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In the development of new electrochemical concepts for the fabrication of high-energy-density batteries, fluoride-ion batteries (FIBs) have emerged as one of the valid candidates for the next generation electrochemical energy storage technologies, showing the potential to match or even surpass the current lithium-ion batteries (LIBs) in terms of energy density, safety without dendritic grains, and elimination of dependence on scarce lithium and cobalt resources. However, the development of FIBs is still in its infancy and their performance is far from satisfactory, with issues such as the lower fluoride-ion conductivity of the electrolytes and the reversibility of the electrodes hindering their commercialization. Previous reviews have mainly focused on inorganic solid electrolytes with a brief emphasis on the development of various fluoride-ion conductors and their ion-conducting properties. Therefore, this review summarizes the current developments in various electrolytes, a systematic overview of the current progress for various fluoride-ion electrolytes is presented by beginning with the history, structure and classification of FIBs, ion-transport mechanisms are briefly discussed. Recent advances in different classes of fluoride-ion electrolytes are described. The methods for optimizing the ionic conductivity characteristics of the fluoride-ion electrolytes are highlighted. Finally, an outlook on the future research direction of FIBs is given by highlighting some critical issues, challenges and prospects of fluoride-ion electrolytes.

Abstract High glucose-induced vascular endothelial injury is a major pathological factor involved in non-healing diabetic wounds. To interrupt this pathological process, we design an all-peptide printable hydrogel platform based on highly efficient and precise one-step click chemistry of thiolated γ-polyglutamic acid, glycidyl methacrylate-conjugated γ-polyglutamic acid, and thiolated arginine-glycine-aspartate sequences. Vascular endothelial growth factor 165-overexpressed human umbilical vein endothelial cells are printed using this platform, hence fabricating a living material with high cell viability and precise cell spatial distribution control. This cell-laden hydrogel platform accelerates the diabetic wound healing of rats based on the unabated vascular endothelial growth factor 165 release, which promotes angiogenesis and alleviates damages on vascular endothelial mitochondria, thereby reducing tissue hypoxia, downregulating inflammation, and facilitating extracellular matrix remodeling. Together, this study offers a promising strategy for fabricating tissue-friendly, high-efficient, and accurate 3D printed all-peptide hydrogel platform for cell delivery and self-renewable growth factor therapy.

Abstract With the rapid development of novel energy conversion and storage technologies, there is a growing demand for enhanced performance in a wide range of electrocatalysts. Perovskite oxides (ABO3) have caused widespread concerns due to their excellent electrocatalytic properties, low cost, stable and reliable performance. In recent years, the research on anion O‐site doping of perovskite oxides has been a cynosure, which is considered as a promising route for enhancing performance. However, a systematic review summarizing the research progress of anion‐doped perovskite oxides is still lacking. Therefore, this review mainly introduces the elements and strategies of various common anions doped at O‐site of perovskite oxides, analyzes their influence on the physical and chemical properties of perovskites, and separately concludes their applications in electrocatalysis. This review will provide ideas and prospects for the development of subsequent anion doping strategies for high performance perovskite oxides.

Hydrogen energy, the cleanest fuel, presents extensive applications in renewable energy technologies such as fuel cells. However, the transition process from carbon-based (fossil fuel) energy to desired hydrogen energy is usually hindered by inevitable scientific, technological, and economic obstacles, which mainly involves complex hydrocarbon reforming reactions. Hence, this paper provides a systematic and comprehensive analysis focusing on the hydrocarbon reforming mechanism. Accordingly, recent related studies are summarized to clarify the intrinsic difference among the reforming mechanism. Aiming to objectively assess the activated catalyst and deactivation mechanism, the rate-determining steps of reforming process have been emphasized, summarized, and analyzed. Specifically, the effect of metals and supports on individual reaction processes is discussed followed by the metal-support interaction. Current tendency and research map could be established to promote the technology development and expansion of hydrocarbon reforming field. This review could be considered as the guideline for academics and industry designing appropriate catalysts.

Intraductal papillary mucinous neoplasms (IPMNs) of the pancreas are a risk factor for the development of adenocarcinoma. However, the presence of a component of sarcomatoid carcinoma in the malignant tumor has rarely been described in the literature. A 30-year-old Chinese woman was admitted to our hospital with vague abdominal pain and a poor appetite for 2 months. Computed tomography revealed a huge, unilocular, solid-cystic mass in the pancreatic body, and tail. The patient underwent an en bloc resection of the distal pancreatic tumor with splenectomy and regional lymphadenectomy. Pathologic examination revealed an IPMN associated tubular adenocarcinoma containing a component of sarcomatoid (spindle-shaped cell) carcinoma. Immunohistochemical results revealed that the mononuclear spindle-shaped cells were positive for both pan-cytokeratin and vimentin. There was no evidence of perineural or vascular infiltration, lymph nodal metastasis, or positive surgical margins. The patient developed local recurrence 3 months after surgery for which she received chemoradiotherapy at another hospital. Distant metastases were detected 6 months after the surgery and the patient expired 9 months after surgical resection. We concluded that the presence of sarcomatoid change in IPMN-associated pancreatic adenocarcinoma may indicate poor prognosis.

Graphite carbon nitride (g-C3N4), a two-dimensional polymer semiconductor material, has good semiconductor properties, suitable electronic energy band structure, excellent physical and chemical stability. It is widely used in the field of energy and materials science such as photoelectric conversion. In this paper, the progress of g-C3N4 in dye sensitized solar cells (DSSC) and perovskite solar cells (PSC) was reviewed. As a new semiconductor material, g-C3N4 has the advantages of simple preparation, abundant amino and Lewis basic groups. Therefore, on the basis of excellent structure of g-C3N4, its electronic and optical properties are utilized to further expand its application in the field of photoelectric conversion.

Nitrogen–oxygen sensors are pivotal for NOX emission detection, and they have been designed as key components in vehicles’ exhaust systems. However, severe thermal stress concentrations during thermal cycling in the sensors create knotty structural damage issues, which are inevitable during the frequent start–stop events of the vehicles. Herein, to illustrate the effect of thermal concentration on a sensor’s structure, we simulated the temperature and stress field of a sensor through finite element analysis. The failure modes of the sensor based on the multilayer structure model were analyzed. Our simulation indicated that the thermal deformation and stress of the sensors increased significantly when the heating temperature in the sensors increased from 200 to 800 °C. High stress regions were located at the joint between the layers and the right angle of the air chamber. These results are consistent with the sensor failure locations that were observed by SEM, and the sensor’s failures mainly manifested in the form of cracks and delamination. The results suggest that both the multilayer interfaces and the shape of the air chamber could be optimized to reduce the thermal stress concentrations of the sensors. It is beneficial to improve the reliability of the sensor under thermal cycling operation.

Sweet potato is a rich source of resistant starch, fibre, vitamins and minerals, which is associated with healthy benefits. In this study, the effects of high hydrostatic pressure (HHP) treatment at 200–600 MPa on the digestibility of sweet potato flour (SPF) through starch composition analysis, in vitro digestion assays, and glycemic index (GI) and response in diabetic mice. Changes in the morphology of starch granules post-treatment were observed using an scanning electron microscope (SEM). Treatments at 400 and 600 MPa increased amylose in sweet potato starch and significantly increased the proportion of slowly digestible starch (SDS), as indicated by in vitro digestion assays. Resistant starch content decreased, with no significant change in rapidly digestible starch. Peak glucose levels in diabetic mice post-consuming SPF treated at 400 and 600 MPa were 476 and 514, respectively, significantly lower than 608 in the control group. The area under the curve (AUC) of 400 MPa treated-SPF is 14% lower than control SPF. The GI of SPF in the control group was 78.6, reducing to 66.2 and 68.3 post-HHP treatment at 400 and 600 MPa, respectively, with no significant difference in the 200 MPa group from that of the control group. SEM observations showed that damage to starch granules increased with increasing processing pressure. HHP caused the starch granules to gelatinize and recoagulate, forming an irregular shape. The HHP treatment changed the composition of SPF, significantly increasing SDS content and it stabilized postprandial blood glucose levels and reduced GI, rendering it a potential method to develop processed products of sweet potatoes with a low GI, providing a novel technical option for developing health-promoting products.