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2. Effect of Mg dissolution on cyclic voltammetry and open circuit potentiometry of molten MgCl2–KCl–NaCl candidate heat transfer fluid for concentrating solar power

Author

Nicole E. Orabona, Olivia R. Dale, Parker Okabe, Suhee Choi, Charles Inman, and Michael F. Simpson

Subjects
chemistry.chemical_classification, Renewable Energy, Sustainability and the Environment, Magnesium, Inorganic chemistry, Salt (chemistry), chemistry.chemical_element, 02 engineering and technology, 010402 general chemistry, 021001 nanoscience & nanotechnology, Electrochemistry, 01 natural sciences, Redox, Chloride, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, medicine, Hydroxide, Cyclic voltammetry, 0210 nano-technology, Dissolution, medicine.drug
Abstract

Molten chloride salts have recently gained attention for application to heat transfer and thermal energy storage in concentrating solar power (CSP) plants. In this study, we studied the electrochemical effect of addition of hydroxide ions and/or dissolved metals added to MgCl2–KCl–NaCl salt mixture. Open circuit potentiometry indicated that the salt's redox potential increased with addition of hydroxide ions and decreased with the addition of soluble magnesium metal. Cyclic voltammetry indicated that a reduction peak associated with hydroxides vanished with addition of Mg0. Hydrogen gas was evolved when a mixture of Mg metal and MgCl2–KCl–NaCl containing NaOH was heated to 650 °C. These results demonstrate the benefit and mechanism for redox potential control in this salt using dissolved Mg metal.

Published
2019
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3. Letter from Charles Inman Barnard to Henry Cabot Lodge (1902-09-20)

Author

Barnard, Charles Inman, 1850-1942, Barnard, Charles Inman, 1850-1942, Barnard, Charles Inman, 1850-1942, and Barnard, Charles Inman, 1850-1942

Abstract

Charles Inman Barnard reports that French newspaper Le Figaro has an article with a quotation from Alphonse Daudet which appeared in one of President Roosevelt's book. The subject of the quotation is French women's fear of maternity.

Published
1902

4. Letter from C. I. Barnard to Henry Cabot Lodge (1902-03-09)

Author

Barnard, Charles Inman, 1850-1942, Barnard, Charles Inman, 1850-1942, Barnard, Charles Inman, 1850-1942, and Barnard, Charles Inman, 1850-1942

Abstract

C. I. Barnard encloses clippings from the French press, which has displayed an increasing interest in the United States and President Roosevelt. Much of this attention is likely arising from Prince Heinrich of Prussia's visit and the potential for improved American-German relations.

Published
1902

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