Search

We present spatially resolved measurements of SO$_2$ and NaCl winds on Io at several unique points in its orbit: before and after eclipse, and at maximum eastern and western elongation. The derived wind fields represent a unique case of meteorology in a rarified, volcanic atmosphere. Through the use of Doppler shift measurements in emission spectra obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) between $\sim346$-430GHz ($\sim0.70$-0.87 mm), line-of-sight winds up to $\sim-100$ m s$^{-1}$ in the approaching direction and >250 m s$^{-1}$ in the receding direction were derived for SO$_2$ at altitudes of $\sim10$-50 km, while NaCl winds consistently reached $\sim$|150-200| m s$^{-1}$ in localized regions up to $\sim30$ km above the surface. The wind distributions measured at maximum east and west Jovian elongations, and on the subJovian hemisphere pre- and post-eclipse, were found to be significantly different and complex, corroborating the results of simulations that include surface temperature and frost distribution, volcanic activity, and interactions with the Jovian magnetosphere. Further, the wind speeds of SO$_2$ and NaCl are often inconsistent in direction and magnitude, indicating that the processes that drive the winds for the two molecular species are different and potentially uncoupled; while the SO$_2$ wind field can be explained through a combination of sublimation-driven winds, plasma torus interactions, and plume activity, the NaCl winds appear to be primarily driven by the plasma torus., Comment: 8 Figures, 2 Tables. Accepted for publication in ApJ Letters

Polycyclic aromatic hydrocarbons (PAHs) are expected to be the most abundant class of organic molecules in space. Their interstellar lifecycle is not well understood, and progress is hampered by difficulties detecting individual PAH molecules. Here, we present the discovery of CN-functionalized pyrene, a 4-ring PAH, in the dense cloud TMC-1 using the 100-m Green Bank Telescope. We derive an abundance of 1-cyanopyrene of ~1.52 x $10^{12}$ cm$^{-2}$, and from this estimate that the un-substituted pyrene accounts for up to ~0.03-0.3% of the carbon budget in the dense interstellar medium which trace the birth sites of stars and planets. The presence of pyrene in this cold (~10 K) molecular cloud agrees with its recent measurement in asteroid Ryugu where isotopic clumping suggest a cold, interstellar origin. The direct link to the birth site of our solar system is strengthened when we consider the solid state pyrene content in the pre-stellar materials compared to comets, which represent the most pristine material in the solar system. We estimate that solid state pyrene can account for 1% of the carbon within comets carried by this one single organic molecule. The abundance indicates pyrene is an "island of stability" in interstellar PAH chemistry and suggests a potential cold molecular cloud origin of the carbon carried by PAHs that is supplied to forming planetary systems, including habitable worlds such as our own., Comment: Version of manuscript revised to comply with licensing requirements

Submillimeter and millimeter wavelengths provide a unique view of the Universe, from the gas and dust that fills and surrounds galaxies to the chromosphere of our own Sun. Current single-dish facilities have presented a tantalising view of the brightest (sub-)mm sources, and interferometers have provided the exquisite resolution necessary to analyse the details in small fields, but there are still many open questions that cannot be answered with current facilities. In this report we summarise the science that is guiding the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST). We demonstrate how tranformational advances in topics including star formation in high redshift galaxies, the diffuse circumgalactic medium, Galactic ecology, cometary compositions and solar flares motivate the need for a 50m, single-dish telescope with a 1-2 degree field of view and a new generation of highly multiplexed continuum and spectral cameras. AtLAST will have the resolution to drastically lower the confusion limit compared to current single-dish facilities, whilst also being able to rapidly map large areas of the sky and detect extended, diffuse structures. Its high sensitivity and large field of view will open up the field of submillimeter transient science by increasing the probability of serendipitous detections. Finally, the science cases listed here motivate the need for a highly flexible operations model capable of short observations of individual targets, large surveys, monitoring programmes, target of opportunity observations and coordinated observations with other observatories. AtLAST aims to be a sustainable, upgradeable, multipurpose facility that will deliver orders of magnitude increases in sensitivity and mapping speeds over current and planned submillimeter observatories., Comment: 47 pages, 12 figures. For further details on AtLAST see https://atlast.uio.no

Sub-mm and mm wavelengths provide a unique view of the Universe, from the gas and dust that fills and surrounds galaxies to the chromosphere of our own Sun. Current single-dish facilities have presented a tantalising view of the brightest (sub-)mm sources, and interferometers have provided the exquisite resolution necessary to analyse the details in small fields, but there are still many open questions that cannot be answered with current facilities: Where are all the baryons? How do structures interact with their environments? What does the time-varying (sub-)mm sky look like? In order to make major advances on these questions and others, what is needed now is a facility capable of rapidly mapping the sky spatially, spectrally, and temporally, which can only be done by a high throughput, single-dish observatory. An extensive design study for this new facility is currently being undertaken. In this paper, we focus on the key science drivers and the requirements they place on the observatory. As a 50m single dish telescope with a 1-2{\deg} field of view, the strength of the Atacama Large Aperture Submillimeter Telescope (AtLAST) is in science where a large field of view, highly multiplexed instrumentation and sensitivity to faint large-scale structure is important. AtLAST aims to be a sustainable, upgradeable, multipurpose facility that will deliver orders of magnitude increases in sensitivity and mapping speeds over current and planned telescopes., Comment: 12 pages, Conference proceedings paper for the 2024 SPIE Astronomical Telescopes + Instrumentation meeting

Titan's atmospheric composition and dynamical state have previously been studied over numerous epochs by both ground- and space-based facilities. However, stratospheric measurements remain sparse during Titan's northern summer and fall. The lack of seasonal symmetry in observations of Titan's temperature field and chemical abundances raises questions about the nature of the middle atmosphere's meridional circulation and evolution over Titan's 29-yr seasonal cycle that can only be answered through long-term monitoring campaigns. Here, we present maps of Titan's stratospheric temperature, acetonitrile (or methyl cyanide; CH$_3$CN), and monodeuterated methane (CH$_3$D) abundances following Titan's northern summer solstice obtained with Band 9 ($\sim0.43$ mm) ALMA observations. We find that increasing temperatures towards high-southern latitudes, currently in winter, resemble those observed during Titan's northern winter by the Cassini mission. Acetonitrile abundances have changed significantly since previous (sub)millimeter observations, and we find that the species is now highly concentrated at high-southern latitudes. The stratospheric CH$_3$D content is found to range between 4-8 ppm in these observations, and we infer the CH$_4$ abundance to vary between $\sim0.9-1.6\%$ through conversion with previously measured D/H values. A global value of CH$_4=1.15\%$ was retrieved, lending further evidence to the temporal and spatial variability of Titan's stratospheric methane when compared with previous measurements. Additional observations are required to determine the cause and magnitude of stratospheric enhancements in methane during these poorly understood seasons on Titan., Comment: Accepted for publication in the Planetary Science Journal. 9 Figures, 1 table

The study of transient and variable events, including novae, active galactic nuclei, and black hole binaries, has historically been a fruitful path for elucidating the evolutionary mechanisms of our universe. The study of such events in the millimeter and submillimeter is, however, still in its infancy. Submillimeter observations probe a variety of materials, such as optically thick dust, which are hard to study in other wavelengths. Submillimeter observations are sensitive to a number of emission mechanisms, from the aforementioned cold dust, to hot free-free emission, and synchrotron emission from energetic particles. Study of these phenomena has been hampered by a lack of prompt, high sensitivity submillimeter follow-up, as well as by a lack of high-sky-coverage submillimeter surveys. In this paper, we describe how the proposed Atacama Large Aperture Submillimeter Telescope (AtLAST) could fill in these gaps in our understanding of the transient universe. We discuss a number of science cases that would benefit from AtLAST observations, and detail how AtLAST is uniquely suited to contributing to them. In particular, AtLAST's large field of view will enable serendipitous detections of transient events, while its anticipated ability to get on source quickly and observe simultaneously in multiple bands make it also ideally suited for transient follow-up. We make theoretical predictions for the instrumental and observatory properties required to significantly contribute to these science cases, and compare them to the projected AtLAST capabilities. Finally, we consider the unique ways in which transient science cases constrain the observational strategies of AtLAST, and make prescriptions for how AtLAST should observe in order to maximize its transient science output without impinging on other science cases., Comment: 19 pages, 5 figures

During the most active period of star formation in galaxies, which occurs in the redshift range 1

The study of planets and small bodies within our Solar System is fundamental for understanding the formation and evolution the Earth and other planets. Compositional and meteorological studies of the giant planets provide a foundation for understanding the nature of the most commonly observed exoplanets, while spectroscopic observations of the atmospheres of terrestrial planets, moons, and comets provide insights into the past and present-day habitability of planetary environments, and the availability of the chemical ingredients for life. While prior and existing (sub)millimeter observations have led to major advances in these areas, progress is hindered by limitations in the dynamic range, spatial and temporal coverage, as well as sensitivity of existing telescopes and interferometers. Here, we summarize some of the key planetary science use cases that factor into the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST), a proposed 50-m class single dish facility: (1) to more fully characterize planetary wind fields and atmospheric thermal structures, (2) to measure the compositions of icy moon atmospheres and plumes, (3) to obtain detections of new, astrobiologically relevant gases and perform isotopic surveys of comets, and (4) to perform synergistic, temporally-resolved measurements in support of dedicated interplanetary space missions. The improved spatial coverage (several arcminutes), resolution ($\sim1.2''-12''$), bandwidth (several tens of GHz), dynamic range ($\sim10^5$) and sensitivity ($\sim1$ mK km s$^{-1}$) required by these science cases would enable new insights into the chemistry and physics of planetary environments, the origins of prebiotic molecules and the habitability of planetary systems in general., Comment: Submitted to Open Research Europe (AtLAST collection). 19 pages

Understanding the physical processes that regulate star formation and galaxy evolution are major areas of activity in modern astrophysics. Nearby galaxies offer unique opportunities to inspect interstellar medium (ISM), star formation (SF), radiative, dynamic and magnetic physics in great detail from sub-galactic (kpc) scales to sub-cloud (sub-pc) scales, from quiescent galaxies to starbursts, and from field galaxies to overdensities. In this case study, we discuss the major breakthroughs in this area of research that will be enabled by the Atacama Large Aperture Submillimeter Telescope (AtLAST), a proposed 50-m single-dish submillimeter telescope. The new discovery space of AtLAST comes from its exceptional sensitivity, in particular to extended low surface brightness emission, a very large 2 degree field of view, and correspondingly high mapping efficiency. This paper focuses on four themes which will particularly benefit from AtLAST: 1) the LMC and SMC, 2) extragalactic magnetic fields, 3) the physics and chemistry of the interstellar medium, and 4) star formation and galaxy evolution. With ~1000-2000h surveys each, AtLAST could deliver deep dust continuum maps of the entire LMC and SMC fields at parsec-scale resolution, high-resolution maps of the magnetic field structure, gas density, temperature and composition of the dense and diffuse ISM in ~100 nearby galaxies, as well as the first large-scale blind CO survey in the nearby Universe, delivering molecular gas masses for up to 10^6 galaxies (3 orders of magnitude more than current samples). Through such observing campaigns, AtLAST will have a profound impact on our understanding of the baryon cycle and star formation across a wide range of environments., Comment: 29 pages, 11 figues, submitted to Open Research Europe as part of the AtLAST collection: https://open-research-europe.ec.europa.eu/collections/atlast/about

Our knowledge of galaxy formation and evolution has incredibly progressed through multi-wavelength observational constraints of the interstellar medium (ISM) of galaxies at all cosmic epochs. However, little is known about the physical properties of the more diffuse and lower surface brightness reservoir of gas and dust that extends beyond ISM scales and fills dark matter haloes of galaxies up to their virial radii, the circumgalactic medium (CGM). New theoretical studies increasingly stress the relevance of the latter for understanding the feedback and feeding mechanisms that shape galaxies across cosmic times, whose cumulative effects leave clear imprints into the CGM. Recent studies are showing that a -- so far unconstrained -- fraction of the CGM mass may reside in the cold (T < 1e4 K) molecular and atomic phase, especially in high-redshift dense environments. These gas phases, together with the warmer ionised phase, can be studied in galaxies from z ~ 0 to z ~ 10 through bright far-infrared and sub-millimeter emission lines such as [C II] 158${\mu}$m, [O III] 88 ${\mu}$m, [C I] 609${\mu}$m, [C I] 370${\mu}$m, and the rotational transitions of CO. Imaging such hidden cold CGM can lead to a breakthrough in galaxy evolution studies but requires a new facility with the specifications of the proposed Atacama Large Aperture Submillimeter Telescope (AtLAST). In this paper, we use theoretical and empirical arguments to motivate future ambitious CGM observations with AtLAST and describe the technical requirements needed for the telescope and its instrumentation to perform such science., Comment: Submitted to Open Research Europe as part of the AtLAST collection: https://open-research-europe.ec.europa.eu/collections/atlast/about

Observations at (sub-)millimeter wavelengths offer a complementary perspective on our Sun and other stars, offering significant insights into both the thermal and magnetic composition of their chromospheres. Despite the fundamental progress in (sub-)millimeter observations of the Sun, some important aspects require diagnostic capabilities that are not offered by existing observatories. In particular, simultaneous observations of the radiation continuum across an extended frequency range would facilitate the mapping of different layers and thus ultimately the 3D structure of the solar atmosphere. Mapping large regions on the Sun or even the whole solar disk at a very high temporal cadence would be crucial for systematically detecting and following the temporal evolution of flares, while synoptic observations, i.e., daily maps, over periods of years would provide an unprecedented view of the solar activity cycle in this wavelength regime. As our Sun is a fundamental reference for studying the atmospheres of active main sequence stars, observing the Sun and other stars with the same instrument would unlock the enormous diagnostic potential for understanding stellar activity and its impact on exoplanets. The Atacama Large Aperture Submillimeter Telescope (AtLAST), a single-dish telescope with 50\,m aperture proposed to be built in the Atacama desert in Chile, would be able to provide these observational capabilities. Equipped with a large number of detector elements for probing the radiation continuum across a wide frequency range, AtLAST would address a wide range of scientific topics including the thermal structure and heating of the solar chromosphere, flares and prominences, and the solar activity cycle. In this white paper, the key science cases and their technical requirements for AtLAST are discussed., Comment: 18 pages, 4 figures, submitted to Open Research Europe as part of a collection on the Atacama Large Aperture Submillimeter Telescope (AtLAST) -- revised version

As we learn more about the multi-scale interstellar medium (ISM) of our Galaxy, we develop a greater understanding for the complex relationships between the large-scale diffuse gas and dust in Giant Molecular Clouds (GMCs), how it moves, how it is affected by the nearby massive stars, and which portions of those GMCs eventually collapse into star forming regions. The complex interactions of those gas, dust and stellar populations form what has come to be known as the ecology of our Galaxy. Because we are deeply embedded in the plane of our Galaxy, it takes up a significant fraction of the sky, with complex dust lanes scattered throughout the optically recognisable bands of the Milky Way. These bands become bright at (sub-)millimetre wavelengths, where we can study dust thermal emission and the chemical and kinematic signatures of the gas. To properly study such large-scale environments, requires deep, large area surveys that are not possible with current facilities. Moreover, where stars form, so too do planetary systems, growing from the dust and gas in circumstellar discs, to planets and planetesimal belts. Understanding the evolution of these belts requires deep imaging capable of studying belts around young stellar objects to Kuiper belt analogues around the nearest stars. Here we present a plan for observing the Galactic Plane and circumstellar environments to quantify the physical structure, the magnetic fields, the dynamics, chemistry, star formation, and planetary system evolution of the galaxy in which we live with AtLAST; a concept for a new, 50m single-dish sub-mm telescope with a large field of view which is the only type of facility that will allow us to observe our Galaxy deeply and widely enough to make a leap forward in our understanding of our local ecology., Comment: 27 pages, submitted to Open Research Europe as part of the AtLAST collection: https://open-research-europe.ec.europa.eu/collections/atlast/about

An omnipresent feature of the multi-phase ``cosmic web'' is that warm/hot (>$10^5$ K) ionized gas pervades it. This gas constitutes a relevant contribution to the overall universal matter budget across multiple scales, from the several tens of Mpc-scale IGM filaments, to the Mpc ICM, all the way down to the CGM surrounding individual galaxies, on scales from ~1 kpc up to their respective virial radii (~100 kpc). The study of the hot baryonic component of cosmic matter density represents a powerful means for constraining the intertwined evolution of galactic populations and large-scale cosmological structures, for tracing the matter assembly in the Universe and its thermal history. To this end, the SZ effect provides the ideal observational tool for measurements out to the beginnings of structure formation. The SZ effect is caused by the scattering of the photons from the cosmic microwave background off the hot electrons embedded within cosmic structures, and provides a redshift-independent perspective on the thermal and kinematic properties of the warm/hot gas. Still, current and future (sub)mm facilities have been providing only a partial view of the SZ Universe due to any combination of: limited angular resolution, spectral coverage, field of view, spatial dynamic range, sensitivity. In this paper, we motivate the development of a wide-field, broad-band, multi-chroic continuum instrument for the Atacama Large Aperture Submillimeter Telescope (AtLAST) by identifying the scientific drivers that will deepen our understanding of the complex thermal evolution of cosmic structures. On a technical side, this will necessarily require efficient multi-wavelength mapping of the SZ signal with an unprecedented spatial dynamic range (from arcsecond to degree scales) and we employ theoretical forecasts to determine the key instrumental constraints for achieving our goals. [abridged], Comment: 29 pages, 17 figures, 1 table. Submitted to Open Research Europe as part of the AtLAST Design Study collection: https://open-research-europe.ec.europa.eu/collections/atlast/about. Comments are welcome

We carried out a sensitive survey of C$_2$ and C$_3$ using the EDIBLES data set. We also expanded our searches to C$_4$, C$_5$, and $^{13}$C$^{12}$C isotopologue in the most molecule-rich sightlines. We fit synthetic spectra generated following a physical excitation model to the C$_2$ (2-0) Phillips band to obtain the C$_2$ column density ($N$) as well as the kinetic temperature ($T_\textrm{kin}$) and number density ($n$) of the host cloud. The C$_3$ molecule was measured through its $\tilde{A} - \tilde{X}$ (000-000) electronic origin band system. We simulated the excitation of this band with a double-temperature Boltzmann distribution. We present the largest combined survey of C$_2$ and C$_3$ to date in which the individual transitions can be resolved. In total we detected C$_2$ in 51 velocity components along 40 sightlines, and C$_3$ in 31 velocity components along 27 sightlines. The two molecules are detected in the same velocity components. We find a very good correlation between $N$(C$_2$) and $N$(C$_3$) with Pearson $r = 0.93$ and an average $N$(C$_2$)/$N$(C$_3$) ratio of 15.5$\pm$1.4. A comparison with the behaviour of the C$_2$ DIBs shows that there are no clear differences among sightlines with and without detection of C$_2$ and C$_3$. This is in direct contrast to the better-studied non-C$_2$ DIBs who have reduced strengths in molecule-rich environments. We also identify for the first time the $Q$(2), $Q$(3), and $Q$(4) transitions of the $^{13}$C$^{12}$C (2-0) Phillips band in a stacked average spectrum, and estimate the isotopic ratio of carbon $^{12}$C/$^{13}$C as 79$\pm$8. Our search for the C$_4$ and C$_5$ optical bands was unsuccessful., Comment: 31 pages, 23 figures. To appear in A&A

Interstellar lines observed toward stellar targets change slowly over long timescales, mainly due to the proper motion of the background target relative to the intervening clouds. On longer timescales, the cloud's slowly changing physical and chemical conditions can also cause variation. We searched for systematic variations in the absorption profiles of the diffuse interstellar bands (DIBs) and interstellar atomic and molecular lines by comparing the high-quality data set from the ESO diffuse interstellar bands extensive exploration survey (EDIBLES) to older archival observations, bridging typical timescales of 10 years with a maximum timescale of 22 years. We found good archival observations for 64 EDIBLES targets. Our analysis focused on 31 DIBs, 7 atomic, and 5 molecular lines. We considered various systematic effects and applied a robust Bayesian test to establish which absorption features could display significant variations. While systematic effects greatly complicate our search, we find evidence for variations in the profiles of the $\lambda\lambda$4727 and 5780 DIBs in a few sightlines. Toward HD~167264, we find a new \ion{Ca}{i} cloud component that appears and becomes stronger after 2008. The same sightline furthermore displays marginal but systematic changes in the column densities of the atomic lines originating from the leading cloud component in the sightline. Similar variations are seen toward HD~147933. Our high-quality spectroscopic observations and archival data show that it is possible to probe interstellar time variations on time scales of typically a decade. Even though systematic uncertainties, as well as the generally somewhat lower quality of older data, complicate matters, we can conclude that time variations can be made visible, both in atomic lines and DIB profiles for a few targets, but that generally, these features are stable along many lines of sight., Comment: 180 pages, 138 figures, accepted for publication in A&A journal

A lower-than-solar elemental nitrogen content has been demonstrated for several comets, including 1P/Halley and 67P/C-G with independent in situ measurements of volatile and refractory budgets. The recently discovered semi-refractory ammonium salts in 67P/C-G are thought to be the missing nitrogen reservoir in comets. The thermal desorption of ammonium salts from cometary dust particles leads to their decomposition into ammonia and a corresponding acid. The NH$_{3}$/H$_{2}$O ratio is expected to increase with decreasing heliocentric distance with evidence for this in near-infrared observations. NH$_{3}$ has been claimed to be more extended than expected for a nuclear source. Here, the aim is to constrain the NH$_{3}$/H$_{2}$O ratio in comet C/2020 F3 (NEOWISE) during its July 2020 passage. OH emission from comet C/2020 F3 (NEOWISE) was monitored for 2 months with NRT and observed from GBT on 24 July and 11 August 2020. Contemporaneously with the 24 July 2020 OH observations, the NH$_{3}$ hyperfine lines were targeted with GBT. The concurrent GBT and NRT observations allowed the OH quenching radius to be determined at $\left(5.96\pm0.10\right)\times10^{4}$ km on 24 July 2020, which is important for accurately deriving $Q(\text{OH})$. C/2020 F3 (NEOWISE) was a highly active comet with $Q(\text{H}_{2}\text{O}) \approx 2\times10^{30}$ molec s$^{-1}$ one day before perihelion. The $3\sigma$ upper limit for $Q_{\text{NH}_{3}}/Q_{\text{H}_{2}\text{O}}$ is $<0.29\%$ at $0.7$ au from the Sun. The obtained NH$_{3}$/H$_{2}$O ratio is a factor of a few lower than measurements for other comets at such heliocentric distances. The abundance of NH$_{3}$ may vary strongly with time depending on the amount of water-poor dust in the coma. Lifted dust can be heated, fragmented, and super-heated; whereby, ammonium salts, if present, can rapidly thermally disintegrate and modify the NH$_{3}$/H$_{2}$O ratio., Comment: Accepted for publication in A&A; 18 pages, 8 figures, 6 tables

We report observations of the Didymos-Dimorphos binary asteroid system using the Atacama Large Millimeter/Submillimeter Array (ALMA) and the Atacama Compact Array (ACA) in support of the Double Asteroid Redirection Test (DART) mission. Our observations on UT 2022 September 15 provided a pre-impact baseline and the first measure of Didymos-Dimorphos' spectral emissivity at $\lambda=0.87$ mm, which was consistent with the handful of siliceous and carbonaceous asteroids measured at millimeter wavelengths. Our post-impact observations were conducted using four consecutive executions each of ALMA and the ACA spanning from T$+$3.52 to T$+$8.60 hours post-impact, sampling thermal emission from the asteroids and the impact ejecta. We scaled our pre-impact baseline measurement and subtracted it from the post-impact observations to isolate the flux density of mm-sized grains in the ejecta. Ejecta dust masses were calculated for a range of materials that may be representative of Dimorphos' S-type asteroid material. The average ejecta mass over our observations is consistent with 1.3--6.4$\times10^7$ kg, with the lower and higher values calculated for amorphous silicates and for crystalline silicates, respectively. Owing to the likely crystalline nature of S-type asteroid material, the higher value is favored. These ejecta masses represent 0.3--1.5\% of Dimorphos' total mass and are in agreement with lower limits on the ejecta mass based on measurements at optical wavelengths. Our results provide the most sensitive measure of mm-sized material in the ejecta and demonstrate the power of ALMA for providing supporting observations to spaceflight missions.

The extraordinary 2021 September-October outburst of Centaur 29P/Schwassmann-Wachmann 1 afforded an opportunity to test the composition of primitive Kuiper disk material at high sensitivity. We conducted nearly simultaneous multi-wavelength spectroscopic observations of 29P/Schwassmann-Wachmann 1 using iSHELL at the NASA Infrared Telescope Facility and nFLASH at the Atacama Pathfinder EXperiment (APEX) on 2021 October 6, with follow-up APEX/nFLASH observations on 2021 October 7 and 2022 April 3. This coordinated campaign between near-infrared and radio wavelengths enabled us to sample molecular emission from a wealth of coma molecules and to perform measurements that cannot be accomplished with either wavelength alone. We securely detected CO emission on all dates with both facilities, including velocity-resolved spectra of the CO (J=2-1) transition with APEX/nFLASH and multiple CO (v=1-0) rovibrational transitions with IRTF/iSHELL. We report rotational temperatures, coma kinematics, and production rates for CO and stringent (3-sigma) upper limits on abundance ratios relative to CO for CH4, C2H6, CH3OH, H2CO, CS, and OCS. Our upper limits for CS/CO and OCS/CO represent their first values in the literature for this Centaur. Upper limits for CH4, C2H6, CH3OH, and H2CO are the most stringent reported to date, and are most similar to values found in ultra CO-rich Oort cloud comet C/2016 R2 (PanSTARRS), which may have implications for how ices are preserved in cometary nuclei. We demonstrate the superb synergy of coordinated radio and near-infrared measurements, and advocate for future small body studies that jointly leverage the capabilities of each wavelength.

Using data from the GOTHAM (GBT Observations of TMC-1: Hunting for Aromatic Molecules) survey, we report the first astronomical detection of the C10H- anion. The astronomical observations also provided the necessary data to refine the spectroscopic parameters of C10H-. From the velocity stacked data and the matched filter response, C10H- is detected at >9{\sigma} confidence level at a column density of 4.04e11 cm-2. A dedicated search for the C10H radical was also conducted towards TMC-1. In this case, the stacked molecular emission of C10H was detected at a ~3.2{\sigma} confidence interval at a column density of 2.02e11 cm-2. However, since the determined confidence level is currently <5{\sigma}, we consider the identification of C10H as tentative. The full GOTHAM dataset was also used to better characterize the physical parameters including column density, excitation temperature, linewidth, and source size for the C4H, C6H and C8H radicals and their respective anions, and the measured column densities were compared to the predictions from a gas/grain chemical formation model and from a machine learning analysis. Given the measured values, the C10H-/C10H column density ratio is ~2.0 - the highest value measured between an anion and neutral species to date. Such a high ratio is at odds with current theories for interstellar anion chemistry. For the radical species, both models can reproduce the measured abundances found from the survey; however, the machine learning analysis matches the detected anion abundances much better than the gas/grain chemical model, suggesting that the current understanding of the formation chemistry of molecular anions is still highly uncertain., Comment: 38 Pages, 24 Figures, 12 Tables, 8 Appendices

We report the first detection of deuterated water (HDO) toward an extragalactic hot core. The HDO 2$_{11}$-2$_{12}$ line has been detected toward hot cores N105-2A and 2B in the N105 star-forming region in the low-metallicity Large Magellanic Cloud (LMC) dwarf galaxy with the Atacama Large Millimeter/submillimeter Array (ALMA). We have compared the HDO line luminosity ($L_{\rm HDO}$) measured toward the LMC hot cores to those observed toward a sample of seventeen Galactic hot cores covering three orders of magnitude in $L_{\rm HDO}$, four orders of magnitude in bolometric luminosity ($L_{\rm bol}$), and a wide range of Galactocentric distances (thus metallicities). The observed values of $L_{\rm HDO}$ for the LMC hot cores fit very well into the $L_{\rm HDO}$ trends with $L_{\rm bol}$ and metallicity observed toward the Galactic hot cores. We have found that $L_{\rm HDO}$ seems to be largely dependent on the source luminosity, but metallicity also plays a role. We provide a rough estimate of the H$_2$O column density and abundance ranges toward the LMC hot cores by assuming that HDO/H$_2$O toward the LMC hot cores is the same as that observed in the Milky Way; the estimated ranges are systematically lower than Galactic values. The spatial distribution and velocity structure of the HDO emission in N105-2A is consistent with HDO being the product of the low-temperature dust grain chemistry. Our results are in agreement with the astrochemical model predictions that HDO is abundant regardless of the extragalactic environment and should be detectable with ALMA in external galaxies., Comment: 21 pages, 2 tables, 9 figures (including appendices); Accepted for publication in the Astrophysical Journal

Several diffuse interstellar bands (DIBs) have profiles with resolved sub-peaks that resemble rotational bands of large molecules. Analysis of these profiles can constrain the sizes and geometries of the DIB carriers, especially if the profiles exhibit clear variations along lines of sight probing different physical conditions. Using the extensive data set from the EDIBLES survey we searched for systematic variations in the peak-to-peak separation of these sub-peaks for the $\lambda\lambda$5797, 6379, and 6614 DIBs in lines of sight with a single dominant interstellar cloud. We used the spectra of twelve single-cloud sight lines to measure the peak-to-peak separation in the band profile substructures for these DIBs. We adopted the rotational contour formalism to infer the rotational constant for each DIB carrier and the rotational excitation temperature in the sight lines. We compared these to rotational constants for linear and spherical molecules to estimate the DIB carrier sizes. All three DIBs have peak separations that vary systematically between lines of sight, indicating correlated changes in the rotational excitation temperatures. We derived $B_{6614}$=$(22.2\pm8.9)\times 10^{-3}$ cm$^{-1}$, consistent with previous estimates. Assuming a similar rotational temperature for the $\lambda$6614 DIB carrier and assuming a linear carrier, we found B$_{5797}^{\rm linear}=(5.1\pm2.0)\times10^{-3}~{\rm cm}^{-1}$ and B$_{6379}^{\rm linear} =(2.3\pm0.9)\times10^{-3}~{\rm cm}^{-1}$. If the carriers of those DIBs however are spherical species, their rotational constants are half that value, $B_{5797}^{\rm spherical} = (2.6\pm1.0)\times10^{-3}~{\rm cm}^{-1}$ and $B_{6379}^{\rm spherical} = (1.1\pm0.4)\times10^{-3}~{\rm cm}^{-1}$. We estimate molecule sizes that range from 7--9 carbon atoms ($\lambda$6614 carrier, linear) to 77--114 carbon atoms ($\lambda$6379, spherical)., Comment: 21 pages, 56 figures. Accepted for publication in Astronomy & Astrophysics

The Large Magellanic Cloud (LMC) is the nearest laboratory for detailed studies on the formation and survival of complex organic molecules (COMs), including biologically important ones, in low-metallicity environments--typical for earlier cosmological epochs. We report the results of 1.2 mm continuum and molecular line observations of three fields in the star-forming region N105 with the Atacama Large Millimeter/submillimeter Array (ALMA). N105 lies at the western edge of the LMC bar with on-going star formation traced by H$_2$O, OH, and CH$_3$OH masers, ultracompact H II regions, and young stellar objects. Based on the spectral line modeling, we estimated rotational temperatures, column densities, and fractional molecular abundances for twelve 1.2 mm continuum sources. We identified sources with a range of chemical make-ups, including two bona fide hot cores and four hot core candidates. The CH$_3$OH emission is widespread and associated with all the continuum sources. COMs CH$_3$CN and CH$_3$OCH$_3$ are detected toward two hot cores in N105 together with smaller molecules typically found in Galactic hot cores (e.g., SO$_2$, SO, and HNCO) with the molecular abundances roughly scaling with metallicity. We report a tentative detection of the astrobiologically relevant formamide molecule (NH$_2$CHO) toward one of the hot cores; if confirmed, this would be the first detection of NH$_2$CHO in an extragalactic sub-solar metallicity environment. We suggest that metallicity inhomogeneities resulting from the tidal interactions between the LMC and the Small Magellanic Cloud (SMC) might have led to the observed large variations in COM abundances in LMC hot cores., Comment: 75 pages, 48 figures, 7 tables (including appendices); Accepted for publication in the Astrophysical Journal

The interstellar traveler, 2I/Borisov, is the first clearly active extrasolar comet, ever detected in our Solar system. We obtained high-resolution interferometric observations of 2I/Borisov with the Atacama Large Millimeter/submillimeter Array (ALMA), and multi-color optical observations with the Very Large Telescope (VLT) to gain a comprehensive understanding of the dust properties of this comet. We found that the dust coma of 2I/Borisov consists of compact "pebbles" of radii exceeding ~1 mm, suggesting that the dust particles have experienced compaction through mutual impacts during the bouncing collision phase in the protoplanetary disk. We derived a dust mass loss rate of >= 200 kg/s and a dust-to-gas ratio >=3. Our long term monitoring of 2I/Borisov with VLT indicates a steady dust mass loss with no significant dust fragmentation and/or sublimation occurring in the coma. We also detected emissions from carbon monoxide gas (CO) with ALMA and derived the gas production rate of Q(CO) (3.3+/-0.8)x10^{26} mole/s. We found that the CO/H$_2$O mixing ratio of 2I/Borisov changed drastically before and after perihelion, indicating the heterogeneity of the cometary nucleus, with components formed at different locations beyond the volatile snow-line with different chemical abundances. Our observations suggest that 2I/Borisov's home system, much like our own system, experienced efficient radial mixing from the innermost parts of its protoplanetary disk to beyond the frost line of CO., Comment: 12 pages, 4 figures

We report the first survey of molecular emission from cometary volatiles using standalone Atacama Compact Array (ACA) observations of the Atacama Large Millimeter/Submillimeter Array (ALMA) toward comet C/2015 ER61 (PanSTARRS) carried out on UT 2017 April 11 and 15, shortly after its April 4 outburst. These measurements of HCN, CS, CH$_3$OH, H$_2$CO, and HNC (along with continuum emission from dust) probed the inner coma of C/2015 ER61, revealing asymmetric outgassing and discerning parent from daughter/distributed source species. This work presents spectrally integrated flux maps, autocorrelation spectra, production rates, and parent scale lengths for each molecule, and a stringent upper limit for CO. HCN is consistent with direct nucleus release in C/2015 ER61, whereas CS, H$_2$CO, HNC, and potentially CH$_3$OH are associated with distributed sources in the coma. Adopting a Haser model, parent scale lengths determined for H$_2$CO (L$_p$ $\sim$ 2200 km) and HNC (L$_p$ $\sim$ 3300 km) are consistent with previous work in comets, whereas significant extended source production (L$_p$ $\sim$ 2000 km) is indicated for CS, suggesting production from an unknown parent in the coma. The continuum presents a point-source distribution, with a flux density implying an excessively large nucleus, inconsistent with other estimates of the nucleus size. It is best explained by the thermal emission of slowly-moving outburst ejectas, with total mass 5--8 $\times$ 10$^{10}$ kg. These results demonstrate the power of the ACA for revealing the abundances, spatial distributions, and locations of molecular production for volatiles in moderately bright comets such as C/2015 ER61.

Ubiquitous unidentified infrared emission bands are seen in many astronomical sources. Although these bands are widely, if not unanimously, attributed to the collective emission from polycyclic aromatic hydrocarbons, no single species from this class has been detected in space. We present the discovery of two -CN functionalized polycyclic aromatic hydrocarbons, 1- and 2-cyanonaphthalene, in the interstellar medium aided by spectral matched filtering. Using radio observations with the Green Bank Telescope, we observe both bi-cyclic ring molecules in the molecular cloud TMC-1. We discuss potential in situ gas-phase formation pathways from smaller organic precursor molecules.

We report the detection of CH$_3$OH emission in comet 46P/Wirtanen on UT 2018 December 8 and 9 using the Atacama Compact Array (ACA), part of the Atacama Large Millimeter/Submillimeter Array (ALMA). These interferometric measurements of CH$_3$OH along with continuum emission from dust probed the inner coma ($<$2000 km from the nucleus) of 46P/Wirtanen approximately one week before its closest approach to Earth ($\Delta$ = 0.089 -- 0.092 au), revealing rapidly varying and anisotropic CH$_3$OH outgassing during five separate ACA executions between UT 23:57 December 7 and UT 04:55 December 9, with a clear progression in the spectral line profiles over a timescale of minutes. We present spectrally integrated flux maps, production rates, rotational temperatures, and spectral line profiles of CH$_3$OH during each ACA execution. The variations in CH$_3$OH outgassing are consistent with Wirtanen's 9 hr nucleus rotational period derived from optical and millimeter wavelength measurements and thus are likely coupled to the changing illumination of active sites on the nucleus. The consistent blue offset of the line center indicates enhanced CH$_3$OH sublimation from the sunward hemisphere of the comet, perhaps from icy grains. These results demonstrate the exceptional capabilities of the ACA for time-resolved measurements of comets such as 46P/Wirtanen.

Using radio observations with the Green Bank Telescope, evidence has now been found for a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based on additional observations of an ongoing, large-scale, high-sensitivity spectral line survey (GOTHAM) at centimeter wavelengths toward this source, we have used a combination of spectral stacking, Markov chain Monte Carlo (MCMC), and matched filtering techniques to detect 2-cyanocyclopentadiene, a low-lying isomer of 1-cyanocyclopentadiene, which was recently discovered there by the same methods. The new observational data also yields a considerably improved detection significance for the more stable isomer and evidence for several individual transitions between 23 - 32 GHz. Through our MCMC analysis, we derive total column densities of $8.3\times10^{11}$ and $1.9\times10^{11}$ cm$^{-2}$ for 1- and 2-cyanocyclopentadiene respectively, corresponding to a ratio of 4.4(6) favoring the former. The derived abundance ratios point towards a common formation pathway - most likely being cyanation of cyclopentadiene by analogy to benzonitrile., Comment: 6 pages, 3 figures and 1 table in the main text. 2 tables and 2 figures in the Appendix. Accepted for publication in The Astrophysical Journal Letters. Supplementary data available in the DataVerse entry provided in text

The detection of phosphine (PH3) in the atmosphere of Venus has been recently reported based on millimeter-wave radio observations (Greaves et al. 2020), and its re-analyses (Greaves et al. 2021a/b). In this Matters Arising we perform an independent reanalysis, identifying several issues in the interpretation of the spectroscopic data. As a result, we determine sensitive upper-limits for PH3 in Venus' atmosphere (>75 km, above the cloud decks) that are discrepant with the findings in G2020 and G2021a/b. The measurements target the fundamental first rotational transition of PH3 (J=1-0) at 266.944513 GHz, which was observed with the James Clerk Maxwell Telescope (JCMT) in June 2017 and with the Atacama Large Millimeter/submillimeter Array (ALMA) in March 2019. This line's center is near the SO2 (J=309,21-318,24) transition at 266.943329 GHz (only 1.3 km/s away from the PH3 line) which represents a potential source of contamination. The JCMT and ALMA data, as presented in G2020, are at spectral resolutions comparable to the frequency separation of the two lines. Moreover, the spectral features identified are several km/s in width, and therefore do not permit distinct spectroscopic separation of the candidate spectral lines of PH3 and SO2. We present the radiative transfer modelling we have performed and then discuss the ALMA and JCMT analyses in turn.

We report the first detection on Titan of the small cyclic molecule cyclopropenylidene (c-C3H2) from high sensitivity spectroscopic observations made with the Atacama Large Millimeter/sub-millimeter Array (ALMA). Multiple lines of cyclopropenylidene were detected in two separate datasets: ~251 GHz in 2016 (Band 6) and ~352 GHz in 2017 (Band 7). Modeling of these emissions indicates abundances of 0.50 +/- 0.14 ppb (2016) and 0.28 +/- 0.08 (2017) for a 350 km step model, which may either signify a decrease in abundance, or a mean value of 0.33 +/- 0.07 ppb. Inferred column abundances are (3-5)E12 cm-2 in 2016 and (1-2)E12 cm-2 in 2017, similar to photochemical model predictions. Previously the C3H3+ ion has been measured in Titan's ionosphere by Cassini's Ion and Neutral Mass Spectrometer (INMS), but the neutral (unprotonated) species has not been detected until now, and aromatic versus aliphatic structure could not be determined by the INMS. Our work therefore represents the first unambiguous detection of cyclopropenylidene, the second known cyclic molecule in Titan's atmosphere along with benzene (C6H6) and the first time this molecule has been detected in a planetary atmosphere. We also searched for the N-heterocycle molecules pyridine and pyrimidine finding non-detections in both cases, and determining 2-{\sigma} upper limits of 1.15 ppb (c-C5H5N) and 0.85 ppb (c-C4H4N2) for uniform abundances above 300 km. These new results on cyclic molecules provide fresh constraints on photochemical pathways in Titan's atmosphere, and will require new modeling and experimental work to fully understand the implications for complex molecule formation., Comment: 34 pages, 13 figures. 8 tables

The earliest stages of low-mass star-formation are unclear, but it has been proposed that Chamaeleon-MMS1 is a candidate First Hydrostatic Core (FHSC), the transition stage between a prestellar and protostellar core. This work describes the local (~4000 AU) outflow activity associated with Chamaeleon-MMS1 and its effect on the surrounding material in order to determine the evolutionary state of this young low-mass source. We used the Atacama Large Millimeter/sub-millimeter Array (ALMA) to observe Chamaeleon MMS1 at 220 GHz at high spatial (~75 AU) and spectral resolutions (0.1-0.3 km/s). A low energy outflow is detected through its interaction with the surrounding cloud. The outflow consists of two components, a broad spectral feature to the northeast and narrow features to both the northeast and southwest. The rotational temperature of formaldehyde (H2CO) is calculated to be 50 (+/-30) K toward the continuum source with similarly low temperatures (25-45 K) toward clumps affected by the outflow. Methanol (CH3OH) is only detected toward gas clumps located away from the continuum source, where the methanol is expected to have been released by the energy of the outflow through ice sputtering in shock waves. Chamaeleon-MMS1 shows outflow activity with the power source being either a single precessing outflow or two outflows from a binary system. While molecular emission and high outflow speeds rule it out as a FHSC, the outflow is less energetic than outflows detected from other Class 0 objects and the inferred gas temperatures toward the continuum source are relatively low, which indicates that Cha-MMS1 is one of the youngest known sources., Comment: 13 pages, 16 figures. This paper was previously submitted and revised

Much like six-membered rings, five-membered rings are ubiquitous in organic chemistry, frequently serving as the building blocks for larger molecules, including many of biochemical importance. From a combination of laboratory rotational spectroscopy and a sensitive spectral line survey in the radio band toward the starless cloud core TMC-1, we report the astronomical detection of 1-cyano-1,3-cyclopentadiene, $c$-C$_5$H$_5$CN}, a highly polar, cyano derivative of cyclopentadiene, $c$-C$_5$H$_6$. The derived abundance of $c$-C$_5$H$_5$CN} is far greater than predicted from astrochemical models which well reproduce the abundance of many carbon chains. This finding implies either an important production mechanism or a large reservoir of aromatic material may need to be considered. The apparent absence of its closely-related isomer, 2-cyano-1,3-cyclopentadiene, may arise from its lower stability or be indicative of a more selective pathway for formation of the 1-cyano isomer, perhaps one starting from acyclic precursors. The absence of N-heterocycles such as pyrrole and pyridine is discussed in light of the astronomical finding., Comment: Accepted for publication in Nature Astronomy. 36 pages comprising five figures, two tables, five supplementary tables, and six supplementary figures

As the inventory of interstellar molecules continues to grow, the gulf between small species, whose individual rotational lines can be observed with radio telescopes, and large ones, such as polycyclic aromatic hydrocarbons (PAHs) best studied in bulk via infrared and optical observations, is slowly being bridged. Understanding the connection between these two molecular reservoirs is critical to understanding the interstellar carbon cycle, but will require pushing the boundaries of how far we can probe molecular complexity while still retaining observational specificity. Toward this end, we present a method for detecting and characterizing new molecular species in single-dish observations toward sources with sparse line spectra. We have applied this method to data from the ongoing GOTHAM (GBT Observations of TMC-1: Hunting Aromatic Molecules) Green Bank Telescope (GBT) large program, discovering six new interstellar species. In this paper we highlight the detection of HC$_{11}$N, the largest cyanopolyyne in the interstellar medium., Comment: 42 pages, 36 figures, 9 tables, to appear in Nature Astronomy

We present an overview of the GOTHAM (GBT Observations of TMC-1: Hunting Aromatic Molecules) Large Program on the Green Bank Telescope. This and a related program were launched to explore the depth and breadth of aromatic chemistry in the interstellar medium at the earliest stages of star formation, following our earlier detection of benzonitrile ($c$-C$_6$H$_5$CN) in TMC-1. In this work, details of the observations, use of archival data, and data reduction strategies are provided. Using these observations, the interstellar detection of propargyl cyanide (HCCCH$_2$CN) is described, as well as the accompanying laboratory spectroscopy. We discuss these results, and the survey project as a whole, in the context of investigating a previously unexplored reservoir of complex, gas-phase molecules in pre-stellar sources. A series of companion papers describe other new astronomical detections and analyses., Comment: Accepted in the Astrophysical Journal Letters

We report an astronomical detection of HC$_4$NC for the first time in the interstellar medium with the Green Bank Telescope toward the TMC-1 molecular cloud with a minimum significance of $10.5 \sigma$. The total column density and excitation temperature of HC$_4$NC are determined to be $3.29^{+8.60}_{-1.20}\times 10^{11}$ cm$^{-2}$ and $6.7^{+0.3}_{-0.3}$ K, respectively, using the MCMC analysis. In addition to HC$_4$NC, HCCNC is distinctly detected whereas no clear detection of HC$_6$NC is made. We propose that the dissociative recombination of the protonated cyanopolyyne, HC$_5$NH$^+$, and the protonated isocyanopolyyne, HC$_4$NCH$^+$, are the main formation mechanisms for HC$_4$NC while its destruction is dominated by reactions with simple ions and atomic carbon. With the proposed chemical networks, the observed abundances of HC$_4$NC and HCCNC are reproduced satisfactorily., Comment: Accepted in the Astrophysical Journal Letters

Telescope and detector developments continuously enable deeper and more detailed studies of astronomical objects. Larger collecting areas, improvement in dispersion and detector techniques, and higher sensitivities allow detection of more molecules in a single observation, at lower abundances, resulting in better constraints of the targets physical and chemical conditions. Improvements on current telescopes, and not to mention future observatories, both in space and on the ground, will continue this trend, ever improving our understanding of the Universe. Planetary exploration missions carry instrumentation to unexplored areas, and reveal details impossible to observe from the Earth by performing in-situ measurements. Space based observatories allow observations of object at wavelength ranges absorbed by the Earths atmosphere. The depth of understanding from all of these studies can be greatly enhanced by combining observations: ground-based and space-based, low-resolution and high-resolution, local and global-scale, similar observations over a broader or different spectra range, or by providing temporal information through follow-ups. Combined observations provide context and a broader scope of the studied object, and in this white paper, we outline a number of studies where observations are synergistically applied to increase the scientific value of both datasets. Examples include atmospheric studies of Venus, Mars, Titan, comets, Jupiter, as well as more specific cases describing synergistic studies in the Juno mission, and ground-based radar studies for near Earth objects. The examples aim to serve as inspiration for future synergistic observations, and recommendations are made based on the lessons learned from these examples., Comment: This is a white paper submitted to the Planetary Decadal Survey

The study of comets affords a unique window into the birth, infancy, and subsequent history of the solar system. There is strong evidence that comets incorporated pristine interstellar material as well as processed nebular matter, providing insights into the composition and prevailing conditions over wide swaths of the solar nebula at the time of planet formation. Dynamically new Oort cloud comets harbor primitive ices that have been stored thousands of astronomical units from the Sun and have suffered minimal thermal or radiative processing since their emplacement ~4.5 Gyr ago. Periodic, more dynamically evolved comets such as the Halley-type and Jupiter-family comets reveal the effects of lives spent over a range of heliocentric distances, including perihelion passages into the very inner solar system. Systematically characterizing the information imprinted in the native ice compositions of these objects is critical to understanding the formation and evolution of the solar system, the presence of organic matter and water on the terrestrial planets, the chemistry present in protoplanetary disks around other stars, and the nature of interstellar interlopers such as 2I/Borisov. Although comet rendezvous and sample return missions can provide remarkable insights into the properties of a few short-period comets, the on-sky capacity necessary to perform population-level comet studies while simultaneously remaining sensitive to the paradigm-challenging science that individual comets can reveal can only be provided by remote sensing observations. Here we report the state-of-the-art in ground- and space-based remote sensing of cometary volatiles, review the remarkable progress of the previous decade, articulate the pressing questions that ground- and space-based work will address over the next ten years, and advocate for the technology and resources necessary to realize these aspirations., Comment: White paper for the National Academies of Sciences, Engineering, and Medicine Planetary Science and Astrobiology Decadal Survey 2023-2032

In circumstellar gas, the complex organic molecule methanol has been found almost exclusively around young stellar objects, and is thus regarded as a signpost of recent star formation. Here we report the first probable detection of methanol around an evolved high-mass star, in the complex circumstellar environment around the Luminous Blue Variable $\eta$ Carinae, while using ALMA to investigate molecular cloud conditions traced by CO (2-1) in an orbit phase of the massive binary preceding the 2020 periastron. Favoring methanol over a $^{13}$CS alternative, the emission originates from hot ($T_{\rm{gas}} \simeq$ 700 K) material, $\sim$2$''$ (0.02 pc) across, centered on the dust-obscured binary in contrast to the CO which traces inner layers of the extended massive equatorial torus, and is accompanied by prominent absorption in a cooler ($T_{\rm{gas}} \simeq$ 110 K) layer of gas. We also report detections of water in $Herschel$/HIFI observations at 557 GHz and 988 GHz. The methanol abundance is several to 50 times higher than observed towards several lower mass stars, while water abundances are similar to those observed in cool, dense molecular clouds. The very high methanol:water abundance ratio in the core of $\eta$ Carinae may suggest methanol formation processes similar to Fischer-Tropsch-type catalytic reactions on dust grains. These observations prove that complex molecule formation can occur in the chemically evolved environments around massive stars in the end stages of their evolution, given sufficient gas densities and shielding conditions as may occur in material around massive interacting companions and merger remnants., Comment: Accepted by ApJ Letters

We present the first radio/submillimeter detection of monodeuterated methane (CH$_3$D) in Titan's atmosphere, using archival data from of the Atacama Large Millimeter/submillimeter Array (ALMA). The $J_K=2_1-1_1$ and $J_K=2_0-1_0$ transitions at 465.235 and 465.250 GHz ($\sim0.644$ mm) were measured at significance levels of $4.6\sigma$ and $5.7\sigma$, respectively. These two lines were modeled using the Non-linear optimal Estimator for MultivariatE spectral analySIS (NEMESIS) radiative transfer code to determine the disk-averaged CH$_3$D volume mixing ratio = $6.157\times10^{-6}$ in Titan's stratosphere (at altitudes $\gt130$ km). By comparison with the CH$_4$ vertical abundance profile measured by Cassini-Huygens mass spectrometry, the resulting value for D/H in CH$_4$ is $(1.033\pm0.081)\times10^{-4}$. This is consistent with previous ground-based and in-situ measurements from the Cassini-Huygens mission, though slightly lower than the average of the previous values. Additional CH$_3$D observations at higher spatial resolution will be required to determine a value truly comparable with the Cassini-Huygens CH$_4$ measurements, by measuring CH$_3$D with ALMA close to Titan's equator. In the post-Cassini era, spatially resolved observations of CH$_3$D with ALMA will enable the latitudinal distribution of methane to be determined, making this an important molecule for further studies., Comment: 9 pages, 4 figures

Several of NASA missions (TESS, JWST, WFIRST, etc.) and mission concepts (LUVOIR, HabEx, and OST) emphasize the exploration and characterization of exoplanets, and the study of the interstellar medium. We anticipate that a much broader set of chemical environments exists on exoplanets, necessitating data from a correspondingly broader set of chemical reactions. Similarly, the conditions that exist in astrophysical environments are very different from those traditionally probed in laboratory chemical kinetics studies. These are areas where quantum mechanical theory, applied to important reactions via well-validated chemical kinetics models, can fill a critical knowledge gap. Quantum chemical calculations are also introduced to study interior of planets, photochemical escape, and many critical chemical pathways (e.g. prebiotic environments, contaminations, etc.) After years of development of the relevant quantum chemical theories and significant advances in computational power, quantum chemical simulations have currently matured enough to describe real systems with an accuracy that competes with experiments. These approaches, therefore, have become the best possible alternative in many circumstances where performing experiments is too difficult, too expensive, or too dangerous, or simply not possible. In this white paper, several existing quantum chemical studies supporting exoplanetary science, planetary astronomy, and astrophysics are described, and the potential positive impacts of improved models associated with scientific goals of missions are addressed. In the end, a few recommendations from the scientific community to strengthen related research efforts at NASA are provided.

The carriers of the diffuse interstellar bands (DIBs) are largely unidentified molecules ubiquitously present in the interstellar medium (ISM). After decades of study, two strong and possibly three weak near-infrared DIBs have recently been attributed to the C60+ fullerene based on observational and laboratory measurements. There is great promise for the identification of the over 400 other known DIBs, as this result could provide chemical hints towards other possible carriers. In an effort to systematically study the properties of the DIB carriers, we have initiated a new large-scale observational survey: the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). The main objective is to build on and extend existing DIB surveys to make a major step forward in characterising the physical and chemical conditions for a statistically significant sample of interstellar lines-of-sight, with the goal to reverse-engineer key molecular properties of the DIB carriers. EDIBLES is a filler Large Programme using the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Paranal, Chile. It is designed to provide an observationally unbiased view of the presence and behaviour of the DIBs towards early-spectral-type stars whose lines-of-sight probe the diffuse-to-translucent ISM. Such a complete dataset will provide a deep census of the atomic and molecular content, physical conditions, chemical abundances and elemental depletion levels for each sightline. Achieving these goals requires a homogeneous set of high-quality data in terms of resolution (R ~ 70000 -- 100000), sensitivity (S/N up to 1000 per resolution element), and spectral coverage (305--1042 nm), as well as a large sample size (100+ sightlines). In this first paper the goals, objectives and methodology of the EDIBLES programme are described and an initial assessment of the data is provided., Comment: 29 pages (including 14 pages appendix), 15 figures, accepted by A&A

We present APEX 218 GHz observations of molecular emission in a complete sample of embedded protostars in the Ophiuchus star-forming region. To study the physical properties of the cores, we calculate H$_2$CO and c-C$_3$H$_2$ rotational temperatures, both of which are good tracers of the kinetic temperature of the molecular gas. We find that the H$_2$CO temperatures range between 16 K and 124 K, with the highest H$_2$CO temperatures toward the hot corino source IRAS 16293-2422 (69-124 K) and the sources in the $\rho$ Oph A cloud (23-49 K) located close to the luminous Herbig Be star S 1, which externally irradiates the $\rho$ Oph A cores. On the other hand, the c-C$_3$H$_2$ rotational temperature is consistently low (7-17 K) in all sources. Our results indicate that the c-C$_3$H$_2$ emission is primarily tracing more shielded parts of the envelope whereas the H$_2$CO emission (at the angular scale of the APEX beam; 3600 au in Ophiuchus) mainly traces the outer irradiated envelopes, apart from in IRAS 16293-2422, where the hot corino emission dominates. In some sources, a secondary velocity component is also seen, possibly tracing the molecular outflow., Comment: 19 pages, 9 figures, accepted for publication in ApJ

The formation pathways of different types of organic molecules in protostellar envelopes and other regions of star formation are subjects of intense current interest. We here present observations of C$_4$H and CH$_3$OH, tracing two distinct groups of interstellar organic molecules, toward 16 protostars in the Ophiuchus and Corona Australis molecular clouds. Together with observations in the literature, we present C$_4$H and CH$_3$OH data from single-dish observations of 40 embedded protostars. We find no correlation between the C$_4$H and CH$_3$OH column densities in this large sample. Based on this lack of correlation, a difference in line profiles between C$_4$H and CH$_3$OH, and previous interferometric observations of similar sources, we propose that the emission from these two molecules is spatially separated, with the CH$_3$OH tracing gas that has been transiently heated to high ($\sim$70-100 K) temperatures, and the C$_4$H tracing the cooler large-scale envelope where CH$_4$ molecules have been liberated from ices. These results provide insight in the differentiation between hot corino and warm carbon-chain chemistry in embedded protostars., Comment: 7 pages, 2 figures, accepted for publication in ApJL

The general lack of molecular oxygen in molecular clouds is an outstanding problem in astrochemistry. Extensive searches with SWAS, Odin and Herschel have only produced two detections; upper limits to the O_2 abundance in the remaining sources observed are about 1000 times lower than predicted by chemical models. Previous atomic oxygen observations and inferences from observations of other molecules indicated that high abundances of O atoms might be present in dense cores exhibiting large amounts of CO depletion. Theoretical arguments concerning the oxygen gas-grain interaction in cold dense cores suggested that, if O atoms could survive in the gas after most of the rest of the heavy molecular material has frozen out on to dust, then O_2 could be formed efficiently in the gas. Using Herschel HIFI we searched a small sample of four depletion cores - L1544, L694-2, L429, Oph D - for emission in the low excitation O_2 N_J=3_3-1_2 line at 487.249 GHz. Molecular oxygen was not detected and we derive upper limits to its abundance in the range N(O_2)/N(H_2) = (0.6 - 1.6)x10^{-7}. We discuss the absence of O_2 in the light of recent laboratory and observational studies., Comment: Accepted for publication in ApJ

We present sub-millimeter spectra of HCN isotopologues on Titan, derived from publicly available ALMA flux calibration observations of Titan taken in early 2014. We report the detection of a new HCN isotopologue on Titan, H$^{13}$C$^{15}$, and confirm an earlier report of detection of DCN. We model high signal-to-noise observations of HCN, H$^{13}$CN, HC$^{15}$N, DCN, and H$^{13}$C$^{15}$ to derive abundances and infer the following isotopic ratios: $^{12}$C/$^{13}$C = 89.8 $\pm$ 2.8, $^{14}$N/$^{15}$N = 72.3 $\pm$ 2.2, D/H = (2.5 $\pm$ 0.2)$\times$10$^{-4}$, and HCN/H$^{13}$C$^{15}$ = 5800 $\pm$ 270 (1$\sigma$ errors). The carbon and nitrogen ratios are consistent with and improve on the precision of previous results, confirming a factor of $\sim$2.3 elevation in $^{14}$N/$^{15}$N in HCN compared to N$_2$ and a lack of fractionation in $^{12}$C/$^{13}$C from the protosolar value. This is the first published measurement of D/H in a nitrile species on Titan, and we find evidence for a factor of $\sim$2 deuterium enrichment in hydrogen cyanide compared to methane. The isotopic ratios we derive may be used as constraints for future models to better understand the fractionation processes occurring in Titan's atmosphere., Comment: Accepted for publication in Astrophysical Journal Letters. 14 pages, 3 figures, 2 tables

We report interferometric observations of carbon monoxide (CO) and its isotopologues in Titan's atmosphere using the Atacama Large Millimeter/submillimeter Array (ALMA). The following transitions were detected: CO (J = 1-0, 2-1, 3-2, 6-5), $^{13}$CO (J = 2-1, 3-2, 6-5), C$^{18}$O (J = 2-1, 3-2), and C$^{17}$O (J = 3-2). Molecular abundances and the vertical atmospheric temperature profile were derived by modeling the observed emission line profiles using NEMESIS, a line-by-line radiative transfer code. We present the first spectroscopic detection of $^{17}$O in the outer solar system with C$^{17}$O detected at > 8$\sigma$ confidence. The abundance of CO was determined to be 49.6 ${\pm}$ 1.8 ppm, assumed to be constant with altitude, with isotopic ratios $^{12}$C/$^{13}$C = 89.9 ${\pm}$ 3.4, $^{16}$O/$^{18}$O = 486 ${\pm}$ 22, and $^{16}$O/$^{17}$O = 2917${\pm}$359. The measurements of $^{12}$C/$^{13}$C and $^{16}$O/$^{18}$O ratios are the most precise values obtained in Titan's atmospheric CO to date. Our results are in good agreement with previous studies and suggest no significant deviations from standard terrestrial isotopic ratios., Comment: Accepted for publication in ApJ Letters