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Renewable lignocellulosic biomass is a favorable energy resource since its co-pyrolysis with hydrogen-rich plastics can produce high-yield and high-quality biofuel. In contrast to earlier co-pyrolysis research that concentrated on increasing product yield, this study comprehends the synergistic effects of two distinct feedstocks that were not considered earlier. This work focuses on co-pyrolyzing wheat straw (WS) with non-reusable polyethylene terephthalate (PET) for the production of pyrolysis oil. WS and PET were blended in different ratios (100/0, 80/20, 60/40, 40/60, 20/80, and 0/100), and pyrolysis experiments were conducted in a fixed-bed reactor under different temperatures to assess their synergistic effect on oil yield. Synergy rates of up to 7.78 % were achieved on yield for the blends of plastic and biomass at a temperature of 500 °C. In comparison to individual biomass or plastics, co-pyrolyzing PET-biomass blends demonstrated good process interaction and promoted the yields of value-added products. The heating value of the pyrolysis oils was in the range of 16.45–28.64 MJ/kg, which depends on the amount of plastic present in the feedstock. The physical analysis of the oils shows that they can be used for heat production by direct combustion in boilers or furnaces. The correlation between WS and PET was validated with the aid of Fourier transform infrared spectroscopy (FT-IR) and gas chromatography-mass spectrometry (GC-MS) analysis. The GC-MS result demonstrated the presence of different compounds such as O-H compounds, esters, carbonyl group elements, acids, hydrocarbons, aromatics, and nitrogenated compounds in the pyrolysis oil, which differed based on the proportions of PET in the feedstock. The increased hydrocarbon and reduced oxygen percentages in the pyrolysis oil were implicitly caused by enhanced hydrocarbon pool mechanisms, in which the breakdown of PET may be supplied as a hydrogen donor. Overall, waste lignocellulosic biomass and plastics can be used to produce biofuels, which helps reduce the amount of solid waste that ends up in landfills. This study also revealed that future research should be focused on the reaction mechanisms of WS and PET co-pyrolysis in order to examine the synergistic interactions.

In this study, the investigation on the effect of plastic during co-pyrolysis with biomass was carried out in a fixed reactor. Pyrolysis of neem wood bark (NB), low density polyethylene (LDPE) and their blends at different ratios was performed in order to evaluate the product distribution. The effects of reaction temperature and NB-to-LDPE blend ratio on product distribution and the chemical compositions of pyrolysis oil were examined. The co-pyrolysis of NB and LDPE increased the yield and quality of the bio-oil. The experiments were conducted under different LDPE addition percentages such as 20%, 40%, 50%, 60% and 80%. Under the optimum experimental condition of 60% addition of LDPE and a temperature of 450 °C, the maximum yield of bio-oil (64.8 wt%) and hydrocarbon (75.2%) was achieved with the lowest yield of oxygenated compounds. The calorific value of the co-pyrolysis oil was found to be higher than that of the NB pyrolysis oil. The relationship between NB and LDPE during co-pyrolysis was validated with the help of gas chromatography-mass spectrometry (GC–MS) analysis, which showed decreased oxygenated compounds. [ABSTRACT FROM AUTHOR]

Co-pyrolysis of palm wastes of empty fruit bunch (EFB) and palm frond (PF) with low-density polyethylene (LDPE) and polypropylene (PP) were investigated to find the synergistic effect of biomass-plastic pair on the yield and composition of bio-oil produced. The pyrolysis process of individual materials and their corresponding blends were employed in a fixed bed reactor at heating rate of 20 °C/min with a nitrogen flow rate of 250 mL/min. The co-pyrolysis results showed that EFB:LDPE with weight ratio of 1:1 has the largest synergy on bio-oil yield, while a negative synergy was revealed for PF:PP co-pyrolysis. In regard of bio-oil chemical composition, the synergistic effect was positive for the formation of aliphatic hydrocarbons and all feedstock decreased the overall oxygenated compounds of fuel substitute. The hydrogen generated from plastic promoted the decarboxylation of acids and decarbonylation reactions of carbonyls and sugars.

Co-pyrolysis of palm wastes of empty fruit bunch (EFB) and palm frond (PF) with low-density polyethylene (LDPE) and polypropylene (PP) were investigated to find the synergistic effect of biomass-plastic pair on the yield and composition of bio-oil produced. The pyrolysis process of individual materials and their corresponding blends were employed in a fixed bed reactor at heating rate of 20 °C/min with a nitrogen flow rate of 250 mL/min. The co-pyrolysis results showed that EFB:LDPE with weight ratio of 1:1 has the largest synergy on bio-oil yield, while a negative synergy was revealed for PF:PP co-pyrolysis. In regard of bio-oil chemical composition, the synergistic effect was positive for the formation of aliphatic hydrocarbons and all feedstock decreased the overall oxygenated compounds of fuel substitute. The hydrogen generated from plastic promoted the decarboxylation of acids and decarbonylation reactions of carbonyls and sugars. [ABSTRACT FROM AUTHOR]