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A series of polyvinylidene fluoride (PVDF) hollow fiber ultrafiltration membranes made of different titanium dioxide (TiO2) concentrations with the presence of polyvinylpyrrolidone as additive was prepared. The membrane performances were characterized in terms of pure water flux, permeate flux, and oil rejection, while the membrane morphologies were analyzed using scanning electron microscope and atomic force microscope. The experimental results showed that when 2 wt.% TiO2 was incorporated into PVDF membranes, optimized permeate flux and oil rejection of 70.48 L/m2 h (±1.41) and 99.7% (±0.3), respectively, could be obtained when tested using 250 ppm synthesized oily solution under vacuum condition. Compared to the PVDF membrane without TiO2 addition, all the composite membranes showed relatively higher permeate flux and oil rejection. Based on the results obtained, it is reported that the composite PVDF membrane incorporated with 2 wt.% TiO2 exhibited the best separation performance in which comp...

Polyethersulfone (PES) hollow fiber membranes were fabricated via the dry-wet phase inversion spinning technique, aiming to produce an asymmetric, micro porous ultrafiltration hollow-fiber specifically for hemodialysis membrane. The objective of this study is to investigate the effect of spinning conditions on the morphological and permeation properties of the fabricated membrane. Among the parameters that were studied in this work are air gap distance, dope extrusion rate, bore fluid flow rate, and the take-up speed. The contact angle was measured to determine the hydrophilicity of the fibers. Membrane with sufficient hydrophilicity properties is desired for hemodialysis application to avoid fouling and increase its biocompatibility. The influences of the hollow fiber's morphology (i.e., diameter and wall thickness) on the performance of the membranes were evaluated by pure water flux and BSA rejection. The experimental results showed that the dope extrusion rate to bore fluid flow rate ratio should be maintained at 1:1 ratio to produce a perfectly rounded asymmetric hollow fiber membrane. Moreover, the flux of the hollow fiber spun at higher air gap distance had better flux than the one spun at lower air gap distance. Furthermore, spinning asymmetric hollow fiber membranes at high air gap distance helps to produce a thin and porous skin layer, leading to a better flux but a relatively low percentage of rejection for BSA separation. Findings from this study would serve as primary data which will be a useful guide for fabricating a high performance hemodialysis hollow fiber membrane. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43633.