Search

Your search keyword '"Bhat, Muneer-Ul-Shafi"' showing total 9 results
Start Over Author "Bhat, Muneer-Ul-Shafi"
9 results on '"Bhat, Muneer-Ul-Shafi"'

4. Metal‐Free Tunable 1,2‐Difunctionalization of Terminal Alkynes: Synthesis of β‐Substituted α,β‐Unsaturated Ketones.

Author

Bhat, Muneer‐Ul‐Shafi, Ganie, Majid Ahmad, and Shah, Bhahwal Ali

Subjects
*KETONES, *ALKYNES, *ACETIC acid, *ACYLATION
Abstract

A metal‐free tunable 1,2‐difunctionalization of the terminal alkynes showcasing a tandem installation of C−C and C−S bonds has been developed. The key enabling factor for the approach is the use of acetic acid as an acyl source to synthesize β‐substituted α,β‐unsaturated ketones. The reaction at room temperature leads to the regioselective acylation at the terminal carbon of alkynes, whereas at −78 °C, the acylation occurs at the more substituted carbon. [ABSTRACT FROM AUTHOR]

Published
2023
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results