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In powder bed fusion additive manufacturing, the volumetric energy density E V is a commonly used parameter to quantify process energy input. However, recent results question the suitability of E V as a design parameter, as varying the contributing parameters may yield different part properties. Herein, beam current, scan velocity, and line offset in electron beam powder bed fusion (PBF-EB) of the titanium aluminide alloy TNM–B1 are systematically varied while maintaining an overall constant E V. The samples are evaluated regarding surface morphology, relative density, microstructure, hardness, and aluminum loss due to evaporation. Moreover, the specimens are subjected to two different heat treatments to obtain fully lamellar (FL) and nearly lamellar (NLγ) microstructures, respectively. With a combination of low beam currents, low-to-intermediate scan velocities, and low line offsets, parts with even surfaces, relative densities above 99.9%, and homogeneous microstructures are achieved. On the other hand, especially high beam currents promote the formation of surface bulges and pronounced aluminum evaporation, resulting in inhomogeneous banded microstructures after heat treatment. The results demonstrate the importance of considering the individual parameters instead of E V in process optimization for PBF-EB. Funder: Deutsche Forschungsgemeinschaft, DFG (404665753, 406109547)

This contribution describes the investigation of flow channels which are designed to be directly integrated into an aerospike engine by means of additive manufacturing with laser powder bed fusion (LPBF). During the experimental testing of a previous aerospike engine in 2019, it was observed that high surface roughness of such additively manufactured integrated channels caused a significant reduction in the mass flow rates of the propellants ethanol and liquid oxygen as well as the coolant due to increased pressure drop. In an extensive study within the CFDmikroSAT project, various factors influencing this surface roughness are, therefore, being investigated, which include the geometry of the channels as well as selected manufacturing parameters of the LPBF process, such as layer thickness and component orientation. To further reduce the roughness after manufacturing, suitable post-processing methods are also being investigated for internal cavities, initially analysing the abrasive flow machining process. Within the paper, the overall investigation approach is presented, such as the overview of the considered specimens, and the initial results of a various studies with selected specimens are discussed. These studies consist of the examination of surface roughness reduction, shape accuracy and flow behaviour of post-processed cooling channel specimens. Finally, a brief overview of the already manufactured aerospike demonstrator is presented.

Electron beam powder bed fusion (EB-PBF) is a powder-bed fusion additive manufacturing process, which is suitable for fabricating high-performance parts for a wide range of industrial applications, such as medical and aerospace. Due to its deep curing capabilities, the metastable β-alloy Ti-5Al-5Mo-5V-3Cr (Ti-5553) is currently mostly used in the landing gear of airplanes. However, its great mechanical properties make it also attractive for small, complex, and load-bearing components. In this study, nine melting parameter sets, combining different scanning speeds and beam currents, were used in the EB-PBF ARCAM A2X system. Furthermore, the correlation between the microstructure and the mechanical properties was investigated and analyzed by applying µ-focus computer tomography and microscopic methods (optical, SEM/EDS). A significant influence of the different melting parameters on the microstructure as well as on the mechanical performance was found. In a subsequent step, three melting parameters were selected and the specimens were heat-treated (BASCA, STA) for further investigation. The experimental results of this work indicate that Ti-5553 parts can be manufactured successfully with high quality (ρ > 99.60%), and post-processing heat-treatments can be used to modify the microstructure in such a way that the parts are suitable for a large variety of possible applications.

Additive manufacturing technologies, particularly electron beam powder bed fusion (PBF-EB/M), are becoming increasingly important for the processing of intermetallic titanium aluminides. This study presents the effects of hot isostatic pressing (HIP) and subsequent two-step heat treatments on the microstructure and mechanical properties of the TNM-B1 alloy (Ti–43.5Al–4Nb–1Mo–0.1B) fabricated via PBF-EB/M. Adequate solution heat treatment temperatures allow the adjustment of fully lamellar (FL) and nearly lamellar (NL-β) microstructures. The specimens are characterized by optical microscopy and scanning electron microscopy (SEM), X-ray computed tomography (CT), X-ray diffraction (XRD), and electron backscatter diffraction (EBSD). The mechanical properties at ambient temperatures are evaluated via tensile testing and subsequent fractography. While lack-of-fusion defects are the main causes of failure in the as-built condition, the mechanical properties in the heat-treated conditions are predominantly controlled by the microstructure. The highest ultimate tensile strength is achieved after HIP due to the elimination of lack-of-fusion defects. The results reveal challenges originating from the PBF-EB/M process, for example, local variations in chemical composition due to aluminum evaporation, which in turn affect the microstructures after heat treatment. For designing suitable heat treatment strategies, particular attention should therefore be paid to the microstructural characteristics associated with additive manufacturing. Validerad;2023;Nivå 2;2023-04-19 (hanlid);Funder: German Research Foundation (DFG) (404665753, 40610954)

Electron beam powder bed fusion (PBF-EB/M) has been attracting great research interest as a promising technology for additive manufacturing of titanium aluminide alloys. However, challenges often arise from the process-induced evaporation of aluminum, which is linked to the PBF-EB/M process parameters. This study applies different volumetric energy densities during PBF-EB/M processing to deliberately adjust the aluminum contents in additively manufactured Ti–43.5Al–4Nb–1Mo–0.1B (TNM-B1) samples. The specimens are subsequently subjected to hot isostatic pressing (HIP) and a two-step heat treatment. The influence of process parameter variation and heat treatments on microstructure and defect distribution are investigated using optical and scanning electron microscopy, as well as X-ray computed tomography (CT). Depending on the aluminum content, shifts in the phase transition temperatures can be identified via differential scanning calorimetry (DSC). It is confirmed that the microstructure after heat treatment is strongly linked to the PBF-EB/M parameters and the associated aluminum evaporation. The feasibility of producing locally adapted microstructures within one component through process parameter variation and subsequent heat treatment can be demonstrated. Thus, fully lamellar and nearly lamellar microstructures in two adjacent component areas can be adjusted, respectively. Validerad;2023;Nivå 2;2023-04-19 (hanlid);Funder: German Research Foundation (Deutsche Forschungsgemein-schaft, DFG), (404665753, 406109547)

A major part of laser additive manufacturing focuses on the fabrication of metallic parts for applications in the space and aerospace sectors. Especially, the processing of the very brittle titanium aluminides can be particularly challenging because of their distinct tendency to lamellar interface cracking. In the present paper, a gamma titanium aluminide (γ-TiAl) nozzle, manufactured via electron beam melting, is extended and adapted via hybrid laser metal deposition. The presented example considers a new field of application for this class of materials and approaches the process-specific manipulation of the composition and/or microstructure via the adjustment of processing temperatures, temperature gradients and solidification conditions. Furthermore, intrinsic heat treatment is investigated for electron beam melting and laser metal deposition with powder, and the resulting influence is releated to conventional processing.

In the present work, we study the role of programming strain (50% and 100%), end loads (0, 0.5, 1.0, and 1.5 MPa), and chemical environments (acetone, ethanol, and water) on the exploitable stroke of linear shape memory polymer (SMP) actuators made from ESTANE ETE 75DT3 (SMP-E). Dynamic mechanical thermal analysis (DMTA) shows how the uptake of solvents results in a decrease in the glass temperature of the molecular switch component of SMP-E. A novel in situ technique allows studying chemically triggered shape recovery as a function of time. It is found that the velocity of actuation decreases in the order acetone &gt, ethanol &gt, water, while the exploitable strokes show the inverse tendency and increases in the order water &gt, acetone. The results are interpreted on the basis of the underlying chemical (how solvents affect thermophysical properties) and micromechanical processes (the phenomenological spring dashpot model of Lethersich type rationalizes the behavior). The study provides initial data which can be used for micromechanical modeling of chemically triggered actuation of SMPs. The results are discussed in the light of underlying chemical and mechanical elementary processes, and areas in need of further work are highlighted.

In this contribution, diffusion of water, acetone, and ethanol into a polymer matrix has been studied experimentally and numerically by finite element approaches. Moreover, the present study reports an assessment of different thermomechanical conditions of the shape-memory (SM) performance, for example, stress- or strain-holding times in stress- or strain-controlled thermomechanical cycles and the effect of maximum strain. According to the results presented here, the uptake of acetone in Estane is much higher than ethanol and follows classical Fickian diffusion. Further, a series of thermomechanical measurements conducted on dry and physically (hydrolytically) aged polyether urethanes revealed that incorporation of water seems to have an appreciable impact on the shape recovery ratios which can be attributed to the additional physical crosslinks. However, no obvious difference in shape fixation of dry and physically (hydrolytically) aged samples could be recognized. Furthermore, by decreasing the strain-holding time, shape recovery improves significantly. Moreover, the shape fixity is found to be independent of holding time. The shape recovery ratio decreased dramatically with an increase in the stress-holding time.

Additive manufacturing has been considered a suitable process for developing high-performance parts of medical or aerospace industries. The electron beam powder bed fusion process, EB-PBF, is a powder bed fusion process carried out in a vacuum, in which the parts are melted using a highly focused electron beam. The material class of metastable β-titanium alloys, and especially Ti-5Al-5Mo-5V-3Cr, show great potential for use as small and highly complex load-bearing parts. Specimens were additively manufactured with optimised process parameters and different heat treatments used in order to create tailored mechanical properties. These heat-treated specimens were analysed with regard to their microstructure (SEM) and their mechanical strength (tensile testing). Furthermore, in situ tensile tests, using a Deben CT5000 and a YXLON ff35 industrial µ-CT, were performed and failure-critical defects were detected, analysed and monitored. Experimental results indicate that, if EB-PBF-manufactured Ti-5553 is heat-treated differently, a variety of mechanical properties are possible. Regarding their fracture mechanisms, failure-critical defects can be detected at different stages of the tensile test and defect growth behaviour can be analysed.

Intermetallic Titanium Aluminides (TiAl) have been designed for high-temperature lightweight applications. Powder-bed additive manufacturing (AM) processes such as laser powder bed fusion (LPBF) or electron beam melting (EBM) allow near-net-shape production of TiAl components. However, TiAl parts produced by LPBF or EBM do not reach the structural integrity and mechanical properties of forged parts. The main post-processing step of TiAl parts made by AM is hot-isostatic pressing (HIP), which has several disadvantages such as a long process time and an undesired coarsening of the microstructure. High-performance TiAl components such as turbine blades are thus still produced by isothermal forging of preforms made by investment casting and hot isostatic pressing. Due to the low workability of TiAl alloys, often more than one deformation step is required, and the tooling costs and the low material yield make this process chain very expensive. This paper explores the feasibility of combining AM with isothermal forming in order to replace HIP by thermomechanical post-processing. The hot forming behavior of the Ti-43.5Al-4Nb-1Mo-0.1B (at. %) TNM-B1 alloy, manufactured by EBM and LPBF, is analyzed concerning the evolution of the voids and grain sizes and compared to hot isostatic pressing. It is shown that the fine microstructure produced by AM yields a much lower flow stress and faster globularization kinetics in comparison to conventional cast and HIPed material. While HIP experiments are shown to significantly coarsen the microstructure, isothermal hot working is shown to convert the AM microstructure to a dense and refined state. Moderate hot working with total strains of ∼1 of AM pre-forms may thus serve as an alternative process chain to conventional large strains forging of cast pre-forms and to AM + HIP in the series production of high-performance TiAl components.

The present work studies the diffusion of small molecules (acetone, ethanol, and water) in a shape memory polymer (SMP) of type Estane ETE 75DT3 (SMP-E), which represents a thermoplastic polyurethane. The work aims at providing background information on the chemical reaction between SMPs and small molecules which can limit the service life of SMP actuators operating in harsh chemical environments. Weight gain studies after immersion of plate specimens in liquid acetone, ethanol, and water yield data which can be assessed on the basis of analytical and numerical solutions of Fick’s second law. The diffusion coefficients which are obtained for 21, 30, and 40 °C in the present study scale as D acetone > D ethanol > D water. The diffusion coefficients show Arrhenius types of temperature dependencies with apparent activation energies of 33 (acetone), 59 (ethanol), and 58 (water) kJ mol−1. The diffusion coefficients and the apparent activation energies obtained in the present work are in reasonable agreement with data which were reported for the reaction of the three small molecules with similar polymers in the literature. It is not straightforward to correlate differences in molecular mobility with individual physical properties. The Hansen solubility parameter (originally derived to explain solubility not mobility) qualitatively rationalizes the observed differences.

Additive manufacturing processes have the potential to produce near-net shaped complex final parts in various industries such as aerospace, medicine, or automotive. Powder bed based and nozzle based processes like laser metal deposition (LMD), laser powder bed fusion (LPBF), and electron beam melting (EBM) are commercially available, but selecting the most suitable process for a specific application remains difficult and mainly depends on the individual know-how within a certain company. Factors such as the material used, part dimension, geometrical features, as well as tolerance requirements contribute to the overall manufacturing costs that need to be economically reasonable compared to conventional processes. Within this contribution, the quantitative analysis of basic geometrical features such as cylinders, thin walls, holes, and cooling channels of a special designed benchmark demonstrator manufactured by LMD; LPBF and EBM are presented to compare the geometrical accuracy within and between these processes to verify existing guidelines, connect the part quality to the process parameters, and demonstrate process-specific limitations. The fabricated specimens are investigated in a comprehensive manner with 3D laser scanning and CT scanning with regard to dimensional and geometrical accuracy of outer and inner features. The obtained results will be discussed and achievable as-built tolerances for assessed demonstrator parts will be classified according to general tolerance classes described [DIN ISO 2768-1, Allgemeintoleranzen—Teil 1: Toleranzen fur Langen- und Winkelmase ohne einzelne Toleranzeintragung (1991). Accessed 26 February 2018; DIN ISO 2768-2, Allgemeintoleranzen—Teil 2: Toleranzen fur Form und Lage ohne einzelne Toleranzeintragung (1991). Accessed 26 February 2018].

Alloys based on the titanium–tantalum system are considered for application as high-temperature shape memory alloys due to their martensite start temperatures, which can surpass 200 °C. In the present work we study the evolution of microstructure and the influence of creep on the phase transformation behavior of a Ti70Ta30 (at.%) high-temperature shape memory alloy. Creep tests were performed in a temperature range from 470 to 530 °C at stresses between 90 and 150 MPa. The activation energy for creep was found to be 307 kJ mol−1 and the stress exponent n was determined as 3.7. Scanning and transmission electron microscopy investigations were carried out to characterize the microstructure before and after creep. It was found that the microstructural evolution during creep suppresses subsequent martensitic phase transformations.

A major part of additive manufacturing focuses on the fabrication of metallic parts in different fields of applications. Examples include components for jet engines and turbines and also implants i ...

Conventional tactile and optical testing methods are not capable to detect complex inner geometries or complex surface shapes. Detecting porosities in parts is also not possible with those nondestructive methods. Among other material parameters, geometrical accuracy is essential to determine part's quality. Additive manufacturing processes also have to be optimized regarding geometry deviations caused by distortion or unfavorable orientation in the build chamber. For additive manufactured parts that incorporate previously mentioned features, high-performance computer tomography is the more suitable nondestructive testing method. Components of different materials such as plastics, ceramics, composites, or metals can be completely characterized. This nondestructive testing method was used for porosity analysis regarding the shape and local distribution of pores in an additive manufactured part to find correlations concerning the most suitable process conditions. The measured part data were also compared to original CAD files to determine zones of deviation and apply specific process strategies to avoid distortion. This paper discusses the results of integrating high-performance computer tomography (power: 500 W, max. part size: O 300 mm, 300 × 430 mm2) in a productionlike environment of additively manufactured parts for a wide range of technologies (i.e., electron beam melting and selective laser melting).Conventional tactile and optical testing methods are not capable to detect complex inner geometries or complex surface shapes. Detecting porosities in parts is also not possible with those nondestructive methods. Among other material parameters, geometrical accuracy is essential to determine part's quality. Additive manufacturing processes also have to be optimized regarding geometry deviations caused by distortion or unfavorable orientation in the build chamber. For additive manufactured parts that incorporate previously mentioned features, high-performance computer tomography is the more suitable nondestructive testing method. Components of different materials such as plastics, ceramics, composites, or metals can be completely characterized. This nondestructive testing method was used for porosity analysis regarding the shape and local distribution of pores in an additive manufactured part to find correlations concerning the most suitable process conditions. The measured part data were also compared to ...