201. On the simultaneous deployment of two single particle mass spectrometers at an urban background and a road side site during SAPUSS.
- Author
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Dall’Osto, Manuel, Beddows, David C. S., McGillicuddy, Eoin J., Esser-Gietl, Johanna K., Harrison, Roy M., and Wenger, John C.
- Abstract
The Aerosol Time-of-Flight Mass Spectrometer (ATOFMS) provides size resolved information on the chemical composition of single particles with high time resolution. Within SAPUSS (Solving Aerosol Problems by Using Synergistic Strategies), continuous ATOFMS measurements of ambient particles were made simultaneously at two urban locations: urban background (UB) site and road side (RS) site in the city of Barcelona (Spain) from 17th September to 18th October 2010. Two different instrumental configurations were used: ATOFMS (TSI 3800) with a converging nozzle inlet (high efficiency at about 800-2000nm) at the UB site and ATOFMS (TSI 3800-100) with an aerodynamic lens inlet (high efficiency at about 300-700nm) at the RS site. This is the first time, to our knowledge, that two ATOFMS instruments have been deployed in the same field study. The different instrument configurations had an impact on the observed particle types at the two sites. Nevertheless, ten particle types were detected at both locations, including local and regional elemental carbon (22.7-58.9% of total particles), fresh and aged sea salt (1.0-14.6%), local and regional nitrate -containing aerosols (3-11.6%), local lead-containing metallic particles (0.1-0.2%) and transported Fe-nitrate particles (0.8-2.5%). The ATOFMS at the UB also characterised four particle types: calcium-containing dust (0.9%), Saharan dust (1.3%), vanadium-containing particles (0.9%) and vegetative debris (1.7%). By contrast, the high statistical counts of fine particles detected at the RS allowed identification of eight particle types. Four of these contained amines of primary and secondary origin. Aminium salts were found related to coarse sulphate rich particle types, suggesting heterogeneous reaction mechanisms for their formation. The other four particle types mainly containing organic carbon were found spiking at different types of the day, showing a complex single particle mixing state relationship between organic carbon and nitrate. This ATOFMS study clearly shows that the composition of atmospheric fine particles in Barcelona, and likely other Mediterranean urban areas, is complex, with a wide range of local and regional sources combining with chemical processing to produce at least twenty-two different particle types exhibiting different temporal behaviour. The advantage of using two ATOFMS instruments is also demonstrated, with the nozzle-skimmer configuration enabling detection of coarse dust particles and the aerodynamic lens configuration allowing better identification of particles rich in organic carbon and amines. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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