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In this contribution, we propose a new approach to enhance the ablation properties of carbon/carbon (C/C) composites. 2.5D CFMP/C composites were obtained by mesophase pitch-based carbon fiber (CFMP) as the reinforcing carbon fibers, which facilitates the high aerodynamic heat flow near the stagnation to be rapidly guided to the low heat flow region at the rear of the structure. The results show that the surface temperature of 2.5D CFMP/C composites is 100 °C lower than that of 2.5D CFPAN/C composites prepared by traditional PAN-based carbon fiber (CFPAN), and the mass ablation rate and linear ablation rate of 2.5D CFMP/C composites decreased from 3.307 mg/s to 1.412 mg/s and from 3.067 µm/s to 0.501 µm/s, respectively. In addition, the mechanical properties of the 2.5D CFMP/C composites are outstanding, which will lay the foundation for their stability in ablative environments. Our work will bring new blessings for the further development of C/C composites in the aerospace field. [ABSTRACT FROM AUTHOR]

The mechanical properties of graphene reinforced composites are often hampered by challenges related to the dispersion and aggregation of graphene within the matrix. This paper explores the mechanism of cooling rate, process temperature, and process pressure's influence on the agglomeration behavior of graphene and the tensile response of composites from a computer simulation technology, namely molecular dynamics. Our findings reveal that the cooling rate exerts minimal influence on the tensile response of composites. Conversely, processing temperature significantly affects the degree of graphene aggregation, with higher temperatures leading to the formation of larger-sized graphene clusters. In contrast, processing pressure exhibits negligible impact on the degree of graphene aggregation, and increasing pressure effectively mitigates the formation of large-sized graphene clusters. Moreover, we elucidate the intrinsic factors governing the mechanical response to variations in processing parameters. Notably, we observe that the stretching process facilitates the decomposition of large-sized graphene clusters into smaller ones. This research contributes to the advancement of lightweight metal matrix composites by offering insights into optimizing processing parameters. Additionally, it provides crucial theoretical underpinnings for developing high-performance graphene-reinforced composites. [ABSTRACT FROM AUTHOR]

Pores are common defects generated during fabrication, which restrict the application of carbon/carbon (C/C) composites. To quantitatively understand the effects of pores on mechanical strength, this paper proposes a representative volume element model of unidirectional (UD) C/C composites based on the finite element method. The Hashin criterion and exponential degraded rule are used as the failure initiation and evolution of pyrolytic carbon matrices, respectively. Interfacial zones are characterized using the cohesive constitutive. At the same time, periodic boundary conditions are employed to study transverse tensile, compressive, and shear deformations of UD C/C composites. Predicted results are compared with the experimental results, which shows that the proposed model can effectively simulate the transverse mechanical behaviors of UD C/C composites. Based on this model, the effects of microstructural parameters including porosity, pore locations, the distance between two pores, pore clustering, and pore shapes on the mechanical strength are investigated. The results show that porosity markedly reduces the strength as porosity increases. When the porosity increases from 4.59% to 12.5%, the transverse tensile, compressive, and shear strengths decrease by 35.91%, 37.52%, and 30.76%, respectively. Pore locations, the distance between two pores, and pore clustering have little effect on the shear strength of UD C/C composites. For pore shapes, irregular pores more easily lead to stress concentration and matrix failure, which greatly depresses the bearing capacity of UD C/C composites. [ABSTRACT FROM AUTHOR]

Needled carbon/carbon composites contain complex microstructures such as irregular pores, anisotropic pyrolytic carbon, and interphases between fibers and pyrolytic carbon matrices. Additionally, these composites have hierarchical structures including weftless plies, short-cut fiber plies, and needled regions. To predict the effective elastic properties of needled carbon/carbon composites, this paper proposes a novel sequential multiscale method. At the microscale, representative volume element (RVE) models are established based on the microstructures of the weftless ply, short-cut fiber ply, and needled region, respectively. In the microscale RVE model, a modified Voronoi tessellation method is developed to characterize anisotropic pyrolytic carbon matrices. At the macroscale, an RVE model containing hierarchical structures is developed to predict the effective elastic properties of needled carbon/carbon composites. For the data interaction between scales, the homogenization results of microscale models are used as inputs for the macroscale model. By comparing these against the experimental results, the proposed multiscale model is validated. Furthermore, the effect of porosity on the effective elastic properties of needled carbon/carbon composites is investigated based on the multiscale model. The results show that the effective elastic properties of needled carbon/carbon composites decrease with the increase in porosity, but the extent of decrease is different in different directions. [ABSTRACT FROM AUTHOR]