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The sensitivity and spectral coverage of JWST is enabling us to test our assumptions of ultracool dwarf atmospheric chemistry, especially with regards to the abundances of phosphine (PH$_3$) and carbon dioxide (CO$_2$). In this paper, we use NIRSpec PRISM spectra ($\sim$0.8$-$5.5 $\mu$m, $R\sim$100) of four late T and Y dwarfs to show that standard substellar atmosphere models have difficulty replicating the 4.1$-$4.4 $\mu$m wavelength range as they predict an overabundance of phosphine and an underabundance of carbon dioxide. To help quantify this discrepancy, we generate a grid of models using PICASO based on the Elf Owl chemical and temperature profiles where we include the abundances of these two molecules as parameters. The fits to these PICASO models show a consistent preference for orders of magnitude higher CO$_2$ abundances and a reduction in PH$_3$ abundance as compared to the nominal models. This tendency means that the claimed phosphine detection in UNCOVER$-$BD$-$3 could instead be explained by a CO$_2$ abundance in excess of standard atmospheric model predictions; however the signal-to-noise of the spectrum is not high enough to discriminate between these cases. We discuss atmospheric mechanisms that could explain the observed underabundance of PH$_3$ and overabundance of CO$_2$, including a vertical eddy diffusion coefficient ($K_{\mathrm{zz}}$) that varies with altitude, incorrect chemical pathways, or elements condensing out in forms such as NH$_4$H$_2$PO$_4$. However, our favored explanation for the required CO$_2$ enhancement is that the quench approximation does not accurately predict the CO$_2$ abundance, as CO$_2$ remains in chemical equilibrium with CO after CO quenches., Comment: Accepted, 15 pages, 9 figures

We present infrared spectral energy distributions of 23 late-type T and Y dwarfs obtained with the James Webb Space Telescope. The spectral energy distributions consist of NIRSpec PRISM and MIRI LRS spectra covering the $\sim$1--12 $\mu$m wavelength range at $\lambda/ \Delta \lambda \approx 100$ and broadband photometry at 15, 18, and 21 $\mu$m. The spectra exhibit absorption features common to these objects including H$_2$O, CH$_4$, CO, CO$_2$, and NH$_3$. Interestingly, while the spectral morphology changes relatively smoothly with spectral type at $\lambda < 3$ $\mu$m and $\lambda > 8$ $\mu$m, it shows no clear trend in the 5 $\mu$m region where a large fraction of the flux emerges. The broad wavelength coverage of the data enables us to compute the first accurate measurements of the bolometric fluxes of cool brown dwarfs. Combining these bolometric fluxes with parallaxes from Spitzer and HST, we also obtain the first accurate bolometric luminosities of these cool dwarfs. We then used the Sonora Bobcat solar metallicity evolutionary models to estimate the radii of the dwarfs which results in effective temperature estimates ranging from $\sim$1000 to 350 K with a median uncertainty of $\pm$20 K which is nearly an order of magnitude improvement over previous work. We also discuss how various portions of the spectra either do or do not exhibit a clear sequence when ordered by their effective temperatures., Comment: Accepted, 33 pages, 19 figures, 8 tables, Fixed Appendix table (photometry ordering) and Fixed Table 1 (full designation of WISE2018 and WISE0410 photometry)

We present an atmospheric retrieval analysis of the Y0 brown dwarf WISE J035934.06$-$540154.6 using the low-resolution 0.96--12 $\mu$m JWST spectrum presented in \citet{Beiler_2023}. We obtain volume number mixing ratios of the major gas-phase absorbers (H$_2$O, CH$_4$, CO, CO$_2$, PH$_3$, and H$_2$S) that are 3--5$\times$ more precise than previous work that used HST spectra. We also find an order-of-magnitude improvement in the precision of the retrieved thermal profile, a direct result of the broad wavelength coverage of the JWST data. We used the retrieved thermal profile and surface gravity to generate a grid of chemical forward models with varying metallicity, (C/O)$_\textrm{atm}$, and strengths of vertical mixing as encapsulated by the eddy diffusion coefficient $K_\textrm{zz}$. Comparison of the retrieved abundances with this grid of models suggests that the deep atmosphere of WISE 0359$-$54 shows signs of vigorous vertical mixing with $K_\textrm{zz}=10^9$ [cm$^{2}$ s$^{-1}$]. To test the sensitivity of these results to our 5-knot spline thermal profile model, we performed a second retrieval using the \citet{Madhusudhan_2009} thermal profile model. While the results of the two retrievals generally agree well, we do find differences between the retrieved values of mass and volume number mixing ratio of H$_2$S with fractional differences of the median values of $-$0.64 and $-$0.10, respectively. In addition, the 5-knot thermal profile is consistently warmer at pressure between 1 and 70 bar. Nevertheless, our results underscore the power that the broad-wavelength infrared spectra obtainable with the James Webb Space Telescope have to characterize the atmospheres of cool brown dwarfs.

We present the first JWST spectral energy distribution of a Y dwarf. This spectral energy distribution of the Y0 dwarf WISE J035934.06$-$540154.6 consists of low-resolution ($\lambda$/$\Delta\lambda$ $\sim$ 100) spectroscopy from 1$-$12 $\mu$m and three photometric points at 15, 18, and 21 $\mu$m. The spectrum exhibits numerous fundamental, overtone, and combination rotational-vibrational bands of H$_2$O, CH$_4$, CO, CO$_2$, and NH$_3$, including the previously unidentified $\nu_3$ band of NH$_3$ at 3 $\mu$m. Using a Rayleigh-Jeans tail to account for the flux emerging at wavelengths greater than 21 $\mu$m, we measure a bolometric luminosity of $1.523\pm0.090\times10^{20}$ W. We determine a semi-empirical effective temperature estimate of $467^{+16}_{-18}$ K using the bolometric luminosity and evolutionary models to estimate a radius. Finally, we compare the spectrum and photometry to a grid of atmospheric models and find reasonably good agreement with a model having $T_{\mathrm{eff}}$=450 K, log $g$=3.25 [cm s$^{-2}$], [M/H]=$-0.3$. However, the low surface gravity implies an extremely low mass of 1 $M_{\rm{Jup}}$ and a very young age of 20 Myr, the latter of which is inconsistent with simulations of volume-limited samples of cool brown dwarfs.

We present a $L$-band (2.98--3.96$\mu$m) spectroscopic study of 8 young L dwarfs with spectral types ranging from L2 to L7. Our spectra (${\lambda}/{\Delta \lambda}\approx$ 250 to 600) were collected using the Gemini Near-InfraRed Spectrograph. We first examine the young $L$-band spectral sequence, most notably analyzing the evolution of the $Q$-branch of methane absorption feature at 3.3 $\mu$m. We find the $Q$-branch feature first appears between L3 and L6, as previously seen in older field dwarfs. Secondly, we analyze how well various atmospheric models reproduce the $L$-band and published near-IR (0.7--2.5 $\mu$m) spectra of our objects by fitting five different grids of model spectra to the data. Best-fit parameters for the combined near-IR and $L$-band data are compared to best-fit parameters for just the near-IR data, isolating the impact that the addition of the $L$-band has on the results. This addition notably causes a $\sim$100 K drop in the best-fit effective temperature. Also, when clouds and a vertical mixing rate ($K_{\mathrm{zz}}$) are included in the models, thick clouds and higher $K_{\mathrm{zz}}$ values are preferred. Five of our objects also have previously published effective temperatures and surface gravities derived using evolutionary models, age estimates, and bolometric luminosities. Comparing model spectra matching these parameters to our spectra, we find disequilibrium chemistry and clouds are needed to match these published effective temperatures. Three of these objects are members of AB Dor, allowing us to show the temperature dependence of the $Q$-branch of methane., Comment: 26 pages, 19 figures, Accepted for publication in MNRAS

The coldest brown dwarf, WISE 0855, is the closest known planetary-mass, free-floating object and has a temperature nearly as cold as the solar system gas giants. Like Jupiter, it is predicted to have an atmosphere rich in methane, water, and ammonia, with clouds of volatile ices. WISE 0855 is faint at near-infrared wavelengths and emits almost all its energy in the mid-infrared. Skemer et al. 2016 presented a spectrum of WISE 0855 from 4.5-5.1 micron (M band), revealing water vapor features. Here, we present a spectrum of WISE 0855 in L band, from 3.4-4.14 micron. We present a set of atmosphere models that include a range of compositions (metallicities and C/O ratios) and water ice clouds. Methane absorption is clearly present in the spectrum. The mid-infrared color can be better matched with a methane abundance that is depleted relative to solar abundance. We find that there is evidence for water ice clouds in the M band spectrum, and we find a lack of phosphine spectral features in both the L and M band spectra. We suggest that a deep continuum opacity source may be obscuring the near-infrared flux, possibly a deep phosphorous-bearing cloud, ammonium dihyrogen phosphate. Observations of WISE 0855 provide critical constraints for cold planetary atmospheres, bridging the temperature range between the long-studied solar system planets and accessible exoplanets. JWST will soon revolutionize our understanding of cold brown dwarfs with high-precision spectroscopy across the infrared, allowing us to study their compositions and cloud properties, and to infer their atmospheric dynamics and formation processes., Comment: 19 pages, 21 figures. Accepted for publication in ApJ