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Preservation or curing of hides/skins is performed as the primary step of leather processing to conserve them from putrefaction. Normally preservation is carried out using common salt (NaCl), which is discharged in the soak liquor contributing to ~ 70%, of total dissolved solids (TDS) load of entire leather manufacturing. In an attempt to reduce the TDS and chlorides, phyto-based preservation using garlic peel (Allium sativum) and white onion peel (Allium cepa) was carried out. Different concentrations of salt in combination with garlic peel and white onion peel were applied on freshly flayed goat skins based on its green weight and compared to control (40% salt). Sensory evaluation of the preserved skin was done by assessing different parameters like hair slip, putrefaction and odour. Estimation of hydroxyproline (HP) release, moisture content and microbial load were carried out at regular intervals. Skins that remained in good condition for 14 days were further processed into leather and properties were examined which were found comparable to the conventionally cured skins. Hence, this cleaner curing technique helps in reducing the TDS and chlorides in the effluent, thus controlling the pollution caused by tanneries through sustainable leather processing.

Raw hides and skins are preserved before processing them into leather, to protect the skin protein from microbial attack. The salting method of preservation using about 50% w/w common salt is the most popularly practiced preservation method worldwide. This conventional system results in high saline wastewater leading to a huge amount of pollution load in terms of total dissolved solids and chlorides which is discharged into the effluent during the soaking process in leather manufacture. In order to overcome these wastes problem at their source, researchers have been involved in search of alternative preservation methods using salt-less or less-salt options. In the present study, the herbal Rumex abyssinicus (mekmeko) roots, which were shade dried at room temperature and powdered was investigated for its effectiveness in the preservation of goat skins. The efficacy of this new preservation method was assessed at different curing period for a month. In the assessment, the following parameters viz., moisture content, extractable nitrogen content, soluble hydroxyproline, hydrothermal stability, bacterial count, and visual evaluation of skins (hair slip and putrefaction odor) were assessed. The mekmeko preservation experiments were compared with parameters obtained using the conventional curing method. After 30 days of preservation, the experimental and control skins were processed into upper leather and their quality was evaluated by analyzing the physical characteristics, organoleptic properties and fiber structure using scanning electron microscope. The results showed that the curing system using 10% mekmeko powder with 15% common salt is efficient in preserving the raw goat skins. The quality of the experimental crust leathers produced from the optimized preservation system is comparable with the control leathers. The generation of the pollution load during leather processing was determined by analyzing biochemical oxygen demand, chemical oxygen demand, total dissolved solids, and chlorides from soaking liquor. Most importantly, 55% total dissolved solids and 70% chloride reduction in the soaking liquor was achieved by using the plant-based method of preservation. The less-salt preservation system based on mekmeko is a cleaner alternative for the conventional salt-based preservation method.