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This study explores the effects of different types of nanoparticles, namely nano-SiO2 (NS), nano-TiO2 (NT), and nano-Fe2O3 (NF) on the fresh properties, mechanical properties, and microstructure of cement mortar containing fly ash as a supplementary cementitious material. These nanoparticles existed in powder form and were incorporated into the mortar at the dosages of 1%, 3%, and 5% wt.% of cement. Also, fly ash has been added into in mortars with a constant dosage of 30% wt.% of cement. Compressive and flexural strength tests were performed to evaluate the mechanical properties of the mortar specimens with different nanoparticles at three curing ages, 7, 14, and 28 days. Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) tests were conducted to study the microstructure and the hydration products of the mortars. To elucidate the effects of nanoparticles on the binder phase, additional experiments were performed on accompanying cement pastes: nanoindentation and open porosity measurements. The study shows that, if added in appropriate amounts, all nanoparticles investigated can result in significantly improved mechanical properties compared to the reference materials. However, exceeding of the optimal concentration results in clustering of the nanoparticles and reduces the mechanical properties of the composites, which is accompanied with increasing the porosity. This study provides guidelines for further improvement of concretes with blended cements through use of nanoparticles., Materials and Environment

Studies have shown that the incorporation of waste tire rubber aggregates reduces the strength, increases permeability and decrease thermal conductivity of concrete. However, only a few studies have investigated the effect of surface-modified rubber aggregates on the properties of concrete. This study investigates the effect of the surface treatment of waste tire rubber as coarse aggregates with different oxidizing solutions and different treatment durations on the mechanical, durability and thermal properties of concrete. The properties of concrete incorporated with 8% rubber coarse aggregates (by volume of natural aggregates) which were treated with three different solutions: water (H2O), 20% sodium hydroxide (NaOH) and 5% calcium hypochlorite [Ca(ClO)2] (both as% weight of water) for durations of 2, 24, and 72 h, respectively. The effect of these treatments on the compressive strength, splitting tensile strength, water permeability, thermal conductivity and diffusivity of concrete was investigated. Results show that Ca(ClO)2 has a more positive effect on the strength and permeability compared to NaOH solution and water. Experimental results were statistically analyzed using ANOVA and Post Hoc tests. The analyses showed that the improvement of concrete strength is only significant when the treatment with NaOH and Ca(ClO)2 is prolonged to 72 h. Furthermore, the microstructural analysis of concrete showed that the improvement in the strength is due to the improved bonding between cement paste and rubber aggregates as a result of surface treatment. This microstructural improvement also resulted in lower water permeability of concrete. However, the thermal conductivity and diffusivity increased when the surface treatment duration increases as there are less air voids in the samples. This study shows that, with appropriate pretreatment, a certain percentage of natural aggregates can be safely replaced with waste tire rubber aggregates while maintaining sufficient quali, Materials and Environment

This study explores the effects of different types of nanoparticles, namely nano-SiO2 (NS), nano-TiO2 (NT), and nano-Fe2O3 (NF) on the fresh properties, mechanical properties, and microstructure of cement mortar containing fly ash as a supplementary cementitious material. These nanoparticles existed in powder form and were incorporated into the mortar at the dosages of 1%, 3%, and 5% wt.% of cement. Also, fly ash has been added into in mortars with a constant dosage of 30% wt.% of cement. Compressive and flexural strength tests were performed to evaluate the mechanical properties of the mortar specimens with different nanoparticles at three curing ages, 7, 14, and 28 days. Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) tests were conducted to study the microstructure and the hydration products of the mortars. To elucidate the effects of nanoparticles on the binder phase, additional experiments were performed on accompanying cement pastes: nanoindentation and open porosity measurements. The study shows that, if added in appropriate amounts, all nanoparticles investigated can result in significantly improved mechanical properties compared to the reference materials. However, exceeding of the optimal concentration results in clustering of the nanoparticles and reduces the mechanical properties of the composites, which is accompanied with increasing the porosity. This study provides guidelines for further improvement of concretes with blended cements through use of nanoparticles., Materials and Environment

Studies have shown that the incorporation of waste tire rubber aggregates reduces the strength, increases permeability and decrease thermal conductivity of concrete. However, only a few studies have investigated the effect of surface-modified rubber aggregates on the properties of concrete. This study investigates the effect of the surface treatment of waste tire rubber as coarse aggregates with different oxidizing solutions and different treatment durations on the mechanical, durability and thermal properties of concrete. The properties of concrete incorporated with 8% rubber coarse aggregates (by volume of natural aggregates) which were treated with three different solutions: water (H2O), 20% sodium hydroxide (NaOH) and 5% calcium hypochlorite [Ca(ClO)2] (both as% weight of water) for durations of 2, 24, and 72 h, respectively. The effect of these treatments on the compressive strength, splitting tensile strength, water permeability, thermal conductivity and diffusivity of concrete was investigated. Results show that Ca(ClO)2 has a more positive effect on the strength and permeability compared to NaOH solution and water. Experimental results were statistically analyzed using ANOVA and Post Hoc tests. The analyses showed that the improvement of concrete strength is only significant when the treatment with NaOH and Ca(ClO)2 is prolonged to 72 h. Furthermore, the microstructural analysis of concrete showed that the improvement in the strength is due to the improved bonding between cement paste and rubber aggregates as a result of surface treatment. This microstructural improvement also resulted in lower water permeability of concrete. However, the thermal conductivity and diffusivity increased when the surface treatment duration increases as there are less air voids in the samples. This study shows that, with appropriate pretreatment, a certain percentage of natural aggregates can be safely replaced with waste tire rubber aggregates while maintaining sufficient quali, Materials and Environment

The abundance of waste plastic is a major issue for the sustainability of the environment as plastic pollutes rivers, land, and oceans. However, the versatile behavior of plastic (it is lightweight, flexible, strong, moisture-resistant, and cheap) can make it a replacement for or alternative to many existing composite materials like concrete. Over the past few decades, many researchers have used waste plastic as a replacement for aggregates in concrete. This paper presents a comprehensive review of the engineering properties of waste recycled plastic. It is divided into three sections, along with an introduction and conclusion. The influence of recycled waste plastics on the fresh properties of concrete is discussed first, followed by its influence on the mechanical and durability properties of concrete. Current experimental results have shown that the mechanical and durability properties of concrete are altered due to the inclusion of plastic. However, such concrete still fulfills the requirements of many engineering applications. This review also advocates further study of possible pre-treatment of waste plastic properties for the modification of its surface, shape, and size in order to improve the quality of the composite product and make its use more widespread, Materials and Environment

The abundance of waste plastic is a major issue for the sustainability of the environment as plastic pollutes rivers, land, and oceans. However, the versatile behavior of plastic (it is lightweight, flexible, strong, moisture-resistant, and cheap) can make it a replacement for or alternative to many existing composite materials like concrete. Over the past few decades, many researchers have used waste plastic as a replacement for aggregates in concrete. This paper presents a comprehensive review of the engineering properties of waste recycled plastic. It is divided into three sections, along with an introduction and conclusion. The influence of recycled waste plastics on the fresh properties of concrete is discussed first, followed by its influence on the mechanical and durability properties of concrete. Current experimental results have shown that the mechanical and durability properties of concrete are altered due to the inclusion of plastic. However, such concrete still fulfills the requirements of many engineering applications. This review also advocates further study of possible pre-treatment of waste plastic properties for the modification of its surface, shape, and size in order to improve the quality of the composite product and make its use more widespread, Materials and Environment