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Recent discoveries of hydrocarbons along the western margin of the Norwegian Barents Shelf have emphasised the need for a better understanding of the source rock potential of the Upper Palaeozoic succession. In this study, a comprehensive set of organic geochemical data have been collected from the Carboniferous – Permian interval outcropping on Svalbard in order to re‐assess the offshore potential. Four stratigraphic levels with organic‐rich facies have been identified: (i) Lower Carboniferous (Mississippian) fluvio‐lacustrine intervals with TOC between 1 and 75 wt.% and a cumulative organic‐rich section more than 100 m thick; (ii) Upper Carboniferous (Pennsylvanian) evaporite‐associated marine shales and organic‐rich carbonates with TOC up to 20 wt.%; (iii) a widespread lowermost Permian organic‐rich carbonate unit, 2–10 m thick, with 1–10 wt. % TOC; and (iv) Lower Permian organic‐rich marine shales with an average TOC content of 10 wt.%. Petroleum can potentially be tied to organic‐rich facies at formation level based on the gammacerane index, δ13C of the aromatic fraction and/or the Pr/Ph ratio. Relatively heavy δ13C values, a low gammacerane index and high Pr/Ph ratios characterize Lower Carboniferous non‐marine sediments, whereas evaporite‐associated facies have lighter δ13C, a higher gammacerane index and lower Pr/Ph ratios. [ABSTRACT FROM AUTHOR]

The Søgne Basin in the Danish-Norwegian Central Graben is unique in the North Sea because it has been proven to contain commercial volumes of hydrocarbons derived only from Middle Jurassic coaly source rocks. Exploration here relies on the identification of good quality, mature Middle Jurassic coaly and lacustrine source rocks and Upper Jurassic - lowermost Cretaceous marine source rocks. The present study examines source rock data from almost 900 Middle Jurassic and Upper Jurassic - lowermost Cretaceous samples from 21 wells together with 286 vitrinite reflectance data from 14 wells. The kerogen composition and kinetics for bulk petroleum formation of three Middle Jurassic lacustrine samples were also determined. Differences in kerogen composition between the coaly and marine source rocks result in two principal oil windows: (i) the effective oil window for Middle Jurassic coaly strata, located at ∼3800 m and spanning at least ∼650 m; and (ii) the oil window for Upper Jurassic - lowermost Cretaceous marine mudstones, located at ∼3250 m and spanning ∼650 m. A possible third oil window may relate to Middle Jurassic lacustrine deposits. Middle Jurassic coaly strata are thermally mature in the southern part of the Søgne Basin and probably also in the north, whereas they are largely immature in the central part of the basin. HI values of the Middle Jurassic coals range from ∼150-280 mg HC/g TOC indicating that they are gas-prone to gas/oil-prone. The overall source rock quality of the Middle Jurassic coaly rocks is fair to good, although a relatively large number of the samples are of poor source rock quality. At the present day, Middle Jurassic oil-prone or gas/oil-prone rocks occur in the southern part of the basin and possibly in a narrow zone in the northern part. In the remainder of the basin, these deposits are considered to be gas-prone or are absent. Wells in the northernmost part of the Søgne Basin / southernmost Steinbit Terrace encountered Middle Jurassic organic-rich lacustrine mudstones with sapropelic kerogen, high HI values reaching 770 mg HC/g TOC and E-distributions characterised by a single dominant E-peak. The presence of lacustrine mudstones is also suggested by a limited number of samples with HI values above 300 mg HC/g TOC in the southern part of the basin; in addition, palynofacies demonstrate a progressive increase in the abundance and areal extent of lacustrine and brackish open water conditions during Callovian times. A regional presence of oil-prone Middle Jurassic lacustrine source rocks in the Søgne Basin, however, remains speculative. Middle Jurassic kitchen areas may be present in an elongated palaeo-depression in the northern part of the Søgne Basin and in restricted areas in the south. Upper Jurassic - lowermost Cretaceous mudstones are thermally mature in the central, western and northern parts of the basin; they are immature in the eastern part towards the Coffee Soil Fault, and overmature in the southernmost part. Only a minor proportion of the mudstones have HI values >300 mg HC/g TOC, and the present-day source rock quality is for the best samples fair to good. In the south and probably also in most of the northern part of the Søgne Basin, the mudstones are most likely gas-prone, whereas they may be gas/oil-prone in the central part of the basin. A narrow elongated zone in the northern part of the basin may be oil-prone. The marine mudstones are, however, volumetrically more significant than the Middle Jurassic strata. Possible Upper Jurassic - lowermost Cretaceous kitchen areas are today restricted to the central Søgne Basin and the elongated palaeo-depression in the north. [ABSTRACT FROM AUTHOR]

Lacustrine and marine oil shales with Type I and Type I-II kerogen constitute significant petroleum source rocks around the world. Contrary to common belief, such rocks show considerable compositional variability which influences their hydrocarbon generation characteristics. A global set of 23 Ordovician – Miocene freshwater and brackish water lacustrine and marine oil shales has been studied with regard to their organic composition, petroleum potential and generation kinetics. In addition their petroleum generation characteristics have been modelled. The oil shales can be classified as lacosite, torbanite, tasmanite and kukersite. They are thermally immature. Most of the shales contain >10 wt% TOC and the highest sulphur contents are recorded in the brackish water and marine oil shales. The kerogen is sapropelic and is principally composed of a complex of algal-derived organic matter in the form of: (i) telalginite (Botryococcus-, Prasinophyte- (Tasmanites?) or Gloeocapsomorpha-type); (ii) lamalginite (laminated, filamentous or network structure derived from Pediastrum- or Tetraedron-type algae, from dinoflagellate/acritarch cysts or from thin-walled Prasinophyte-type algae); (iii) fluorescing amorphous organic matter (AOM) and (iv) liptodetrinite. High atomic H/C ratios reflect the hydrogen-rich Type I and Type I-II kerogen, and Hydrogen Index values generally >300 mg HC/g TOC and reaching nearly 800 mg HC/g TOC emphasise the oil-prone nature of the oil shales. The kerogen type and source rock quality appear not to be related to age, depositional environment or oil shale type. Therefore, a unique, global activation energy (Ea) distribution and frequency factor (A) for these source rocks cannot be expected. The differences in kerogen composition result in considerable variations in Ea-distributions and A-factors. Generation modelling using custom kinetics and the known subsidence history of the Malay-Cho Thu Basin (Gulf of Thailand/South China Sea), combined with established and hypothetical temperature histories, show that the oil shales decompose at different rates during maturation. At a maximum temperature of ∼120°C reached during burial, only limited kerogen conversion has taken place. However, oil shales characterised by broader Ea-distributions with low Ea-values (and a single approximated A-factor) show increased decomposition rates. Where more deeply buried (maximum temperature ∼150°C), some of the brackish water and marine oil shales have realised the major part of their generation potential, whereas the freshwater oil shales and other brackish water oil shales are only ∼30–40% converted. At still higher temperatures between ∼165°C and 180°C all oil shales reach 90% conversion. Most hydrocarbons from these source rocks will be generated within narrow oil windows (∼20–80% kerogen conversion). Although the brackish water and marine oil shales appear to decompose faster than the freshwater oil shales, this suggests that with increasing heatflow the influence of kerogen heterogeneity on modelling of hydrocarbon generation declines. It may thus be critical to understand the organic facies of Type I and Type I-II source rocks, particularly in basins with moderate heatflows and restricted burial depths. Measurement of custom kinetics is recommended, if possible, to increase the accuracy of any computed hydrocarbon generation models. [ABSTRACT FROM AUTHOR]

Coals and coaly mudstones of the Cretaceous Atane Formation are exposed along the north coast of the island of Disko and the south coast of Nuussuaq peninsula, West Greenland. Numerous oil seepages have been found in the region, but the so-called Kuugannguaq oil type only occurs at the north coast of Disko. The oil is presumed to have been generated from coaly (Type III) source rocks in the Vaigat strait where the Atane Formation is thermally mature due to deep burial. The exposed coals and coaly mudstones may thus be thermally immature equivalents of the active source rocks. The exposed section at Qullissat on the island of Disko is composed of four sedimentary facies associations: delta plain, distributary channel, delta front, and transgressive sand sheet. Samples of coals and coaly mudstones from the delta plain association were analysed for their total organic carbon (wt % TOC) and total sulphur (wt % TS) contents, and their source rock potential was determined by Rock-Eval pyrolysis. The organic matter composition was analysed by reflected light microscopy and the thermal maturity was established by vitrinite reflectance measurements. The Qullissat samples were supplemented with source rock screening data from coals and coaly mudstones from the Atane Formation at Paatuut on the south coast of Nuussuaq. The coals and coaly mudstones from Qullissat are dominated by huminite, but several samples have a considerable content of inertinite. The mineral content is high in some samples. Inundations of the peat-mires may have been quite frequent resulting in the formation of the coaly mudstones. TS contents (0.13–8.97 wt %) and the presence of framboidal pyrite suggest that the precursor peats were influenced by seawater, and that peat formation probably occurred during rises in relative sea-level. The organic matter is thermally immature, and a constructed vitrinite reflectance gradient for the region suggests that the Qullissat section prior to exhumation was buried to 1,500–1,600 m depth. Hydrogen Index (HI) values from both Qullissat and Paatuut are generally low; estimated maximum HI values for three Qullissat coals yield values of 140–190 mg HC/g TOC. The coals are gas-prone and only marginally oil-prone, and may in addition possess a limited oil expulsion efficiency. The effective oil window extends from approximately 1.0–1.6%Ro and the start of the effective oil window is located at about 3,000 m depth. Very thick sedimentary successions in the Vaigat strait indicate that such burial depths have been reached for the Atane Formation offshore, and up-dip migration of hydrocarbons from these source rocks may have generated the Kuugannguaq oil seepage. [ABSTRACT FROM AUTHOR]