Search

We analyze the general relation between canonical and grand canonical ensembles in the thermodynamic limit. We begin our discussion by deriving, with an alternative approach, some standard results first obtained by Kac and coworkers in the late 1970s. Then, motivated by the Bose-Einstein condensation (BEC) of trapped gases with a fixed number of atoms, which is well described by the canonical ensemble and by the recent groundbreaking experimental realization of BEC with photons in a dye-filled optical micro-cavity under genuine grand canonical conditions, we apply our formalism to a system of non-interacting Bose particles confined in a two-dimensional harmonic trap. We discuss in detail the mathematical origin of the inequivalence of ensembles observed in the condensed phase, giving place to the so-called grand canonical catastrophe of density fluctuations. We also provide explicit analytical expressions for the internal energy and specific heat and compare them with available experimental data. For these quantities, we show the equivalence of ensembles in the thermodynamic limit., Comment: 24 pages, 2 figures, to be published in the journal Entropy, invited paper for a special issue on "Matter-Aggregating Systems at a Classical vs. Quantum Interface"

Within the Landau-Ginzburg picture of phase transitions, scalar field theories develop phase separation because of a spontaneous symmetry-breaking mechanism. This picture works in thermodynamics but also in the dynamics of phase separation. Here we show that scalar non-equilibrium field theories undergo phase separation just because of non-equilibrium fluctuations driven by a persistent noise. The mechanism is similar to what happens in Motility-Induced Phase Separation where persistent motion introduces an effective attractive force. We observe that Noise-Induced Phase Separation occurs in a region of the phase diagram where disordered field configurations would otherwise be stable at equilibrium. Measuring the local entropy production rate to quantify the time-reversal symmetry breaking, we find that such breaking is concentrated on the boundary between the two phases.

Using the path integral representation of the non-equilibrium dynamics, we compute the most probable path between arbitrary starting and final points, followed by an active particle driven by persistent noise. We focus our attention on the case of active particles immersed in harmonic potentials, where the trajectory can be computed analytically. Once we consider the extended Markovian dynamics where the self-propulsive drive evolves according to an Ornstein-Uhlenbeck process, we can compute the trajectory analytically with arbitrary conditions on position and self-propulsion velocity. We test the analytical predictions against numerical simulations and we compare the analytical results with those obtained within approximated equilibrium-like dynamics.

We numerically investigate the correlation function, the response and the breakdown of the Fluctuation-Dissipation Theorem (FDT) in active particles close to the motility-induced critical point. We find a strong FDT violation in the short time and wavelength regime, where the response function has a larger amplitude than the fluctuation spectrum. Conversely, at larger spatiotemporal scales, the FDT is restored and the critical slowing-down is compatible with the Ising universality class. Building on these results, we develop a novel field-theoretical description employing a space-time correlated noise which qualitatively captures the numerical results already at the Gaussian level. By performing a one-loop renormalization group analysis we show that the correlated noise does not change the critical exponents with respect to the equilibrium. Our results demonstrate that a correlated noise field is a fundamental ingredient to capture the features of critical active matter at the coarse-grained level., Comment: 17 pages, 4 figures

We perform large-scale computer simulations of an off-lattice two-dimensional model of active particles undergoing a motility-induced phase separation (MIPS) to investigate the systems critical behaviour close to the critical point of the MIPS curve. By sampling steady-state configurations for large system sizes and performing finite size scaling analysis we provide exhaustive evidence that the critical behaviour of this active system belongs to the Ising universality class. In addition to the scaling observables that are also typical of passive systems, we study the critical behaviour of the kinetic temperature difference between the two active phases. This quantity, which is always zero in equilibrium, displays instead a critical behavior in the active system which is well described by the same exponent of the order parameter in agreement with mean-field theory., Comment: 14 pages, 13 figures

We employ Statistical Field Theory techniques for coarse-graining the steady-state properties of Active Ornstein-Uhlenbeck particles. The computation is carried on in the framework of the Unified Colored Noise approximation that allows an effective equilibrium picture. We thus develop a mean-field theory that allows to describe in a unified framework the phenomenology of scalar Active Matter. In particular, we are able to describe through spontaneous symmetry breaking mechanism two peculiar features of Active Systems that are (i) The accumulation of active particles at the boundaries of a confining container, and (ii) Motility-Induced Phase Separation (MIPS). \textcolor{black}{We develop a mean-field theory for steric interacting active particles undergoing to MIPS and for Active Lennard-Jones (ALJ) fluids.} \textcolor{black}{Within this framework}, we discuss the universality class of MIPS and ALJ \textcolor{black}{showing that it falls into Ising universality class.} We \textcolor{black}{thus} compute analytically the critical line $T_c(\tau)$ for both models. In the case of MIPS, $T_c(\tau)$ gives rise to a reentrant phase diagram compatible with an inverse transition from liquid to gas as the strength of the noise decreases. \textcolor{black}{However, in the case of particles interacting through anisotropic potentials, } the field theory acquires a $\varphi^3$ term that, \textcolor{black}{in general, cannot be canceled performing the expansion around the critical point.} In this case, the \textcolor{black}{Ising} critical point might \textcolor{black}{be replaced} by a first-order phase transition \textcolor{black}{region}.

Genetic regulatory circuits universally cope with different sources of noise that limit their ability to coordinate input and output signals. In many cases, optimal regulatory performance can be thought to correspond to configurations of variables and parameters that maximize the mutual information between inputs and outputs. Such optima have been well characterized in several biologically relevant cases over the past decade. Here we use methods of statistical field theory to calculate the statistics of the maximal mutual information (the `capacity') achievable by tuning the input variable only in an ensemble of regulatory motifs, such that a single controller regulates N targets. Assuming (i) sufficiently large N, (ii) quenched random kinetic parameters, and (iii) small noise affecting the input-output channels, we can accurately reproduce numerical simulations both for the mean capacity and for the whole distribution. Our results provide insight into the inherent variability in effectiveness occurring in regulatory systems with heterogeneous kinetic parameters., Comment: 14 pages, 6 figures

A disordered mean field model for multimode laser in open and irregular cavities is proposed and discussed within the replica analysis. The model includes the dynamics of the mode intensity and accounts also for the possible presence of a linear coupling between the modes, due, e.g., to the leakages from an open cavity. The complete phase diagram, in terms of disorder strength, source pumping and non-linearity, consists of four different optical regimes: incoherent fluorescence, standard mode locking, random lasing and the novel spontaneous phase locking. A replica symmetry breaking phase transition is predicted at the random lasing threshold. For a high enough strength of non-linearity, a whole region with nonvanishing complexity anticipates the transition, and the light modes in the disordered medium display typical discontinuous glassy behavior, i.e., the photonic glass has a multitude of metastable states that corresponds to different mode-locking processes in random lasers. The lasing regime is still present for very open cavities, though the transition becomes continuous at the lasing threshold., Comment: 26 pages, 13 figures

The behavior of a newly introduced overlap parameter is analyzed, measuring the correlation between intensity fluctuations of waves in random media in different physical regimes, with varying amount of disorder and non-linearity. Its relationship is established to the standard Parisi overlap order parameter in replica theory for spin-glasses. In the complex spherical spin-glass model, describing the onset and behavior of random lasers, replica symmetry breaking in the intensity fluctuation overlap is shown to occur at high pumping or low temperature. This order parameter identifies the laser transition in random media and describes its glassy nature in terms of emission spectra data, the only data so far accessible in random laser measurements. The theoretical analysis is, eventually, compared to recent intensity fluctuation overlap measurements demonstrating the validity of the theory and providing a straightforward interpretation of different spectral behaviors in different random lasers., Comment: 11 pages, 3 figures

We present a unified approach to the theory of multimodal laser cavities including a variable amount of structural disorder. A general mean-field theory is studied for waves in media with variable non-linearity and randomness. Phase diagrams are reported in terms of optical power, degree of disorder and degree of non-linearity, tuning between closed and open cavity scenario's. In the thermodynamic limit of infinitely many modes the theory predicts four distinct regimes: a continuous wave behavior for low power, a standard mode-locking laser regime for high power and weak disorder, a random laser for high pumped power and large disorder and an intermediate regime of phase locking occurring in presence of disorder below the lasing threshold., Comment: 9 pages, 3 figures

The Ising and BEG models critical behavior is analyzed in 2D and 3D by means of a renormalization group scheme on small clusters made of a few lattice cells. Different kinds of cells are proposed for both ordered and disordered model cases. In particular, cells preserving a possible antiferromagnetic ordering under decimation allow for the determination of the N\'eel critical point and its scaling indices. These also provide more reliable estimates of the Curie fixed point than those obtained using cells preserving only the ferromagnetic ordering. In all studied dimensions, the present procedure does not yield the strong disorder critical point corresponding to the transition to the spin-glass phase. This limitation is thoroughly analyzed and motivated., Comment: 14 pages, 12 figures

We report some results on the quenched disordered Spherical multi-$p$-Spin Model in presence of ferromagnetic couplings. In particular, we present the phase diagrams of some representative cases that schematically describe, in the mean-field approximation, the behavior of most known transitions in glassy materials, including dynamic arrest in super-cooled liquids, amorphous-amorphous transitions and spin-glass transitions. A simplified notation is introduced in order to compute systems properties in terms of an effective, self-induced, field encoding the whole ferromagnetic information., Comment: 34 pages, 7 figures

In many mean-field glassy systems, the low-temperature Gibbs measure is dominated by exponentially many metastable states. We analyze the evolution of the metastable states as temperature changes adiabatically in the solvable case of the spherical $s+p$-spin glass model, extending the work of Barrat, Franz and Parisi J. Phys. A 30, 5593 (1997). We confirm the presence of level crossings, bifurcations, and temperature chaos. For the states that are at equilibrium close to the so-called dynamical temperature $T_d$, we find, however, that the following state method (and the dynamical solution of the model as well) is intrinsically limited by the vanishing of solutions with non-zero overlap at low temperature.

We discuss the relevance of information contained in cross-correlations among different degrees of freedom, which is crucial in non-equilibrium systems. In particular we consider a stochastic system where two degrees of freedom $X_1$ and $X_2$ - in contact with two different thermostats - are coupled together. The production of entropy and the violation of equilibrium fluctuation-dissipation theorem (FDT) are both related to the cross-correlation between $X_1$ and $X_2$. Information about such cross-correlation may be lost when single-variable reduced models, for $X_1$, are considered. Two different procedures are typically applied: (a) one totally ignores the coupling with $X_2$; (b) one models the effect of $X_2$ as an average memory effect, obtaining a generalized Langevin equation. In case (a) discrepancies between the system and the model appear both in entropy production and linear response; the latter can be exploited to define effective temperatures, but those are meaningful only when time-scales are well separated. In case (b) linear response of the model well reproduces that of the system; however the loss of information is reflected in a loss of entropy production. When only linear forces are present, such a reduction is dramatic and makes the average entropy production vanish, posing problems in interpreting FDT violations., Comment: 30 pages, 4 figures, 4 appendixes

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and structural relaxation. The study of the dynamics allows for predictions on the system relaxation above the temperature of dynamic arrest in the mean-field approximation, that are compared with the outcomes of the equations of motion directly derived within the Mode Coupling Theory (MCT) for under-cooled viscous liquids. Varying the external thermodynamic parameters a wide range of phenomenology can be represented, from a very clear separation of structural and secondary peak in the susceptibility loss to excess wing structures., Comment: 13 pages, 8 figures

We investigate the thermodynamic phase transition taking place in the Blume-Capel model in presence of quenched disorder in three dimensions (3D). In particular, performing Exchange Montecarlo simulations, we study the behavior of the order parameters accross the first order phase transition and its related coexistence region. This transition is an Inverse Freezing., Comment: 9 pages, 6 figures, Contribution to the XII International Workshop on Complex Systems

We present a numerical study of the random Blume-Capel model in three dimension. The phase diagram is characterized by spin-glass/paramagnet phase transitions both of first and second order in the thermodynamic sense. Numerical simulations are performed using the Exchange-Monte Carlo algorithm, providing clear evidence for inverse freezing. The main features at criticality and in the phase coexistence region are investigated. We are not privy to other 3D short-range systems with quenched disorder undergoing inverse freezing., Comment: 4 pages, 3 figures

The nature of polyamorphism and amorphous-to-amorphous transition is investigated by means of an exactly solvable model with quenched disorder, the spherical s+p multi-spin interaction model. The analysis is carried out in the framework of Replica Symmetry Breaking theory and leads to the identification of low temperature glass phases of different kinds. Besides the usual `one-step' solution, known to reproduce all basic properties of structural glasses, also a physically consistent `two-step' solution arises. More complicated phases are found as well, as temperature is further decreased, expressing a complex variety of metastable states structures for amorphous systems., Comment: 8 pages, 7 figures, longer version, new references added

We study mean field systems whose free energy landscape is dominated by marginally stable states. We review and develop various techniques to describe such states, elucidating their physical meaning and the interrelation between them. In particular, we give a physical interpretation of the two-group replica symmetry breaking scheme and confirm it by establishing the relation to the cavity method and to the counting of solutions of the Thouless-Anderson-Palmer equations. We show how these methods all incorporate the presence of a soft mode in the free energy landscape and interpret the occurring order parameter functions in terms of correlations between the soft mode and the local magnetizations. The general formalism is applied to the prototypical case of the Sherrington-Kirkpatrick-model where we re-examine the physical properties of marginal states under a new perspective., Comment: 27 pages, 8 figures

We present the detailed analysis of the spherical s+p spin glass model with two competing interactions: among p spins and among s spins. The most interesting case is the 2+p model with p > 3 for which a very rich phase diagram occurs, including, next to the paramagnetic and the glassy phase represented by the one step replica symmetry breaking ansatz typical of the spherical p-spin model, other two amorphous phases. Transitions between two contiguous phases can also be of different kind. The model can thus serve as mean-field representation of amorphous-amorphous transitions (or transitions between undercooled liquids of different structure). The model is analytically solvable everywhere in the phase space, even in the limit where the infinite replica symmetry breaking ansatz is required to yield a thermodynamically stable phase., Comment: 21 pages, 18 figures

We analyze the Blume-Emery-Griffiths model with disordered magnetic interaction that displays the inverse freezing phenomenon. The behavior of this spin-1 model in crystal field is studied throughout the phase diagram and the transition and spinodal lines for the model are computed using the Full Replica Symmetry Breaking Ansatz that always yields a thermodynamically stable phase. We compare the results both with the formulation of the same model in terms of Ising spins on lattice gas, where no reentrance takes place, and with the model with generalized spin variables recently introduced by Schupper and Shnerb [Phys. Rev. Lett. {\bf 93} 037202 (2004)], for which the reentrance is enhanced as the ratio between the degeneracy of full to empty sites increases. The simplest version of all these models, known as the Ghatak-Sherrington model, turns out to hold all the general features characterizing an inverse transition to an amorphous phase, including the right thermodynamic behavior., Comment: 4 pages, 4 figures

The study of the mean-field static solution of the Random Blume-Emery-Griffiths-Capel model, an Ising-spin lattice gas with quenched random magnetic interaction, is performed. The model exhibits a paramagnetic phase, described by a stable Replica Symmetric solution. When the temperature is decreased or the density increases, the system undergoes a phase transition to a Full Replica Symmetry Breaking spin-glass phase. The nature of the transition can be either of the second order (like in the Sherrington-Kirkpatrick model) or, at temperature below a given critical value, of the first order in the Ehrenfest sense, with a discontinuous jump of the order parameter and accompanied by a latent heat. In this last case coexistence of phases takes place. The thermodynamics is worked out in the Full Replica Symmetry Breaking scheme, and the relative Parisi equations are solved using a pseudo-spectral method down to zero temperature., Comment: 24 pages, 12 figures

The time-dependent susceptibility for the finite-size mean-field Random Orthogonal model (ROM) is studied numerically for temperatures above the mode-coupling temperature. The results show that the imaginary part of the susceptibility $\chi''(\nu)$ obeys the scaling form proposed for glass-forming liquids with the peak frequency decreasesing as the temperature is lowered consistently with the Vogel-Fulcher law with a critical temperature remarkably close to the known critical temperature $T_c$ of the model where the configurational entropy vanishes., Comment: 9 pages, 4 figures. To appera in Phil. Mag. B

We prove the existence of chaos in temperature in the Sherringhton-Kirkpatrick model. The effect is exceedingly small, namely of the ninth order in perturbation theory. The equations describing two systems at different temperatures constrained to have a fixed overlap are studied analytically and numerically, yielding information about the behaviour of the overlap distribution function $P_{T_1,T_2}(q)$ in finite-size systems., Comment: REVTEX, 6 pages, 2 figures

We study the mean-field static solution of the Blume-Emery-Griffiths-Capel model with quenched disorder, an Ising-spin lattice gas with quenched random magnetic interaction. The thermodynamics is worked out in the Full Replica Symmetry Breaking scheme. The model exhibits a high temperature/low density paramagnetic phase. When the temperature is decreased or the density increased, the system undergoes a phase transition to a Full Replica Symmetry Breaking spin-glass phase. The nature of the transition can be either of the second order (like in the Sherrington-Kirkpatrick model) or, at temperature below a given critical value (tricritical point), of the first order in the Ehrenfest sense, with a discontinuous jump of the order parameter and a latent heat. In this last case coexistence of phases occurs., Comment: 4 pages, 8 figures

An alternative scenario for the glass transition based on the cooperative nature of nucleation processes and the role of entropic effects is presented. The new ingredient is to relate the dissipation during the relaxation process to the release of strain energy driven by the nucleation of progressively larger cooperative spatial regions. Using an equiprobability hypothesis for the transition between different metastable configurations, we obtain a relation between the free energy dissipation rate and the size of the largest cooperative regions. Th is leads to a new phenomenological relation between the largest relaxation time in the supercooled liquid phase and the effective temperature. This differs from the classical Adam-Gibbs relation in that predicts no divergence of the primary relaxation time at the Kauzmann temperature but a crossover from fragile to strong behavior., Comment: 5 pages, 1 figure (included). RevTeX

In this talk we discuss the possibility of constructing a fluctuation theory for structural glasses in the non-equilibrium aging state. After reviewing well known results in a toy model we discuss some of the key assumptions which support the validity of this theory, in particular the role of the configurational entropy and its relation to the effective temperature. Recent numerical results for mean-field finite-size glasses agree with this scenario., Comment: Disordered and Complex Systems, 10-14 July 2000, Conference Proceedings, 7 pages + 1 figure