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To date, about two dozen low-mass embedded protostars exhibit rich spectra with lines of complex organic molecule (COM). These protostars seem to possess different enrichment in COMs. However, the statistics of COM abundance in low-mass protostars are limited by the scarcity of observations. This study introduces the Perseus ALMA Chemistry Survey (PEACHES), which aims at unbiasedly characterizing the chemistry of COMs toward the embedded (Class 0/I) protostars in the Perseus molecular cloud. Of 50 embedded protostars surveyed, 58% of them have emission from COMs. A 56%, 32%, and 40% of the protostars have CH$_3$OH, CH$_3$OCHO, and N-bearing COMs, respectively. The detectability of COMs depends neither on the averaged continuum brightness temperature, a proxy of the H$_2$ column density, nor on the bolometric luminosity and the bolometric temperature. For the protostars with detected COMs, CH$_3$OH has a tight correlation with CH$_3$CN, spanning more than two orders of magnitude in column densities normalized by the continuum brightness temperature, suggesting a chemical relation between CH$_3$OH and CH$_3$CN and a large chemical diversity in the PEACHES samples at the same time. A similar trend with more scatter is also found between all identified COMs, hinting at a common chemistry for the sources with COMs. The correlation between COMs is insensitive to the protostellar properties, such as the bolometric luminosity and the bolometric temperature. The abundance of larger COMs (CH$_3$OCHO and CH$_3$OCH$_3$) relative to that of smaller COMs (CH$_3$OH and CH$_3$CN) increases with the inferred gas column density, hinting at an efficient production of complex species in denser envelopes., 55 pages, 9 tables, 24 figures. Updated after publication in ApJ. Figure 18 appears as a figure set in ApJ

Disentangling the different stages of the star-formation process, in particular in the high-mass regime, is a challenge in astrophysics. Chemical clocks could help alleviating this problem, but their evolution strongly depends on many parameters, leading to degeneracy in the interpretation of the observational data. One of these uncertainties is the degree of CO depletion. We present here the first self-consistent magneto-hydrodynamic simulations of high-mass star-forming regions at different scales, fully coupled with a non-equilibrium chemical network, which includes C-N-O bearing molecules. Depletion and desorption processes are treated time-dependently. The results show that full CO-depletion (i.e. all gas-phase CO frozen-out on the surface of dust grains), can be reached very quickly, in one third or even smaller fractions of the free-fall time, whether the collapse proceeds on slow or fast timescales. This leads to a high level of deuteration in a short time both for typical tracers like N$_2$H$^+$, as well as for the main ion H$_3^+$, the latter being in general larger and more extended. N$_2$ depletion is slightly less efficient, and no direct effects on N-bearing molecules and deuterium fractionation are observed. We show that CO depletion is not the only driver of deuteration, and that there is a strong impact on $D_{frac}$ when changing the grain-size. We finally apply a two-dimensional gaussian Point Spread Function to our results to mimic observations with single-dish and interferometers. Our findings suggest that the low-values observed in high-mass star-forming clumps are in reality masking a full-depletion stage in the inner 0.1 pc region., accepted on ApJ

Recent surveys uncovered new Young Massive Clusters (YMCs) that host dozens of Red Supergiants (RSGs) in the inner Milky Way. These clusters are ideal for studying the most recent and violent star formation events in the inner Galaxy. However, due to the high extinction that affects the Galactic plane, they need to be studied through infrared (IR) spectroscopy. IR spectra of RSGs have proven to be powerful tools for obtaining chemical abundances. We present the first [Fe$/$H] measurement ($-$0.07$\pm$0.02) for the YMC VdBH 222 through analysis of its RSGs using VLT/X-shooter spectra. We find no evidence for Multiple Stellar Populations (MSPs) in this YMC, contrary to what is routinely observed in older massive clusters., Comment: 9 pages, 5 figures, Accepted for Publication in ApJ

This work introduces new low-temperature gas opacities in the range 3.2 ≲ log ( T / K ) ≲ 4.5 computed with the ÆSOPUS code under the assumption of thermodynamic equilibrium. In comparison to the previous version, ÆSOPUS 1.0, we updated and expanded molecular absorption to include 80 species, mostly using the recommended line lists currently available from the ExoMol and HITRAN databases. Furthermore, in light of a recent study, we revised the H− photodetachment cross section, added the free–free absorption of other negative ions of atoms and molecules, and updated the collision-induced absorption due to H2/H2, H2/H, H2/He, and H/He pairs. Using the new input physics, we computed tables of Rosseland mean opacities for several scaled-solar chemical compositions, including Magg et al.'s most recent one, as well as α-enhanced mixtures. The differences in opacity between the new ÆSOPUS 2.0 and the original ÆSOPUS 1.0 versions, as well as other sets of calculations, are discussed. The new opacities are released to the community via a dedicated webpage that includes both precomputed tables for widely used chemical compositions and a web interface for calculating opacities on the fly for any abundance distribution.