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The peel of Hylocereus undatus was employed in the preparation of biochar and firstly applied for tetracycline removal from aqueous solution. Based on different characterization techniques, the material was found to possess a variety of surface functional groups on a porous structure and a pH point of zero charge (pHpzc) of 9.3. Adsorption of tetracycline (TC) was conducted under varying conditions, revealing significant effects of carbonization temperature, solution pH, adsorbent dose, ionic strength, contact time and initial concentration of TC on the biochar adsorption capacity. Kinetic data on TC adsorption were best described using the Elovich kinetic model, with an initial adsorption rate of 167.3 mg g−1 min−1. Isotherm data on adsorption of the desired biochar showed the best fit with the Temkin isotherm model, followed by the Langmuir model, displaying maximum adsorption capacity at 12.4 mg g−1. The electrostatic interactions between the charged biochar surfaces and certain fractions of TC were proposed as the major mechanism, together with H-bonding, pore-filling effect and π–π interaction. This study demonstrates great potential of H. undatus peel as a starting material to prepare an effective and reusable adsorbent in the removal of TC. NOVELTY STATEMENT: Literature is available on a large number of plant-based biochar adsorbents for the removal of antibiotics. However, to the best of our knowledge, no report has been published on applying biochar derived from Hylocereus undatus peel for antibiotics removal. This type of fruit peel is available in massive amounts in Vietnam and is considered as an agricultural solid waste. Therefore, to fill the gap in the literature and to converse this leftover waste into a value-added byproduct, we chose this study to prepare H. undatus peel-derived biochar for the elimination of TC in an aqueous solution. [ABSTRACT FROM AUTHOR]

Many initiatives have incorporated graphene oxide (GO) and biomass into aerogels for wastewater treatment. We report on the facile fabrication of a magnetic GO/Fe 3 O 4 /banana peel-derived cellulose (bio-cellulose) aerogel using an ultrasound-assisted mechanical mixing method and freeze-drying technique for the removal of tetracycline (TC). The component materials and composite aerogel were characterized using Fourier-transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), Raman spectroscopy, field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), nitrogen adsorption-desorption analysis, and vibrating sample magnetometry (VSM). The effects of solution pH and adsorbent dose on the adsorption performance of the synthesized adsorbents were investigated. The adsorption behavior at the equilibrium of the GO/Fe 3 O 4 /bio-cellulose aerogel was studied and analyzed using four well-known non-linear models: Langmuir, Freundlich, Sips, and Temkin. The results showed that the experimental data fitted well with the Freundlich and Sips isotherm models. The maximum adsorption capacity achieved from the Sips model was 238.7 mg g -1 . The adsorption kinetics were studied and proved to follow the Elovich kinetic model with an initial rate of 0.89 g g -1 min -1 . These results confirm the favorable adsorption of TC on the heterogeneous surface that exhibits a wide range distribution of adsorption energies of the desired GO/Fe 3 O 4 /bio-cellulose aerogel. The experimental findings demonstrate that the aerogel possesses the notable features of environmental friendliness, cost-effectiveness, and comparatively high TC adsorption capacity. Therefore, utilizing biomass to develop the structure of the magnetic GO-based composite aerogel is significantly promising for antibiotic-containing wastewater treatments., Competing Interests: The authors declare that there are no competing interests that could have appeared to influence the work reported in this paper., (This journal is © The Royal Society of Chemistry.)