7 results on '"Andrzej Kwaśnica"'
Search Results
2. Effect of Drying Methods on Chemical and Sensory Properties of Cannabis sativa Leaves
- Author
-
Andrzej Kwaśnica, Natalia Pachura, Ángel A. Carbonell-Barrachina, Hanán Issa-Issa, Dorota Szumny, Adam Figiel, Klaudia Masztalerz, Marta Klemens, and Antoni Szumny
- Subjects
cannabinoids ,drying ,essential oils ,GC-MS ,profiling terpenoids ,sensory analysis ,Organic chemistry ,QD241-441 - Abstract
Hemp is used as a source of fiber, oil and bioactive substances including volatile and cannabinoid-containing substances. This paper presents, for the first time, results on the evaluation of drying methods (convective, vacuum–microwave and combined convective pre-drying and vacuum–microwave finishing drying) of hemp leaves on the qualitative and quantitative changes in secondary metabolites, including essential oils, cannabinoids and sterols. A ranking and descriptive test of hemp leaves was also performed. Drying kinetics was presented using three models, including logarithmic, Midilli and modified Page. The SPME-Arrow technique was used to determine 41 volatile compounds, of which caryophyllene, β-myrcene and α-humulene were dominant in dried and fresh leaves. Regarding the essential oils obtained, 64 were identified, with caryophyllene, humulene epoxide II and limonene being the dominant ones. For preserving the highest amount of oils, the best method was the convective pre-drying followed by vacuum–microwave finishing drying (CD60-VMD) combined method, where the retention of volatile compounds was 36.08%, whereas the CD70 and 240-VMD methods resulted in the highest loss of 83%. The predominant cannabinoids in fresh hemp leaves were CBDA 6.05 and CBD 2.19 mg g−1. Drying caused no change in the cannabinoid profile of the plant material. β-Sitosterol, campesterol and lupeol were dominant in the phytosterol and triterpene fractions. No changes in either quality or quantity were observed in any of the variants found.
- Published
- 2023
- Full Text
- View/download PDF
3. Indicators of Engine Performance Powered by a Biofuel Blend Produced from Microalgal Biomass: A Step towards the Decarbonization of Transport
- Author
-
Patryk Ratomski, Małgorzata Hawrot-Paw, Adam Koniuszy, Wojciech Golimowski, Andrzej Kwaśnica, and Damian Marcinkowski
- Subjects
microalgal oil ,biodiesel ,diesel engine ,energy parameters ,exhaust emissions ,Technology - Abstract
According to the EU Directive, the so-called RED II, there is increasing significance for biofuels produced from biomass with low indirect land use change (ILUC) risk. Such an alternative and sustainable feedstock could be microalgae, among others, used for biodiesel production. This is due to the high lipid content of their cells and their potential ability to accumulate significant amounts of carbon dioxide in their biomass, which has a positive effect on the carbon footprint of the product. The aim of this study was to determine the effect of adding algal biodiesel to conventional diesel fuel on selected performance parameters of a diesel engine, taking into account the composition of the emitted exhaust gas. Energy-related engine performance parameters such as power, hourly and specific fuel consumption, engine thermal efficiency, and indicated efficiency were determined. No significant differences were found in the energy parameters of engine operation with the fuels tested. In terms of carbon monoxide and NOx emissions, at the highest engine torque, more favorable parameters were obtained for fuel with biodiesel produced from rapeseed oil (B/RME). Under the same conditions, carbon dioxide emissions for the fuel with the addition of biodiesel from microalgae (B/Algae) were 8.1% lower.
- Published
- 2023
- Full Text
- View/download PDF
4. Analysis of Changes in the Amount of Phytosterols after the Bleaching Process of Hemp Oils
- Author
-
Andrzej Kwaśnica, Mirosława Teleszko, Damian Marcinkowski, Dominik Kmiecik, Anna Grygier, and Wojciech Golimowski
- Subjects
Cannabis sativa L. ,phytosterols ,hemp oil ,Finola ,Earlina8FC ,Secuieni Jubileu ,Organic chemistry ,QD241-441 - Abstract
Unrefined vegetable oils from niche oilseeds are now sought after by consumers because of their unique nutritional properties and taste qualities. The color and flavor intensity of niche oils is a big problem, and their refining is not industrially feasible due to the small production scale. The study undertaken aimed analyze the effect of changing the amount of phytosterols (PSs) after the bleaching process of hemp oils of the ‘Finola’, ‘Earlina 8FC’ and ‘Secuieni Jubileu’ varieties. Cold-pressed (C) and hot-pressed (H) crude vegetable oils were bleached with selected bleaching earth (BE) at two concentrations. The post-process BE was extracted with methanol. The amount of PSs in the crude oils and the extract after washing the BE with methanol was analyzed by GC (gas chromatography). The study shows that the bleaching process did not significantly affect the depletion of PSs in the oils. Trace amounts of PSs remain on the BE and, due to methanol extraction, can be extracted from the oil. The conclusion of the performed research is that the bleaching of hemp oil does not cause depletion of the oil, and it significantly improves organoleptic properties. The oil bleaching process results in an oil loss of less than 2% by weight of the bleached oil, while the loss depends on the type of BE used. The study shows that the loss of phytosterols after the bleaching process averages 2.69 ± 0.69%, and depends on the type of BE used and the oil extracted from different varieties of hemp seeds.
- Published
- 2022
- Full Text
- View/download PDF
5. Quality of Oil Pressed from Hemp Seed Varieties: ‘Earlina 8FC’, ‘Secuieni Jubileu’ and ‘Finola’
- Author
-
Wojciech Golimowski, Mirosława Teleszko, Damian Marcinkowski, Dominik Kmiecik, Anna Grygier, and Andrzej Kwaśnica
- Subjects
Cannabis sativa L. ,sterols ,hemp oil ,‘Finola’ ,‘Earlina8FC’ ,Secuieni Jubileu ,Organic chemistry ,QD241-441 - Abstract
In the last decade, the demand for edible niche oils has increased. Therefore, the aim of this study was to characterize the seeds hemp (Cannabis sativa L.) varieties: ‘Finola’ (FIN-314)’, ‘Earlina 8FC’, and ‘Secuieni Jubileu’, and cold and hot pressed oils were prepared from each seed. The seeds were examined for moisture content, granulometric distribution, bulk density, and fat content. Seeds were pressed without and with preconditioning (60 °C), and oil yield and pressing time were recorded. The oil was filtered through cellulose membranes. Oil–water content, oil color, fatty acid profile, and sterol content were studied. From the study conducted, there are significant differences in the parameters of oil recovery and its quality compared to ‘Finola’ seed oil, which is widely reported in the literature. ‘Finola’ oil yield was the lowest, with an average of 79% compared to ‘Earlina’ (82%) and ‘S. Jubileu’ (84%). All oil samples contained a comparable amount of sterols, with campesterol (0.32 mg/g), β-sitosterol (1.3 mg/g) and Δ5-avenasterol (0.15 mg/g) predominating. From the organoleptic evaluation, it was evident that both varieties hemp oils and marc (‘Earlina’ and ‘S. Jubileu’) were not bitter like the “Finola” oil and marc. More detailed studies in this direction have to be undertaken.
- Published
- 2022
- Full Text
- View/download PDF
6. Volatile Composition and Sensory Properties as Quality Attributes of Fresh and Dried Hemp Flowers (Cannabis sativa L.)
- Author
-
Andrzej Kwaśnica, Natalia Pachura, Klaudia Masztalerz, Adam Figiel, Aleksandra Zimmer, Robert Kupczyński, Katarzyna Wujcikowska, Angel A. Carbonell-Barrachina, Antoni Szumny, and Henryk Różański
- Subjects
Cannabis sativa L. ,drying methods ,essential oils ,sensory evaluation ,Chemical technology ,TP1-1185 - Abstract
Flowers of hemp (Cannabis sativa L.) are widely used in cosmetics, food, and in the pharmaceutical industry. The drying process plays a key role in retention of aroma and also in the quality of products. Seven variants of hemp flower drying, including convection drying (CD), vacuum–microwave drying (VMD), and combined drying consisting of convective pre-drying followed by vacuum–microwave finishing drying (CPD-VMFD) were checked in this study. For each process, we applied the two-term model. Dried material was submitted to color and chromatographical assessments. Analyses of obtained essential oil showed the presence of 93 volatile compounds, predominantly β-myrcene, limonene, and β-(E)-caryophyllene, as well as α-humulene. Application of 240 W during VMD and 50 °C during CD gave the highest retention of aroma compounds, amounting to 85 and 76%, respectively, but with huge color changes. Additionally, sensory analysis proved that drying with a microwave power of 240 W provides a product most similar to fresh material.
- Published
- 2020
- Full Text
- View/download PDF
7. Illicit drugs street samples and their cutting agents. The result of the GC-MS based profiling define the guidelines for sensors development
- Author
-
Lukasz Poltorak, Monika Haczkiewicz, Sławomira Skrzypek, Konrad Rudnicki, Andrzej Kwaśnica, Karolina Sipa, and Anna Żubrycka
- Subjects
Traditional medicine ,Illicit Drugs ,Chemistry ,Street drugs ,MDMA ,Gas Chromatography-Mass Spectrometry ,Methamphetamine ,Analytical Chemistry ,Heroin ,Substance Abuse Detection ,Amphetamine ,Cutting agent ,Cocaine ,mental disorders ,medicine ,Gas chromatography–mass spectrometry ,medicine.drug ,Methadone - Abstract
In this work, we have focused on the profiling of 5647 street samples covering marijuana, common and new recreational illicit drugs. All samples were analyzed using gas chromatography-mass spectrometry (GC-MS) technique. In total we have identified 53 illicit drugs with Δ-9-tetrahydrocannabinol (THC), amphetamine, N-ethylhexedrone, 3,4-methylenedioxy methamphetamine (MDMA), 4-chloromethcathinone (4-CMC), α-pyrrolidinoisohexaphenone (α-PHiP), cocaine, and 4-chloroethcathinone (4-CEC) being most commonly found and making 38.5, 17.8, 15.5, 8.0, 3.5, 2.7, 2.1, and 2.0% of the total studied pool, respectively. Except for methadone, all analyzed street samples were spiked with at least one cutting agent. Caffeine was the most frequently found adulterating addition present in around 33% (excluding marijuana) of the analyzed samples. Other identified cutting agents make an impressive group of more than 160 compounds. Finally, we have tabulated, illustrated, and discussed presented data in a view of smart and portable sensors development.
- Published
- 2022
- Full Text
- View/download PDF
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.