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As the main material of the converter transformer dry-type bushing, the dielectric properties of epoxy/crepe paper at different temperatures and frequencies are related to the electric field and thermal field distribution of the bushing, which directly affects the safe and stable operation of the bushing. Here we report the dielectric response of samples of dry-type bushing insulation measured at a range of temperatures appropriate to operation and down to frequencies below those usually used. A significant loss peak observed below power frequency is interpreted as originating from the charging of internal epoxy resin interfaces by the transport of charge carriers on structured paths in the epoxy-impregnated crepe paper layers. A simulation model is proposed that allows estimation of the space charge and field distribution at any given frequency. [ABSTRACT FROM AUTHOR]

XLPE and its nanocomposites have been subjected to a progressive step voltage until failure occurred, and the results analyzed in terms of an inverse power law ageing expression. The step-stress tests have been conducted at three temperature 20°C,40°C and 60°C, and the exponent n of the inverse power law ageing expression has been estimated for the two materials by a new method, which fully considers the contribution to the failure of the whole sequence of voltage steps, including ageing processes at the lower voltages, the final step and the process of voltage increase. It was found that the value of exponent n increases slightly with increasing temperature for both XLPE and its nano-composites. More importantly the value of n for the nano-composites was found to be substantially lower than that for XLPE at all temperatures. A complementary experiment in which the space charge distribution was measured under the same step-stress protocol as the breakdown tests has also been carried out and the results of both experiments are discussed. [ABSTRACT FROM AUTHOR]

We report the results of electrical treeing tests carried out on a range of silicone dielectric gel samples made by varying the ratio of the same two components used for cross-linking a commercial silicone gel. These samples range from liquids to elastomers via two-phase gels. The extent of the curing is followed by means of FTIR spectroscopy and the samples are characterized through their dynamical mechanical properties. It is shown that the gel samples exhibit treeing behavior that includes features typical of both liquids and solids. A filamentary structure is produced that has permanence together with attached bubbles that self-heal locally during treeing, although differences in detail were found depending on the degree of curing. Removal of the treeing voltage allows a more substantial self-healing to occur. This behavior is discussed in terms of the two-phase liquid-solid nature of the silicone gels. [ABSTRACT FROM AUTHOR]

A bipolar charge transport model is used to simulate the formation of space charge in XLPE plaques placed under a temperature gradient. The model is used to assess the relative importance of charge migration and blocked extraction for three possible effects of the temperature gradient. The simulations were carried out for samples with different thicknesses and the results verified by comparison with experiment. In this way it has been shown that not only does the temperature gradient influence space charge accumulation through its introduction of a conductivity gradient, but also through differences in the injecting and extracting processes at electrodes of different temperature. [ABSTRACT FROM AUTHOR]

The dielectric response of crosslinked polyethylene (XLPE) insulated, miniature power cables, extruded with inner and outer semicons, was measured over the frequency range 10-4 to 104 Hz at temperatures from 20 to 100 °C. A dielectric spectrometer was used for the frequency range 10-4 to 10-2 Hz. A bespoke noise-free power supply was constructed and used to measure the dc conductivity and, using a Fourier transform technique, it was also used to measure the very low dielectric tanδ losses encountered at frequencies of 1 to 100 Hz. Tanδ measurements of <10-5 were found in this frequency range and attributed to a β-mode dielectric relaxation lying above 100 Hz due to motion of chain segments in the amorphous region and an α-mode relaxation lying below 1 Hz window due to twists of chains in the crystal lamellae. The dc conductivity measurements were consistent with those of the dielectric spectrometer and indicate lower dc conductivities in vacuum degassed cables than have been previously reported for XLPE (less than 10-17 S.m-1). The conduction process is thermally activated with an activation energy of approximately 1.1 eV. Higher conductivities were found for nondegassed cables. A transformer ratio bridge was used for measurements in the range 1 to 10 kHz; loss in this region was shown to be due to the series resistance of the semicon layers. Thermal ageing of the cables at 135 °C for 60 days caused significant increases in the conductivity and tanδ and it is considered that such measurements may be a sensitive way of measuring electrical degradation due to thermal aging. [ABSTRACT FROM AUTHOR]

Previously we have reported the existence of small-amplitude charge pulses in crosslinked Polyethylene (XLPE) and epoxy resin with a mobility several orders of magnitude higher than that found for the incoherent charge transport relevant to the steady state current. Here the relationship of this phenomenon to mechanical relaxation in the material is investigated by using a series of epoxy resin nanocomposites based on a resin that has its flexibility increased above that of the fully cured glassy epoxy network by the addition of a suitable flexibilizing chemical. Differential Scanning Calorimetry (DSC) measurements show that the stiffness of the nanocomposite is progressively increased as the nanoparticle concentration increases. Pulsed Electro-Acoustic (PEA) measurements reveal that both positive and negative fast charge pulses exist in the unfilled epoxy at 45 and 70°C under a field of 10 kV/mm with mobility 5×10 to 9×10 m V s, amplitude between 2×10 and 3.6×10 C m and repetition rates between 8 and 12 s. These values are reduced progressively as the nanoparticle concentration is increased from 0% in the unfilled epoxy. A β-mode mechanical relaxation is identified in the loss modulus by Dynamical Mechanical Analysis (DMA), whose activation energy moves to higher values with increasing nanoparticle concentration. It is shown that the repetition rates of both positive and negative pulses have similar values and are correlated with the β-mode activation energy; a similar correlation is found for the activation energy of the mobility of positive pulses. The correlation of the activation energy of the mobility of negative pulses and that of the β-mode is weaker although both show a progressive increase with nanoparticle concentration. The modification of the fast charge pulse properties by the mechanical stiffness of the epoxy nanocomposite is discussed in terms of the theory presented previously for their formation and transport. [ABSTRACT FROM AUTHOR]

The results of an investigation into electrical tree growth in XLPE cable insulation using an embedded needle electrode are reported for a range of voltages from 9 kV rms to 27 kV rms. The partial discharge (PD) activity and tree structures were measured simultaneously throughout the tree growth and the trees were recorded from initiation up to and including the final runaway stage. A multifractal analysis was also performed on the tree structures as they propagated, and it was found that their fractal dimension increased and the distribution of embedded structures changed as small side channels were added to the tree as it grew. At 11 kV rms only branch trees were found and only bush (bush-branch) trees at higher voltages, but at 9 kV rms trees of three different shapes were formed. Observation of the tree shapes at 9 kV rms under reflected light followed by a detailed analysis using con-focal Raman spectroscopy, showed that the stagnated and branch-pine (monkey puzzle) tree shapes were due to the formation of a conducting graphitic deposit upon the walls on tree branches in the region of the needle electrode. This was not present in the branch trees produced at 9 kV rms. A simple scheme is presented for the formation of branch-pine trees and their corresponding PD activity based on the concept of conducting branch generation. The trees produced at 13 kV rms and above have a bush shape, which converts into a bushbranch shape when a runaway branch grows from their periphery. This is shown to happen when the field at the bush tree periphery exceeded a voltage independent critical value, which was estimated to be 100 MV/m. The consequence of this result for the initiation of the runaway stage in branch trees is commented upon. [ABSTRACT FROM AUTHOR]