1. ChemFET Anion Sensor Based on MOF Nanoparticles.
- Author
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Banning, Douglas H., Davenport, Audrey M., Lakanen, Natalie M., Huang, Jiawei, Brozek, Carl K., and Johnson, Darren W.
- Subjects
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FIELD-effect transistors , *METAL-organic frameworks , *COPPER , *SURFACE chemistry , *SUPRAMOLECULAR chemistry - Abstract
Nanoparticles of metal‐organic frameworks (nanoMOFs) possess the unusual combination of both internal and external surfaces. While internal surfaces have been the focus of fundamental and applications‐based MOF studies, the chemistry of the external surfaces remains scarcely understood. Herein we report that specific ion interactions with nanoparticles of Cu(1,2,3‐triazolate)2 (Cu(TA)2) resemble the Hofmeister behavior of proteins and the supramolecular chemistry of synthetic macromolecules. Inspired by these anion‐selective interactions, we tested the performance of Cu(TA)2 nanoparticles as chemical field effect transistor (ChemFET) anion sensors. Rather than size‐based selectivity, the detection limits of the devices exhibit a Hofmeister trend, with the greatest sensitivity towards anions perchlorate, iodide, and nitrate. These results highlight the importance of the pore‐based supramolecular interactions, rather than localized donor‐acceptor pairs, in designing MOF‐based technologies. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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