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Urbanization and agricultural activities are increasingly threatening karstic systems and the water resources they provide, which are crucial for the livelihood of rural communities. Over the past decade, the Río Grande de Comitán-Lagos de Montebello (RGC-LM) watershed in Chiapas, Mexico, has experienced significant deterioration in water quality. The objective of this study was to analyze the water quality dynamics within the RGC-LM watershed and their potential interaction with land use change. We conducted assessments of the physicochemical and microbiological parameters across the lotic and lentic systems within the watershed over eight monitoring campaigns (from 2013 to 2020). Cluster Analysis (CA) and Principal Component Analysis (PCA) statistical approaches were performed to identify the main drivers of surface water quality variability. This approach aims to enhance water quality assessments within environmental management strategies, with the goal of promoting sustainable land-use practices aimed at protecting and improving water resources within the watershed. Our findings indicate that there is a substantial difference between the upper and lower watershed water quality. The good water quality conditions observed in the higher altitude lakes (mountain lakes) can be attributed to favorable topographical features, specific land use patterns, and effective conservation measures. In contrast, the lotic system in the middle watershed and the lentic water bodies located at lower altitudes (plain lakes) exhibit signs of water quality degradation due to inefficient wastewater treatment and agricultural runoff. This study highlights the importance of implementing adequate environmental management strategies to address these water quality challenges effectively. Given the pressing issue of water quality degradation in karstic environments, we emphasize on the need for increased monitoring frequency of both physicochemical and microbiological parameters to capture seasonal variations and to further understand the vulnerability of water resources in karstic environments. Future assessment of nutrient concentrations, pesticide levels, and blue-green algae populations will also be crucial for evaluating the trophic state at a watershed scale.

Water quality monitoring networks in the global south often display inefficiencies because monitoring strategies are frequently designed based on subjective professional judgments to define the temporal and spatial attributes of the networks, leading to poor cost–benefit relationships. The Lerma-Santiago Hydrological System (LSHS) in Mexico currently experiences severe environmental degradation caused by uncontrolled pollutant emissions from urban centers, agricultural, livestock, and industrial activities settled in the basin. While both the national and state authorities monitor this hydrological system, there has never been an effort to assess the monitoring efficiency of these two networks. The aim of the present study was to assess through multivariate statistical analyses the potential for coordination between these two interacting networks. For this purpose, two independent large water quality datasets with temporal and spatial attributes measured by two different authorities (the federal and the state) were used to identify those sites where coordination should be rationalized and those parameters that should continue to be monitored. The case study herein presented highlights the duplication in efforts to monitor surface water quality in the Lerma-Santiago hydrologic system, which implies a lack of coordination between the authorities and shows that water quality monitoring networks have not been reassessed since they were first implemented. Furthermore, using the case study of the Lerma-Santiago in Mexico, we expanded on various deficiencies, such as the use of different sampling frequencies and analytical methods by the authorities and inefficient communication among federal and state authorities. This study has revealed a large potential for coordinating two water quality monitoring networks (WQMN) in the Lerma-Santiago Hydrological System and a methodological approach that may be used to assess this potential. Coordination strategies for WQMNs can lead to significant cost reductions, extended network reach, and higher overall data quality in developing countries with limited financial resources and technical capabilities. [ABSTRACT FROM AUTHOR]