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Wolff et al. (2016) comment on Smart et al. (2014) and in doing so concentrate on issues other than the main point. They do not dispute our central assertion, the inadequate resolution of nearly all extant ice cores for detection of impulsive nitrate events (spikes) from any source, including past solar proton events (SPEs). We explain why comparing two short-length cores from other researchers and analyzed by different methods is insufficient for disputing subannual reproducibility, and call for a multiple, fine-resolution, replicate core study to resolve this issue. While acknowledging the creation of nitrate by SPEs and the existence of ice core nitrate spikes detected by others, they present several weak arguments, such as alleged scavenging of nitrate by some unnamed and unmeasured aerosol, and why no enhanced nitrate signal for documenting SPE statistics should be distinguishable in the ice. These are not derived from the main points in our Smart et al. (2014) paper. We address these briefly and show that ionization from the February 1956 SPE was sufficient to produce a winter, likely acidic, nitrate spike at Summit, Greenland. While noting some convergence of interpretation, we show why their claim that nitrate spikes cannot be used for deriving SPE statistics is unproven and why rejection of fine resolution core studies as unreliable is premature.

In order to support the very high time resolution required to observe short-term variations in nitrates and all other ions represented by electrical conductivity in polar ice, a Fourier transform infrared spectrometer was developed for measurement of deuterium concentration in ice samples, as an additional support for the timescale of ultra-high resolution. The portable instrument provided the possibility to measure deuterium concentration on exactly the same samples as used for measuring nitrate concentrations and liquid electrical conductivity, thus verifying that the original dating of the annual variations in nitrate was correct. We present basic information about how the high-resolution data were obtained and discuss their reliability and significance.

We discuss results from a high-sensitivity, multichannel, very high frequency, and surface-based radar depth sounder/imager. The instrument was used to map deep internal layers and characterize basal conditions over a 240- km2 grid in the vicinity of the West Antarctic Ice Sheet Divide ice core site. The ice thickness at the core site was found to be about 3470 m, and we detected internal layers to within 350 m of the ice/bed interface. Radar-detected layer stratigraphy does not show evidence of flow-induced disturbances that might complicate the depth-age relationship and the interpretation of climate history preserved in the ice. We also found that bed reflectivity over the region varies by more than 30 dB. Approximately 15 dB of this variability appears to be the result of transitions from a frozen to a thawed bed in a number of places. The remainder probably results from changes in bed roughness. Our data are important for planning drilling to the bed, as well as providing constraints and boundary conditions for regional ice-flow models.

Solar energetic particles ionize the atmosphere, leading to production of nitrogen oxides. It has been suggested that some such events are visible as layers of nitrate in ice cores, yielding archives of energetic, high fluence solar proton events (SPEs). There has been controversy, due to slowness of transport for these species down from the upper stratosphere; past numerical simulations based on an analytic calculation have shown very little ionization below the mid stratosphere. These simulations suffer from deficiencies: they consider only soft SPEs and narrow energy ranges; spectral fits are poorly chosen; with few exceptions secondary particles in air showers are ignored. Using improved simulations that follow development of the proton-induced air shower, we find consistency with recent experiments showing substantial excess ionization down to 5 km. We compute nitrate available from the 23 February 1956 SPE, which had a high fluence, hard spectrum, and well-resolved associated nitrate peak in a Greenland ice core. For the first time, we find this event can account for ice core data with timely (~ 2 months) transport downward between 46 km and the surface, thus indicating an archive of high fluence, hard spectrum SPE covering the last several millennia. We discuss interpretations of this result, as well as the lack of a clearly-defined nitrate spike associated with the soft-spectrum 3-4 August 1972 SPE. We suggest that hard-spectrum SPEs, especially in the 6 months of polar winter, are detectable in ice cores, and that more work needs to be done to investigate this., Comment: JGR Atmospheres, in press

The presence of photon induced ionization from supernovae at detectable levels in the polar ice sheets has been an interesting issue for some time. Evidence for such a signal is reported in 1200-year time sequences from the Antarctic continent at South Pole and Vostok, respectively. The supernova candidate events all appear as nitrate concentration spikes apparently caused by ionization from high energy radiation interacting with the upper atmosphere of the Earth. Further support for this interpretation has been obtained from an ice core drilled in Greenland covering 430 years. These ultrahigh resolution measurements (averaging 18 data points/year) have revealed nitrate anomalies at the times of the Tycho and Kepler Supernovae. In addition, the possibility is being suggested that the supernova Cassiopeia A appears in the record, thus pinpointing its year of occurrence. Other, less understood phenomena such as γ-ray bursts also occasionally may produce anomalies in the nitrate record.

Based on cosmological rates, it is probable that at least once in the last Gy the Earth has been irradiated by a gamma-ray burst in our Galaxy from within 2 kpc. Using a two-dimensional atmospheric model we have performed the first computation of the effects upon the Earth's atmosphere of one such impulsive event. A ten second burst delivering 100 kJ/m^2 to the Earth penetrates to the stratosphere and results in globally averaged ozone depletion of 35%, with depletion reaching 55% at some latitudes. Significant global depletion persists for over 5 years after the burst. This depletion would have dramatic implications for life since a 50% decrease in ozone column density results in approximately three times the normal UVB flux. Widespread extinctions are likely, based on extrapolation from UVB sensitivity of modern organisms. Additional effects include a shot of nitrate fertilizer and NO2 opacity in the visible providing a cooling perturbation to the climate over a similar timescale. These results lend support to the hypothesis that a GRB may have initiated the late Ordovician mass extinction (Melott et al. 2004)., 4 color figures; Revised version to be published in Astrophysical Journal Letters. Moderate revisions, including more detail on atmospheric processes, on probable climactic and biogeochemical effects, an improved color scheme for graphics, and an animation of computed DNA damage level

Gamma-ray bursts (hereafter GRB) produce a flux of radiation detectable across the observable Universe, and at least some of them are associated with galaxies. A GRB within our own Ggalaxy could do considerable damage to the Earth's biosphere; rate estimates suggest that a dangerously near GRB should occur on average two or more times per billion years. At least five times in the history of life, the Earth experienced mass extinctions that eliminated a large percentage of the biota. Many possible causes have been documented, and GRB may also have contributed. The late Ordovician mass extinction approximately 440 million years ago may be at least partly the result of a GRB. A special feature of GRB in terms of terrestrial effects is a nearly impulsive energy input of order 10 s. Due to expected severe depletion of the ozone layer, intense solar ultraviolet radiation would result from a nearby GRB, and some of the patterns of extinction and survivorship at this time may be attributable to elevated levels of UV radiation reaching the Earth. In addition a GRB could trigger the global cooling which occurs at the end of the Ordovician period that follows an interval of relatively warm climate. Intense rapid cooling and glaciation at that time, previously identified as the probable cause of this mass extinction, may have resulted from a GRB., Comment: Accepted for publication in the International Journal of Astrobiology. 24 pages, moderate revisions, including more quantitative detail on GRB rates, atmospheric effects, and more description of correlations of extinction rates with habitat and lifestyle of fossil fauna

Estimates made in the 1970's indicated that a supernova occurring within tens of parsecs of Earth could have significant effects on the ozone layer. Since that time, improved tools for detailed modeling of atmospheric chemistry have been developed to calculate ozone depletion, and advances have been made in theoretical modeling of supernovae and of the resultant gamma-ray spectra. In addition, one now has better knowledge of the occurrence rate of supernovae in the galaxy, and of the spatial distribution of progenitors to core-collapse supernovae. We report here the results of two-dimensional atmospheric model calculations that take as input the spectral energy distribution of a supernova, adopting various distances from Earth and various latitude impact angles. In separate simulations we calculate the ozone depletion due to both gamma-rays and cosmic rays. We find that for the combined ozone depletion roughly to double the ``biologically active'' UV flux received at the surface of the Earth, the supernova must occur at, 24 pages, 4 Postscript figures, to appear in The Astrophysical Journal, 2003 March 10, vol. 585

Ice cores are archives of climate change and possibly large solar proton events (SPEs). Wolff et al. (2012) used a single event, a nitrate peak in the GISP2-H core, which McCracken et al. (2001a) time associated with the poorly quantified 1859 Carrington event, to discredit SPE-produced, impulsive nitrate deposition in polar ice. This is not the ideal test case. We critique the Wolff et al. analysis and demonstrate that the data they used cannot detect impulsive nitrate events because of resolution limitations. We suggest re-examination of the top of the Greenland ice sheet at key intervals over the last two millennia with attention to fine resolution and replicate sampling of multiple species. This will allow further insight into polar depositional processes on a sub-seasonal scale, including atmospheric sources, transport mechanisms to the ice sheet, post-depositional interactions, and a potential SPE association., 22 pages, 7 figures in Journal of Geophysical Research: Space Physics 119, 2014

Firestone (2014) asserted evidence for numerous (23) nearby (d, 8 pages, 1 figure. to be published in the Interenational Journal of Astrobiology

This study shows the results of a model of polar cap absorption events (PCAs) using solar energetic proton flux as an input. The proton data are recorded by the Charged Particle Measurement Experiment (CPME) on board the IMP 8 satellite and are collected by the Applied Physics Laboratory at Johns Hopkins University. The IMP 8 satellite orbits the Earth at distances between 30 and 35 Earth radii, which places it in the solar energetic particle environment throughout most of its orbit. It has been shown in previous studies that these solar energetic particles have direct and immediate access to the polar atmosphere [Reid, 1970]. Our model shows that the majority of the ionization resulting from the influx of solar energetic protons occurs in the altitude range from ∼ 50–90 km. Excess ionization at these altitudes causes enhanced absorption of cosmic HF radio waves. The levels of absorption used for comparison in this study were measured directly by the riometer at South Pole station, Antarctica. The results show a very strong correlation between the incident proton flux and measured path-integrated cosmic HF radio noise absorption for significant events, involving absorptions greater than 1.0 dB. For absorption levels lower than this it is obvious that other phenomena dominate. For HF radio waves the primary contributors to PCA are protons with energies near 20 MeV. This study extends the correlated observations of interplanetary particles and PCA throughout a 9-year period. The close quantitative agreement between the measured and calculated values of absorption supports the validity of the assumptions and suppositions made by this model. The data also suggest a method by which the path-integrated cosmic noise absorption may be used to probe the E and D layers of the ionosphere to determine the effective ion-electron recombination coefficients within these regions.

A two-dimensional photochemical transport model which has inputs that characterize the odd nitrogen production associated with galactic cosmic rays, solar particle events (SPEs), and lower thermospheric contributions (auroral electrons and solar EUV and soft X-rays) is used to compute odd nitrogen concentrations in the polar middle atmosphere from 1 January 1970 to 31 December 1994. We are able to separate out of the total odd nitrogen budget the contributions of the energetic charged particles according to type. The SPE contributions to annual average odd nitrogen concentrations in the polar stratosphere (latitudes > 50°) are computed to be significant (>10%) only for the larger events of August 1972 and October 1989. The SPE contributions to odd nitrogen concentrations in the polar middle atmosphere are found to be asymmetric with respect to hemispheres. The computed SPE contributions to odd nitrogen concentrations at 30 km are significant more often over the South Pole than the North Pole. The thermospheric contributions to odd nitrogen concentrations in the polar middle atmosphere are asymmetric with respect to hemispheres. A stronger thermospheric influence in the stratosphere is computed over the South Pole than the North Pole. An attempt has been made to compare the modeled odd nitrogen of the polar middle atmosphere to an ultra-high resolution polar ice cap nitrate sequence to examine the hypothesis that the nitrate sequences exhibit a signal associated with energetic particles. Variations of odd nitrogen production and modeled concentrations associated with energetic particles themselves cannot explain all of the huge variations observed in the fine structure present in nitrate data from the polar ice cap nitrates, but may be able to explain parts of some of them.

In August of 2008 a radar survey was conducted at the NEEM site in Greenland. An example echogram showing internal layers all the way to the bed, a digital elevation map around the drill site, and a side looking synthetic aperture radar image will be presented. The echogram appears to show a fairly continuous Eemian layer where predicted by modeling. Additionally the area around the drill site is very flat although some slope variation is observed. Finally side looking SAR images show reflected power variations that need more analysis to determine their source.

Approximately 70% of the year-to-year variability in world grain yields for 1968–1987 can be explained by a simple model involving three variables: yields, winter northern hemisphere areal snow cover and annual solar activity in the preceding year. Eighty five percent of the world grain yield variability can be explained by this model, due to an enhanced solar signal, in years when the Quasi-Biennial Oscillation (QBO) is in its west phase. This result is bolstered by recent similar findings by others and supports the detectable impact of solar activity on weather in the stratosphere and troposphere when measured on a global scale.

Gamma-Ray Bursts (GRBs) are likely to have made a number of significant impacts on the Earth during the last billion years. We have used a two-dimensional atmospheric model to investigate the effects on the Earth's atmosphere of GRBs delivering a range of fluences, at various latitudes, at the equinoxes and solstices, and at different times of day. We have estimated DNA damage levels caused by increased solar UVB radiation, reduction in solar visible light due to $\mathrm{NO_2}$ opacity, and deposition of nitrates through rainout of $\mathrm{HNO_3}$. For the ``typical'' nearest burst in the last billion years, we find globally averaged ozone depletion up to 38%. Localized depletion reaches as much as 74%. Significant global depletion (at least 10%) persists up to about 7 years after the burst. Our results depend strongly on time of year and latitude over which the burst occurs. We find DNA damage of up to 16 times the normal annual global average, well above lethal levels for simple life forms such as phytoplankton. The greatest damage occurs at low to mid latitudes. We find reductions in visible sunlight of a few percent, primarily in the polar regions. Nitrate deposition similar to or slightly greater than that currently caused by lightning is also observed, lasting several years. We discuss how these results support the hypothesis that the Late Ordovician mass extinction may have been initiated by a GRB., Comment: Minor revisions, includes more discussion of reaction rates; 1 new figure. Accepted for publication in ApJ. 68 pages, 21 figures, 12 tables

Nitrate flux has been determined in the snow sequence deposited at Windless Bight on the Ross Ice Shelf (Antarctica). The data were obtained from on-site analysis of nitrate concentrations from a glaciological pit and a firn core spanning the time interval from midwinter 1971 to January 1986. The high resolution data can be combined with precipitation records collected from adjacent areas to provide a record of nitrate flux. The resulting time series contains a signal which corresponds to the two major solar events of 1972 and 1984. The concentration and flux profiles may be useful in studies of Antarctic ozone depletion.

For the past 51 years nitrate deposition in snow and firn layers at the South Pole exhibits a significant linear relationship with sunspot numbers and the ‘aa’ index of geomagnetic activity. Currently known atmospheric processes may explain these results. A high resolution nitrate record from deep ice cores could be valuable for both Sun and climate studies.

This is a study of the ionization input of interplanetary (including solar flare) energetic protons and alpha particles into the south polar ionosphere over the interval 1982–1985. Energetic particle data are collected by the charged particle measurement experiment (CPME) of the Applied Physics Laboratory/Johns Hopkins University, onboard the IMP 8 satellite orbiting the Earth at 30–35 Earth radii. It is well known that interplanetary ions have full and prompt access to the polar ionosphere. The incremental ionization produced at 20–120 km. altitudes causes enhanced radio wave absorption which is observed by riometers operated by the University of Maryland, at South Pole, Antarctica. We compute the expected absorption from the vertical structure of the ionization deposited by these energetic particles and compare the computed values with the observations. The contribution of the alpha particles is found to be quite small as a percentage of the absorption except at the peak of the day 35, 1983, event, when their contribution to the absorption is about 0.6 dB out of a total of 3.4 dB. The dominant contribution to absorption at 30 MHz usually arises from protons below 10 MeV, specifically in the 2- to 4-MeV interval. We have propagated the observed fluxes and energy spectra of protons and alpha particles through a seasonally adjusted slab model of the polar atmosphere. The atmospheric ionization resulting from the slowing and stopping of protons and alpha particles is used to estimate an equilibrium vertical ionization profile which is then convolved with an absorption efficiency profile to yield a calculated absorption. There is good agreement between the computed and observed absorption when the daily averaged absorption is above 0.1 dB; this shows that the interplanetary ions are the dominant contributors on those days. This set of observations constitutes the most complete and definitive illustration to date of the control by interplanetary particles of the shape and magnitude of the ionization profile in the lower ionosphere.