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(2060) Chiron is a large centaur that has been reported active on multiple occasions including during aphelion passage. Studies of Chirons coma during active periods have resulted in the detection of C(triple)N and CO outgassing. Significant work remains to be undertaken to comprehend the activation mechanisms on Chiron and the parent molecules of the gas phases detected. This work reports the study of the ices on Chirons surface and coma and seeks spectral indicators of volatiles associated with the activity. Additionally, we discuss how these detections could be related to the activation mechanism for Chiron and, potentially, other centaurs. In July 2023, the James Webb Space Telescope (JWST) observed Chiron when it was active near its aphelion. We present JWST/NIRSpec spectra from 0.97 to 5.27 microns with a resolving power of 1000, and compare them with laboratory data for identification of the spectral bands. We report the first detections on Chiron of absorption bands of several volatile ices, including CO2, CO, C2H6, C3H8, and C2H2. We also confirm the presence of water ice in its amorphous state. A key discovery arising from these data is the detection of fluorescence emissions of CH4, revealing the presence of a gas coma rich in this hyper-volatile molecule, which we also identify to be in non-local thermal equilibrium (nonLTE). CO2 gas emission is also detected in the fundamental stretching band at 4.27 microns. We argue that the presence of CH4 emission is the first proof of the desorption of CH4 due to a density phase transition of amorphous water ice at low temperature in agreement with the estimated temperature of Chiron during the JWST observations (61 K). Detection of photolytic and proton irradiation products of CH4 and CO2 on the surface, in the coma ice grains, or in the ring material is also detected via a forest of absorption features from 3.5 to 5.3 microns., Comment: 4 figures in paper plus 2 more in the appendix. Accepted as A&A Letter

We observed Sedna, Gonggong, and Quaoar with the NIRSpec instrument on the James Webb Space Telescope (JWST). All three bodies were observed in the low-resolution prism mode at wavelengths spanning 0.7 to 5.2 $\mu$m. Quaoar was also observed at 10x higher spectral resolution from 0.97 to 3.16 $\mu$m using medium-resolution gratings. Sedna's spectrum shows a large number of absorption features due to ethane (C$_2$H$_6$), as well as acetylene (C$_2$H$_2$), ethylene (C$_2$H$_4$), H$_2$O, and possibly minor CO$_2$. Gonggong's spectrum also shows several, but fewer and weaker, ethane features, along with stronger and cleaner H$_2$O features and CO$_2$ complexed with other molecules. Quaoar's prism spectrum shows even fewer and weaker ethane features, the deepest and cleanest H$_2$O features, a feature at 3.2 $\mu$m possibly due to HCN, and CO$_2$ ice. The higher-resolution medium grating spectrum of Quaoar reveals several overtone and combination bands of ethane and methane (CH$_4$). Spectra of all three objects show steep red spectral slopes and strong, broad absorptions between 2.7 and 3.6 $\mu$m indicative of complex organic molecules. The suite of light hydrocarbons and complex organic molecules are interpreted as the products of irradiation of methane. We infer that the differences in apparent abundances of irradiation products are likely due to their distinctive orbits, which lead to different timescales of methane retention and to different charged particle irradiation environments. In all cases, however, the continued presence of light hydrocarbons implies a resupply of methane to the surface. We suggest that these three bodies have undergone internal melting and geochemical evolution similar to the larger dwarf planets and distinct from all smaller KBOs., Comment: 32 pages, 9 figures, 5 tables, accepted for publication in Icarus

James Webb Space Telescope's NIRSpec infrared imaging spectrometer observed the outer solar system dwarf planets Eris and Makemake in reflected sunlight at wavelengths spanning 1 through 5 microns. Both objects have high albedo surfaces that are rich in methane ice, with a texture that permits long optical path lengths through the ice for solar photons. There is evidence for N2 ice absorption around 4.2 um on Eris, though not on Makemake. No CO ice absorption is seen at 4.67 um on either body. For the first time, absorption bands of two heavy isotopologues of methane are observed at 2.615 um (13CH4), 4.33 um (12CH3D), and 4.57 um (12CH3D). These bands enable us to measure D/H ratios of (2.5 +/- 0.5) x 10-4 and (2.9 +/- 0.6) x 10-4, along with 13C/12C ratios of 0.012 +/- 0.002 and 0.010 +/- 0.003 in the surface methane ices of Eris and Makemake, respectively. The measured D/H ratios are much lower than that of presumably primordial methane in comet 67P/Churyumov-Gerasimenko, but they are similar to D/H ratios in water in many comets and larger outer solar system objects. This similarity suggests that the hydrogen atoms in methane on Eris and Makemake originated from water, indicative of geochemical processes in past or even ongoing hot environments in their deep interiors. The 13C/12C ratios are consistent with commonly observed solar system values, suggesting no substantial enrichment in 13C as could happen if the methane currently on their surfaces was the residue of a much larger inventory that had mostly been lost to space. Possible explanations include geologically recent outgassing from the interiors as well as processes that cycle the surface methane inventory to keep the uppermost surfaces refreshed.

Space weathering is a process that changes the surface of airless planetary bodies. Prime space weathering agents are solar wind irradiation and micrometeoroid bombardment. These processes alter planetary reflectance spectra and often modify their compositional diagnostic features. In this work we focused on simulating and comparing the spectral changes caused by solar wind irradiation and by micrometeoroid bombardment to gain a better understanding of these individual space weathering processes. We used olivine and pyroxene pellets as proxies for planetary materials. To simulate solar wind irradiation we used hydrogen, helium, and argon ions with energies from 5 to 40 keV and fluences of up to $10^{18}$ particles/cm$^2$. To simulate micrometeoroid bombardment we used individual femtosecond laser pulses. We analysed the corresponding evolution of different spectral parameters, which we determined by applying the Modified Gaussian Model, and we also conducted principal component analysis. The original mineralogy of the surface influences the spectral evolution more than the weathering agent, as seen from the diverse evolution of the spectral slope of olivine and pyroxene upon irradiation. The spectral slope changes seen in olivine are consistent with observations of A-type asteroids, while the moderate to no slope changes observed in pyroxene are consistent with asteroid (4) Vesta. We also observed some differences in the spectral effects induced by the two weathering agents. Ions simulating solar wind have a smaller influence on longer wavelengths of the spectra than laser irradiation simulating micrometeoroid impacts. This is most likely due to the different penetration depths of ions and laser pulses. Our results suggest that in some instances it might be possible to distinguish between the contributions of the two agents on a weathered surface., Comment: Astronomy and Astrophysics

Context. Near- and mid-infrared observations have revealed the presence of organic refractory materials in the solar system, in cometary nuclei and on the surface of centaurs, Kuiper-belt and trans-neptunian objects. In these astrophysical environments, organic materials can be formed because of the interaction of frozen volatile compounds with cosmic rays, stellar/solar particles, and favoured by thermal processing. The analysis of laboratory analogues of such materials gives information on their properties, complementary to observations. Aims. We present new experiments to contribute in the understanding of the chemical composition of organic refractory materials in space. Methods. We bombard frozen water, methanol and ammonia mixtures with 40 keV H$^+$ and we warm the by-products up to 300~K. The experiments allow the production of organic residues that we analyse by means of infrared spectroscopy and by Very High Resolution Mass Spectrometry to study their chemical composition and their high molecular diversity, including the presence of hexamethylenetetramine and its derivatives. Results. We find that the accumulated irradiation dose plays a role in determining the residue's composition. Conslusions. Based on the laboratory doses, we estimate the astrophysical timescales to be short enough to induce an efficient formation of organic refractory materials at the surface of icy bodies in the outer solar system., Comment: in publication on Astronomy & Astrophysics, sect. Planets and planetary systems

Anhydrous pyroxene-rich interplanetary dust particles (IDPs) have been proposed as surface analogs for about two-thirds of all C-complex asteroids. However, this suggestion appears to be inconsistent with the presence of hydrated silicates on the surfaces of some of these asteroids including Ceres. Here we report the presence of enstatite (pyroxene) on the surface of two C-type asteroids (Ceres and Eugenia) based on their spectral properties in the mid-infrared range. The presence of this component is particularly unexpected in the case of Ceres because most thermal evolution models predict a surface consisting of hydrated compounds only. The most plausible scenario is that Ceres' surface has been partially contaminated by exogenous enstatite-rich material, possibly coming from the Beagle asteroid family. This scenario questions a similar origin for Ceres and the remaining C-types, and it possibly supports recent results obtained by the Dawn mission (NASA) that Ceres may have formed in the very outer solar system. Concerning the smaller C-types such as Eugenia, both their derived surface composition (enstatite and amorphous silicates) and low density suggest that these bodies accreted from the same building blocks, namely chondritic porous, pyroxene-rich IDPs and volatiles (mostly water ice), and that a significant volume fraction of these bodies has remained unaffected by hydrothermal activity likely implying a late accretion. In addition, their current heliocentric distance may best explain the presence or absence of water ice at their surfaces. Finally, we raise the possibility that CI chondrites, Tagish Lake-like material, or hydrated IDPs may be representative samples of the cores of these bodies.

Under cosmic irradiation, the interstellar water ice mantles evolve towards a compact amorphous state. Crystalline ice amorphisation was previously monitored mainly in the keV to hundreds of keV ion energies. We experimentally investigate heavy ion irradiation amorphisation of crystalline ice, at high energies closer to true cosmic rays, and explore the water-ice sputtering yield. We irradiated thin crystalline ice films with MeV to GeV swift ion beams, produced at the GANIL accelerator. The ice infrared spectral evolution as a function of fluence is monitored with in-situ infrared spectroscopy (induced amorphisation of the initial crystalline state into a compact amorphous phase). The crystalline ice amorphisation cross-section is measured in the high electronic stopping-power range for different temperatures. At large fluence, the ice sputtering is measured on the infrared spectra, and the fitted sputtering-yield dependence, combined with previous measurements, is quadratic over three decades of electronic stopping power. The final state of cosmic ray irradiation for porous amorphous and crystalline ice, as monitored by infrared spectroscopy, is the same, but with a large difference in cross-section, hence in time scale in an astrophysical context. The cosmic ray water-ice sputtering rates compete with the UV photodesorption yields reported in the literature. The prevalence of direct cosmic ray sputtering over cosmic-ray induced photons photodesorption may be particularly true for ices strongly bonded to the ice mantles surfaces, such as hydrogen-bonded ice structures or more generally the so-called polar ices., Comment: 22pages, 11 figures, accepted in A&A

2003 EL61 is the largest member of a group of TNOs with similar orbits and 'unique' spectra (neutral slope in the visible and the deepest water ice absorption bands ever observed in the TNb). Studying the composition of the surface of 2003 EL61 provides useful constrains on the origin of this particular group of TNOs and on the outer Solar system's history. We present visible and near-infrared spectra of 2003 EL61 obtained with the 4.2m WHT and the 3.6m TNG at the Roque de los Muchachos Observatory (Canary Islands, Spain). Near infrared spectra were obtained at different rotational phases covering almost one complete rotational period. Spectra are fitted using Hapke scattering models and constraints on the surface composition are derived. No significant variations in the spectral slope and in the depth of the water ice absorption bands at different rotational phases are evident, suggesting that the surface of 2003 EL61 is homogeneous. The scattering models show that a 1:1 intimate mixture of crystalline and amorphous water ice is the most probable composition for the surface of this TNO, and constrain the presence of other minor constituents to a maximum of 8% The derived composition suggests that: a) cryovolcanism is unlikely to be the main resurfacing process responsible for the high presence of water ice on the surface of these bodies; b) the surface is older than 10^8 yr. Any catastrophic event, like the collision suggested to be the origin of this population, had to happen at least 10^8 yr ago; c) the surface of 2003 EL61 is depleted of carbon chains. According to the orbital parameters of this population, this makes it a possible source of carbon-depleted Jupiter family comets., Comment: 9 pages, 7 graphs. Keywords: water ice, carbon-depleted, Kuiper Belt, astrochemistry, spectroscopy

Recent results suggest that there is a group of TNOs (2003 EL61 being the biggest member), with surfaces composed of almost pure water ice and with very similar orbital elements. We study the surface composition of another TNO that moves in a similar orbit, 2005 RR43, and compare it with the surface composition of the other members of this group. We report visible and near-infrared spectra, obtained with the 4.2m William Herschel Telescope and the 3.58m Telescopio Nazionale Galileo at the "Roque de los Muchachos" Observatory (La Palma, Spain). The spectrum of 2005 RR43 is neutral in color in the visible and dominated by very deep water ice absorption bands in the near infrared (D= 70.3 +/- 2.1 % and 82.8 +/- 4.9 % at 1.5 \mu and 2.0 \mu respectively). It is very similar to the spectrum of the group of TNOs already mentioned. All of them present much deeper water ice absorption bands (D>40 %) than any other TNO except Charon. Scattering models show that its surface is covered by water ice, a significant fraction in crytalline state with no trace (5 % upper limit) of complex organics. Possible scenarios to explain the existence of this population of TNOs are discussed: a giant collision, an originally carbon depleted composition, or a common process of continuous resurfacing. We conclude that TNO 2005 RR43 is member of a group, may be a population, of TNOs clustered in the space of orbital parameters that show abundant water ice and no signs of complex organics. The lack of complex organics in their surfaces suggests a significant smaller fraction of carbonaceous volatiles like CH4 in this population than in "normal" TNOs. A carbon depleted population of TNOs could be the origin of the population of carbon depleted Jupiter family comets already noticed by A'Hearn et al. (1995)., Comment: Final Version (Paper Accepted) 4 pages, 2 figures. Changed title, abstract, discussion