1. CARBON NANOPARTICLES BASED ON THERMALLY EXPANDED GRAPHITE: EFFECT OF THE TEG OBTAINING ROUTE ON THE PARTICLES MORPHOLOGY
- Author
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E.V. Raksha, V.A. Glazunova, O.N. Oskolkova, P.V. Sukhov, G.K. Volkova, A.A. Davydova, Yu.V. Berestneva, and M.V. Savoskin
- Subjects
few-layer graphenes ,liquid-phase exfoliation ,graphite nitrate ,cointercalation ,Physical and theoretical chemistry ,QD450-801 - Abstract
The paper presents the investigation results of the morphology of carbon nanoparticles formed during liquid-phase exfoliation of thermally expanded graphite in tert-butanol. The thermally expanded graphite used in this work was obtained by thermal expansion of graphite nitrate with acetic and formic acids in the thermal shock mode at 500°C and 900°C. Initial cointercalate was shown by powder X-ray diffraction analysis to be the mixture of the II^nd and the IV^th stage intercalation compounds. It has been established by transmission electron microscopy that dispersions of carbon nanoparticles formed during the exfoliation of thermally expanded graphite in tert-butanol via sonication contain mainly few-layer graphenes, the planar dimensions of which reach 8 μm. The influence of the conditions for thermally expanded graphite obtaining on the morphology of resulting carbon nanoparticles is discussed. Dispersions based on thermally expanded graphite obtained at a lower temperature, in addition to few-layer graphenes, also contain a significant amount of amorphous carbon particles with planar sizes up to 100 nm.
- Published
- 2021
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