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Abstract Corrosion in carbonated concrete is an example of corrosion in dense porous media of tremendous socio-economic and scientific relevance. The widespread research endeavors to develop novel, environmentally friendly cements raise questions regarding their ability to protect the embedded steel from corrosion. Here, we propose a fundamentally new approach to explain the scientific mechanism of corrosion kinetics in dense porous media. The main strength of our model lies in its simplicity and in combining the capillary condensation theory with electrochemistry. This reveals that capillary condensation in the pore structure defines the electrochemically active steel surface, whose variability upon changes in exposure relative humidity is accountable for the wide variability in measured corrosion rates. We performed experiments that quantify this effect and find good agreement with the theory. Our findings are essential to devise predictive models for the corrosion performance, needed to guarantee the safety and sustainability of traditional and future cements.

Considering that forests are crucial in the ecosystem of our planet and that forests provide timber products as well as several ecosystem services, it is evident that the application of sustainable forest operations (SFOs) is of substantial importance to achieve sustainable forest management (SFM). One of the most important issues to be evaluated when dealing with SFOs is limiting the disturbance and impacts related to logging. Harvesting activities can indeed alter the conditions of soil through compaction and litter removal which can also lead to modifications from the biological point of view, for example, diminishing the presence of soil microarthropods. While keeping these objectives in focus, the aim of the present study was to evaluate physico-chemical and biological impacts on forest soil in Mediterranean beech forests after forest logging with two different extraction systems, which are forestry-fitted farm tractors equipped with winch and forwarder. Specifically, authors aimed to investigate: (i) soil disturbance levels of ground-based extraction methods; (ii) soil disturbance levels of the applied forestry intervention; (iii) soil disturbance levels between winching-skidding and forwarding. Findings showed that the physical, chemical, and biological soil features were slightly disturbed by the forestry itself. In addition, forest operations and machine traffic showed clear soil disturbance, resulting in a substantial alteration of the characteristics. Between the two extraction techniques tested, winching caused less disturbance while forwarding had stronger impacts. However, it should be noted that these impact levels are found only on approximately 28% of the surface where operations were carried out. From the evidence gathered in this study, winching seems a less impactful extraction method in the studied context. On the other hand, to decrease the impact of forwarding, some technical adjustments such as bogie-tracks, as well as improved operator training, should be applied.

Castor is a candidate crop that grows in marginal lands in the Mediterranean area. It can be grown by utilizing minimal resources to provide unique industrial chemicals or to serve as an energy crop. However, it can be also cultivated with intensive inputs providing higher yields. Whether a high input or a low input scheme is more sustainable depends on the economic and environmental impacts of each case. The objective of the present study, therefore, was to evaluate these impacts under the Mediterranean climate and farming conditions by examining two alternative scenarios: a castor crop grown on a low-inputs field vs. a crop grown in a high-inputs one. The environmental impacts were estimated by following a Life Cycle Assessment (LCA) methodology based on GHG emissions. Furthermore, a sensitivity analysis was performed by switching the functional unit from 1 Mg of castor oil to 1 hectare. The economic feasibility of the castor crop production was assessed by calculating the gross margin, which is referred to the difference between revenues and the variable costs due to the agricultural phases. In addition, the ratio between gross margin and GWP (Global Warming Potential) emissions was applied to calculate the economic performance (gross margin) per unit of environmental burden. Findings showed that the castor oil produced by high inputs resulted in a more sustainable scenario due to its higher yield than low-inputs ones. On the other hand, sensitivity analysis showed that the field management with low inputs showed GHG emissions that were 27% lower than those emitted from the field management with high inputs. Moreover, from an economic point of view, by switching the field management from low inputs to high ones, the Gross Margin increased by about 73%. Finally, the high-inputs scenario showed the best ratio between economic performance and GHG emitted into the atmosphere.

This paper focused on eggs enriched with omega-3-fatty acids with the aim of understanding if functional eggs were of interest to Italian consumers, and analyzing which characteristics of table egg quality, consumers’ attitudes and socio-demographic characteristics affect the consumers’ willingness to pay (WTP) a premium price for eggs enriched with omega-3-fatty acids. We performed an online survey on 312 Italian consumers. The analysis was based on the Tobit regression model. The findings showed that unmarried females were more willing to pay a premium price for functional eggs than male consumers. Furthermore, the probability of showing a higher WTP for functional eggs increased among consumers reporting a higher income. Moreover, the WTP for functional eggs increased with the growing importance that people attributed to items such as the size of eggs, rearing type, feed given to chickens, and the provenience and brand of eggs. These results suggested that consumers need to have clear information about functional eggs. As expected, WTP for functional eggs decreased with increasing neophobia and food techno-neophobia factors. In conclusion, the findings showed an interesting potential for eggs enriched with omega-3-fatty acids, which seems to be a product with high possibility to be greatly appreciated on the market, especially if accompanied by a good, informative campaign for increasing people’s knowledge level.

The potential to use Subsurface Water Retention Systems (SWRSs) to combat desertification and improve agriculture in arid and semiarid areas has already been investigated and proved promising. Nevertheless, a lack of specific machinery has prevented this technology from demonstrating its effectiveness on vast areas. In the present study, a specific prototype is presented along with the results obtained from a preliminary study conducted to assess effectiveness, performance and associated cost. During the test, the machinery permitted the construction of a SWRS 100 cm belowground using a 140 kW tractor. The effective field capacity (EFC) averaged at 0.19 ha h−1 whilst total cost was estimated to be as high as 4800.00 € ha−1. However, 93% of the cost was associated with the purchase cost of the removable impermeable film. A removal operation was also investigated using a 42 kW excavator for evaluating the EFC and cost which averaged at 0.2 ha h−1 and 655.79 € ha−1, respectively.

After many decades when its cultivation was prohibited, hemp is regaining its position as one of the most versatile cultivated crops. Multiplication of monoecious hemp varieties requires manual male plants rouging to keep a high share of monoecious plants in the population. It forces relatively small multiplication fields usually oscillating around 5 ha, where the use of big harvesting machines is not economically feasible. The B-800 mower prototype for hemp panicles proved to be a good alternative to harvest seeds of tall fibrous hemp. The test results of the mower analyzed in this study show that although seed loss on a moderate slope (0.37%) was significantly higher than on a flat slope (0.13%), it was still much lower than in the case of harvesting hemp seed with a combined harvester. Moreover, the field efficiency of 93% is very satisfactory as it is reported for much bigger machines. Finally, the harvesting costs proved to be much lower than most of the machines used for harvesting hemp seed.

The contribution of castor oil for reaching the targets set by RED1 and RED2 in Europe can be tangible if the problem related to the mechanical harvesting is overcome. Dwarf hybrids suitable for mechanical harvesting are already available on the market but the residual moisture of plants and capsules has to be lowered in order to allow mechanization. In the present case of study, three common terminating products (Glyphosate GLY, Diquat DIQ and Spotlight DEF) were tested on Kaiima C1012 hybrid in a complete randomized block design to assess the effectiveness of using chemical products to decrease residual moisture in castor plants. Plants were harvested via combine harvester equipped with cereal header to evaluate seed loss (due to dehiscence, impact and cleaning shoe) and the dehulling capacity of the combine harvester’s cleaning shoe. DIQ decreased significantly moisture content of capsules (7.32%) in comparison to the other treatments, while the lowest plant moisture was recorded in DIQ (62.38%) and GLY (59.12%). The use of DIQ triggered the highest impact seed loss (61.75%) in comparison with GLY (46.50%) and DEF (29.02%). Control plants could not be harvested mechanically due to the high residual moisture content and high density of weeds. The present case of study provides highlights regarding the need to further investigate the best practice to terminate castor plants and to develop a specific combine header to reduce seed loss from impact.

Castor is a crop with an evergreen habit so artificially-induced ripening is an essential precondition for mechanical harvesting of new dwarf annual hybrids. Plants’ moisture imposes a determinant effect both on pre-harvest and post-harvest seed loss, so frequent monitoring of crop ripening is crucial for identifying the optimum moisture for harvest. Remote sensing information from Unmanned Aerial Systems (UASs) along with field measurements were utilized in the present study in order to evaluate three harvest aid chemicals, herbicides glyphosate (GLY) and diquat (DIQ) and the defoliant Spotlight® (DEF) for terminating the castor crop and identifying opportunities for using remote sensing as a tool for monitoring crop ripening. The results showed that glyphosate required more than two weeks to dry out the crop while diquat and spotlight® presented a rapid action within two to four days. Nineteen vegetation indexes (VIs) were derived from a multispectral and an RGB camera mounted on two UAS and were plotted against field measurements. NDVI presented a higher accuracy (R2 = 0.67) for predicting the castor stems’ and leaves’ moisture content while OSAVI and SIPI2 were more powerful in predicting moisture of capsules (R2 > 0.76). High efficiency was also obtained with VARIgreen, an index estimated from the common bands of a conventional RGB camera. The best performing VIs were further utilized in multiple linear regression models also incorporating the date of spraying as information. The VI models further improved the predicting power with an R2 of up to 0.73 for stems and leaves and 0.81 for capsules.

Em função do envelhecimento populacional e aumento de doenças crônicas não transmissíveis, a Estratégia Saúde da Família (ESF) tem se deparado com as necessidades das pessoas em processo de morte. A partir da análise do trabalho de profissionais da saúde que cuidaram de pessoas em processo de morte, o objetivo deste artigo é discutir as necessidades de saúde nesse processo, a fim de subsidiar o trabalho com essa população, especialmente na Atenção Primária à Saúde. Participaram da entrevista, após serem selecionados por dois questionários, onze profissionais (enfermeiros e médicos) da ESF de Campinas/SP. A análise de dados foi pautada no referencial teórico-metodológico da Psicologia histórico-cultural. Como resultado, tem-se que as necessidades dos pacientes e familiares não são restritas ao momento de vida (proximidade da morte), mas referem-se, também, às condições de vulnerabilidade social.

Integrating information about the spatial distribution of carbon stocks and species diversity in tropical forests over large areas is fundamental for climate change mitigation and biodiversity conservation. In this study, spatial models showing the distribution of carbon stocks and the number of species were produced in order to identify areas that maximize carbon storage and biodiversity in the tropical forests of the Yucatan Peninsula, Mexico. We mapped carbon density and species richness of trees using L-band radar backscatter data as well as radar texture metrics, climatic and field data with the random forest regression algorithm. We reduced sources of errors in plot data of the national forest inventory by using correction factors to account for carbon stocks of small trees (2) of 0.28 and 0.31 and a relative mean square error of 38.5% and 33.0% for aboveground biomass and species richness, respectively, at pixel level. Estimates of carbon density were influenced mostly by radar backscatter and climatic data, while those of species richness were influenced mostly by radar texture and climatic variables. Correlation between carbon density and species richness was positive in 79.3% of the peninsula, while bivariate maps showed that 39.6% of the area in the peninsula had high carbon stocks and species richness. Our results highlight the importance of combining carbon and diversity maps to identify areas that are critical—both for maintaining carbon stocks and for conserving biodiversity.

Opuntia ficus indica is a source of vitamins and minerals, and recently, it has been used as ingredient to make a new functional pasta. Italy produces the highest amount of pasta in the world and it is also the second-highest producer of opuntia globally. This study sought to identify the consumer willingness to pay for pasta featuring Opuntia ficus indica and to understand what factors influence their choice. This study is the first in food research to analyze consumers’ willingness to pay for a new functional pasta featuring Opuntia ficus indica. Data were collected by using a web-based survey; the sample was composed of 342 consumers and an ordered logistic regression model was applied. The findings showed that the educational and higher income levels of respondents play important roles in the willingness to pay for functional pasta. Moreover, the healthy and nutritional features of functional pasta together with the respondents’ willingness to eat it, their curiosity towards this new food and their need to get more information about functional pasta should improve consumers’ willingness to pay for it. The findings should be useful for firms to draw marketing strategies considering the positive consumers’ attitude toward the use of Opuntia ficus indica in pasta production.

Opuntia ficus-indica is a source of minerals and vitamins and has recently been used as ingredient to make a new functional variety of pasta. Italy was the first country in the world to produce pasta and is also the second largest producer of Opuntia in the world. According to an Italian sample, this study considers the main factors that could influence consumers when choosing functional pasta (featuring Opuntia) and characterizes distinct hypothetical consumer segments in terms of their food habits, pasta choices, and perceptions toward functional pasta featuring Opuntia. Data were collected using a web-based survey and with 328 respondents. Factor analysis (FA) with orthogonal rotation (varimax) was used to simplify the observed variables and hierarchical cluster analysis was performed with the FA results. Seven clusters were identified and the main results show that the level of education plays an important role in the perception of functional pasta. In fact, the perceptions of well-educated people differed from poorly-educated people. Moreover, the results showed significant respondent interest regarding health benefits and the nutritional and environmental aspects of functional pasta, which should encourage people’s acceptance and consumption of this new functional food. In addition, the respondent preferences reflect a value of experience towards the pasta, i.e., the belief of cooking typical Italian pasta. This means that Opuntia used for the production of functional pasta should maintain the organoleptic and physical properties of durum wheat-based pasta. In addition, respondent preferences for pasta featuring Opuntia could also be driven by its price.