signatures from host rock (matrix) minerals and localized shock melt products (pockets and veins). The concentrations of argon in analyzed phases from all four meteorites have been quantified using the measured J values, 40Ar/39Ar ratios and K2O wt% in each phase. Melt pockets contain, on average, 10 times more gas (7–24ppb 40Ar) than shock veins and matrix minerals (0.3–3ppb 40Ar). The 40Ar/36Ar ratio of the Martian atmosphere, estimated from melt pocket argon extractions corrected for cosmogenic 36Ar, is: Los Angeles (∼1852), Zagami (∼1744) and NWA 1068 (∼1403). In addition, Los Angeles shows evidence for variable mixing of two distinct trapped noble gas reservoirs: (1) Martian atmosphere in melt pockets, and (2) a trapped component, possibly Martian interior (40Ar/36Ar: 480–490) in matrix minerals. Average apparent 40Ar/39Ar ages determined for matrix minerals in the four analyzed meteorites are 1290Ma (Los Angeles), 692Ma (Zagami), 515Ma (NWA 1068) and 1427Ma (DaG 476). These 40Ar/39Ar apparent ages are substantially older than the ∼170–474Ma radiometric ages given by other isotope dating techniques and reveal the presence of trapped 40Ar. Cosmic ray exposure (CRE) ages were measured using spallogenic 36Ar and 38Ar production. Los Angeles (3.1±0.2Ma), Zagami (2.9±0.4Ma) and NWA 1068 (2.0±0.5Ma) yielded ages within the range of previous determinations. DaG 476, however, yielded a young CRE age (0.7±0.25Ma), attributed to terrestrial alteration. The high spatial variation of argon indicates that the incorporation of Martian atmospheric argon into near-surface rocks is controlled by localized glass-bearing melts produced by shock processes. In particular, the larger (mm-size) melt pockets contain near end-member Martian atmospheric argon. Based on petrography, composition and argon isotopic data we conclude that the investigated melt pockets formed by localized in situ shock melting associated with ejection. Three processes may have led to atmosphere incorporation: (1) argon implantation due to atmospheric shock front collision with the Martian surface, (2) transformation of an atmosphere-filled cavity into a localized melt zone, and (3) shock implantation of atmosphere trapped in cracks, pores and fissures. [Copyright &y& Elsevier]
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- 2007
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162. Precise dating of low-temperature deformation: Strain-fringe analysis by [sup 40]Ar-[sup 39] Ar laser microprobe.
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Sherlock, Sarah C., Kelley, Simon P., Zalasiewicz, Jan A., Schonfield, David I., Evans, Jane A., Merriman, Richard J., and Kemp, Simon J.
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ROCK deformation , *GRAPTOLITES , *SLATE - Abstract
Pyritized graptolites from the Welsh Basin (United Kingdom) slate belt acted as rigid bodies during cleavage formation, and epizonal white micas formed within the resulting strain shadows, orthogonal to the principal stress orientation. Although the quantities of mica are small, they are a pure synkinematic mineral and have been dated by [sup 40]Ar-[sup 39]Ar infrared laser microprobe as a means to dating cleavage. Four samples of strain-fringe mica from different hand samples yielded ages ranging from 394.4 ± 3.1 to 397.8 ± 1.8 Ma (2σ), with a mean age of 396.1 ± 1.4 Ma (2σ). By focusing on minerals that are unequivocally synkinematic, this technique provides a novel solution to the problems of isotopically dating slaty cleavage. Previous studies have predominantly relied on dating whole-rock slate samples or separated illite grains by [sup 40]Ar-[sup 39]Ar techniques; problems encountered included (1) separating the effects of isotopic contamination by detrital phases, (2) [sup 39]At loss during the irradiation of illite mineral separates, and (3) thermally induced [sup 40]Ar loss in nature from fine-grained minerals. By circumventing these problems, this new method provides the first unequivocal and high-precision age data for Acadian deformation in the well-characterized Welsh Basin slate belt. With such precision, the method may afford geologists the opportunity to track tectonic fronts across orogens and assess the rates of accretion processes in areas that are peripheral to sites of continent-continent collision. [ABSTRACT FROM AUTHOR]
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- 2003
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163. Dating fault-generated pseudotachylytes: comparison of [sup 40]Ar/[sup 39]Ar stepwise-heating, laser-ablation and Rb-Sr microsampling analyses.
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Müller, Wolfgang, Kelley, Simon P., and Villa, Igor M.
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GEOLOGICAL time scales ,LASER ablation ,MINERALOGY ,PETROLOGY - Abstract
Three different geochronological techniques (stepwise-heating, laser-ablation [sup 40]Ar/[sup 39]Ar, Rb-Sr microsampling) have been evaluated for dating fault-generated pseudotachylytes sampled along the Periadriatic Fault System (PAF) of the Alps. Because pseudotachylytes are whole-rock systems composed of melt, clast and alteration phases, chemical control from both Ar isotopes (C1/K, Ca/K ratios) and EMPA analyses is crucial for their discrimination. When applied to stepwiseheating [sup 40]Ar/[sup 39]Ar analyses, this approach yields accurate melt-related ages, even for complex age spectra. The spatial resolution of laser-ablation [sup 40]Ar/[sup 39]Ar analyses is capable of contrasting melt, clast and alteration phases in situ, provided the clasts are not too fine grained, the latter of which results in integrated "mixed" ages without geological information. Elevated C1/K and Ca/K ratios were found to be an invaluable indicator for the presence of clast admixture or inherited [sup 40]Ar. Due to incomplete isotopic resetting during frictional melting, Rb-Sr microsampling dating did not furnish geologically meaningful ages. On the basis of isotopic disequilibria among pseudotachylyte matrix phases, and independent Rb-Sr microsampling dating of cogenetic (ultra)mylonites, the concordant [sup 40]Ar/[sup 39]Ar pseudotachylyte ages are interpreted as formation ages. The investigated pseudotachylytes altogether reveal a Cretaceous to Miocene history for the entire PAF, consistent with independent geological evidence. Individual faults, however, consistently reveal narrower intervals of enhanced activity lasting a few million years. Electronic supplementary material to this paper can be obtained by using the Springer LINK server at http://dx.doi.org/ 10. [ABSTRACT FROM AUTHOR]
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- 2002
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164. A laser probe 40Ar/39Ar investigation of poikilitic shergottite NWA 4797: implications for the timing of shock metamorphism
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Walton, Erin L., Kelley, Simon, Herd, Christopher D. K., and Irving, Anthony J.
- Abstract
Spatially resolved argon isotope measurements have been performed on neutron-irradiated samples of NW Africa (NWA) 4797. Shock heating of NWA 4797 completely melted and vesiculated precursor igneous plagioclase, which cooled to an assemblage of plagioclase crystals with interstitial glasses of variable composition (Ca/K ratios). Using a focused ultraviolet laser beam, is has been possible to distinguish between argon isotopic signatures from groundmass minerals (igneous olivine + pyroxene), plagioclase and a shock vein. This study focuses on the potential for this meteorite to shed light on shock ages of shergottites.Apparent 40Ar/39Ar ages of groundmass minerals show that there are large amounts of excess argon in this phase, yielding a wide range of calculated ages from 690 ± 30 Ma to several apparent ages older than 4.5 Ga. A traverse of laser-probe extractions across the 1 mm-diameter shock vein in NWA 4797 yielded apparent 40Ar/39Ar ages younger than the groundmass. A signature of the Martian atmosphere, identified by 40Ar/36Ar ratios of 1600–1900, was not found in the NWA 4797 shock vein. This is distinct from other shergottites where the products of shock melting contain a nearly pure sample of Martian atmosphere. We attribute this to a distinct formation mechanism, and hence gas-trapping mechanism, of the NWA 4797 shock vein.We undertook 44 analyses of plagioclase areas identified by SEM analysis. Ages ranged from 45 ± 27 to 3771 ± 109 Ma and yield an average age of 375 ± 77 Ma, considerably younger than ages obtained in this study from either the groundmass or the shock vein. A plot of age v. 37Ar/39Ar for plagioclase showed a continuum of ages from the oldest to youngest ages measured. Older ages are correlated with higher Ca/K ratios of plagioclase, indicating contamination from groundmass minerals rich in excess argon. The youngest ages correlate to plagioclase extractions with the lowest Ca/K ratios, interpreted to have crystallized from a nearly pure plagioclase melt with contributions from a K-rich mesostasis. We see no evidence for multiple shock events in NWA 4797. Rather, we favour the interpretation that the cosmic-ray exposure (CRE) age of 3.0±0.5 Ma, obtained on NWA 4797 in this study using cosmogenic 38Ar, approximates the timing of shock melting in this meteorite.Supplementary material:Laser probe argon isotopic data for NWA 4797 obtained in this study are available at http://www.geolsoc.org.uk/SUP18602.
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- 2014
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165. Observation of centimetre-scale argon diffusion in alkali feldspars: implications for 40Ar/39Ar thermochronology
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Flude, Stephanie, Halton, Alison M., Kelley, Simon P., Sherlock, Sarah C., Schwanethal, James, and Wilkinson, Camilla M.
- Abstract
New data from a gem-quality feldspar from Itrongay, Madagascar, record naturally occurring 40Ar/39Ar age profiles which can be numerically modelled by invoking a single diffusion mechanism and show that microtexturally simple crystals are capable of recording complex thermal histories. We present the longest directly measured, naturally produced 40Ar*-closure profiles from a single, homogeneous orthoclase feldspar. These data appear to confirm the assumption that laboratory derived diffusion parameters are valid in nature and over geological timescales. Diffusion domains are defined by crystal faces and ancient cracks, thus in gem-quality feldspars the diffusion domain size equates to the physical grain size. The data also illustrate the potential of large, gem-quality feldspars to record detailed thermal histories over tens of millions of years and such samples should be considered for future studies on the slow cooling of continental crust.Supplementary material:Ar-isotope data, standards and constants used in calculations and irradiation parameters are available at http://www.geolsoc.org.uk/SUP18720.
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- 2014
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166. Ar diffusion and solubility measurements in plagioclases using the ultra-violet laser depth-profiling technique
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Wartho, Jo-Anne, Kelley, Simon P., and Elphick, Stephen C.
- Abstract
We describe the first direct measurements of Ar diffusion and solubility in plagioclases using ultra-violet (UV) laser ablation depth-profiling and noble gas mass spectrometer analyses of experimentally treated (599–1000 °C, 50–200 MPa of Ar) crystal fragments of labradorite and oligoclase. Labradorite 40Ar gain diffusion profiles were measured, yielding an activation energy of 26.72±4.58 kcal mol−1(118.0±19.16 kJ mol−1) and a frequency factor of 9.77×10−9(+8.79×10−8, −8.79×10−9) cm2s−1(95% confidence). The Ar solubility in labradorite was measured yielding a value of <0.2 ppb bar−1, which is similar to or lower than many rock forming minerals.The labradorite diffusion parameters indicate Ar closure temperatures of 211 °C for a spherical diffusion geometry, and 243 °C for a planar diffusion geometry (for 100 µm-diameter grains, with cooling rates of 10 °C Ma−1). The data indicate that labradorite is less Ar retentive than K-feldspar at low temperatures, but more Ar retentive than K-feldspar at high temperatures, corroborating previous work on plagioclase. The relatively slow Ar diffusion rates in labradorite at magmatic temperatures may explain the common observation of older ages in large plagioclase grains in acidic volcanic systems.Supplementary material:Details of the UV laser depth profiles obtained from the labradorite and oligoclase samples used in this study are available at www.geolsoc.org.uk/SUP18608.
- Published
- 2014
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167. Heal Thyself: Using Endogenous Regeneration to Repair Bone
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Alman, Benjamin A., Kelley, Simon P., and Nam, Diane
- Abstract
Bone has the capacity to repair itself after an injury, and this occurs in normal fracture repair. This reparative process can be harnessed to regenerate segments of bone using distraction osteogenesis, in which the healing bone is slowly stretched. The use of animal models is identifying the important sources of cells for this endogenous bone regeneration, signaling molecules that regulate this reparative process, and the environmental cues important for success bone regeneration. A more complete understanding of the cells and pathways involved in this process can be applied to improve the outcome of distraction osteogenesis and to the development of methods to enhance endogenous bone regeneration.
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- 2011
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168. Mantle processes during Gondwana break-up and dispersal
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Hawkesworth, Chris, Kelley, Simon, Turner, Simon, Le Roex, Anton, and Storey, Bryan
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This paper reviews the Mesozoic continental flood basalts (CFBs) associated with the break-up and dispersal of Gondwana from 185-60 Ma, the conditions for melt generation in mantle plumes and within the continental mantle lithosphere, and possible causes for lithospheric extension. The number of CFB provinces within Gondwana is much less than the number of mantle plumes that are likely to have been emplaced beneath it in the 300 Ma prior to its initial break-up. Also, the difference between the age of the peak of CFB volcanism and that of the oldest adjacent ocean crust decreases with the age of volcanism during the break-up and dispersal of Gondwana. The older CFBs of Karoo and Ferrar appear to have been derived largely from source regions within the mantle lithosphere. It is only in the younger Paranâ-Etendeka and Deccan CFBs that there are igneous rocks with major, trace element and radiogenic isotope ratios indicative of melting within a mantle plume. These younger CFBs are also clearly associated with hot spot traces on the adjacent ocean floor. The widespread 180 Ma magmatic event is attributed to partial melting within the lithosphere in response to thermal incubation over 300 Ma. In the case of the Ferrar (Antarctica) this was focussed by regional plate margin forces. The implication is that supercontinents effectively self-destruct in response to the build up of heat and resultant magmatism, since these effects significantly weaken the lithosphere and make it more susceptible to break-up in response to regional tectonics. The younger CFB of Paranâ-Etendeka was generated, at least in part, because the continental lithosphere had been thinned in response to regional tectonics. While magmatism in the Deccan was triggered by the emplacement of the plume, that too may have been beneath slightly thinned lithosphere.
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- 1999
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169. 3-D, 40Ar&z.sbnd;39Ar geochronology in the Parana´ continental flood basalt province
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Stewart, Kathy, Turner, Simon, Kelley, Simon, Hawkesworth, Chris, Kirstein, Linda, and Mantovani, Marta
- Abstract
New 40Ar39Ar analyses of borehole samples from the Parana´-Etendeka continental flood basalt province provide critical evidence of eruption rates in unexposed regions. When combined with surface samples, the new data clarify the duration of this major volcanic province. New ages from both surface and borehole samples confirm a 10–12 million year duration of magmatism, which post-dates the Tithonian mass extinction, and provide a unique 3-dimensional picture of the spatial and temporal eruption of the lava pile. Chemically defined magma types are diachronous and the onset of magmatism occurred 500–1000 km inland, migrating southeast towards the incipient South Atlantic ocean. Calculated eruption rates increased from 0.03 km3 yr−1 between 138 and 135 Ma, through 0.13 km3 yr−1 between 135 and 133 Ma, to 0.21 km3 yr−1 between 133 and 131 Ma, supporting the notion that the rate of magmatism increased with time and proximity to the developing South Atlantic. After 131 Ma the continental eruption rates dropped dramatically to 0.01 km3 yr−1, presumably because rifting had occurred, and eruption centred in the oceanic Rio Grande Rise with eruption rates of around 0.3–0.5 km3 yr−1.Given the available constraints on the potential temperature of the plume, thickness of the continental lithosphere and degrees of extension through time, predicted melt production rates within the plume seriously underestimate the calculated eruption rates on the continent. However, the eruption rates can be reconciled if melting occurred by conductive heating of volatile-enriched mantle. The diachronous nature of the magma types supports the idea that melting occurred over a wide area and that the different magma types reflect different source regions rather than the temporal evolution of magmas from a single source. Given that 10 million years is appropriate to the timescales for conductive heating above the mantle plume, it is suggested that these distinct source regions were located within the lithospheric mantle, consistent with geochemical studies.
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- 1996
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170. Argon behaviour in an inverted Barrovian sequence, Sikkim Himalaya: the consequences of temperature and timescale on 40Ar/39Ar mica geochronology
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Mottram, Catherine M., Warren, Clare J., Halton, Alison M., Kelley, Simon P., Harris, Nigel B. W., Mottram, Catherine M., Warren, Clare J., Halton, Alison M., Kelley, Simon P., and Harris, Nigel B. W.
- Abstract
40Ar/39Ar dating of metamorphic rocks sometimes yields complicated datasets which are difficult to interpret in terms of timescales of the metamorphic cycle. Single-grain fusion and step-heating data were obtained for rocks sampled through a major thrust-sense shear zone (the Main Central Thrust) and the associated inverted metamorphic zone in the Sikkim region of the eastern Himalaya. This transect provides a natural laboratory to explore factors influencing apparent 40Ar/39Ar ages in similar lithologies at a variety of metamorphic pressure and temperature (P–T) conditions. The 40Ar/39Ar dataset records progressively younger apparent age populations and a decrease in within-sample dispersion with increasing temperature through the sequence. The white mica populations span ~ 2–9 Ma within each sample in the structurally lower levels (garnet grade) but only ~ 0–3 Ma at structurally higher levels (kyanite-sillimanite grade). Mean white mica single-grain fusion population ages vary from 16.2 ± 3.9 Ma (2σ) to 13.2 ± 1.3 Ma (2σ) from lowest to highest levels. White mica step-heating data from the same samples yields plateau ages from 14.27 ± 0.13 Ma to 12.96 ± 0.05 Ma. Biotite yield older apparent age populations with mean single-grain fusion dates varying from 74.7 ± 11.8 Ma (2σ) at the lowest structural levels to 18.6 ± 4.7 Ma (2σ) at the highest structural levels; the step-heating plateaux are commonly disturbed. Temperatures > 600 °C at pressures of 0.4–0.8 GPa sustained over > 5 Ma, appear to be required for white mica and biotite ages to be consistent with diffusive, open-system cooling. At lower temperatures, and/or over shorter metamorphic timescales, more 40Ar is retained than results from simple diffusion models suggest. Diffusion modelling of Ar in white mica from the highest structural levels suggests that the high-temperature rocks cooled at a r
171. New 40Ar/39Ar dating of the Antrim Plateau Volcanics, Australia: clarifying an age for the eruptive phase of the Kalkarindji continental flood basalt province
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Marshall, Peter E., Halton, Alison M., Kelley, Simon P., Widdowson, Mike, Sherlock, Sarah C., Marshall, Peter E., Halton, Alison M., Kelley, Simon P., Widdowson, Mike, and Sherlock, Sarah C.
- Abstract
The Kalkarindji flood basalt province of northern Australia erupted in the mid-Cambrian. Today the province consists of scattered volcanic and intrusive suites, the largest being the Antrim Plateau Volcanics (APV) in Northern Territory. Accurate dating of Kalkarindji has proved challenging with previous studies focused on minor volcanics and intrusive dykes in Northern Territory and Western Australia. These previously published data, corrected to the same decay constants, range from 512.8 to 509.6 ± 2.5 Ma [2σ], placing Kalkarindji in apparent synchronicity with the Cambrian Stage 4–5 biotic crisis at 510 ± 1 Ma. This study utilises 40Ar/39Ar dating of basalts from the APV to accurately date the major volcanic eruptions in this province. Results yield an age of 508.0–498.3 ± 5.5 Ma [2σ], indicating the APV is younger than the intrusives. These dates allude to a relative timing discrepancy, where intrusive activity in the North Australian Craton preceded the eruption of the APV as the last magmatic activity in the region. The determination of these largest eruptions to be later than 510 Ma, effectively disassociates Kalkarindji lavas from being a major cause of the 510 Ma biotic crisis, but cannot definitively discount any deleterious effects on the fragile Cambrian ecosystem.
172. Observation of centimetre-scale argon diffusion in alkali feldspars: implications for 40Ar/39Ar thermochronology
- Author
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Flude, Stephanie, Halton, Alison M., Kelley, Simon P., Sherlock, Sarah C., Schwanethal, James, Wilkinson, Camilla M., Flude, Stephanie, Halton, Alison M., Kelley, Simon P., Sherlock, Sarah C., Schwanethal, James, and Wilkinson, Camilla M.
- Abstract
New data from a gem-quality feldspar from Itrongay, Madagascar, record naturally occurring 40Ar/39Ar age profiles which can be numerically modelled by invoking a single diffusion mechanism and show that microtexturally simple crystals are capable of recording complex thermal histories. We present the longest directly measured, naturally produced 40Ar*-closure profiles from a single, homogeneous orthoclase feldspar. These data appear to confirm the assumption that laboratory derived diffusion parameters are valid in nature and over geological timescales. Diffusion domains are defined by crystal faces and ancient cracks, thus in gem-quality feldspars the diffusion domain size equates to the physical grain size. The data also illustrate the potential of large, gem-quality feldspars to record detailed thermal histories over tens of millions of years and such samples should be considered for future studies on the slow cooling of continental crust.
173. Noble gas transport into the mantle facilitated by high solubility in amphibole
- Author
-
Jackson, Colin R.M., Parman, Steven W., Kelley, Simon P., Cooper, Reid F., Jackson, Colin R.M., Parman, Steven W., Kelley, Simon P., and Cooper, Reid F.
- Abstract
The chemical evolution of both the Earth’s atmosphere and mantle can be traced using noble gases. Their abundance in mantle and atmosphere is largely determined by a balance between the flux of noble gases from the Earth’s interior through magmatism, and the recycling of noble gases from the atmosphere back into the mantle at subduction zones. The flux of noble gases back into the mantle has long been thought to be negligible. Analyses of samples from the mantle now suggest that this recycling flux is more significant, but the mechanism is unclear. Here we present high-pressure experimental measurements that demonstrate high solubility of noble gases in amphibole, an important hydrous mineral in altered oceanic crust. Noble gas solubility correlates with the concentration of unoccupied A-sites, sites within the amphibole lattice structure that are constituted by a pair of opposing tetrahedra rings. We conclude that A-sites are energetically favourable locations for noble gas dissolution in amphibole that could allow recycling of noble gases into the mantle by subduction of altered oceanic crust. As many hydrous minerals in subducting slabs, such as serpentine and chlorite, have lattice structures similar to the A-site in amphibole, we suggest that these minerals may provide even more significant recycling pathways.
174. Retention of inherited Ar by alkali feldspar xenocrysts in a magma: Kinetic constraints from Ba zoning profiles
- Author
-
Renne, Paul R., Mulcahy, Sean R., Cassata, William S., Morgan, Leah E., Kelley, Simon P., Hlusko, Leslea, Njau, Jackson, Renne, Paul R., Mulcahy, Sean R., Cassata, William S., Morgan, Leah E., Kelley, Simon P., Hlusko, Leslea, and Njau, Jackson
- Abstract
40Ar/39Ar dating of volcanic alkali feldspars provides critical age constraints on many geological phenomena. A key assumption is that alkali feldspar phenocrysts in magmas contain no initial radiogenic 40Ar (40Ar*), and begin to accumulate 40Ar* only after eruption. This assumption is shown to fail dramatically in the case of a phonolitic lava from southern Tanzania that contains partially resorbed xenocrystic cores which host inherited 40Ar manifest in 40Ar/39Ar age spectra. Magmatic overgrowths on the xenocrysts display variable oscillatory zoning with pisodic pulses of Ba enrichment and intervals of resorption. Ba concentration profiles across contrasting compositional zones are interpreted as diffusion couples. Inferred temperature time histories recorded by these profiles reveal significant variations between phenocrysts. Combined with Ar diffusion kinetics for alkali feldspars and magma temperature inferred from two feldspar thermometry, the results indicate that >1% inherited 40Ar can be retained in such xenocrysts despite immersion in magma at ~900°C for tens to >100 years. In cases where the age contrast between inherited and magmatic feldspars is less pronounced, the age biasing effect of incompletely degassed xenocrysts may easily go undetected.
175. Light noble gas dissolution into ring structure-bearing materials and lattice influences on noble gas recycling
- Author
-
Jackson, Colin R. M., Parman, Stephen W., Kelley, Simon P., Cooper, Reid F., Jackson, Colin R. M., Parman, Stephen W., Kelley, Simon P., and Cooper, Reid F.
- Abstract
Light noble gas (He-Ne-Ar) solubility has been experimentally determined in a range of materials with six-member, tetrahedral ring structures: beryl, cordierite, tourmaline, antigorite, muscovite, F-phlogopite, actinolite, and pargasite. Helium solubility in these materials is relatively high, 4×10-10 to 3×10-7 molg-1bar-1, which is ~100 to 100,000× greater than He solubility in olivine, pyroxene, or spinel. Helium solubility broadly correlates with the topology of ring structures within different minerals. Distinctive He-Ne-Ar solubility patterns are associated with the different ring structure topologies. Combined, these observations suggest ring structures have a strong influence on noble gas solubility in materials and could facilitate the recycling of noble gases, along with other volatiles (i.e., water, chlorine, and fluorine), into the mantle. Measurements of Ne and Ar solubility in antigorite, however, are highly variable and correlated with each other, suggesting multiple factors contribute the solubility of noble gases in serpentine-rich materials
176. Argon redistribution during a metamorphic cycle: Consequences for determining cooling rates
- Author
-
McDonald, Christopher S., Warren, Clare J., Mark, Darren F., Halton, Alison M., Kelley, Simon P., Sherlock, Sarah C., McDonald, Christopher S., Warren, Clare J., Mark, Darren F., Halton, Alison M., Kelley, Simon P., and Sherlock, Sarah C.
- Abstract
40Ar/39Ar thermochronology is commonly used to constrain the rates and times of cooling in exhumed metamorphic terranes, with ages usually linked to temperature via Dodson's closure temperature (TC) formulation. Whilst many metamorphic 40Ar/39Ar data are consistent with the timing of crystallisation or cooling within a chronological framework defined by other, higher temperature, chronometers, other 40Ar/39Ar data are more difficult to interpret. We report white mica and biotite single grain fusion and laser ablation 40Ar/39Ar ages from felsic gneisses from the Western Gneiss Region, Norway. The rocks record isothermal decompression from peak eclogite-facies conditions (white mica stable) to amphibolite-facies conditions (biotite stable) at c. 700 °C. White mica and biotite yield dispersed single grain fusion dates from 416 to 373 Ma and 437 to 360 Ma respectively. In-situ laser ablation analyses provide a similar range, with white mica spot ages ranging from 424 to 370 Ma and biotite spot ages ranging from 437 to 370 Ma. The dates span the duration of the metamorphic cycle suggested by previous studies, and cannot be reconciled with the results of simple models of Ar loss by diffusion during cooling. Samples that show evidence for different physical processes, such as the chemical breakdown of white mica, partial melting, and fluid ingress, generated different age populations to samples that did not experience or record obvious petrological evidence for these processes. Samples that record significant recrystallization and deformation yielded younger white mica (but older biotite) single grain fusion ages than more pristine samples. Amphibolite-facies gneisses that preserve evidence for significant partial melting generated younger biotite ages than samples that recorded evidence for significant hydration. Our data support other reported observations that high-tempera
177. Organic geochemistry of the Boltysh impact crater, Ukraine
- Author
-
Watson, Jonathan S., Gilmour, Iain, Kelley, Simon P., Jolley, David W., Watson, Jonathan S., Gilmour, Iain, Kelley, Simon P., and Jolley, David W.
- Abstract
The Boltysh crater has been know for several decades and was originally drilled in the 1960s - 1980s in a study of economic oil shale deposits. Unfortunately, the cores were not curated and have been lost. However we have recently re-drilled the impact crater and have recovered a near continuous record of ~400m of organic rich sediments deposited in a deep isolated lake which overly the basement rocks spanning a period ~10 Ma. The Boltysh impact crater, centred at 48°54–N and 32°15–E is a complex impact structure formed on the basement rocks of the Ukrainian shield. The age of the impact is 65.17±0.64 Ma [1]. At 24km diameter, the impact is unlikely to have contributed substantially to the worldwide devastation at the end of the Cretaceous. However, the precise age of the Boltysh impact relative to the Chicxulub impact and its location on a stable low lying coastal plain which allowed formation of the postimpact crater lake make it a particularly important locality. After the impact, the crater quickly filled with water, and the crater lake received sediment input from the surrounding land surface for a period >10 Ma [2]. These strata contain a valuable record of Paleogene environmental change in central Europe, and one of very few terrestrial records of the KT event. This preeminent record of the Paleogene of central Europe can help us to answer several related scientific questions. What is the relative age of Boltysh compared with Chicxulub? How long was the hydrothermal system active for after the impact event? How did the devastated area surrounding the crater recover, and how rapid was the recovery? The first sediments to be deposited in the crater lake were a series of relatively thin turbidites, the sediments then become organic rich shales and oil shales. Within the core there is ~400 m of organic rich shales/oil shales spanning a period of ~10 Ma some of which contain macrofossils such as ostracods, fish and plant fossils. Preliminary palynological studie
178. A laser probe 40Ar /39Ar and INAA investigation of four Apollo granulitic breccias
- Author
-
Hudgins, Jillian A., Spray, John G., Kelley, Simon P., Korotev, Randy L., Sherlock, Sarah C., Hudgins, Jillian A., Spray, John G., Kelley, Simon P., Korotev, Randy L., and Sherlock, Sarah C.
- Abstract
Infrared laser probe 40Ar/39Ar geochronology, instrumental neutron activation analysis (INAA) and analytical electron microscopy have been performed on four 0.5 x 1.0 x 0.3 cm polished rock tiles of Apollo 16 and 17 granulitic breccias (60035, 77017, 78155, and 79215). Pyroxene thermometry indicates that these samples were re-equilibrated and underwent peak metamorphic sub-solidus recrystallization at 1000 – 1100°C, which resulted in homogeneous mineral compositions and granoblastic textures. 40Ar/39Ar data from this study reveal that three samples (60035, 77017, and 78155) have peak metamorphic ages of ~4.1 Ga. Sample 79215 has a peak metamorphic age of 3.9 Ga, which may be related to Serenitatis basin formation. All four samples contain moderately high concentrations of meteoritic siderophiles. Enhanced siderophile contents in three of the samples provide evidence for projectile contamination of their target lithologies occurring prior to peak metamorphism. Post-peak metamorphism, low-temperature (<300ºC) events caused the partial resetting of argon in the two finer-grained granulites (60035 and 77017). These later events did not alter the mineralogy or texture of the rocks, but caused minor brecciation and the partial release of argon from plagioclase. Interpretation of the low-temperature data indicates partial resetting of the argon systematics to as young as 3.2 Ga for 60035 and 2.3 Ga for 77017. Cosmic ray exposure ages range from 6.4 to ~339 Ma. Our results increase the amount of high-precision data available for the granulitic breccias and lunar highlands crustal samples. The results demonstrate the survival of pre-Nectarian material on the lunar surface and document the effects of contact metamorphic and impact processes during the pre-Nectarian Epoch, as well as the low-temperature partial resetting of ages by smaller impact events after 3.9 Ga. The mineralogy and chemical composition of these rocks, as well as exhumation constraints, indicate that the
179. Argon redistribution during a metamorphic cycle: Consequences for determining cooling rates
- Author
-
McDonald, Christopher S., Warren, Clare J., Mark, Darren F., Halton, Alison M., Kelley, Simon P., Sherlock, Sarah C., McDonald, Christopher S., Warren, Clare J., Mark, Darren F., Halton, Alison M., Kelley, Simon P., and Sherlock, Sarah C.
- Abstract
40Ar/39Ar thermochronology is commonly used to constrain the rates and times of cooling in exhumed metamorphic terranes, with ages usually linked to temperature via Dodson's closure temperature (TC) formulation. Whilst many metamorphic 40Ar/39Ar data are consistent with the timing of crystallisation or cooling within a chronological framework defined by other, higher temperature, chronometers, other 40Ar/39Ar data are more difficult to interpret. We report white mica and biotite single grain fusion and laser ablation 40Ar/39Ar ages from felsic gneisses from the Western Gneiss Region, Norway. The rocks record isothermal decompression from peak eclogite-facies conditions (white mica stable) to amphibolite-facies conditions (biotite stable) at c. 700 °C. White mica and biotite yield dispersed single grain fusion dates from 416 to 373 Ma and 437 to 360 Ma respectively. In-situ laser ablation analyses provide a similar range, with white mica spot ages ranging from 424 to 370 Ma and biotite spot ages ranging from 437 to 370 Ma. The dates span the duration of the metamorphic cycle suggested by previous studies, and cannot be reconciled with the results of simple models of Ar loss by diffusion during cooling. Samples that show evidence for different physical processes, such as the chemical breakdown of white mica, partial melting, and fluid ingress, generated different age populations to samples that did not experience or record obvious petrological evidence for these processes. Samples that record significant recrystallization and deformation yielded younger white mica (but older biotite) single grain fusion ages than more pristine samples. Amphibolite-facies gneisses that preserve evidence for significant partial melting generated younger biotite ages than samples that recorded evidence for significant hydration. Our data support other reported observations that high-tempera
180. Light noble gas dissolution into ring structure-bearing materials and lattice influences on noble gas recycling
- Author
-
Jackson, Colin R. M., Parman, Stephen W., Kelley, Simon P., Cooper, Reid F., Jackson, Colin R. M., Parman, Stephen W., Kelley, Simon P., and Cooper, Reid F.
- Abstract
Light noble gas (He-Ne-Ar) solubility has been experimentally determined in a range of materials with six-member, tetrahedral ring structures: beryl, cordierite, tourmaline, antigorite, muscovite, F-phlogopite, actinolite, and pargasite. Helium solubility in these materials is relatively high, 4×10-10 to 3×10-7 molg-1bar-1, which is ~100 to 100,000× greater than He solubility in olivine, pyroxene, or spinel. Helium solubility broadly correlates with the topology of ring structures within different minerals. Distinctive He-Ne-Ar solubility patterns are associated with the different ring structure topologies. Combined, these observations suggest ring structures have a strong influence on noble gas solubility in materials and could facilitate the recycling of noble gases, along with other volatiles (i.e., water, chlorine, and fluorine), into the mantle. Measurements of Ne and Ar solubility in antigorite, however, are highly variable and correlated with each other, suggesting multiple factors contribute the solubility of noble gases in serpentine-rich materials
181. Observation of centimetre-scale argon diffusion in alkali feldspars: implications for 40Ar/39Ar thermochronology
- Author
-
Flude, Stephanie, Halton, Alison M., Kelley, Simon P., Sherlock, Sarah C., Schwanethal, James, Wilkinson, Camilla M., Flude, Stephanie, Halton, Alison M., Kelley, Simon P., Sherlock, Sarah C., Schwanethal, James, and Wilkinson, Camilla M.
- Abstract
New data from a gem-quality feldspar from Itrongay, Madagascar, record naturally occurring 40Ar/39Ar age profiles which can be numerically modelled by invoking a single diffusion mechanism and show that microtexturally simple crystals are capable of recording complex thermal histories. We present the longest directly measured, naturally produced 40Ar*-closure profiles from a single, homogeneous orthoclase feldspar. These data appear to confirm the assumption that laboratory derived diffusion parameters are valid in nature and over geological timescales. Diffusion domains are defined by crystal faces and ancient cracks, thus in gem-quality feldspars the diffusion domain size equates to the physical grain size. The data also illustrate the potential of large, gem-quality feldspars to record detailed thermal histories over tens of millions of years and such samples should be considered for future studies on the slow cooling of continental crust.
182. Organic geochemistry of the Boltysh impact crater, Ukraine
- Author
-
Watson, Jonathan S., Gilmour, Iain, Kelley, Simon P., Jolley, David W., Watson, Jonathan S., Gilmour, Iain, Kelley, Simon P., and Jolley, David W.
- Abstract
The Boltysh crater has been know for several decades and was originally drilled in the 1960s - 1980s in a study of economic oil shale deposits. Unfortunately, the cores were not curated and have been lost. However we have recently re-drilled the impact crater and have recovered a near continuous record of ~400m of organic rich sediments deposited in a deep isolated lake which overly the basement rocks spanning a period ~10 Ma. The Boltysh impact crater, centred at 48°54–N and 32°15–E is a complex impact structure formed on the basement rocks of the Ukrainian shield. The age of the impact is 65.17±0.64 Ma [1]. At 24km diameter, the impact is unlikely to have contributed substantially to the worldwide devastation at the end of the Cretaceous. However, the precise age of the Boltysh impact relative to the Chicxulub impact and its location on a stable low lying coastal plain which allowed formation of the postimpact crater lake make it a particularly important locality. After the impact, the crater quickly filled with water, and the crater lake received sediment input from the surrounding land surface for a period >10 Ma [2]. These strata contain a valuable record of Paleogene environmental change in central Europe, and one of very few terrestrial records of the KT event. This preeminent record of the Paleogene of central Europe can help us to answer several related scientific questions. What is the relative age of Boltysh compared with Chicxulub? How long was the hydrothermal system active for after the impact event? How did the devastated area surrounding the crater recover, and how rapid was the recovery? The first sediments to be deposited in the crater lake were a series of relatively thin turbidites, the sediments then become organic rich shales and oil shales. Within the core there is ~400 m of organic rich shales/oil shales spanning a period of ~10 Ma some of which contain macrofossils such as ostracods, fish and plant fossils. Preliminary palynological studie
183. Retention of inherited Ar by alkali feldspar xenocrysts in a magma: Kinetic constraints from Ba zoning profiles
- Author
-
Renne, Paul R., Mulcahy, Sean R., Cassata, William S., Morgan, Leah E., Kelley, Simon P., Hlusko, Leslea, Njau, Jackson, Renne, Paul R., Mulcahy, Sean R., Cassata, William S., Morgan, Leah E., Kelley, Simon P., Hlusko, Leslea, and Njau, Jackson
- Abstract
40Ar/39Ar dating of volcanic alkali feldspars provides critical age constraints on many geological phenomena. A key assumption is that alkali feldspar phenocrysts in magmas contain no initial radiogenic 40Ar (40Ar*), and begin to accumulate 40Ar* only after eruption. This assumption is shown to fail dramatically in the case of a phonolitic lava from southern Tanzania that contains partially resorbed xenocrystic cores which host inherited 40Ar manifest in 40Ar/39Ar age spectra. Magmatic overgrowths on the xenocrysts display variable oscillatory zoning with pisodic pulses of Ba enrichment and intervals of resorption. Ba concentration profiles across contrasting compositional zones are interpreted as diffusion couples. Inferred temperature time histories recorded by these profiles reveal significant variations between phenocrysts. Combined with Ar diffusion kinetics for alkali feldspars and magma temperature inferred from two feldspar thermometry, the results indicate that >1% inherited 40Ar can be retained in such xenocrysts despite immersion in magma at ~900°C for tens to >100 years. In cases where the age contrast between inherited and magmatic feldspars is less pronounced, the age biasing effect of incompletely degassed xenocrysts may easily go undetected.
184. Noble gas transport into the mantle facilitated by high solubility in amphibole
- Author
-
Jackson, Colin R.M., Parman, Steven W., Kelley, Simon P., Cooper, Reid F., Jackson, Colin R.M., Parman, Steven W., Kelley, Simon P., and Cooper, Reid F.
- Abstract
The chemical evolution of both the Earth’s atmosphere and mantle can be traced using noble gases. Their abundance in mantle and atmosphere is largely determined by a balance between the flux of noble gases from the Earth’s interior through magmatism, and the recycling of noble gases from the atmosphere back into the mantle at subduction zones. The flux of noble gases back into the mantle has long been thought to be negligible. Analyses of samples from the mantle now suggest that this recycling flux is more significant, but the mechanism is unclear. Here we present high-pressure experimental measurements that demonstrate high solubility of noble gases in amphibole, an important hydrous mineral in altered oceanic crust. Noble gas solubility correlates with the concentration of unoccupied A-sites, sites within the amphibole lattice structure that are constituted by a pair of opposing tetrahedra rings. We conclude that A-sites are energetically favourable locations for noble gas dissolution in amphibole that could allow recycling of noble gases into the mantle by subduction of altered oceanic crust. As many hydrous minerals in subducting slabs, such as serpentine and chlorite, have lattice structures similar to the A-site in amphibole, we suggest that these minerals may provide even more significant recycling pathways.
185. A laser probe 40Ar /39Ar and INAA investigation of four Apollo granulitic breccias
- Author
-
Hudgins, Jillian A., Spray, John G., Kelley, Simon P., Korotev, Randy L., Sherlock, Sarah C., Hudgins, Jillian A., Spray, John G., Kelley, Simon P., Korotev, Randy L., and Sherlock, Sarah C.
- Abstract
Infrared laser probe 40Ar/39Ar geochronology, instrumental neutron activation analysis (INAA) and analytical electron microscopy have been performed on four 0.5 x 1.0 x 0.3 cm polished rock tiles of Apollo 16 and 17 granulitic breccias (60035, 77017, 78155, and 79215). Pyroxene thermometry indicates that these samples were re-equilibrated and underwent peak metamorphic sub-solidus recrystallization at 1000 – 1100°C, which resulted in homogeneous mineral compositions and granoblastic textures. 40Ar/39Ar data from this study reveal that three samples (60035, 77017, and 78155) have peak metamorphic ages of ~4.1 Ga. Sample 79215 has a peak metamorphic age of 3.9 Ga, which may be related to Serenitatis basin formation. All four samples contain moderately high concentrations of meteoritic siderophiles. Enhanced siderophile contents in three of the samples provide evidence for projectile contamination of their target lithologies occurring prior to peak metamorphism. Post-peak metamorphism, low-temperature (<300ºC) events caused the partial resetting of argon in the two finer-grained granulites (60035 and 77017). These later events did not alter the mineralogy or texture of the rocks, but caused minor brecciation and the partial release of argon from plagioclase. Interpretation of the low-temperature data indicates partial resetting of the argon systematics to as young as 3.2 Ga for 60035 and 2.3 Ga for 77017. Cosmic ray exposure ages range from 6.4 to ~339 Ma. Our results increase the amount of high-precision data available for the granulitic breccias and lunar highlands crustal samples. The results demonstrate the survival of pre-Nectarian material on the lunar surface and document the effects of contact metamorphic and impact processes during the pre-Nectarian Epoch, as well as the low-temperature partial resetting of ages by smaller impact events after 3.9 Ga. The mineralogy and chemical composition of these rocks, as well as exhumation constraints, indicate that the
186. Relationships between marginal thrusting and movement on major, internal shear zones in the Northern Highland Caledonides, Scotland
- Author
-
Kelley, Simon P, primary and Powell, Derek, additional
- Published
- 1985
- Full Text
- View/download PDF
187. The impact of public health lockdown measures during the COVID-19 pandemic on the epidemiology of children's orthopedic injuries requiring operative intervention.
- Author
-
Tarchala, Magdalena, Bradley, Catharine S., Grant, Samuel, Verma, Yashvi, Camp, Mark, Matava, Clyde, and Kelley, Simon P.
- Subjects
- *
CHILDREN'S injuries , *COVID-19 pandemic , *STAY-at-home orders , *EMERGENCY room visits , *MUSCULOSKELETAL system injuries - Abstract
Background: In March 2020, Ontario instituted a lockdown to reduce spread of the SARS-CoV-2 virus. Schools, recreational facilities, and nonessential businesses were closed. Restrictions were eased through 3 distinct stages over a 6-month period (March to September 2020). We aimed to determine the impact of each stage of the COVID-19 public health lockdown on the epidemiology of operative pediatric orthopedic trauma. Methods: A retrospective cohort study was performed comparing emergency department (ED) visits for orthopedic injuries and operatively treated orthopedic injuries at a level 1 pediatric trauma centre during each lockdown stage of the pandemic with caseloads during the same date ranges in 2019 (prepandemic). Further analyses were based on patients' demographic characteristics, injury severity, mechanism of injury, and anatomic location of injury. Results: Compared with the prepandemic period, ED visits decreased by 20% (1356 v. 1698, p < 0.001) and operative cases by 29% (262 v. 371, p < 0.001). There was a significant decrease in the number of operative cases per day in stage 1 of the lockdown (1.3 v. 2.0, p < 0.001) and in stage 2 (1.7 v. 3.0; p < 0.001), but there was no significant difference in stage 3 (2.4 v. 2.2, p = 0.35). A significant reduction in the number of playground injuries was seen in stage 1 (1 v. 62, p < 0.001) and stage 2 (6 v. 35, p < 0.001), and there was an increase in the number of self-propelled transit injuries (31 v. 10, p = 0.002) during stage 1. In stage 3, all patient demographic characteristics and all characteristics of operatively treated injuries resumed their prepandemic distributions. Conclusion: Provincial lockdown measures designed to limit the spread of SARS-CoV-2 significantly altered the volume and demographic characteristics of pediatric orthopedic injuries that required operative management. The findings from this study will serve to inform health system planning for future emergency lockdowns. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
188. Earth science and Planetary science: The 2014 ESTA Annual Course and Conference at Milton Keynes 26th to 28th September 2014.
- Author
-
Kelley, Simon
- Subjects
EARTH science education ,SCIENCE education ,CONFERENCES & conventions - Abstract
The article offers information on the 2014 British Earth Science Teachers' Association (ESTA) Annual Course and Conference, held in Milton Keynes, England from September 26-28, 2014.
- Published
- 2014
189. Can neonatal pelvic osteotomies permanently change pelvic shape in patients with exstrophy? Understanding late rediastasis.
- Author
-
Kenawey, Mohamed, Wright, James G, Hopyan, Sevan, Murnaghan, Michael Lucas, Howard, Andrew, and Kelley, Simon P
- Abstract
Background: Pelvic osteotomies are frequently used as part of the surgical management of bladder exstrophy. The outcomes are often measured on the basis of the residual symphyseal diastasis. The aims of this study were to evaluate and validate a more reliable radiographic measure of ischiopubic rotation, to utilize this measure in analyzing pelves from patients with exstrophy and controls, and to propose a model for rediastasis in a pelvis with exstrophy.Methods: Pelvic radiographs of 164 normal children two months to eighteen years of age were used to determine the changes in interpubic and interischial distances and in the interischial/interpubic (IS/IP) ratio with age. Twenty-one pelvic CT (computed tomography) studies of normal children, two to sixteen years of age, were also used to study the change in the ischiopubic divergence angle. The same parameters were measured on radiographs or CT or magnetic resonance imaging studies of seventy-three patients with classic bladder exstrophy who were followed for two to nineteen years after exstrophy closure with or without pelvic osteotomies.Results: In normal children, the interpubic distance and the ischiopubic divergence angle had a narrow range and were constant with age, whereas the interischial distance and the IS/IP ratio increased progressively and were strongly correlated with age. In the patients with exstrophy, the interpubic distance was positively correlated with the interischial distance, whereas the IS/IP ratio was lower than that in normal controls and was not correlated with age.Conclusions: The IS/IP ratio is a useful measure of ischiopubic rotation and can be used to characterize pelvic growth, including the phenomenon of rediastasis in patients with exstrophy. Pelvic rediastasis is a progressive increase in interpubic distance resulting from growth without loss of rotational correction, as shown by the constancy of the IS/IP ratio with age in these patients. A better rotational position at the time of osteotomy may lead to a better pelvic shape at maturity.Clinical Relevance: Symphyseal rediastasis following neonatal pelvic osteotomies in patients with exstrophy is not due to loss of correction and progressive derotation of the hemipelves but is a consequence of the normal three-dimensional growth of the pelvis. The best correction of the pelvic deformity should always be the aim even in neonatal pelvic osteotomies because this will permanently change the pelvic shape. [ABSTRACT FROM AUTHOR]- Published
- 2014
- Full Text
- View/download PDF
190. When can muscovite 40Ar/39Ar dating constrain the timing of metamorphic exhumation?
- Author
-
Warren, Clare J., Hanke, Felix, and Kelley, Simon P.
- Subjects
- *
MUSCOVITE , *ARGON , *METAMORPHISM (Geology) , *CRYSTALLIZATION , *DIFFUSION , *MATHEMATICAL models - Abstract
Abstract: Metamorphic cooling rates determined using muscovite 40Ar/39Ar ages underpin many tectonic models, but are based on several simplifying approximations. We demonstrate that a number of these approximations, especially those relating to the assignment of a single “closure temperature”, might not hold for certain metamorphic scenarios, and particularly for metamorphism during rapid orogenic cycles. Using numerical diffusion models that include a recently reported significant pressure dependence of Ar diffusion in muscovite, we systematically interrogate the approximations associated with linking 40Ar/39Ar dates to pressure–temperature histories. The results of the simulations are presented in a simple graphic form allowing evaluation of the pressure–temperature (PT) regions in which Ar diffusion is efficient, and hence those in which the muscovite may yield true 40Ar/39Ar cooling ages. We suggest that a robust method for determining whether metamorphic muscovite 40Ar/39Ar ages relate to the timing of cooling involves: (1) the determination of the PT conditions and relative timing of muscovite crystallisation during the metamorphic cycle, (2) the collection of high precision and high spatial resolution 40Ar/39Ar data from muscovite grains and (3) the comparison between analytical data and numerical diffusion models which test different post-crystallisation pressure–temperature histories. [Copyright &y& Elsevier]
- Published
- 2012
- Full Text
- View/download PDF
191. 40Ar/39Ar dating of oil generation and migration at complex continental margins.
- Author
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Mark, Darren F., Parnell, John, Kelley, Simon P., Lee, Martin R., and Sherlock, Sarah C.
- Subjects
- *
PETROLEUM migration , *FLUID inclusions , *FELDSPAR , *JURASSIC stratigraphic geology , *RESERVOIRS - Abstract
Oil-bearing fluid inclusions trapped within authigenic K-feldspar in Late Jurassic reservoirs throughout the UK Atlantic margin are evidence for an early oil migration event from Late Jurassic source rocks in the Faeroe-Shetland Basin. Previous compound-specific isotope studies confirm the hydrocarbon provenance. Temperaturecomposition- time data show that the Late Jurassic source rocks were oil mature 113 ± 3.5 Ma (2σ). This new 40Ar/39Ar authigenic K-feldspar age shows that the Late Jurassic source rocks were oil mature 30-40 m.y. prior to current estimates. [ABSTRACT FROM AUTHOR]
- Published
- 2010
- Full Text
- View/download PDF
192. Excess argon (40ArE) uptake during slate formation: A 40Ar/39Ar UV laserprobe study of muscovite strain-fringes from the Palaeozoic Welsh Basin, UK
- Author
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Sherlock, Sarah C., Zalasiewicz, Jan, Kelley, Simon P., and Evans, Jane
- Subjects
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GEOLOGICAL formations , *SLATE , *ARGON , *MUSCOVITE , *ROCK mechanics , *OROGENIC belts ,DEVONIAN stratigraphic geology - Abstract
Abstract: Syn-kinematic pure muscovite strain-fringes grew around pyritized graptolites in response to the early Devonian (Acadian) closure and uplift of the Peri-Gondwanan Welsh Basin. They record Ar-isotope information on the timing of low-temperature deformation and the mudrock to slate transition. Here we have applied three different 40Ar/39Ar laserprobe dating methods to strain-fringes from the central Welsh Basin to test for variations in age and to explore the technical limitations of the method. Infrared laserprobe step-heating analyses yielded only occasional plateau ages (varying between ca. 403 Ma and 422 Ma) and strong evidence for discordance in the Ar-system. Likewise, ages from infrared laserprobe total fusion analysis are scattered, and range from ca. 390 Ma to 651 Ma. By contrast, ultraviolet laserprobe intra-fringe age profiles revealed a complex pattern of ages across individual strain-fringes. This is the highest spatial resolution technique available, and the resulting age profiles consistently showed an oscillatory pattern comprising troughs, or ‘baseline’ ages that are all within error of ca. 397 Ma, and peaks, or ‘apparent’ ages, ranging up to ca. 550 Ma. These ‘apparent’ ages we interpret as the results of repeated, periodic assimilation of excess 40Ar (40ArE) during deformation and the mudrock to slate transition. Here, basinal fluids carrying 40ArE are driven through bulk mudrock during contractional phases of the Acadian orogen, and 40ArE is taken up by muscovite strain-fringes. The concentration of 40ArE varies with metamorphic grade, and is inversely proportional to the temperature of metamorphism, and we suggest is controlled by the solubility of Ar in water, which has potentially quite severe implications for 40Ar/39Ar dating of K-bearing minerals in any mudrock. These results provide a first record of Ar-isotope information in strain-fringes, and a first record of orogenically-driven fluid-flow through bulk deforming mudrock. They also demonstrate how the high spatial resolution ultraviolet laserprobe 40Ar/39Ar method can access Ar-isotope information that is obscured by lower spatial resolution laser analysis, or bulk sampling methods. [Copyright &y& Elsevier]
- Published
- 2008
- Full Text
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193. A laser probe 40Ar/39Ar and INAA investigation of four Apollo granulitic breccias
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Hudgins, Jillian A., Spray, John G., Kelley, Simon P., Korotev, Randy L., and Sherlock, Sarah C.
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LASER beams , *NUCLEAR activation analysis , *ELECTRON microscopy , *GEOLOGICAL time scales , *IGNEOUS rocks , *TILES , *BRECCIA , *TEMPERATURE measurements , *METAMORPHIC rocks - Abstract
Abstract: Infrared laser probe 40Ar/39Ar geochronology, instrumental neutron activation analysis (INAA) and analytical electron microscopy have been performed on four 0.5×1.0×0.3cm polished rock tiles of Apollo 16 and 17 granulitic breccias (60035, 77017, 78155, and 79215). Pyroxene thermometry indicates that these samples were re-equilibrated and underwent peak metamorphic sub-solidus recrystallization at 1000–1100°C, which resulted in homogeneous mineral compositions and granoblastic textures. 40Ar/39Ar data from this study reveal that three samples (60035, 77017, and 78155) have peak metamorphic ages of ∼4.1Ga. Sample 79215 has a peak metamorphic age of 3.9Ga, which may be related to Serenitatis basin formation. All four samples contain moderately high concentrations of meteoritic siderophiles. Enhanced siderophile contents in three of the samples provide evidence for projectile contamination of their target lithologies occurring prior to peak metamorphism. Post-peak metamorphism, low-temperature (<300°C) events caused the partial resetting of argon in the two finer-grained granulites (60035 and 77017). These later events did not alter the mineralogy or texture of the rocks, but caused minor brecciation and the partial release of argon from plagioclase. Interpretation of the low-temperature data indicates partial resetting of the argon systematics to as young as 3.2Ga for 60035 and 2.3Ga for 77017. Cosmic ray exposure ages range from 6.4 to ∼339Ma. Our results increase the amount of high-precision data available for the granulitic breccias and lunar highlands crustal samples. The results demonstrate the survival of pre-Nectarian material on the lunar surface and document the effects of contact metamorphic and impact processes during the pre-Nectarian Epoch, as well as the low-temperature partial resetting of ages by smaller impact events after 3.9Ga. The mineralogy and chemical composition of these rocks, as well as exhumation constraints, indicate that the source of heat for metamorphism was within kilometers of the surface via burial beneath impact-melt sheets or hot ejecta blankets. [Copyright &y& Elsevier]
- Published
- 2008
- Full Text
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194. Crystal–melt partitioning of noble gases (helium, neon, argon, krypton, and xenon) for olivine and clinopyroxene
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Heber, Veronika S., Brooker, Richard A., Kelley, Simon P., and Wood, Bernard J.
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SEPARATION (Technology) , *NOBLE gases , *OLIVINE , *NONMETALS - Abstract
Abstract: Mineral–melt partition coefficients of all noble gases (min/melt D i ) have been obtained for olivine (ol) and clinopyroxene (cpx) by UV laser ablation (213nm) of individual crystals grown from melts at 0.1GPa mixed noble gas pressure. Experimental techniques were developed to grow crystals virtually free of melt and fluid inclusions since both have been found to cause profound problems in previous work. This is a particularly important issue for the analysis of noble gases in crystals that have very low partition coefficients relative to coexisting melt and fluid phases. The preferred partitioning values obtained for the ol–melt system for He, Ne, Ar, Kr, and Xe are 0.00017(13), 0.00007(7), 0.0011(6), 0.00026(16), and , respectively. The respective cpx–melt partition coefficients are 0.0002(2), 0.00041(35), 0.0011(7), 0.0002(2), and . The data confirm the incompatible behaviour of noble gases for both olivine and clinopyroxene but unlike other trace elements these values show little variation for a wide range of atomic radius. The lack of dependence of partitioning on atomic radius is, however, consistent with the partitioning behaviour of other trace elements which have been found to exhibit progressively lower dependence of min/melt D i on radius as the charge decreases. As all noble gases appear to exhibit similar min/melt D i values we deduce that noble gases are not significantly fractionated from each other by olivine and clinopyroxene during melting and fractional crystallisation. Although incompatible, the partitioning values for noble gases also suggest that significant amounts of primordial noble gases may well have been retained in the mantle despite intensive melting processes. The implication of our data is that high primordial/radiogenic noble gas ratios (3He/4He, 22Ne/21Ne, and 36Ar/40Ar) characteristic of plume basalt sources can be achieved by recycling a previously melted (depleted) mantle source rather than reflecting an isolated, non-degassed primordial mantle region. [Copyright &y& Elsevier]
- Published
- 2007
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195. Dating of Multistage Fluid Flow in Sandstones.
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Mark, Darren F., Parnell, John, Kelley, Simon P., Lee, Martin, Sherlock, Sarah C., and Carr, Andrew
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FLUIDS , *SEDIMENTARY basins , *LASERS , *ARGON , *POTASSIUM , *RESERVOIRS - Abstract
Through ultraviolet laser argon-argon dating of potassium feldspar cements containing fluid inclusions, we determined temperature-composition-time data for paleofluids in a sedimentary basin, including data for an evolving episode of fluid flow recorded in distinct phases of cement. The fluid evolved from mixed aqueous oil 83 million years ago to purely aqueous by 76 million years ago, thus dating the time of oil charge in this reservoir. [ABSTRACT FROM AUTHOR]
- Published
- 2005
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196. 40Ar–39Ar dating of detrital muscovite in provenance investigations: a case study from the Adelaide Rift Complex, South Australia
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Haines, Peter W., Turner, Simon P., Kelley, Simon P., Wartho, Jo-Anne, and Sherlock, Sarah C.
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GEMS & precious stones , *SILICATE minerals , *FLOOD basalts - Abstract
Detrital zircon ages are commonly used to investigate sediment provenance and supply routes. Here, we explore the advantages of employing multiple, complimentary techniques via a case study of the Neoproterozoic and Cambrian of the Adelaide Rift Complex, South Australia. Detrital muscovite Ar–Ar ages are presented from stratigraphic units, or equivalents, that have previously been the subject of U–Pb detrital zircon dating, and, in some cases, whole-rock Sm–Nd isotope studies. The zircon age ranges and whole-rock Sm–Nd isotope data suggest that early Neoproterozoic sediments from near the base of the Adelaide Rift Complex comprise a mixture of detritus derived from the adjacent Gawler Craton (Palaeoproterozoic to earliest Mesoproterozoic) and overlying Gairdner flood basalts. In contrast, detrital muscovites from this level have a broad scatter of Mesoproterozoic infrared (IR) laser total fusion Ar–Ar ages, while UV laser traverses indicate that the age spread reflects partial resetting by multiple heating events, rather than a mixture of sources. Younger Neoproterozoic sediments document replacement of the Gawler Craton by the more distant Musgrave and/or Albany–Fraser Orogens as the main provenance. The Cambrian Kanmantoo Group marks an abrupt change in depositional style and a new sediment source. The Kanmantoo Group have older Nd model ages than underlying strata, yet are dominated by near to deposition-aged (∼500–650 Ma) detrital zircons and muscovites, suggesting rapid cooling and exhumation of a tectonically active provenance region. Although this source remains uncertain, evidence points towards the distant Pan-African orogenic belts. Deposition in the Adelaide Rift Complex was terminated in the late Early Cambrian by the Delamerian Orogeny, and the results of previous detrital mineral dating studies from the Lachlan Fold Belt to the east are consistent with at least partial derivation of these sediments from reworked upper Adelaide Rift Complex (Kanmantoo Group), rather than a continuation of sediment supply from the Kanmantoo Group sediment source. More broadly, the data suggest a close link between basin formation and orogen exhumation, and we also speculate that mantle plumes have played a significant role in crustal evolution at this Palaeo-Pacific margin of Gondwanaland, challenging the notion that subduction zones are the principle sites of crustal growth and sediment provenance. [Copyright &y& Elsevier]
- Published
- 2004
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197. Fingerprinting polyorogenic detritus using the [sup 40]Ar/[sup 39]Ar ultraviolet laser microprobe.
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Sherlock, Sarah C., Jones, Kevin A., and Kelley, Simon P.
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MICROPROBE analysis , *DETRITUS , *GEOLOGICAL time scales - Abstract
Investigates the utilization of [sup 40]Ar/[sup 39]Ar ultraviolet laser microprobes (UVLAMP) in the analysis of detrital white micas. Characteristic of detrital micas evolution; Efficiency of UVLAMP in the analysis of now-eroded mountain belts; Implication of [sup 40]Ar/[sup 39]Ar geochronology for orogenic uplift.
- Published
- 2002
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198. The Boltysh impact structure: An early Danian impact event during recovery from the K-Pg mass extinction.
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Pickersgill, Annemarie E., Mark, Darren F., Lee, Martin R., Kelley, Simon P., and Jolley, David W.
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CRETACEOUS-Paleogene boundary , *MASS extinctions , *SCIENCE conferences , *LUNAR craters , *GEOLOGICAL time scales , *PALEOGENE , *IMPACT craters , *PETROLEUM geology - Published
- 2021
- Full Text
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199. Interpreting and reporting 40Ar/39Ar geochronologic data.
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Schaen, Allen J., Jicha, Brian R., Hodges, Kip V., Vermeesch, Pieter, Stelten, Mark E., Mercer, Cameron M., Phillips, David, Rivera, Tiffany A., Jourdan, Fred, Matchan, Erin L., Hemming, Sidney R., Morgan, Leah E., Kelley, Simon P., Cassata, William S., Heizler, Matt T., Vasconcelos, Paulo M., Benowitz, Jeff A., Koppers, Anthony A. P., Mark, Darren F., and Niespolo, Elizabeth M.
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MASS spectrometers , *METADATA , *LONGEVITY , *EXTRATERRESTRIAL beings , *NEUTRONS , *DISPERSION (Chemistry) - Abstract
The 40Ar/39Ar dating method is among the most versatile of geochronometers, having the potential to date a broad variety of K-bearing materials spanning from the time of Earth's formation into the historical realm. Measurements using modern noble-gas mass spectrometers are now producing 40Ar/39Ar dates with analytical uncertainties of ~0.1%, thereby providing precise time constraints for a wide range of geologic and extraterrestrial processes. Analyses of increasingly smaller subsamples have revealed age dispersion in many materials, including some minerals used as neutron fluence monitors. Accordingly, interpretive strategies are evolving to address observed dispersion in dates from a single sample. Moreover, inferring a geologically meaningful "age" from a measured "date" or set of dates is dependent on the geological problem being addressed and the salient assumptions associated with each set of data. We highlight requirements for collateral information that will better constrain the interpretation of 40Ar/39Ar data sets, including those associated with single-crystal fusion analyses, incremental heating experiments, and in situ analyses of microsampled domains. To ensure the utility and viability of published results, we emphasize previous recommendations for reporting 40Ar/39Ar data and the related essential metadata, with the amendment that data conform to evolving standards of being findable, accessible, interoperable, and reusable (FAIR) by both humans and computers. Our examples provide guidance for the presentation and interpretation of 40Ar/39Ar dates to maximize their interdisciplinary usage, reproducibility, and longevity. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
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200. Geochronology and Thermochronology by the 40Ar/39Ar Method, 2nd edn, by Ian McDougall and T. Mark Harrison. Oxford University Press, Oxford, 1999. 269 pp. ISBN 0195109201. £65.
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Kelley, Simon P.
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GEOLOGICAL time scales , *NONFICTION - Abstract
The article reviews the book "Geochronology and Thermochronology by the 40Ar/39Ar Method," 2nd ed., by Ian McDougall and T. Mark Harrison.
- Published
- 2000
- Full Text
- View/download PDF
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