Search

Byline: Ahmet Demir, M. Sinan Bilgili, Bestamin Ozkaya In this study, a comparison of methane (CH4) generation rates for two test cells, one operated with (enhanced) and another without leachate recirculation at Odayeri Sanitary Landfill were compared using their bio-chemical methane potentials (BMP). Initial methane potential is approximately 34.5 m CH4/wet ton of solid waste. The remaining methane potential for the control (C1) and the enhanced (C2) cells are 32.6 m CH4/wet ton and 31.1 m CH4/wet ton of refuse after eight months of operation, respectively. The produced CH4 quantities for C1 and C2 after eight months of operation are 1.9 m CH4/wet ton and 3.4 m CH4/wet ton, respectively. On the other hand, 5.5% and 9.9% of the total potential are generated in eight months. However, the CH4 generation rates for the first year are determined as 2.85 and 5.10 m/ton/year for C1 and C2 test cells, respectively. Due to the appropriate conditions such as moisture content, solid waste decomposition rate is enhanced at a rate of 79% at C2 test cell relative to C1 test cell. Hence, C2 test cell shows more decomposition relative to the C1 test cell.

Copyright of Sigma: Journal of Engineering & Natural Sciences / Mühendislik ve Fen Bilimleri Dergisi is the property of Sigma: Journal of Engineering & Natural Sciences / Mühendislik ve Fen Bilimleri Dergisi and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Sigma: Journal of Engineering & Natural Sciences / Mühendislik ve Fen Bilimleri Dergisi is the property of Sigma: Journal of Engineering & Natural Sciences / Mühendislik ve Fen Bilimleri Dergisi and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The aim of this study was to investigate the aerobic and anaerobic degradation of phenol and its derivatives in aerobic and anaerobic landfills. Phenolic compounds were extracted from leachate samples using the solid phase micro-extraction method. In this study, analysis of the 24 phenolic compounds included in the standard mixture and the change in the concentrations over time of 23 of the 24 compounds found in the calibration mix standard were determined in both aerobic and anaerobic landfill reactors. It can be concluded that faster and complete removal of phenol, chlorophenol, dichlorophenols, and trichlorophenol were achieved in the aerobic landfill while aerobic treatment was less effective on tetrachlorophenol and pentachlorophenol. In the anaerobic landfill, anaerobic reductive dechlorination probably occurred from all the highly chlorinated phenols and resulted in the accumulation of phenol and chlorophenol. The phenol could not be further degraded because the anaerobic methanogenic phase did not start during the 150 days of operation in an anaerobic landfill reactor. Nitrophenols can be degraded rapidly under aerobic conditions. These compounds are degraded to amino groups in the first step and then these amino groups are degraded to methane and CO2 under anaerobic conditions. Although the degradation could not reach the methanogenic phase in anaerobic landfill reactor during the operational period, it is indicated that nitrophenol concentrations decreased in the anaerobic reactor. This is revealed as a result of the formation of the amino groups. [ABSTRACT FROM AUTHOR]

The main aim of this study was to investigate the effect of leachate recirculation and aeration on volatile fatty acid (VFA) concentrations in aerobic and anaerobic landfill leachate samples. In this study, two aerobic (A1, A2) and two anaerobic (AN1, AN2) reactors with (A1, AN1) and without (A2, AN2) leachate recirculation were used in order to determine the change of volatile fatty acids components in landfill leachate. VFA degradation rate was almost 100% in each reactor but the degradation rate show notable differences. In aerobic landfill reactors, total VFA concentrations decreased below 1000 mg L−1 after 120 days of operation and only caproic and acetic acids were determined at this time. The stabilization of the VFA concentrations takes about 350 and 450 days for AN1 and AN2 reactors, respectively. VFA concentrations were higher than that of aerobic reactors because of the acidogenic phase occurred in anaerobic environment. According to the results of VFA components, the stabilization of the waste was achieved after 120 days of operation in aerobic landfills. At this time, anaerobic reactors were in the acidogenic phase which results with the high concentrations of VFA. The results also indicated that leachate recirculation does not affect the degradation rate in aerobic landfills as much as it does in anaerobic landfills [ABSTRACT FROM PUBLISHER]

In this study; properties and quality of municipal solid waste compost were investigated and compared in pilot-and real-scale plants. The compost quality was determined in terms of pH, moisture content, organic matter content, total Kjeldahl nitrogen (TKN), total phosphorus (TP), total organic carbon (TOC), C/N ratio, phytotoxicity, Salmonella sp., stability index (SI), heavy metal and evaluated considering German compost quality standard (LAGA). Further, the applicability and utility of the end products from two aerobic pilot scale landfill reactors with (Al) and without (A2) leachate recirculation and Istanbul Solid Waste Recycling and Composting Plant (CP) were evaluated. pH and organic content of compost products were around 7.7-8.0 and 36.5-46.5%, respectively. The compost moisture content in Al reactor was determined as 70%, which was the highest value due to the leachate recirculation. Carbon to nitrogen (C/N) ratios were 7.3, 5.3 and 12.8 in A1, A2 and CP end-products in respective order. Heavy metal concentrations of Cu, Cd and Cr exceeded the allowable standards values stipulated for compost products. Salmonella sp. as a hygienic indicator did not found in the compost products. All the end products were in the non-toxic class of the relevant standards as per phytotoxicity tests carried out on compost and soil mixtures of 25 and 50%, and these products were mature and stabile. [ABSTRACT FROM AUTHOR]

The aim of this study was to investigate the aerobic and anaerobic degradation of phenol and its derivatives in aerobic and anaerobic landfills. Phenolic compounds were extracted from leachate samples using the solid phase micro-extraction method. In this study, analysis of the 24 phenolic compounds included in the standard mixture and the change in the concentrations over time of 23 of the 24 compounds found in the calibration mix standard were determined in both aerobic and anaerobic landfill reactors. It can be concluded that faster and complete removal of phenol, chlorophenol, dichlorophenols, and trichlorophenol were achieved in the aerobic landfill while aerobic treatment was less effective on tetrachlorophenol and pentachlorophenol. In the anaerobic landfill, anaerobic reductive dechlorination probably occurred from all the highly chlorinated phenols and resulted in the accumulation of phenol and chlorophenol. The phenol could not be further degraded because the anaerobic methanogenic phase did not start during the 150 days of operation in an anaerobic landfill reactor. Nitrophenols can be degraded rapidly under aerobic conditions. These compounds are degraded to amino groups in the first step and then these amino groups are degraded to methane and CO(2) under anaerobic conditions. Although the degradation could not reach the methanogenic phase in anaerobic landfill reactor during the operational period, it is indicated that nitrophenol concentrations decreased in the anaerobic reactor. This is revealed as a result of the formation of the amino groups.

Leachate and solid waste samples from aerobic and anaerobic simulated landfill reactors operated with and without leachate recirculation were characterized in terms of metals such as Fe, Ca, K, Na, Cd, Cr, Cu, Pb, Ni, and Zn. Metal concentrations of aerobic landfill reactor leachate samples are always below the regulation limits. The higher concentrations in anaerobic landfill leachate samples decreased to regulation limits after the landfill becomes methanogenic. The effect of leachate recirculation is determined in anaerobic landfills more clearly than aerobic landfills. Metal precipitation resulted in a decrease in leachate metal content and an increase in solid waste metal content as expected. Result of the study show that the metal content of landfill leachate samples is not a major concern for both aerobic and anaerobic landfills.