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Microbial contamination poses a threat to both the preservation of library and archival collections and the health of staff and users. This study investigated the microbial communities and potential health risks associated with the UNESCO-classified Norwegian Sea Trade Archive (NSTA) collection exhibiting visible microbial colonization and staff health concerns. Dust samples from book surfaces and the storage environment were analysed using culturing methods, qPCR, Next Generation Sequencing, and mycotoxin, cytotoxicity and azole resistance assays. Penicillium sp., Aspergillus sp., and Cladosporium sp. were the most common fungi identified, with some potentially toxic species like Stachybotrys sp., Toxicladosporium sp. and Aspergillus section Fumigati. Fungal resistance to azoles was not detected. Only one mycotoxin, sterigmatocystin, was found in a heavily contaminated book. Dust extracts from books exhibited moderate to high cytotoxicity on human lung cells, suggesting a potential respiratory risk. The collection had higher contamination levels compared to the storage environment, likely due to improved storage conditions. Even though, overall low contamination levels were obtained, which might be underestimated due to the presence of salt (from cod preservation) that could have interfered with the analyses. This study underlines the importance of monitoring microbial communities and implementing proper storage measures to safeguard cultural heritage and staff well-being., Comment: 17 pages, 7 figures, 2 tables

Electron spin resonance (ESR) spectroscopy in scanning tunneling microscopy (STM) has enabled probing the electronic structure of single magnetic atoms and molecules on surfaces with unprecedented energy resolution, as well as demonstrating coherent manipulation of single spins. Despite this remarkable success, the field could still be greatly advanced by a more quantitative understanding of the ESR-STM physical mechanisms. Here, we present a theory of ESR-STM which quantitatively models not only the ESR signal itself, but also the full background tunneling current, from which the ESR signal is derived. Our theory is based on a combination of Green's function techniques to describe the electron tunneling and a quantum master equation for the dynamics of the spin system along with microwave radiation interacting with both the tunneling current and the spin system. We show that this theory is able to quantitatively reproduce the experimental results for a spin-1/2 system (TiH molecules on MgO) across many orders of magnitude in tunneling current, providing access to the relaxation and decoherence rates that govern the spin dynamics due to intrinsic mechanisms and to the applied bias voltage. More importantly, our work establishes that: (i) sizable ESR signals, which are a measure of microwave-induced changes in the junction magnetoresistance, require surprisingly high tip spin polarizations, (ii) the coupling of the magnetization dynamics to the microwave field gives rise to the asymmetric ESR spectra often observed in this spectroscopy. Additionally, our theory provides very specific predictions for the dependence of the relaxation and decoherence times on the bias voltage and the tip-sample distance. Finally, with the help of electromagnetic simulations, we find that the transitions in our ESR-STM experiments can be driven by the ac magnetic field at the junction., Comment: 17 pages, 6 figures

The increase in non-biodegradable waste is a worldwide concern. Recycling facilities play a crucial role, but their automation is hindered by the complex characteristics of waste recycling lines like clutter or object deformation. In addition, the lack of publicly available labeled data for these environments makes developing robust perception systems challenging. Our work explores the benefits of multimodal perception for object segmentation in real waste management scenarios. First, we present SpectralWaste, the first dataset collected from an operational plastic waste sorting facility that provides synchronized hyperspectral and conventional RGB images. This dataset contains labels for several categories of objects that commonly appear in sorting plants and need to be detected and separated from the main trash flow for several reasons, such as security in the management line or reuse. Additionally, we propose a pipeline employing different object segmentation architectures and evaluate the alternatives on our dataset, conducting an extensive analysis for both multimodal and unimodal alternatives. Our evaluation pays special attention to efficiency and suitability for real-time processing and demonstrates how HSI can bring a boost to RGB-only perception in these realistic industrial settings without much computational overhead.

Radio-frequency particle accelerators are engines of discovery, powering high-energy physics and photon science, but are also large and expensive due to their limited accelerating fields. Plasma-wakefield accelerators (PWFAs) provide orders-of-magnitude stronger fields in the charge-density wave behind a particle bunch travelling in a plasma, promising particle accelerators of greatly reduced size and cost. However, PWFAs can easily degrade the beam quality of the bunches they accelerate. Emittance, which determines how tightly beams can be focused, is a critical beam quality in for instance colliders and free-electron lasers, but is particularly prone to degradation. We demonstrate, for the first time, emittance preservation in a high-gradient and high-efficiency PWFA while simultaneously preserving charge and energy spread. This establishes that PWFAs can accelerate without degradation$\unicode{x2014}$essential for energy boosters in photon science and multistage facilities for compact high-energy particle colliders., Comment: 9 pages, 4 figures, 11 supplementary figures

The nature of the "failed" ferroelectric transition in SrTiO3 has been a long-standing puzzle in condensed matter physics. A compelling explanation is the competition between ferroelectricity and an instability with a mesoscopic modulation of the polarization. These polarization density waves, which should become especially strong near the quantum critical point, break local inversion symmetry and are difficult to probe with conventional x-ray scattering methods. Here we combine a femtosecond x-ray free electron laser (XFEL) with THz coherent control methods to probe inversion symmetry breaking at finite momenta and visualize the instability of the polarization on nanometer lengthscales in SrTiO3. We find polar-acoustic collective modes that are soft particularly at the tens of nanometer lengthscale. These precursor collective excitations provide evidence for the conjectured mesoscopic modulated phase in SrTiO3.

In spite of astonishing advances and developments in remote sensing technologies, meeting the spatio-temporal requirements for flood hydrodynamic modeling remains a great challenge for Earth Observation. The assimilation of multi-source remote sensing data in 2D hydrodynamic models participates to overcome such a challenge. The recently launched Surface Water and Ocean Topography (SWOT) wide-swath altimetry satellite provides a global coverage of water surface elevation at a high resolution. SWOT provides complementary observation to radar and optical images, increasing the opportunity to observe and monitor flood events. This research work focuses on the assimilation of 2D flood extent maps derived from Sentinel-1 C-SAR imagery data, and water surface elevation from SWOT as well as in-situ water level measurements. An Ensemble Kalman Filter (EnKF) with a joint state-parameter analysis is implemented on top of a 2D hydrodynamic TELEMAC-2D model to account for errors in roughness, input forcing and water depth in floodplain subdomains. The proposed strategy is carried out in an Observing System Simulation Experiment based on the 2021 flood event over the Garonne Marmandaise catchment. This work makes the most of the large volume of heterogeneous data from space for flood prediction in hindcast mode paves the way for nowcasting., Comment: Accepted for publication in IEEE 2024 International Geoscience & Remote Sensing Symposium (IGARSS 2024)

Unimolecular current rectifiers are fundamental building blocks in organic electronics. Rectifying behavior has been identified in numerous organic systems due to electron-hole asymmetries of orbital levels interfaced by a metal electrode. As a consequence, the rectifying ratio (RR) determining the diode efficiency remains fixed for a chosen molecule-metal interface. Here, we present a mechanically tunable molecular diode exhibiting an exceptionally large rectification ratio (>10^5) and reversible direction. The molecular system comprises a 7-armchair graphene nanoribbon (GNR) doped with a single unit of substitutional diboron within its structure, synthesized with atomic precision on a gold substrate by on-surface synthesis. The diboron unit creates half-populated in-gap bound states and splits the GNR frontier bands into two segments, localizing the bound state in a double barrier configuration. By suspending these GNRs freely between the tip of a low-temperature scanning tunneling microscope and the substrate, we demonstrate unipolar hole transport through the boron in-gap state's resonance. Strong current rectification is observed, associated with the varying widths of the two barriers, which can be tuned by altering the distance between tip and substrate. This study introduces an innovative approach for the precise manipulation of molecular electronic functionalities, opening new avenues for advanced applications in organic electronics., Comment: 9 pages, 4 figures; SI: 7 pages, 6 figures

We report the confirmation and mass determination of a mini-Neptune transiting the M3.5 V star TOI-4438 (G 182-34) every 7.44 days. A transit signal was detected with NASA's TESS space mission in the sectors 40, 52, and 53. In order to validate the planet TOI-4438 b and to determine the system properties, we combined TESS data with high-precision radial velocity measurements from the CARMENES spectrograph, spanning almost one year, and ground-based transit photometry. We found that TOI-4438 b has a radius of Rb = 2.52 +/- 0.13 R_Earth (5% precision), which together with a mass of Mb=5.4 +/- 1.1 M_Earth (20% precision), results in a bulk density of rho = 1.85+0.51-0.44 g cm-3 (28% precision), aligning the discovery with a volatile-rich planet. Our interior structure retrieval with a pure water envelope yields a minimum water mass fraction of 46% (1-sigma). TOI-4438 b is a volatile-rich mini-Neptune with likely H/He mixed with molecules, such as water, CO_2, and CH_4. The primary star has a J-band magnitude of 9.7, and the planet has a high transmission spectroscopy metric (TSM) of 136 +/- 13. Taking into account the relatively warm equilibrium temperature of T_eq = 435 +/- 15 K, and the low activity level of its host star, TOI-4438 b is one of the most promising mini-Neptunes around an M dwarf for transmission spectroscopy studies., Comment: Accepted for publication on Astronomy & Astrophysics

The first loading of gadolinium (Gd) into Super-Kamiokande in 2020 was successful, and the neutron capture efficiency on Gd reached 50\%. To further increase the Gd neutron capture efficiency to 75\%, 26.1 tons of $\rm Gd_2(\rm SO_4)_3\cdot \rm 8H_2O$ was additionally loaded into Super-Kamiokande (SK) from May 31 to July 4, 2022. As the amount of loaded $\rm Gd_2(\rm SO_4)_3\cdot \rm 8H_2O$ was doubled compared to the first loading, the capacity of the powder dissolving system was doubled. We also developed new batches of gadolinium sulfate with even further reduced radioactive impurities. In addition, a more efficient screening method was devised and implemented to evaluate these new batches of $\rm Gd_2(\rm SO_4)_3\cdot \rm 8H_2O$. Following the second loading, the Gd concentration in SK was measured to be $333.5\pm2.5$ ppm via an Atomic Absorption Spectrometer (AAS). From the mean neutron capture time constant of neutrons from an Am/Be calibration source, the Gd concentration was independently measured to be 332.7 $\pm$ 6.8(sys.) $\pm$ 1.1(stat.) ppm, consistent with the AAS result. Furthermore, during the loading the Gd concentration was monitored continually using the capture time constant of each spallation neutron produced by cosmic-ray muons,and the final neutron capture efficiency was shown to become 1.5 times higher than that of the first loaded phase, as expected., Comment: 34 pages, 13 figures, submitted to Nuclear Inst. and Methods in Physics Research, A

In the recent years, the interest in electric direct current (DC) technologies (such as converters, batteries, electric vehicles, etc.) is increasing due to its potential on energy efficiency and sustainability. However, the vast majority of electric systems and networks are based on alternating current (AC), as they also have certain advantages regarding cost-effective transport and robustness. In this paper, an AC/DC optimal power flow method for hybrid microgrids and several key performance indicators (KPIs) for its techno-economic assessment are presented. The combination of both calculations allows users to clearly determine the viability of their hybrid microgrids. AC/DC networks have been modelled considering their most common elements. For the power flow method, a polynomial optimisation is formulated considering four different objective functions: the minimisation of energy losses, voltage deviation and operational costs, and also the maximisation of the microgrid generation. The power flow method and the techno-economic analysis have been implemented in Python and validated in the Centro de Desarrollo de Energ\'ias Renovables (CEDER) demonstrator for TIGON. The results show that the calculated power flow variables and the ones measured at CEDER are practically the same. In addition, the KPIs have been obtained and compared for four operating scenarios: baseline, no battery, battery flexibility and virtual battery (VB) flexibility. The last one result in the most profitable option.

We have developed a method to determine the most reliable distances for a large group of planetary nebulae. For this purpose, we analyze the distances obtained from \textit{Gaia} parallaxes and three determinations of statistical distances. The most reliable distance is derived for 2211 objects, and uncertainties for these distances are calculated in a homogeneous way. Using our most reliable distances, we compare the distributions of Galactic heights of hydrogen-poor and hydrogen-rich central stars of planetary nebulae. We find that [WR] central stars are closer to the Galactic plane than hydrogen-rich central stars and than other hydrogen-poor central stars. The latter have a similar distribution to hydrogen-rich central stars, which is significantly different from the one of [WR] central stars. This result disagrees with the proposed evolutionary sequence for hydrogen-poor central stars., Comment: 19 pages, 3 figures, 2 tables, accepted in RMxAA

Our aim in this paper is to refine the orbital and physical parameters of the HATS-2 planetary system and study transit timing variations and atmospheric composition thanks to transit observations that span more than ten years and that were collected using different instruments and pass-band filters. We also investigate the orbital alignment of the system by studying the anomalies in the transit light curves induced by starspots on the photosphere of the parent star. We analysed new transit events from both ground-based telescopes and NASA's TESS mission. Anomalies were detected in most of the light curves and modelled as starspots occulted by the planet during transit events. We fitted the clean and symmetric light curves with the JKTEBOP code and those affected by anomalies with the PRISM+GEMC codes to simultaneously model the photometric parameters of the transits and the position, size, and contrast of each starspot. We found consistency between the values we found for the physical and orbital parameters and those from the discovery paper and ATLAS9 stellar atmospherical models. We identified different sets of consecutive starspot-crossing events that temporally occurred in less than five days. Under the hypothesis that we are dealing with the same starspots, occulted twice by the planet during two consecutive transits, we estimated the rotational period of the parent star and, in turn the projected and the true orbital obliquity of the planet. We find that the system is well aligned. We identified the possible presence of transit timing variations in the system, which can be caused by tidal orbital decay, and we derived a low-resolution transmission spectrum., Comment: 23 pages, 21 figures, Accepted for publication in Astronomy & Astrophysics

The Module-0 Demonstrator is a single-phase 600 kg liquid argon time projection chamber operated as a prototype for the DUNE liquid argon near detector. Based on the ArgonCube design concept, Module-0 features a novel 80k-channel pixelated charge readout and advanced high-coverage photon detection system. In this paper, we present an analysis of an eight-day data set consisting of 25 million cosmic ray events collected in the spring of 2021. We use this sample to demonstrate the imaging performance of the charge and light readout systems as well as the signal correlations between the two. We also report argon purity and detector uniformity measurements, and provide comparisons to detector simulations., Comment: 47 pages, 41 figures

We report the generation of a non-benzenoid polycyclic conjugated hydrocarbon, which consists of a biphenyl moiety substituted by indenyl units at the 4,4' positions, on ultra-thin sodium chloride films by tip-induced chemistry. Single-molecule characterization by scanning tunneling and atomic force microscopy reveals an open-shell biradical ground state, with a peculiar electronic configuration wherein the singly-occupied molecular orbitals (SOMOs) are lower in energy than the highest occupied molecular orbital (HOMO)., Comment: Manuscript: 7 pages and 3 figures. Supporting information: 10 pages and 11 figures

High-energy neutrinos could be produced in the interaction of charged cosmic rays with matter or radiation surrounding astrophysical sources. To look for transient sources associated with neutrino emission, a follow-up program of neutrino alerts has been operating within the ANTARES Collaboration since 2009. This program, named TAToO, has triggered robotic optical telescopes (MASTER, TAROT, ROTSE and the SVOM ground based telescopes) immediately after the detection of any relevant neutrino candidate and scheduled several observations in the weeks following the detection. A subset of ANTARES events with highest probabilities of being of cosmic origin has also been followed by the Swift and the INTEGRAL satellites, the Murchison Widefield Array radio telescope and the H.E.S.S. high-energy gamma-ray telescope. The results of twelve years of observations are reported. No optical counterpart has been significantly associated with an ANTARES candidate neutrino signal during image analysis. Constraints on transient neutrino emission have been set. In September 2015, ANTARES issued a neutrino alert and during the follow-up, a potential transient counterpart was identified by Swift and MASTER. A multi-wavelength follow-up campaign has allowed to identify the nature of this source and has proven its fortuitous association with the neutrino. The return of experience is particularly important for the design of the alert system of KM3NeT, the next generation neutrino telescope in the Mediterranean Sea., Comment: 27 pages, 14 figures, submitted to JCAP

In the prevalent picture of ultrafast structural phase transitions, the atomic motion occurs in a slowly varying potential energy surface determined adiabatically by the fast electrons. However, this ignores non-conservative forces caused by electron-lattice collisions, which can significantly influence atomic motion. Most ultrafast techniques only probe the average structure and are less sensitive to random displacements, and therefore do not detect the role played by non-conservative forces in phase transitions. Here we show that the lattice dynamics of the prototypical insulator-to-metal transition of VO2 cannot be described by a potential energy alone. We use the sample temperature to control the preexisting lattice disorder before ultrafast photoexcitation across the phase transition and our ultrafast diffuse scattering experiments show that the fluctuations characteristic of the rutile metal develop equally fast (120 fs) at initial temperatures of 100 K and 300 K. This indicates that additional non-conservative forces are responsible for the increased lattice disorder. These results highlight the need for more sophisticated descriptions of ultrafast phenomena beyond the Born-Oppenheimer approximation as well as ultrafast probes of spatial fluctuations beyond the average unit cell measured by diffraction.

Open-shell polycyclic aromatic hydrocarbons (PAHs) represent promising building blocks for carbon-based functional magnetic materials. Their magnetic properties stem from the presence of unpaired electrons localized in radical states of $\pi$ character. Consequently, these materials are inclined to exhibit spin delocalization, form extended collective states, and respond to the flexibility of the molecular backbones. However, they are also highly reactive, requiring structural strategies to protect the radical states from reacting with the environment. Here, we demonstrate that the open-shell ground state of the diradical 2-OS survives on a Au(111) substrate as a global singlet formed by two unpaired electrons with anti-parallel spins coupled through a conformational dependent interaction. The 2-OS molecule is a protected derivative of the Chichibabin's diradical, featuring a non-planar geometry that destabilizes the closed-shell quinoidal structure. Using scanning tunneling microscopy (STM), we localized the two interacting spins at the molecular edges, and detected an excited triplet state a few millielectronvolts above the singlet ground state. Mean-field Hubbard simulations reveal that the exchange coupling between the two spins strongly depends on the torsional angles between the different molecular moieties, suggesting the possibility of influencing the molecule's magnetic state through structural changes. This was demonstrated here using the STM tip to manipulate the molecular conformation, while simultaneously detecting changes in the spin excitation spectrum. Our work suggests the potential of these PAHs for a new class of all-carbon spin-crossover materials., Comment: 8 pages in the main manuscript, including 4 figures, 21 pages in the supporting info, including 19 figures

The KM3NeT/ARCA neutrino detector is currently under construction at 3500 m depth offshore Capo Passero, Sicily, in the Mediterranean Sea. The main science objectives are the detection of high-energy cosmic neutrinos and the discovery of their sources. Simulations were conducted for the full KM3NeT/ARCA detector, instrumenting a volume of 1 km$^3$, to estimate the sensitivity and discovery potential to point-like neutrino sources and an all-sky diffuse neutrino flux. This paper covers the reconstruction of track- and shower-like signatures, as well as the criteria employed for neutrino event selection. By leveraging both the track and shower observation channels, the KM3NeT/ARCA detector demonstrates the capability to detect the diffuse astrophysical neutrino flux within half a year of operation, achieving a 5$\sigma$ statistical significance. With an angular resolution below 0.1$^\circ$ for tracks and under 2$^\circ$ for showers, the sensitivity to point-like neutrino sources surpasses existing observed limits across the entire sky., Comment: 20 pages, 30 figures, Published by EPJ-C

Human exposure to electromagnetic fields produced by two wearable antennas operating in the 2.4 GHz frequency band was assessed by computational tools. Both antennas were designed to be attached to the skin, but they were intended for different applications. The first antenna was designed for off-body applications, i.e. to communicate with a device placed outside the body, while the second antenna model was optimized to communicate with a device located inside the body. The power absorption in human tissues was determined at several locations of adult male and female body models. The maximum specific absorption rate (SAR) value obtained with the off-body antenna was found on the torso of the woman model and was equal to 0.037 W/kg at 2.45 GHz. SAR levels increased significantly for the antenna transmitting inside the body. In this case, SAR values ranged between 0.23 and 0.45 W/kg at the same body location. The power absorbed in different body tissues and total power absorbed in the body were also calculated; the maximum total power absorbed was equal to 5.2 mW for an antenna input power equal to 10 mW.

Radiofrequency fields are usually measured in order to be compared with electromagnetic exposure limits defined by international standardization organizations with the aim of preserving the human health. However, in the case of WiFi technology, accurate measurement of the radiation coming from user terminals and access points is a great challenge due to the nature of these emissions, which are noncontinuous signals transmitted in the form of pulses of short duration. Most of the methodologies defined up to now for determining WiFi exposure levels use or take as reference exposimeters, broadband probes, and spectrum analyzers without taking into account that WiFi signals are not continuously transmitted. This leads to an overestimation of the radiation level that cannot be considered negligible when data of the actual exposure are needed. To avoid this, other procedures apply empirical weighting factors that account for the actual duration of burst transmissions. However, this implies the implementation of additional measurements for calculating the weighting factors, and thus, increases the complexity of the work. According to this, it was still necessary to define the frequency domain measurement setup that is optimal for obtaining realistic WiFi signal values, without requiring the performance of additional recordings. Thus, the definition of an appropriate methodology to achieve this goal was established as the main objective of this paper. The set of tasks carried out to identify such a configuration, as well as the limitations obtained for other measurement settings, are deeply explained in this paper., Comment: 10 pages

The DVB standard does not mandate the use of authentication and integrity protection for transport streams. This allows malicious third parties to replace legitimate broadcasts by overpowering terrestrial transmissions. The rogue signal can then deliver a malicious broadcast stream to exploit security vulnerabilities on Smart TVs (STVs) in range. We implemented a proof-of-concept attack based on a malicious Hybrid Broadcast Broadband TV app, able to acquire permanent system-level access to an STV over the air, in less than 10 s. These attacks, however, are severely limited in range due to required co-channel protection ratios (CCPRs), which is in direct contradiction to previous publications. We present evidence for these limitations in form of laboratory experiments, extensive simulations, and field measurements. To this end, we developed an automated, low-cost method for CCPR determination, as well as a method for non-disruptive attack range measurements based on a gap filler and the resulting channel impulse response., Comment: 13 pages

This paper presents an evaluation of the WiFi exposure levels inside the university in the 2.4 GHz frequency band. The selected environment is the typical scenario where WiFi exposure concerns have increased in the last years, since a Wireless Local Area Network is deployed close to the users. Measurements of 1 h and 24 h of duration were performed to assess the temporal and spatial variability of the signal. Two instruments were employed, a spectrum analyzer appropriate configured for recording accurate and realistic samples and an exposimeter. A detailed description of the equipment, the measurement procedure and data analysis is provided in order to allow the reproducibility of these types of measurements. Finally, a comparison of the WiFi levels obtained by other authors is presented, concluding that all these methods are useful for determining WiFi exposure distribution, but if more accurate results are required, professional equipment appropriately configured should be used., Comment: 9 pages

This study analyzes the mechanical and elemental properties of lunar meteorites DHOFAR 1084, JAH 838, NWA 11444, and HED meteorite NWA 6013. Utilizing microscale rock mechanics experiments, i.e., nanoindentation testing, this research reveals significant heterogeneity in both mechanical and elemental attributes across the minerals of the samples. Olivines, pyroxen, feldspar, and spinel demonstrate similar compositional and mechanical characteristics. Conversely, other silicate and oxide minerals display variations in their mechanical properties. Terrestrial olivines subjected to nanoindentation tests exhibit increased hardness and a higher Young's modulus compared to their lunar counterparts. A linear correlation is observed between the H/Er ratio and both plastic and elastic energies. Additionally, the alignment of mineral phases along a constant H/Er ratio suggests variations in local porosity. This study also highlights the need for further research focusing on porosity, phase insertions within the matrix, and structural orientations to refine our understanding of these mechanical characteristics. The findings have direct implications for in-situ resource utilization (ISRU) strategies and future state-of-the-art impact models. This comprehensive characterization serves as a foundational resource for future research efforts in space science and mining., Comment: Accepted for publication in Meteoritics & Planetary Science Journal

Since 1987, Spain has been continuously developing several scientific projects, mainly based on Earth Sciences, in Geodesy, Geochemistry, Geology or Volcanology. The need of a geodetic reference frame when doing hydrographic and topographic mapping meant the organization of the earlier campaigns with the main goals of updating the existing cartography and of making new maps of the area. During this period of time, new techniques arose in Space Geodesy improving the classical methodology and making possible its applications to other different fields such as tectonic or volcanism. Spanish Antarctic Geodetic activities from the 1987/1988 to 2006/2007 campaigns are described as well as a geodetic and a levelling network are presented. The first network, RGAE, was designed and established to define a reference frame in the region formed by the South Shetlands Islands, the Bransfield Sea and the Antarctic Peninsula whereas the second one, REGID, was planned to control the volcanic activity in Deception Island. Finally, the horizontal and vertical deformation models are described too, as well as the strategy which has been followed when computing an experimental geoid.

An algorithm to estimate the evolution of learning curves on the whole of a training data base, based on the results obtained from a portion and using a functional strategy, is introduced. We approximate iteratively the sought value at the desired time, independently of the learning technique used and once a point in the process, called prediction level, has been passed. The proposal proves to be formally correct with respect to our working hypotheses and includes a reliable proximity condition. This allows the user to fix a convergence threshold with respect to the accuracy finally achievable, which extends the concept of stopping criterion and seems to be effective even in the presence of distorting observations. Our aim is to evaluate the training effort, supporting decision making in order to reduce the need for both human and computational resources during the learning process. The proposal is of interest in at least three operational procedures. The first is the anticipation of accuracy gain, with the purpose of measuring how much work is needed to achieve a certain degree of performance. The second relates the comparison of efficiency between systems at training time, with the objective of completing this task only for the one that best suits our requirements. The prediction of accuracy is also a valuable item of information for customizing systems, since we can estimate in advance the impact of settings on both the performance and the development costs. Using the generation of part-of-speech taggers as an example application, the experimental results are consistent with our expectations., Comment: 30 pages, 11 figures

In order to minimize the generalization error in neural networks, a novel technique to identify overfitting phenomena when training the learner is formally introduced. This enables support of a reliable and trustworthy early stopping condition, thus improving the predictive power of that type of modeling. Our proposal exploits the correlation over time in a collection of online indicators, namely characteristic functions for indicating if a set of hypotheses are met, associated with a range of independent stopping conditions built from a canary judgment to evaluate the presence of overfitting. That way, we provide a formal basis for decision making in terms of interrupting the learning process. As opposed to previous approaches focused on a single criterion, we take advantage of subsidiarities between independent assessments, thus seeking both a wider operating range and greater diagnostic reliability. With a view to illustrating the effectiveness of the halting condition described, we choose to work in the sphere of natural language processing, an operational continuum increasingly based on machine learning. As a case study, we focus on parser generation, one of the most demanding and complex tasks in the domain. The selection of cross-validation as a canary function enables an actual comparison with the most representative early stopping conditions based on overfitting identification, pointing to a promising start toward an optimal bias and variance control., Comment: 26 pages, 6 figures

The recent trend towards the application of deep structured techniques has revealed the limits of huge models in natural language processing. This has reawakened the interest in traditional machine learning algorithms, which have proved still to be competitive in certain contexts, in particular low-resource settings. In parallel, model selection has become an essential task to boost performance at reasonable cost, even more so when we talk about processes involving domains where the training and/or computational resources are scarce. Against this backdrop, we evaluate the early estimation of learning curves as a practical mechanism for selecting the most appropriate model in scenarios characterized by the use of non-deep learners in resource-lean settings. On the basis of a formal approximation model previously evaluated under conditions of wide availability of training and validation resources, we study the reliability of such an approach in a different and much more demanding operationalenvironment. Using as case study the generation of PoS taggers for Galician, a language belonging to the Western Ibero-Romance group, the experimental results are consistent with our expectations., Comment: 17 papes, 5 figures