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9. Guiding the self-assembly of a second-generation polyphenytene dendrimer into well-defined patterns

Author

UCL - FSA/MAPR - Département des sciences des matériaux et des procédés, Heyen, An J. J. Ver, Buron, Cedric C., Tianshi, Qin, Bauer, Roland, Jonas, Alain M., Muellen, Klaus, De Schryver, Frans C., De Feyter, Steven, UCL - FSA/MAPR - Département des sciences des matériaux et des procédés, Heyen, An J. J. Ver, Buron, Cedric C., Tianshi, Qin, Bauer, Roland, Jonas, Alain M., Muellen, Klaus, De Schryver, Frans C., and De Feyter, Steven

Abstract

A second-generation polyphenylene dendrimer I is shown to self-assemble into nanofibers. To guide the formation of the dendrimer fibers into well-defined patterns, 1H,1H,2H,2H-perfluorodecyltrichlorosilane is grafted in the gas phase onto a silicon substrate. De-wetting of the solution on the nanopatterned surface results in the formation of a nanostructured template, into which fiber growth subsequently occurs under the constraints set by the de-wetted morphology.

Published
2008

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