13 results on '"Cinquino, M."'
Search Results
2. Effect of surface tension and drying time on inkjet-printed PEDOT:PSS for ITO-free OLED devices
- Author
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Antonio Andretta, S. Carallo, Aurora Rizzo, Vincenzo Maiorano, Roberto Giannuzzi, A. G. Monteduro, Marco Cinquino, Marco Pugliese, Augusto Banfi, Giuseppe Gigli, Giovanni Dugnani, Antonella Giuri, Matteo Carugati, Alessandra Zizzari, Carmela Tania Prontera, Cinquino, M., Prontera, C. T., Zizzari, A., Giuri, A., Pugliese, M., Giannuzzi, R., Monteduro, A. G., Carugati, M., Banfi, A., Carallo, S., Rizzo, A., Andretta, A., Dugnani, G., Gigli, G., and Maiorano, V.
- Subjects
Materials science ,Fabrication ,Materials Science (miscellaneous) ,Substrate (printing) ,Organic light-emitting diodes ,Biomaterials ,PSS [PEDOT] ,PEDOT:PSS ,OLED ,Thin film ,Materials of engineering and construction. Mechanics of materials ,ITO-Free ,Surface tension ,business.industry ,Electronic, Optical and Magnetic Materials ,Indium tin oxide ,Inkjet printing ,Printed electronics ,Ceramics and Composites ,TA401-492 ,Optoelectronics ,Co-solvent ,Organic light-emitting diode ,Wetting ,business - Abstract
Highly conductive PEDOT:PSS is one of the most promising materials for indium tin oxide (ITO) substitution in printed electronics. Here, we report the development and optimisation of two PEDOT:PSS ink formulations for the fabrication of inkjet-printed transparent conductive layers. Starting from aqueous commercial solutions, co-solvents and a non-ionic surfactant were employed to modify the surface tension, improve the wetting capability of the ink, and obtain uniform and homogeneous thin films. In particular, the quantities of ethanol and surfactant were systematically adjusted to determine the optimal conditions for inkjet printing. The results demonstrate that a surface tension value between 28 and 40 mN/m and approximately 40 vol.% of a low-boiling-point co-solvent are fundamental to ensure the proper wetting of the glass substrate and a quick-drying process that confers uniformity to the printed thin film. The printed PEDOT:PSS thin films show good morphological, optical, and electrical properties that are similar to those observed for the corresponding spin-coated layers. The organic light-emitting diodes (OLEDs) fabricated with the inkjet-printed PEDOT:PSS electrodes showed a maximum quantum efficiency of 5.5% and maximum current efficiency of 15 cd/A, which is comparable to spin-coated reference devices. These results demonstrate the great potential of polymeric electrodes for the fabrication of high-efficiency printed OLED devices that are compatible with flexible and stretchable substrates.
- Published
- 2022
3. Light-Emitting Textiles: Device Architectures, Working Principles, and Applications
- Author
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Marco Cinquino, Vincenzo Maiorano, Carmela Tania Prontera, Marco Pugliese, Roberto Giannuzzi, Daniela Taurino, Giuseppe Gigli, Cinquino, M., Prontera, C. T., Pugliese, M., Giannuzzi, R., Taurino, D., Gigli, G., and Maiorano, V.
- Subjects
Optical fiber ,Emerging technologies ,Computer science ,Nanotechnology ,Review ,02 engineering and technology ,Light emitting diode ,Light-emitting e-textile ,Electroluminescence ,010402 general chemistry ,01 natural sciences ,law.invention ,Alternating current electroluminescent device ,Application areas ,law ,light electrochemical cells ,OLED ,TJ1-1570 ,Mechanical engineering and machinery ,Electrical and Electronic Engineering ,polymeric optical fibers ,light-emitting e-textiles ,Mechanical Engineering ,alternating current electroluminescent devices ,Light electrochemical cell ,Polymeric optical fibers ,021001 nanoscience & nanotechnology ,light emitting diodes ,0104 chemical sciences ,Control and Systems Engineering ,visual_art ,Electronic component ,visual_art.visual_art_medium ,Light emission ,0210 nano-technology ,Light-emitting diode - Abstract
E-textiles represent an emerging technology aiming toward the development of fabric with augmented functionalities, enabling the integration of displays, sensors, and other electronic components into textiles. Healthcare, protective clothing, fashion, and sports are a few examples application areas of e-textiles. Light-emitting textiles can have different applications: sensing, fashion, visual communication, light therapy, etc. Light emission can be integrated with textiles in different ways: fabricating light-emitting fibers and planar light-emitting textiles or employing side-emitting polymer optical fibers (POFs) coupled with light-emitting diodes (LEDs). Different kinds of technology have been investigated: alternating current electroluminescent devices (ACELs), inorganic and organic LEDs, and light-emitting electrochemical cells (LECs). The different device working principles and architectures are discussed in this review, highlighting the most relevant aspects and the possible approaches for their integration with textiles. Regarding POFs, the methodology to obtain side emissions and the critical aspects for their integration into textiles are discussed in this review. The main applications of light-emitting fabrics are illustrated, demonstrating that LEDs, alone or coupled with POFs, represent the most robust technology. On the other hand, OLEDs (Organic LEDs) are very promising for the future of light-emitting fabrics, but some issues still need to be addressed.
- Published
- 2021
4. Observation of Two Thresholds Leading to Polariton Condensation in 2D Hybrid Perovskites
- Author
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Giuseppe Gigli, Antonio Fieramosca, Vincenzo Maiorano, Marco Pugliese, Giovanni Lerario, Daniele Sanvitto, Luisa De Marco, Marco Cinquino, Dario Ballarini, Francesco Todisco, Carmela Tania Prontera, Laura Polimeno, Vincenzo Ardizzone, Milena De Giorgi, Lorenzo Dominici, Polimeno, L., Fieramosca, A., Lerario, G., Cinquino, M., De Giorgi, M., Ballarini, D., Todisco, F., Dominici, L., Ardizzone, V., Pugliese, M., Prontera, C. T., Maiorano, V., Gigli, G., De Marco, L., and Sanvitto, D.
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Phase transition ,Materials science ,Oscillator strength ,Physics::Optics ,FOS: Physical sciences ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Laser linewidth ,Condensed Matter::Materials Science ,Mesoscale and Nanoscale Physics (cond-mat.mes-hall) ,Polariton ,2D perovskite ,Perovskite (structure) ,Condensed Matter::Quantum Gases ,lasing ,Condensed matter physics ,Condensed Matter - Mesoscale and Nanoscale Physics ,business.industry ,Condensed Matter::Other ,021001 nanoscience & nanotechnology ,Atomic and Molecular Physics, and Optics ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,condensation ,Coherent states ,Photonics ,0210 nano-technology ,business ,Lasing threshold ,Physics - Optics ,Optics (physics.optics) ,polaritons - Abstract
Two dimensional (2D) perovskites are promising materials for photonic applications, given their outstanding nonlinear optical properties, ease of fabrication and versatility. In particular, exploiting their high oscillator strength, the crystalline form of 2D perovskites can be used as excitonic medium in optical microcavities, allowing for the study of their optical properties in the strong light-matter coupling regime. While polariton condensation has been observed in different materials at room temperature, here we observe for the first time two distinct threshold processes in a 2D perovskite, a material that has never shown spontaneous phase transition up to now. In particular, we demonstrate lasing from the bi-exciton state which contributes to populate the lower polariton branch and, at higher excitation powers, eventually leads to the formation of a polariton condensate. The emission linewidth narrowing and a spatial coherence over 50 x 50 um2 area are the smoking gun, the formation of a quantum coherent state in 2D hybrid perovskite. Our results not only show the formation of a polariton condensate in 2D perovskites but they are also crucial for the understanding of the physical mechanisms that leads to coherent phase transition in perovskite-based polariton microcavities.
- Published
- 2020
5. 1-D and 2-D surface structuring of steel by bursts of femtosecond laser pulses
- Author
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Pietro Mario Lugarà, L. Mirenghi, Gaetano Scamarcio, Marco Cinquino, Giuseppe Giannuzzi, Cinzia Di Franco, Antonio Ancona, Rosa Di Mundo, Caterina Gaudiuso, Klotzbach, Udo, Giannuzzi, G., Gaudiuso, C., Cinquino, M., Di Mundo, R., Mirenghi, L., Di Franco, C., Scamarcio, G., Lugara, P. M., and Ancona, A.
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Birefringence ,Materials science ,Linear polarization ,Polarization (waves) ,Laser ,laser induced periodic surface structures ,Molecular physics ,law.invention ,Wavelength ,law ,femtosecond laser ,Femtosecond ,laser ablation ,Hexagonal lattice ,Circular polarization - Abstract
In this work, we report on the fabrication of laser induced periodic surface structures (LIPSS) on stainless steel, using bursts of 200 fs sub-pulses at a wavelength of 1030 nm. A cascade of birefringent crystals was used to generate the bursts with tunable number of sub-pulses and intra-burst delays varying between 1.5 ps and 24 ps. Being such a delay shorter than the typical electron-lattice relaxation time in metals, the sub-pulses impinge on the sample surface when the material is still in a transient state after excitation from the first sub-pulse, thus allowing peculiar structures to be generated depending on the burst features. We obtained 1-D and 2-D periodic surface structures and investigated the influence of number of sub-pulses and polarization on their morphology. In particular, when bursts composed by all-aligned linearly polarized sub-pulses were used, 1-D LIPSS were obtained with different periodicity and depths depending on the number of sub-pulses. Bursts with crossed linear polarization or circular polarization sub-pulses produced 2-D LIPSS with morphology varying from triangular structures arranged in hexagonal lattice to pillar-like ordered or disordered structures depending on the bursts features. In most cases these structures exhibit a superhydrophobic behavior, as assessed by static contact angle measurements, which is achieved after a time of exposition to laboratory air. By XPS analysis we investigated the chemical variations occurring on the surfaces over this time.
- Published
- 2019
6. Enhancing cardiovascular health monitoring: Simultaneous multi-artery cardiac markers recording with flexible and bio-compatible AlN piezoelectric sensors.
- Author
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Cinquino M, Demir SM, Shumba AT, Schioppa EJ, Fachechi L, Rizzi F, Qualtieri A, Patrono L, Mastronardi VM, and De Vittorio M
- Subjects
- Humans, Equipment Design, Male, Blood Pressure physiology, Heart Rate, Monitoring, Physiologic instrumentation, Monitoring, Physiologic methods, Arteries, Adult, Pulse Wave Analysis instrumentation, Biosensing Techniques instrumentation, Cardiovascular Diseases diagnosis
- Abstract
Continuous monitoring of cardiovascular parameters like pulse wave velocity (PWV), blood pressure wave (BPW), stiffness index (SI), reflection index (RI), mean arterial pressure (MAP), and cardio-ankle vascular index (CAVI) has significant clinical importance for the early diagnosis of cardiovascular diseases (CVDs). Standard approaches, including echocardiography, impedance cardiography, or hemodynamic monitoring, are hindered by expensive and bulky apparatus and accessibility only in specialized facilities. Moreover, noninvasive techniques like sphygmomanometry, electrocardiography, and arterial tonometry often lack accuracy due to external electrical interferences, artifacts produced by unreliable electrode contacts, misreading from placement errors, or failure in detecting transient issues and trends. Here, we report a bio-compatible, flexible, noninvasive, low-cost piezoelectric sensor for continuous and real-time cardiovascular monitoring. The sensor, utilizing a thin aluminum nitride film on a flexible Kapton substrate, is used to extract heart rate, blood pressure waves, pulse wave velocities, and cardio-ankle vascular index from four arterial pulse sites: carotid, brachial, radial, and posterior tibial arteries. This simultaneous recording, for the first time in the same experiment, allows to provide a comprehensive cardiovascular patient's health profile. In a test with a 28-year-old male subject, the sensor yielded the SI = 7.1 ± 0.2 m/s, RI = 54.4 ± 0.5 %, MAP = 86.2 ± 1.5 mmHg, CAVI = 7.8 ± 0.2, and seven PWVs from the combination of the four different arterial positions, in good agreement with the typical values reported in the literature. These findings make the proposed technology a powerful tool to facilitate personalized medical diagnosis in preventing CVDs., Competing Interests: Declaration of competing interest The authors declared that they have no conflicts of interest to this work., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)
- Published
- 2025
- Full Text
- View/download PDF
7. Thermochromic Printable and Multicolor Polymeric Composite Based on Hybrid Organic-Inorganic Perovskite.
- Author
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Cinquino M, Prontera CT, Giuri A, Pugliese M, Giannuzzi R, Maggiore A, Altamura D, Mariano F, Gigli G, Esposito Corcione C, Giannini C, Rizzo A, De Marco L, and Maiorano V
- Abstract
Hybrid organic-inorganic perovskites (PVKs) are among the most promising materials for optoelectronic applications thanks to their outstanding photophysical properties and easy synthesis. Herein, a new PVK-based thermochromic composite is demonstrated. It can reversibly switch from a transparent state (transmittance > 80%) at room temperature to a colored state (transmittance < 10%) at high temperature, with very fast kinetics, taking only a few seconds to go from the bleached to the colored state (and vice versa). X-ray diffraction, Fourier-transform infrared spectroscopy, differential scanning calometry, rheological, and optical measurements carried out during heating/cooling cycles reveal that thermochromism in the material is based on a reversible process of PVK disassembly/assembly mediated by intercalating polymeric chains, through the formation and breaking of hydrogen bonds between polymer and perovskite. Therefore, differently from other thermochromic perovskites, that generally work with the adsorption/desorption of volatile molecules, the system is able to perform several heating/cooling cycles regardless of environmental conditions. The color and transition temperature (from 70 to 120 °C) can be tuned depending on the type of perovskite. Moreover, this thermochromic material is printable and can be deposited by cheap techniques, paving the way for a new class of smart coatings with an unprecedented range of colors., (© 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.)
- Published
- 2024
- Full Text
- View/download PDF
8. Managing Growth and Dimensionality of Quasi 2D Perovskite Single-Crystalline Flakes for Tunable Excitons Orientation.
- Author
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Cinquino M, Fieramosca A, Mastria R, Polimeno L, Moliterni A, Olieric V, Matsugaki N, Panico R, De Giorgi M, Gigli G, Giannini C, Rizzo A, Sanvitto D, and De Marco L
- Abstract
Hybrid perovskites are among the most promising materials for optoelectronic applications. Their 2D crystalline form is even more interesting since the alternating inorganic and organic layers naturally forge a multiple quantum-well structure, leading to the formation of stable excitonic resonances. Nevertheless, a controlled modulation of the quantum well width, which is defined by the number of inorganic layers (n) between two organic ones, is not trivial and represents the main synthetic challenge in the field. Here, a conceptually innovative approach to easily tune n in lead iodide perovskite single-crystalline flakes is presented. The judicious use of potassium iodide is found to modulate the supersaturation levels of the precursors solution without being part of the final products. This allows to obtain a fine tuning of the n value. The excellent optical quality of the as synthesized flakes guarantees an in-depth analysis by Fourier-space microscopy, revealing that the excitons orientation can be manipulated by modifying the number of inorganic layers. Excitonic out-of-plane component, indeed, is enhanced when "n" is increased. The combined advances in the synthesis and optical characterization fill in the picture of the exciton behavior in low-dimensional perovskite, paving the way to the design of materials with improved optoelectronic characteristics., (© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.)
- Published
- 2021
- Full Text
- View/download PDF
9. Light-Emitting Textiles: Device Architectures, Working Principles, and Applications.
- Author
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Cinquino M, Prontera CT, Pugliese M, Giannuzzi R, Taurino D, Gigli G, and Maiorano V
- Abstract
E-textiles represent an emerging technology aiming toward the development of fabric with augmented functionalities, enabling the integration of displays, sensors, and other electronic components into textiles. Healthcare, protective clothing, fashion, and sports are a few examples application areas of e-textiles. Light-emitting textiles can have different applications: sensing, fashion, visual communication, light therapy, etc. Light emission can be integrated with textiles in different ways: fabricating light-emitting fibers and planar light-emitting textiles or employing side-emitting polymer optical fibers (POFs) coupled with light-emitting diodes (LEDs). Different kinds of technology have been investigated: alternating current electroluminescent devices (ACELs), inorganic and organic LEDs, and light-emitting electrochemical cells (LECs). The different device working principles and architectures are discussed in this review, highlighting the most relevant aspects and the possible approaches for their integration with textiles. Regarding POFs, the methodology to obtain side emissions and the critical aspects for their integration into textiles are discussed in this review. The main applications of light-emitting fabrics are illustrated, demonstrating that LEDs, alone or coupled with POFs, represent the most robust technology. On the other hand, OLEDs (Organic LEDs) are very promising for the future of light-emitting fabrics, but some issues still need to be addressed.
- Published
- 2021
- Full Text
- View/download PDF
10. Contribution of CT to characterization of focal nodular hyperplasia of the liver.
- Author
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Procacci C, Fugazzola C, Cinquino M, Mangiante G, Zonta L, Andreis IA, Nicoli N, and Pistolesi GF
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- Adenoma diagnostic imaging, Biopsy, Needle, Carcinoma, Hepatocellular diagnostic imaging, Diagnosis, Differential, False Negative Reactions, Humans, Hyperplasia, Liver Neoplasms diagnostic imaging, Predictive Value of Tests, Sensitivity and Specificity, Tomography, X-Ray Computed, Liver diagnostic imaging, Liver pathology, Liver Diseases diagnostic imaging
- Abstract
Our personal series of 20 cases of focal nodular hyperplasia (FNH) of the liver is presented. All lesions were studied with computed tomography (CT), 16 of which with surgical control. Retrospective evaluation of the CT features of the identified FNH, along with those of five hepatocellular adenomas (HCA) and 30 hepatocellular carcinomas (HCC), allowed the definition of specific patterns leading to a correct characterization of FNH in 78% of cases. This greatly reduced the diagnostic errors, with the sole exception of patients with fatty liver in whom nuclear medicine may eventually provide a correct characterization. Fine-needle biopsy is thus only necessary in the dubious cases. A precise diagnostic workup of FNH is necessary, since it may avoid the surgical intervention.
- Published
- 1992
- Full Text
- View/download PDF
11. Roentgen findings in injuries of the wrist.
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FARRELL JT Jr, WILLIAMS BL, and CINQUINO MA
- Subjects
- Humans, Wrist, Wrist Injuries, Wrist Joint
- Published
- 1949
12. JOHN T. FARRELL JR., M.D. 1897-1965.
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CINQUINO MA
- Subjects
- History, 19th Century, History, 20th Century, Medicine, Radiology
- Published
- 1965
13. Memoir of John Thompson Farrell, Jr. 1897-1965.
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Cinquino MA
- Subjects
- History of Medicine, Pennsylvania, Radiology history
- Published
- 1966
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