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Severe episodic air pollution blankets entire cities and regions and have a profound impact on humans and their activities. We compiled daily fine particle (PM2.5) data from 100 cities in five continents, investigated the trends of number, frequency, and duration of pollution episodes, and compared these with the baseline trend in air pollution. We showed that the factors contributing to these events are complex; however, long-term measures to abate emissions from all anthropogenic sources at all times is also the most efficient way to reduce the occurrence of severe air pollution events. In the short term, accurate forecasting systems of such events based on the meteorological conditions favouring their occurrence, together with effective emergency mitigation of anthropogenic sources, may lessen their magnitude and/or duration. However, there is no clear way of preventing events caused by natural sources affected by climate change, such as wildfires and desert dust outbreaks.

The 1990 Clean Air Act Amendments codified major institutional changes relating to the management of air pollutants in the United States. Recent research years has attributed reduced emissions over the past two decades to regulations enacted under these Amendments, but none have separated long-term daily impacts of individual regulatory programs on multiple source categories under a consistent framework. Using daily emissions and air quality measurements along with a detailed review of national and local regulations promulgated after the Amendments, we quantify daily changes in emissions and air quality attributable to regulations on electricity generating units and on-road mobile sources. To quantify daily changes, we develop nine sets of counterfactual emissions and ambient air pollution concentration time series for 10 pollutants that assume individual regulatory programs and combinations thereof were not implemented. In addition to daily impacts, we estimate uncertainties in these results. These counterfactual daily ambient concentrations reveal high seasonality and increasing effectiveness of most regulations between 1999 and 2013. Monthly average counterfactual concentrations in scenarios that assume no new regulations on electricity generating units and mobile sources are greater than observed concentrations for all pollutants except ozone, which has seen increased wintertime concentrations accompany summertime decreases. By the end of the period, electricity generating unit emissions reductions under the Acid Rain Program and Clean Air Interstate Rule and their respective related local programs led to similar PM2.5 concentration decreases. Of the mobile source regulations, rules on gasoline and diesel vehicles led to similar reductions in annual PM2.5, and gasoline programs led to double the summertime ozone reductions as diesel programs. The nine sets of daily time series and their uncertainties were designed for use in air pollution accountability health studies. Keywords: Air pollution accountability, 1990 Clean Air Act Amendments, Power plants, Mobile sources, Regulation

Formation of aerosol from biogenic hydrocarbons relies heavily on anthropogenic emissions since they control the availability of species such as sulfate and nitrate, and through them, aerosol acidity (pH). To elucidate the role that acidity and emissions play in regulating Secondary Organic Aerosol (SOA), we utilize the 2013 Southern Oxidant and Aerosol Study (SOAS) dataset to enhance the extensive mechanism of isoprene epoxydiol (IEPOX)-mediated SOA formation implemented in the Community Multiscale Air Quality (CMAQ) model (Pye et al., 2013), which was then used to investigate the impact of potential future emission controls on IEPOX OA. We found that the Henry’s law coefficient for IEPOX was the most impactful parameter that controls aqueous isoprene OA products, and a value of 1.9 × 107 M atm−1 provides the best agreement with measurements. Non-volatile cations (NVCs) were found in higher-than-expected quantities in CMAQ and exerted a significant influence on IEPOX OA by reducing its production by as much as 30% when present. Consistent with previous literature, a strong correlation of isoprene OA with sulfate, and little correlation with acidity or liquid water content, was found. Future reductions in SO2 emissions are found to not affect this correlation and generally act to increase the sensitivity of IEPOX OA to sulfate, even in extreme cases.

Heat-related mortality in US cities is expected to more than double by the mid-to-late 21st century. Rising heat exposure in cities is projected to result from: 1) climate forcings from changing global atmospheric composition; and 2) local land surface characteristics responsible for the urban heat island effect. The extent to which heat management strategies designed to lessen the urban heat island effect could offset future heat-related mortality remains unexplored in the literature. Using coupled global and regional climate models with a human health effects model, we estimate changes in the number of heat-related deaths in 2050 resulting from modifications to vegetative cover and surface albedo across three climatically and demographically diverse US metropolitan areas: Atlanta, Georgia, Philadelphia, Pennsylvania, and Phoenix, Arizona. Employing separate health impact functions for average warm season and heat wave conditions in 2050, we find combinations of vegetation and albedo enhancement to offset projected increases in heat-related mortality by 40 to 99% across the three metropolitan regions. These results demonstrate the potential for extensive land surface changes in cities to provide adaptive benefits to urban populations at risk for rising heat exposure with climate change.