1. High-areal-capacity Na-ion battery electrode with uncompromised energy and power densities by simultaneous electrospinning-spraying fabrication
- Author
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Ouyang, Mengzheng, Guo, Zhenyu, Salinas-Farran, Luis E, Zhao, Yan, Zhao, Siyu, Zheng, Kaitian, Zhang, Hao, Wang, Mengnan, Li, Guangdong, Li, Feiran, Liu, Xinhua, Yang, Shichun, Xie, Fei, Shearing, Paul R., Titirici, Maria-Magdalena, and Brandon, Nigel P.
- Subjects
Condensed Matter - Materials Science - Abstract
Sodium-ion batteries (SIBs) are cost-effective alternatives to lithium-ion batteries (LIBs), but their low energy density remains a challenge. Current electrode designs fail to simultaneously achieve high areal loading, high active content, and superior performance. In response, this work introduces an ideal electrode structure, featuring a continuous conductive network with active particles securely trapped in the absence of binder, fabricated using a universal technique that combines electrospinning and electrospraying (co-ESP). We found that the particle size must be larger than the network's pores for optimised performance, an aspect overlooked in previous research. The free-standing co-ESP Na2V3(PO4)3 (NVP) cathodes demonstrated state-of-the-art 296 mg cm-2 areal loading with 97.5 wt.% active content, as well as remarkable rate-performance and cycling stability. Co-ESP full cells showed uncompromised energy and power densities (231.6 Wh kg-1 and 7152.6 W kg-1), leading among reported SIBs with industry-relevant areal loadings. The structural merit is analysed using multi-scale X-ray computed tomography, providing valuable design insights.Finally, the superior performance is validated in the pouch cells, highlighting the electrode's scalability and potential for commercial application., Comment: Main manuscript 25 pages, 5 figures. Supplementary 47 pages, including 35 figures and 11 tables
- Published
- 2024