1. Exploring temperature-dependent photoluminescence dynamics of colloidal CdSe nanoplatelets using machine learning approach
- Author
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Ivan P. Malashin, Daniil Daibagya, Vadim Tynchenko, Vladimir Nelyub, Aleksei Borodulin, Andrei Gantimurov, Alexandr Selyukov, Sergey Ambrozevich, and Roman Vasiliev
- Subjects
Machine learning ,CdSe ,Nanoplatelets ,Luminescence ,Temporal dynamics ,Medicine ,Science - Abstract
Abstract The study explore machine learning (ML) techniques to predict temperature-dependent photoluminescence (PL) spectra in colloidal CdSe nanoplatelets (NPLs), leveraging polynomial regression models trained on experimental data from 85 to 270 K spanning temperatures to forecast PL spectra backward to 0 K and forward to 300 K. 6th-degree polynomial models with Tweedie regression were optimal for band energy ( $$B_1$$ ) predictions up to 300 K, while 9th-degree models with LassoLars and Linear Regression regressors were suitable for backward predictions to 0 K. For exciton energy ( $$B_2$$ ), the Lasso model of degree 5 and the Ridge model of degree 4 performed well up to 300 K, while the Tweedie model of degree 2 and Theil-Sen model of degree 2 showed promise for predictions to 0 K. Furthermore, a GA-based approach was utilized to fit experimental data to theoretical model of Fan and Varshni equations, facilitating a comparative analysis with the ML-predicted curves.
- Published
- 2024
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