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47-64 Feedlots have increased in several regions of Argentina, particularly in the Pampas. The absence of adequate treatments of the effluents produced in these establishments creates serious problems to the society. Phytoremediation can be defined as inexpensive and environmentally sustainable strategy used to remove pollutants by plants. The aim of this study was to evaluate the remediation potential of two macrophyte species (Eichhornia crassipes and Hydrocotyle ranunculoides) on a feedlot effluent. This effluent was treated with these species for 31 days. Control and macrophyte treatments decreased dissolved inorganic nitrogen (DIN), Kjeldahl nitrogen (Kj N), biological oxygen demand (BOD), chemical oxygen demand (COD), total dissolved salts (TDS), total phosphorus (TP), Pb, Zn and Cr levels. At macrophyte treatments, relatively constant pH levels were kept and decreased EC and TDS values were obtained compared to control, mitigating the release of contaminants and potential greenhouse gases to the atmosphere. Moreover, significant increases in biomass were obtained, being higher in E. crassipes. The results allow concluding that the presence of aquatic plants increases the removal rates of nutrients, organic matter and heavy metals from wastewater in approximately 10-17 days for a feedlot effluent with high organic load.

The basin area of the Durazno Stream covers approx. 360 km2 of a plain with a gentle slope, mainly devoted to cattle farming and agriculture. This study examines the variability of chemical composition of surface water of the stream in relation to stream discharge, estimated from a hydrological deterministic model from rainfall data. Fifteen samplings were carried out, four in high flow condition and the rest in baseline flow. In each sampling, the main physico-chemical variables were determined. Since discharge data from this stream were not available, it was estimated in situ through an instantaneous unitary hydrograph model. Both estimations of stream discharge were similar. The main forms of dissolved inorganic nitrogen were ammonium and nitrate. The four significant components of PCA that explained 84.4 % of total variance were: mineral component, particulate matter content, ammonium and dissolved phosphorus levels, and nitrates' level. The decreased concentrations of major ions and conductivity during high flow condition suggest solutes' dilution by the massive inflow of water originated by rainfalls. The highest concentrations and loads of suspended solids (SS) (86 mg/l and 22638 kg/day) and particulate organic carbon (POC) (3.1 mg/l and 832 kg/day) were observed in the sample obtained during the rising limb of the hydrograph following a drought period, suggesting that basin erosive processes are more important during the first hours of the storm. Three of the samplings that were carried out in high flow conditions showed low mineral and nutrient content that revealed better water quality. In contrast, the sampling with the greatest total runoff (14.1 mm) showed high concentrations of ammonium (1205 μg/l) and dissolved phosphorus (561 μg/l), suggesting that a long stagnant period on soils with low permeability, could favor reduction processes of nitrate to ammonium and mobilization of dissolved phosphorus to overlying water. The nutrients' loads increased in high flow conditions most likely due to runoff from the riverbank soils. The rise of nutrients, SS, POC and total organic carbon (TOC), loads in the same or in higher proportion than the stream discharge, alerts on the risk of contamination of surface water in an agricultural basin. La cuenca del Arroyo Durazno abarca aproximadamente 360 km2 de una llanura con suave pendiente, dedicada principalmente a ganadería y agricultura. Este estudio examina la variabilidad en la composición química del agua superficial del arroyo en relación con el caudal estimado a través de un modelo hidrológico determinístico a partir de los datos de lluvia. Se realizaron quince muestreos: cuatro en condiciones de alto caudal, los restantes en caudal base. En cada muestreo se determinaron las principales variables fisico-químicas. Dado que no existen datos publicados de caudal de este arroyo, se lo estimó in situ, y a partir del modelo de hidrograma unitario. Ambas estimaciones resultaron similares. Las principales formas de nitrógeno inorgánico disuelto fueron amonio y nitrato. Los primeros 4 factores extraídos del PCA que explicaron 84.4 % de la varianza total fueron: componente mineral, contenido de material particulado, niveles de amonio y fósforo disuelto y nivel de nitratos. El decrecimiento de iones mayoritarios y conductividad durante las condiciones de alto caudal sugiere su dilución por la entrada masiva de agua por lluvias. Las mayores concentraciones y cargas de sólidos suspendidos (SS) (86 mg/l y 22638 kg/día) y carbono orgánico particulado (COP) (3.1 mg/l y 832 kg/día) se hallaron en el muestreo realizado durante la rama ascendente del hidrograma posterior a un período de sequía, sugiriendo que los procesos erosivos de la cuenca son más importantes en las primeras horas de la tormenta. Tres de los muestreos realizados en condiciones de alto caudal presentaron bajo contenido mineral y de nutrientes, indicando mejor calidad de agua. En cambio en el muestreo de mayor lámina de escorrentía acumulada (14.1 mm) las concentraciones de amonio (1205μg/l) y fósforo disuelto (561μg/l) fueron elevadas, sugiriendo que un prolongado periodo de estancamiento en un suelo de baja permeabilidad favorecería los procesos de reducción de nitratos a amonio y la movilización de fósforo disuelto al agua de inundación. Las cargas de nutrientes aumentaron en condiciones de alto caudal probablemente debido al aporte por escorrentía de suelos ribereños. El ascenso en las cargas de nutrientes, SS, COP y carbono orgánico total en igual o mayor magnitud que el caudal alerta sobre el riesgo de contaminación de las aguas superficiales en una cuenca agrícola.