Search

Abstract This study examines the accumulation, distribution, and mobility of Potentially Toxic Elements (PTEs) in the sediments of a low‐lying coastal drainage network (Ravenna, Italy). The aim is to understand the geochemical processes occurring between drainage water and canal bed sediments and assess factors affecting and driving PTE distribution and enrichment in these environments. A geochemical database resulting from the analysis of 203 drainage sediment samples was analyzed using Principal Component Analysis and compared to undisturbed near‐surface sediment samples from the same depth and depositional environment. The results reveal PTEs exceeding national regulation limits. Distance from the sea, electrical conductivity of drainage water, and fertilizer use were identified as the main driving factors. The primary mechanisms for PTE precipitation (As, Co, Mo) and subsequent enrichment in the sediments is attributed to the absorption on Fe‐ and Mn‐oxyhydroxides (HFO and HMO), particularly in high salinity areas near the coast. While Cu, Zn, Pb, Cr, and V also have affinity for HFO and HMO, their adsorption efficiency decreases due to the competition with salt‐derived cations during ongoing salinization processes. Anthropogenic sources, including agriculture, hunting activities, traffic dust, and railways, contribute to the local abundance of other elements (Cr, Ni, Cu, Zn, Pb, and Sn). This paper's significant progress lies in assessing the concurrent interactions of chemical and physical processes that drive PTE distribution and accumulation in reclaimed low‐lying coastal plains. The findings are significant for assessing PTE accumulation risks and sediment toxicity in coastal areas affected by water salinization, drainage, and subsidence, providing valuable information to water management institutions globally.

Coastal wetlands play a fundamental role in mitigating climate change thanks to their ability to store large amounts of organic carbon in the soil. However, degraded freshwater wetlands are also known to be the first natural emitter of methane (CH4). Salinity is known to inhibit CH4 production, but its effect in brackish ecosystems is still poorly understood. This study provides a contribution to understanding how environmental variables may affect greenhouse gas (GHG) emissions in coastal temperate wetlands. We present the results of over 1 year of measurements performed in four wetlands located along a salinity gradient on the northeast Adriatic coast near Ravenna, Italy. Soil properties were determined by coring soil samples, while carbon dioxide (CO2) and CH4 fluxes from soils and standing waters were monitored monthly by a portable gas flux meter. Additionally, water levels and surface and groundwater physical–chemical parameters (temperature, pH, electrical conductivity, and sulfate concentrations of water) were monitored monthly by multiparametric probes. We observed a substantial reduction in CH4 emissions when water depth exceeded the critical threshold of 50 cm. Regardless of the water salinity value, the mean CH4 flux was 5.04 gm-2d-1 in freshwater systems and 12.27 gm-2d-1 in brackish ones. In contrast, when water depth was shallower than 50 cm, CH4 fluxes reached an average of 196.98 gm-2d-1 in freshwater systems, while non-significant results are available for brackish/saline waters. Results obtained for CO2 fluxes showed the same behavior described for CH4 fluxes, even though they were statistically non-significant. Temperature and irradiance strongly influenced CH4 emissions from water and soil, resulting in higher rates during summer and spring.

Unoccupied aerial vehicle (UAV) monitoring surveys are used to assess a dune restoration project in the protected natural area of the Bevano River mouth on the northern Adriatic coast (Ravenna, Italy). The impacts of the installed fences to aid dune development are quantified in terms of sand volume and vegetation cover changes over 5 years using a systematic data processing workflow based on structure-from-motion (SfM) photogrammetry and the Geomorphic Change Detection (GCD) toolset applied to two drone surveys in 2016 and 2021. Accuracy assessment is performed using statistical analysis between ground-truth and model elevation data. Results show that the fence proves to be effective in promoting recovery and growth since significant sand deposition was observed along the dune foot and front – a total area of 3799 m2, volume of 1109 m3, and average depositional depth of 0.29 m. Progradation of around 3–5 m of the foredune and embryo development were also evident. There was a decrease in blowout features of about 155 m2 due to increased deposition and vegetation colonization. There was also an average percent increase of 160 % on wave-induced driftwood and/or debris along the beach and of 9.6 % vegetation within the fence based on the cover analysis on selected transects. Erosion of around 1439 m2 is apparent mostly at the northern portion of the structure, which could be accounted for by the aerodynamic and morphodynamic conditions around the fence and its configuration to trap sediments and efficiency in doing so. Overall, dune fencing coupled with limiting debris cleaning along the protected coast was effective. The proposed workflow can aid in creating transferable guidelines to stakeholders in integrated coastal zone management (ICZM) implementation on Mediterranean low-lying sandy coasts.

Multiple processes contributing to natural land subsidence in a shallow coastal aquifer near Ravenna (Italy) were identified by analysing the relationships among different data set time series (water table level, rainfall, land reclamation drainage, sea level, etc.) and establishing the correlations with vertical ground motion observed at a high-resolution settlement gauge. Our study highlights the presence of three deformation components related to different processes controlling land subsidence: elastic, delayed-elastic, and irreversible (plastic) components. The elastic and delayed-elastic components are closely related to water table fluctuations that change the effective stress in two portions of the coastal aquifer at a daily (in the sandy unconfined portion) and seasonal time scales (in the layered clay-rich semi-confined prodelta portion), respectively. The irreversible component represents the trend in the land subsidence time series and is due to primary consolidation (pore pressure dissipation) of the fine-grained prodelta levels above where the settlement gauge is located. The amplitudes of the elastic component can be up to 0.2–0.3 mm whereas the amplitude of the delayed-elastic component reaches 0.89 mm. The primary consolidation rate of deformation is 0.9 mm yr−1 and constrains the likely age of prodelta sediments deposition to 1300–2800 years before present. The delayed-elastic subsidence rate has similar magnitude to that due to primary consolidation and is connected to poroelastic effects in the prodelta sequence following seasonal variations in water table. Our findings are important for planning land subsidence management and monitoring strategies especially where the surface aquifer structure is heterogeneous due to different depositional settings. The natural land subsidence rate in the Holocene sediments of the shallow coastal aquifer of Ravenna (North eastern Italy) that we measured in this study accounts for 10 %–20 % of the total current land subsidence rate observed in this portion of Ravenna coastal area (10–20 mm yr−1).