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Your search keyword '"Azides -- Thermal properties"' showing total 4 results
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4 results on '"Azides -- Thermal properties"'

1. Inorganic or organic azide-containing hypergolic ionic liquids: as poster published in 1st Korean International Symposium on high energy materials, Incheon, Korea, October 6-9, 2009

Author

Young-Hyuk Joo, Haixiang Gao, Yanqiang Zhang, and Shreeve, Jean'ne M.

Subjects
Azides -- Chemical properties, Azides -- Thermal properties, Ionic solutions -- Chemical properties, Ionic solutions -- Conferences, meetings and seminars, Methyl groups -- Chemical properties, Oxidation-reduction reaction -- Analysis, Chemistry
Published
2010

2. Thermal decomposition of H[N.sub.3]

Author

Knyazev, Vadim D. and Korobeinichev, Oleg P.

Subjects
Azides -- Chemical properties, Azides -- Thermal properties, Chemical reaction, Rate of -- Analysis, Potential energy -- Analysis, Chemicals, plastics and rubber industries
Published
2010

3. Ring strain energy in the cyclooctyl system. The effect of strain energy on [3+2] cycloaddition reactions with azides

Author

Bach, Robert D.

Subjects
Azides -- Chemical properties, Azides -- Thermal properties, Ring formation (Chemistry) -- Analysis, Enthalpy -- Evaluation, Hydrogenation -- Analysis, Chemistry
Abstract

Ring strain energies (SEs) and enthalpies of hydrogenation of a series of E- and Z-alkenes, cyclic alkynes and allenes are computed at the G3 level of theory. The activation energies for [3+2] cycloaddition to benzyl azide and acetamido azide to DIFO are lower in energy than cycloaddition to cyclooctyne.

Published
2009

4. A new mechanism for the conversion of transition metal azides to imido complexes

Author

Hong Wu and Hall, Michael B.

Subjects
Azides -- Chemical properties, Azides -- Thermal properties, Rhenium -- Chemical properties, Rhenium -- Thermal properties, Transition metals -- Chemical properties, Chemistry
Abstract

A new mechanism is described for the conversion of Re azide complexes to the corresponding Re imido complexes by [N.sub.2] loss. The results have shown that the oxo rhenium complex has reacted with Ph[N.sub.3] through rhenium azide intermediates to produce the cis [beta] oxo-imido complex, where cis [beta]-I is both kinetically and thermodynamically favored over cis [beta]-II.

Published
2008

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