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In view of the vital role of water in chemical and physical processes, an exact knowledge of its dielectric function over a large frequency range is important. In this article we report on currently available measurements of the dielectric function of water at room temperature (25$^{\circ}$C) across the full electromagnetic spectrum: microwave, IR, UV and X-ray (up to 100 eV). We provide parameterisations of the complex dielectric function of water with two Debye (microwave) oscillators and high resolution of IR and UV/X-ray oscillators. We also report dielectric parameters for ice-cold water with a microwave/IR spectrum measured at $0.4^\circ$C, while taking the UV spectrum from 25$^{\circ}$C (assuming negligible temperature dependence in UV). We illustrate the consequences of the model via calculations of van der Waals interactions of gas molecules near water surfaces, and an assessment of the thickness of water films on ice and ice films on water. In contrast to earlier models of ice-cold water, we predict that a micron-scale layer of ice is stabilised on a bulk water surface. Similarly, the van der Waals interaction promotes complete freezing rather than supporting a thin premelting layer of water on a bulk ice surface. Density-based extrapolation from warm to cold water of the dielectric function at imaginary frequencies is found to be satisfactory in the microwave but poor (40% error) at IR frequencies.

LIME is a popular approach for explaining a black-box prediction through an interpretable model that is trained on instances in the vicinity of the predicted instance. To generate these instances, LIME randomly selects a subset of the non-zero features of the predicted instance. After that, the perturbed instances are fed into the black-box model to obtain labels for these, which are then used for training the interpretable model. In this study, we present a systematic evaluation of the interpretable models that are output by LIME on the two use-cases that were considered in the original paper introducing the approach; text classification and object detection. The investigation shows that the perturbation and labeling phases result in both data and label shift. In addition, we study the correlation between the shift and the fidelity of the interpretable model and show that in certain cases the shift negatively correlates with the fidelity. Based on these findings, it is argued that there is a need for a new sampling approach that mitigates the shift in the LIME's framework., Comment: Accepted at the Neurip 2019 Workshop "Human-Centric Machine Learning" (poster + spotlight talk)

We present the discovery and high-cadence follow-up observations of SN 2018ivc, an unusual Type II supernova that exploded in NGC 1068 (D=10.1 Mpc). The light curve of SN 2018ivc declines piecewise-linearly, changing slope frequently, with four clear slope changes in the first 30 days of evolution. This rapidly changing light curve indicates that interaction between the circumstellar material and ejecta plays a significant role in the evolution. Circumstellar interaction is further supported by a strong X-ray detection. The spectra are rapidly evolving and dominated by hydrogen, helium, and calcium emission lines. We identify a rare high-velocity emission-line feature blueshifted at ~7800 km/s (in Ha, Hb, Pb, Pg, HeI, CaII), which is visible from day 18 until at least day 78 and could be evidence of an asymmetric progenitor or explosion. From the overall similarity between SN 2018ivc and SN 1996al, the \Ha{} equivalent width of its parent HII region, and constraints from pre-explosion archival Hubble Space Telescope images, we find that the progenitor of SN 2018ivc could be as massive as 52 Msun but is more likely <12 Msun. SN 2018ivc demonstrates the importance of the early discovery and rapid follow-up observations of nearby supernovae to study the physics and progenitors of these cosmic explosions., Comment: Accepted by ApJ. Revised version includes more extensive progenitor analysis

Prussian blue analogues (PBAs) are a broad and important family of microporous inorganic solids, famous for their gas storage, metal-ion immobilisation, proton conduction, and stimuli-dependent magnetic, electronic and optical properties. The family also includes the widely-used double-metal cyanide (DMC) catalysts and the topical hexacyanoferrate/hexacyanomanganate (HCF/HCM) battery materials. Central to the various physical properties of PBAs is the ability to transport mass reversibly, a process made possible by structural vacancies. Normally presumed random, vacancy arrangements are actually crucially important because they control the connectivity of the micropore network, and hence diffusivity and adsorption profiles. The long-standing obstacle to characterising PBA vacancy networks has always been the relative inaccessibility of single-crystal samples. Here we report the growth of single crystals of a range of PBAs. By measuring and interpreting their X-ray diffuse scattering patterns, we identify for the first time a striking diversity of non-random vacancy arrangements that is hidden from conventional crystallographic analysis of powder samples. Moreover, we show that this unexpected phase complexity can be understood in terms of a remarkably simple microscopic model based on local rules of electroneutrality and centrosymmetry. The hidden phase boundaries that emerge demarcate vacancy-network polymorphs with profoundly different micropore characteristics. Our results establish a clear foundation for correlated defect engineering in PBAs as a means of controlling storage capacity, anisotropy, and transport efficiency.

We demonstrate that the Lifshitz interaction energy (excluding the self-energies of the inner and outer spherical regions) for three concentric spherical dielectric media can be evaluated easily using the immense computation power in recent processors relative to those of a few decades ago. As a prototype, we compute the Lifshitz interaction energy for a spherical shell of water immersed in water vapor of infinite extent while enclosing a spherical ball of ice inside the shell, such that two concentric spherical interfaces are formed: one between solid ice and liquid water and the other between liquid water and gaseous vapor. We evaluate the Lifshitz interaction energy for the above configuration at the triple point of water when the solid, liquid, and gaseous states of water coexist, and, thus, extend the analysis of Elbaum and Schick in Phys. Rev. Lett. 66 (1991) 1713 to spherical configurations. We find that, when the Lifshitz energy contributes dominantly to the total energy of this system, which is often the case when electrostatic interactions are absent, a drop of water surrounded by vapor of infinite extent is not stable at the triple point. This instability, that is a manifestation of the quantum fluctuations in the medium, will promote formation of ice in water, which will then grow in size indefinitely. This is a consequence of the finding here that the Lifshitz energy is minimized for large (micrometer size) radius of the ice ball and small (nanometer size) thickness of the water shell surrounding the ice. These results might be relevant to the formation of hail in thunderclouds. These results are tentative in that the self-energies are omitted; surface tension and nucleation energy are not considered., Comment: 15 pages, 9 figures, 1 table, conclusions toned down

We present high-cadence ultraviolet (UV), optical, and near-infrared (NIR) data on the luminous Type II-P supernova SN 2017gmr from hours after discovery through the first 180 days. SN 2017gmr does not show signs of narrow, high-ionization emission lines in the early optical spectra, yet the optical lightcurve evolution suggests that an extra energy source from circumstellar medium (CSM) interaction must be present for at least 2 days after explosion. Modeling of the early lightcurve indicates a ~500R$_{\odot}$ progenitor radius, consistent with a rather compact red supergiant, and late-time luminosities indicate up to 0.130 $\pm$ 0.026 M$_{\odot}$ of $^{56}$Ni are present, if the lightcurve is solely powered by radioactive decay, although the $^{56}$Ni mass may be lower if CSM interaction contributes to the post-plateau luminosity. Prominent multi-peaked emission lines of H$\alpha$ and [O I] emerge after day 154, as a result of either an asymmetric explosion or asymmetries in the CSM. The lack of narrow lines within the first two days of explosion in the likely presence of CSM interaction may be an example of close, dense, asymmetric CSM that is quickly enveloped by the spherical supernova ejecta., Comment: Submitted to ApJ, 25 pages, plus Appendix

Dispersion forces such as van der Waals forces between two microscopic particles, the Casimir--Polder forces between a particle and a macroscopic object or the Casimir force between two dielectric objects are well studied in vacuum. However, in realistic situations the interacting objects are often embedded in an environmental medium. Such a solvent influences the induced dipole interaction. With the framework of macroscopic quantum electrodynamics, these interactions are mediated via an exchange of virtual photons. Via this method the impact of a homogeneous solvent medium can be expressed as local-field corrections leading to excess polarisabilities which have previously been derived for hard boundary conditions. In order to develop a more realistic description, we investigate on a one-dimensional analog system illustrating the influence of a continuous dielectric profile.

The Gradient Boosted Tree (GBT) algorithm is one of the most popular machine learning algorithms used in production, for tasks that include Click-Through Rate (CTR) prediction and learning-to-rank. To deal with the massive datasets available today, many distributed GBT methods have been proposed. However, they all assume a row-distributed dataset, addressing scalability only with respect to the number of data points and not the number of features, and increasing communication cost for high-dimensional data. In order to allow for scalability across both the data point and feature dimensions, and reduce communication cost, we propose block-distributed GBTs. We achieve communication efficiency by making full use of the data sparsity and adapting the Quickscorer algorithm to the block-distributed setting. We evaluate our approach using datasets with millions of features, and demonstrate that we are able to achieve multiple orders of magnitude reduction in communication cost for sparse data, with no loss in accuracy, while providing a more scalable design. As a result, we are able to reduce the training time for high-dimensional data, and allow more cost-effective scale-out without the need for expensive network communication., Comment: SIGIR 2019

Gas hydrates formed in oceans and permafrost occur in vast quantities on Earth representing both a massive potential fuel source and a large threat in climate forecasts. They have been predicted to be important on other bodies in our solar systems such as Enceladus, a moon of Saturn. CO$_2$-hydrates likely drive the massive gas-rich water plumes seen and sampled by the spacecraft Cassini, and the source of these hydrates is thought to be due to buoyant gas hydrate particles. Dispersion forces cause gas hydrates to be coated in a 3-4 nm thick film of ice, or to contact water directly, depending on which gas they contain. These films are shown to significantly alter the properties of the gas hydrate clusters, for example, whether they float or sink. It is also expected to influence gas hydrate growth and gas leakage.

The nearby SN 2017eaw is a Type II-P (``plateau') supernova showing early-time, moderate CSM interaction. We present a comprehensive study of this SN including the analysis of high-quality optical photometry and spectroscopy covering the very early epochs up to the nebular phase, as well as near-UV and near-infrared spectra, and early-time X-ray and radio data. The combined data of SNe 2017eaw and 2004et allow us to get an improved distance to the host galaxy, NGC 6946, as $D \sim 6.85$ $\pm 0.63$ Mpc; this fits in recent independent results on the distance of the host and disfavors the previously derived (30% shorter) distances based on SN 2004et. From modeling the nebular spectra and the quasi-bolometric light curve, we estimate the progenitor mass and some basic physical parameters for the explosion and the ejecta. Our results agree well with previous reports on a RSG progenitor star with a mass of $\sim15-16$ M$_\odot$. Our estimation on the pre-explosion mass-loss rate ($\dot{M} \sim3 \times 10^{-7} -$ $1\times 10^{-6} M_{\odot}$ yr$^{-1}$) agrees well with previous results based on the opacity of the dust shell enshrouding the progenitor, but it is orders of magnitude lower than previous estimates based on general light-curve modeling of Type II-P SNe. Combining late-time optical and mid-infrared data, a clear excess at 4.5 $\mu$m can be seen, supporting the previous statements on the (moderate) dust formation in the vicinity of SN 2017eaw., Comment: 34 pages, 19 figures, 7 tables; accepted for publication in ApJ

We present a density functional theory (DFT) for lattice models with local electron-electron (e-e) and electron-phonon (e-ph) interactions. Exchange-correlation potentials are derived via dynamical mean field theory for the infinite-dimensional Bethe lattice, and analytically for an isolated Hubbard-Holstein site. These potentials exhibit discontinuities as a function of the density, which depend on the relative strength of the e-e and e-ph interactions. By comparing to exact benchmarks, we show that the DFT formalism gives a good description of the linear conductance and real-time dynamics., Comment: 5 pages, 3 figures, supplemental material provided as pdf

We demonstrate the control of multiphoton electron excitations in InAs nanowires (NWs) by altering the crystal structure and the light polarization. Using few-cycle, near-infrared laser pulses from an optical parametric chirped-pulse amplification system, we induce multiphoton electron excitations in InAs nanowires with controlled wurtzite (WZ) and zincblende (ZB) segments. With a photoemission electron microscope, we show that we can selectively induce multiphoton electron emission from WZ or ZB segments of the same wire by varying the light polarization. Developing \textit{ab-initio GW} calculations of 1st to 3rd order multiphoton excitations and using finite-difference time-domain simulations, we explain the experimental findings: While the electric-field enhancement due to the semiconductor/vacuum interface has a similar effect for all NW segments, the 2nd and 3rd order multiphoton transitions in the band structure of WZ InAs are highly anisotropic, in contrast to ZB InAs. As the crystal phase of NWs can be precisely and reliably tailored, our findings opens up for new semiconductor optoelectronics with controllable nanoscale emission of electrons through vacuum or dielectric barriers., Comment: 6 figures, 27 pages (including cover picture)

Hydrogen-rich, core-collapse supernovae are typically divided into four classes: IIP, IIL, IIn, and IIb. In general, interaction with circumstellar material is only considered for Type IIn supernovae. However, recent hydrodynamic modeling of IIP and IIL supernovae requires circumstellar material to reproduce their early light curves. In this scenario, IIL supernovae experience large amounts of mass loss before exploding. We test this hypothesis on ASASSN-15oz, a Type IIL supernova. With extensive follow-up in the X- ray, UV, optical, IR, and radio we present our search for signs of interaction, and the mass-loss history indicated by their detection. We find evidence of short-lived intense mass-loss just prior to explosion from light curve modeling, amounting in 1.5 M$_{\odot}$ of material within 1800 R$_{\odot}$ of the progenitor. We also detect the supernova in the radio, indicating mass-loss rates of $10^{-6}-10^{-7}$ M$_{\odot}$ yr$^{-1}$ prior to the extreme mass-loss period. Our failure to detect the supernova in the X-ray and the lack of narrow emission lines in the UV, optical, and NIR do not contradict this picture and place an upper limit on the mass-loss rate outside the extreme period of $<10^{-4}$ M$_{\odot}$ yr$^{-1}$. This paper highlights the importance gathering comprehensive data on more Type II supernovae to enable detailed modeling of the progenitor and supernova which can elucidate their mass-loss histories and envelope structures and thus inform stellar evolution models., Comment: Submitted to MNRAS including referee comments

Magnetic skyrmions, topologically protected vortex-like configurations in spin textures, are of wide conceptual and practical appeal for quantum information technologies, notably in relation to the making of so-called race-track memory devices. Skyrmions can be created, steered and destroyed with magnetic fields and/or (spin) currents. Here we focus on the latter mechanism, analyzed via a microscopic treatment of the skyrmion-current interaction. The system we consider is an isolated skyrmion in a square-lattice cluster, interacting with electrons spins in a current-carrying quantum wire. For the theoretical description, we employ a quantum formulation of spin-dependent currents via nonequilibrium Green's functions (NEGF) within the generalized Kadanoff-Baym ansatz (GKBA). This is combined with a treatment of skyrmions based on classical localized spins, with the skyrmion motion described via Ehrenfest dynamics. With our mixed quantum-classical scheme, we assess how time-dependent currents can affect the skyrmion dynamics, and how this in turn depends on electron-electron and spin-orbit interactions in the wire. Our study shows the usefulness of a quantum-classical treatment of skyrmion steering via currents, as a way for example to validate/extract an effective, classical-only, description of skyrmion dynamics from a microscopic quantum modeling of the skyrmion-current interaction., Comment: 10 pages, 8 figures, contribution to the proceedings of "Progress in Nonequilibrium Green's Functions VII"

We use tunneling spectroscopy to study the evolution of few-electron spin states in parallel InAs nanowire double quantum dots (QDs) as a function of level detuning and applied magnetic field. Compared to the much more studied serial configuration, parallel coupling of the QDs to source and drain greatly expands the probing range of excited state transport. Owing to a strong confinement, we can here isolate transport involving only the very first interacting single QD orbital pair. For the (2,0)-(1,1) charge transition, with relevance for spin-based qubits, we investigate the excited (1,1) triplet, and hybridization of the (2,0) and (1,1) singlets. An applied magnetic field splits the (1,1) triplet, and due to spin-orbit induced mixing with the (2,0) singlet, we clearly resolve transport through all triplet states near the avoided singlet-triplet crossings. Transport calculations, based on a simple model with one orbital on each QD, fully replicate the experimental data. Finally, we observe an expected mirrored symmetry between the 1-2 and 2-3 electron transitions resulting from the two-fold spin degeneracy of the orbitals., Comment: 17 pages, 8 figures

We present a Python package, pwv_kpno, that provides models for the atmospheric transmission due to precipitable water vapor (PWV) at user specified sites. Using the package, ground-based photometric observations taken between $3,000$ and $12,000$ $\AA$ can be corrected for atmospheric effects due to PWV. Atmospheric transmission in the optical and near-infrared is highly dependent on the PWV column density along the line of sight. By measuring the delay of dual-band GPS signals through the atmosphere, the SuomiNet project provides accurate PWV measurements for hundreds of locations around the world. The pwv_kpno package uses published SuomiNet data in conjunction with MODTRAN models to determine the modeled, time-dependent atmospheric transmission. A dual-band GPS system was installed at Kitt Peak National Observatory (KPNO) in the spring of 2015. Using measurements from this receiver we demonstrate that we can successfully predict the PWV at KPNO from nearby dual-band GPS stations on the surrounding desert floor. The pwv_kpno package can thus provide atmospheric transmission functions for observations taken before the KPNO receiver was installed. Using PWV measurements from the desert floor, we correctly model PWV absorption features present in spectra taken at KPNO. We also demonstrate how to configure the package for use at other observatories.

We present a theory for Casimir--Polder forces acting on greenhouse gas molecules dissolved in a thin water film. Such a nanosized film has recently been predicted to arise on th surface of melting ice as stabilized by repulsive Lifshitz forces. We show that different models for the effective polarizability of greenhouse gas molecules in water lead to different predictions for how Casimir--Polder forces influence the extraction of CH$_4$ and CO$_2$ molecules from the melting ice surface. In the most intricate model of a finite-sized molecule inside a cavity, dispersion potentials push the methane molecules towards the ice surface whereas the carbon dioxide typically will be attracted towards the closest interface (ice or air). Previous models for effective polarizability had suggested that CO$_2$ would also be pushed towards the ice surface. Release of greenhouse gas molecules from the surface of melting ice can potentially influence climate greenhouse effects.

A tenet of time-resolved spectroscopy is -faster laser pulses for shorter timescales- . Here we suggest turning this paradigm around, and slow down the system dynamics via repeated measurements, to do spectroscopy on longer timescales. This is the principle of the quantum Zeno effect. We exemplify our approach with the Auger process, and find that repeated measurements increase the core-hole lifetime, redistribute the kinetic energy of Auger electrons, and alter entanglement formation. We further provide an explicit experimental protocol for atomic Li, to make our proposal concrete., Comment: 5 pages, 4 figures, supplemental material provided

We analyse the Lifshitz pressure between silica and tin separated by a liquid mixture of bromobenzene and chlorobenzene. We show that the phase transition from semimetallic $\alpha$-Sn to metallic $\beta$-Sn can switch Lifshitz forces from repulsive to attractive. This effect is caused by the difference in dielectric functions of $\alpha$-Sn and $\beta$-Sn, giving both attractive and repulsive contributions to the total Lifshitz pressure at different frequency regions controlled by the composition of the intervening liquid mixture. In this way, one may be able to produce phase transition-controlled quantum levitation in liquid medium., Comment: 9 pages, 11 figures (to be published in Phys. Rev. B)

We study spin transport in the one- and two-electron regimes of parallel-coupled double quantum dots (DQDs). The DQDs are formed in InAs nanowires by a combination of crystal-phase engineering and electrostatic gating, with an interdot tunnel coupling ($t$) tunable by one order of magnitude. Large single-particle energy separations (up to 10 meV) and $|g^*|$ factors ($\sim$10) enable detailed studies of the $B$-field-induced transition from a singlet-to-triplet ground state as a function of $t$. In particular, we investigate how the magnitude of the spin-orbit-induced singlet-triplet anticrossing depends on $t$. For cases of strong coupling, we find values of 230 $\mu$eV for the anticrossing using excited-state spectroscopy. Experimental results are reproduced by calculations based on rate equations and a DQD model including a single orbital in each dot., Comment: 5 pages, 4 figures