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Our understanding of the geological history of early Archean crust is limited by poor preservation of igneous features in rocks that have experienced multiple metamorphic and deformation events. Thus, regions with the best preserved Eoarchean rocks, as for example, the northern part of the Itsaq Gneiss Complex (IGC) of Greenland, have been the most intensively studied. The IGC underwent metamorphism at ca 3.6 and 2.7 Ga (Nutman & Bennett 2018). The grade of 2.7 Ga metamorphism varies from granulite facies in the southern part of the IGC (Fӕringehavn terrane) to lower amphibolite facies in the north (Isukasia terrane). This study compares the preservation of zircon in rocks from both terranes of the IGC.Zircon grains from granitic gneisses in the Fӕringehavn terrane have rounded igneous cores with weak oscillatory zoning, surrounded by well-developed light-CL metamorphic rims. The 207Pb/206Pb zircon age obtained by in situ Secondary Ion Mass Spectrometry (SIMS) of these grains is ca 3.64 Ga for the cores, with metamorphic rims recording an age of ca 2.7 Ga. The Isukasia terrane extends either side of the Isua Supracrustal Belt (ISB), rock samples were collected from both the outer (SSE of the ISB) and inner (NNW of the ISB) Isukasia sub-terranes (Nutman & Bennett 2018). Zircon grains from the outer sub-terrane have well preserved igneous morphologies with evidence of metamictisation and fluid alteration but little to no metamorphic rims. The 207Pb/206Pb zircon ages are scattered towards 2.7 Ga, interpreted as the time of metamorphism, with a subgroup at ca 3.79 Ga that is interpreted as a minimum age for magmatic zircon. However, as the samples collected in the vicinity yielded an age of 3.82 Ga (Nutman et al. 1999, Kielman et al. 2018), the age of ca 3.79 Ga may have been disturbed by subsequent events. Zircon grains from the inner sub-terrane of Isukasia have well-preserved igneous cores with oscillatory zoning. Rounding of pyramidal terminations and thin rims are due to metamorphism. The age of crystalization of the protolith as recorded by igneous zircon is ca 3.71 Ga. The difference in the degree of the metamorphism at 2.7 Ga is visible in the structures and preservation of zircon grains. In this example, rounded cores and well-developed metamorphic rims characterize granulite facies, whereas well-preserved cores with oscillatory zoning and thin metamorphic rims represent lower amphibolite facies.This research was funded by NCN grant UMO2019/34/H/ST10/00619 to MAKReferencesKielman, R., Whitehouse, M.,Nemchin, A., & Kemp, A., (2018). A tonalitic analogue to ancient detrical zircon. Chemical Geology, 499, 43-57.Nutman, A.P. & Bennett, V.C., (2018). The 3.9-3.6 Ga Itsaq Gneiss Complex of Greenland. In: Van Kranendonk, M.J., Bennett, V.C. & Hoffmann, J.E., (Eds.). Earth’s Oldest Rocks (2nd ed.), Elsevier, 375-399.Nutman, A.P., Bennett, V.C., Friend, C.R. & Norman, M.D., (1999). Meta-igneous (nongneissic) tonalites and quartz-diorites from an extensive ca. 3800 Ma terrain south of the Isua supracrustal belt, southern West Greenland: constraints on early crust formation. Contrib. Mineral. Petrol. 137, 364–388.

Interpreting Archean geology is often challenging due to the rocks having obscure field relationships and polymetamorphic histories (Kusiak et al. 2019; Dunkley et al. 2020). In such circumstances, U-Pb isotopic analysis of zircon is crucial for revealing the geological history. This study investigates Archean gneisses from the Saglek Block in Canada, which record magmatic and metamorphic history between ca 3.9 Ga and 2.5 Ga. The predominant lithology is the Uivak gneiss which is primarily composed of tonalite-trondhjemite-granodiorite (TTG) with subordinate intermediate to mafic components. Uivak gneiss is traditionally divided into Uivak I and Uivak II, where Uivak I is grey gneiss and Uivak II is characterized by augen texture and Fe-rich geochemistry (Collerson and Bridgwater, 1979). Ages for the magmatic protoliths of Uivak I are >3.6 Ga, whereas Uivak II ages vary between ca 3.6-3.3 Ga (Sałacińska et al. 2019; Wasilewski et al. 2021 and references therein). This study presents geochemical and U-Pb zircon geochronology from Mentzel and Maidmonts Islands. Augen gneiss on Mentzel Island fits the definition of Uivak II augen gneiss and yield a U-Pb zircon age of ca 3.3 Ga. A similar age was reported for Maidmonts gneiss (Sałacińska et al. 2019) and Illuilik gneiss (Wasilewski et al. 2021). On Mentzel Island, granitic bodies intruded the augen gneiss at ca 2.7 Ga and 2.5 Ga during high-T metamorphism. New dating confirms that augen gneiss on Mentzel Island and elsewhere in the Saglek Block belongs to Uivak II gneisses of ca 3.3 Ga. Variations in rare earth element concentration between different ca 3.3 Ga rocks can be attributed to the involvement of different crustal components in the magmatic protolith. On Maidmonts Island, the augen gneiss intrudes grey gneiss with a protolith age of ca 3.7 Ga, which confirms deformation and metamorphism of Uivak I gneiss before ca 3.3 Ga. This research was funded by NCN grants UMO2019/34/H/ST10/00619 to MAK. References:Collerson, K.D. & Bridgwater, D. 1979. Metamorphic development of early Archaean tonalitic and trondhjemitic gneisses: Saglek area, Labrador. In: Barker, F. (Ed.), Trondhjemites, Dacites, and Related Rock. Elsevier, Amsterdam, 205–271.Dunkley et al. 2020. Journal of the Geological Society, 177 (1), 31–49.Kusiak et al. 2018. Chemical Geology, 484, 210–223.Sałacińska et al. 2019. International Journal of Earth Sciences, 108, 753-778.Wasilewski et al. 2021. Precambrian Research, 359, 106092.

Eoarchean rocks in the Napier Complex of East Antarctica are largely known from a few localities in the western Tula Mountains of Enderby Land. Zircon from trondhjemitic and mafic gneisses from Aker Peaks in Kemp Land, 200 km further east, were analysed by secondary ion mass spectrometry (SIMS), yielding concordant U Pb dates between 3860 and 3700 Ma, which can be attributed to magmatic and possibly metamorphic activity. Concurrent analysis of 207Pb/206Pb ratios and Lu Hf isotopes in the trondhjemitic sample by laser ablation ICPMS provide initial eHf(t) estimates for this age range that are slightly sub-chondritic (ca 0 to −2). This can be attributed to the incorporation of older crust into the magmatic protoliths of the gneisses, although there is no requirement that this crustal source be older than Eoarchean. Much scatter in the U Pb dataset is attributable to isotopic disturbance of Pb during high-temperature metamorphism at 2.5 Ga, and if not corrected for, can lead to overestimation of model crust formation ages, a critical problem in the search for evidence of Hadean crust in Eoarchean rocks, and for estimating the timing and rate of ancient continental growth.

Orthopyroxene-bearing felsic gneiss occurs as foliation-parallel layers and bands together with aluminous granulite, mafic granulite, and quartzofeldspathic granulite in the Chilka Lake migmatite complex of the Proterozoic Eastern Ghats Belt, India. The rock was classified previously as charnockite which underwent granulite-facies metamorphism. Field and textural features of this rock show evidence of the partial melting of a biotite-bearing greywacke protolith. Orthopyroxene with/without garnet and cordierite were produced with K-feldspar as peritectic phases of incongruent melting of presumed metaluminous sediments. Fluid-inclusion data suggest the presence of high-density CO2-rich fluids during peak metamorphism, which are similar to those found in associated aluminous granulite. Whole-rock major and trace element data show wide variability of the source materials whereas REE distributions show enriched LREE and flat HREE patterns. Zircon grains from representative samples show the presence of inherited cores having spot dates (SHRIMP) in the range c. 1790–3270 Ma. The overgrowth on zircon was formed predominantly during c. 780–730 Ma and sporadically during c. 550–520 Ma. Some neoblastic zircons with c. 780–730 Ma ages are also present. U-rich dark zones surrounding cores appear partially metamictised, but spot ages from this zone vary within c. 1000–900 Ma. The

Fluid flow in the upper crust not only impacts the redistribution of heat and elements, driving the formation of economic ore deposits, but it also exerts control on metamorphism, metasomatism, and deformation. However, reconstructing the history of fluid flow in ancient basins is exceedingly difficult, particularly in Archean sedimentary rocks because of extensive overprinting and recrystallization. Here, we report U-Pb ages for monazite and xenotime that grew in bedding-parallel veins in 2.63–2.5-b.y.-old shales along the southern Pilbara craton, Australia. The U-Pb ages define six discrete populations, at 2.41 Ga, 2.30 Ga, 2.20 Ga, 2.10 Ga, 2.05 Ga, and 1.66 Ga, which formed ≥200 m.y. after deposition. The abundance of bedding-parallel crack-seal and fibrous veins in banded iron formations (BIFs) and underlying shales suggests a history of episodic buildup of fluid pressure followed by microfracturing, fluid expulsion, and mineral growth. Thermometry of vein minerals indicates temperatures between 230 °C and 320 °C, implicating the migration of hydrothermal fluids. The development of bedding-parallel veins at 2.41 Ga, 2.20 Ga, and 1.66 Ga was coeval with regional orogenic events known to have affected the craton, whereas vein growth at 2.30 Ga, 2.10 Ga, and 2.05 Ga reveals new episodes of deformation and fluid flow. Our results show that well-preserved Archean shales devoid of structural fabrics and >150 km inboard of the craton margin preserve a cryptic history of fluid overpressure, crack-seal vein development, and hydrothermal fluid flow between 2.41 and 1.66 b.y. ago.

The Napier Complex of Enderby and Kemp Lands forms the north-western part of the East Antarctic Shield and consists predominantly of gneisses and granulites metamorphosed during a ca. 2.8 Ga high-grade and a ca. 2.5 Ga ultra-high temperature event. The western segment of the Napier Complex includes coastal outcrops, islands and nunataks around Amundsen and Casey Bays, and the Tula Mountains. This region records some of the highest metamorphic temperatures measured on Earth, affecting a variety of gneisses as old as ca. 3.8 Ga. Five samples of orthogneiss from the less-studied eastern Tula Mountains, including three granitic, one trondhjemitic and one dioritic gneiss, were dated by zircon U-Pb Secondary Ion Mass Spectrometry (SIMS). The three orthogneisses yield protolith ages of 3750 ± 35 Ma (granitic), 3733 ± 21 (trondhjemitic) Ma and 3560 ± 42 Ma (dioritic), whereas the two other granitic orthogneisses record ages of 2903 ± 14 Ma and 2788 ± 24 Ma. Zircon growth during metamorphism occurred at 2826 ± 10 Ma, and also between 2530 Ma and 2480 Ma. Samples from the Tula Mountains can be geochemically subdivided into Y-HREE-Nb-Ta depleted and undepleted groups. Eoarchean granitoids are included in both geochemical groups, as are Meso- and Neoarchean granitoids. The Y-HREE-Nb-Ta depleted granitoids can be generated by medium- to high-pressure melting of mafic crust, whereas undepleted granitoids can be generated by low-pressure melting. However, relatively high potassium contents in most samples, and the presence of xenocrystic/inherited zircon in some, reflect the likely involvement of felsic crustal sources. This diversity in granitoid composition occurs across the Napier Complex. The lack of a simple correlation between protolith age and geochemical type is an indication that magmatism during the Eoarchean (and later) involved diverse sources and processes, including re-melting and recycling of various crustal components, rather than just the formation of juvenile crust.

Systematic changes in whole-rock chemistry, mineralogy, mineral textures, and mineral chemistry are seen along a ca. 95-km traverse of late Archean granitoid orthogneisses in the Shevaroy Block, Eastern Dharwar Craton, southern India. The traverse passes from amphibolite-grade gneisses in the north to granulite-grade rocks (charnockite) in the south. Changes include whole-rock depletion of Rb, Cs, Th, and U in the granulite grade rocks as relative to the amphibolite grade gneisses, and oxidation trends regionally from highly oxidised granulite-facies rocks near the magnetite–haematite buffer to relatively reduced amphibolite-facies rocks below the fayalite-magnetite-quartz. Rare earth elements show limited mobility and are hosted a variety of minerals whose presence is dependent on the metamorphic grade ranging from titanite and allanite in the amphibolite-facies rocks to monazite in the vicinity of the orthopyroxene-in isograd to apatite in the granulite-grade charnockite. Cathodoluminescence and back-scattered electron sub-grain imaging and sensitive high-resolution ion microprobe analysis of zircon from 29 samples of dioritic, tonalitic, and granitic orthogneiss from the traverse reveals magmatic zircon cores that record the emplacement of the granitoid protoliths mostly about 2580 to 2550 Ma, along with a few older mid to late Archean tonalites. Protolith zircon was modified during metamorphism by overgrowth and/or replacement. Relative to igneous cores, U-enriched metamorphic zircon, dominant in the amphibolite-grade gneisses, formed at ca. 2530 Ma, predating retrograde titanite growth at ca. 2500 Ma. Uranium-depleted mantles grew on zircon between 2530 and 2500 Ma in granulite-grade samples south of the orthopyroxene-in isograd. In some of these samples, the U-depleted metamorphic zircon is preceded by mantles of U-undepleted zircon, indicating a progression of metamorphic zircon growth with increasingly depleted compositions between 2530 and 2500 Ma. With increasing metamorphic grade (from amphibolite to granulite) and oxidation state, allanite and monazite disappear from the assemblage and zircon became depleted in U and Th. Whole-rock U-Th compositions became decoupled from relict magmatic zircon compositions, reflecting the development of U-depleted metamorphic zircon and indicating that whole-rock chemical differences along the traverse were produced during metamorphism, rather than just reflecting differences in dioritic vs granitic protoliths. Although in situ anatexis and melt extraction may have played a role, whole-rock and zircon depletion of trace elements can be explained by the action of externally derived, oxidising, low-H2O activity hypersaline fluids migrating up through the mid to lower crust. Fluids and element migration during metamorphism may be the end result of subduction related processes that cumulated in the collision and concatenation of island arcs and continental blocks. These tectonic processes assembled the Dharwar Craton at the end of the Archean.

Nanospheres of lead (Pb) have recently been identified in zircon (ZrSiO4) with the potential to compromise the veracity of U-Pb age determinations. The key assumption that the determined age is robust against the effects of Pb mobility, as long as Pb is not lost from the zircon during subsequent geological events, is now in question. To determine the effect of nanosphere formation on age determination, and whether analysis of nanospheres can yield additional information about the timing of both zircon growth and nanosphere formation, zircons from the Napier Complex in Enderby Land, East Antarctica, were investigated by high-spatial resolution NanoSIMS (Secondary Ion Mass Spectrometry) mapping. Conventional SIMS analyses with >µm resolution potentially mixes Pb from multiple nanospheres with the zircon host, yielding variable average values and therefore unreliable ages. NanoSIMS analyses were obtained of 207Pb/206Pb in nanospheres a few nanometres in diameter that were resolved from 207Pb/206Pb measurements in the zircon host. We demonstrate that analysis for 207Pb/206Pb in multiple individual Pb nanospheres, along with separate analysis of 207Pb/206Pb in the zircon host, can not only accurately yield the age of zircon crystallization, but also the time of nanosphere formation resulting from Pb mobilization during metamorphism. Model ages for both events can be derived that are correlated due to the limited range of possible solutions that can be satisfied by the measured 207Pb/206Pb ratios of nanospheres and zircon host. For the Napier Complex zircons, this yields a model age of ca 3110 Ma for zircon formation and a late Archean model age of 2610 Ma for the metamorphism that produced the nanospheres. The Nanosphere Model Age (NMA) method constrains both the crystallization age and age of the metamorphism to ~±135 Ma, a significant improvement on errors derived from counting statistics.

Oligocene trachytes from the Euganean Hills include various regionally metamorphosed gneissic and granulitic xenoliths. These xenoliths provide the unique opportunity to investigate South Alpine intermediate to deep crustal levels that are not at present exposed in the Eastern Alps. The estimated P–T conditions are in the range of 780–850°C and 0.45–0.55 GPa for a migmatitic gneiss xenolith. Sensitive high-resolution ion microprobe (SHRIMP II) U–Pb analyses on zircon from this xenolith provide concordant ages around 259.7 ± 3.5 Ma, consistent with a proton-induced X-ray emission (PIXE) U–Th–Pb age on monazite of 262 ± 12 Ma. The Sr–Nd–Pb isotopic compositions, and major and trace element data show distinct origins for the different types of xenoliths. Mafic granulite xenoliths have an isotopic signature close to mantle-derived rocks and to Permian gabbroic rocks from the Western Southern Alps. Metapelite xenoliths have high Sr and low Nd initial ratios like those of acid crustal rocks and could possibly represent the source of the crustal component that is dominant in the acid Permian supervolcanoes. The migmatitic xenolith provides the first documented evidence for a Permian thermal event associated with crustal thinning in the Eastern Southern Alps. Here the South Alpine basement escaped most of the Alpine crustal shortening and still preserves most of the original Permian extension under thick Mesozoic cover. Supplementary material: Microprobe analyses of mineralogical phases and Ti-in-biotite geothermometric calculations are available at https://doi.org/10.6084/m9.figshare.c.5032337

The Saglek Block forms the northern part of the Nain Province and underwent widespread metamorphism at c. 2.7 Ga, producing the dominant gneissosity and intercalation of supracrustal sequences. Zircon dating of gneiss samples collected along 80 km of the Labrador coast from Ramah Bay in the north to Hebron Fjord in the south confirms the widespread extent of high-grade metamorphism between 2750 and 2700 Ma. In addition, a distinct event between 2550 and 2510 Ma produced felsic melt with peritectic garnet in metavolcanic gneiss and granoblastic recrystallization in mafic granulite. Ductile deformation of granite emplaced at c. 2550 Ma indicates that this later event involved a degree of tectonism during high-T metamorphism. Such tectonism may be related to a hypothesized post-2.7 Ga juxtaposition of the predominantly Eoarchean Saglek Block against the Mesoarchean Hopedale Block, along a north–south boundary that extends from the coast near Nain to offshore of Saglek Bay. Evidence of reworking of c. 2.7 Ga gneisses by c. 2.5 Ga tectonothermal activity has been found elsewhere on the margins of the North Atlantic Craton, of which the Nain Province represents the western margin. In particular, a recent suggestion that c. 2.5 Ga metamorphic ages along the northern margin of the North Atlantic Craton in SW Greenland may record the final assembly of the craton could also apply to the western margin as represented by the rocks of the Nain Province. Supplementary material: Plots and geochemical data are available at https://doi.org/10.6084/m9.figshare.c.4567934

[Extract]: Granite generation is a fundamental process for the growth and evolution of Earth’s continental crust. I-type granitic rocks, nominally derived from infracrustal sources, are the most common granite type and are voluminously emplaced in convergent margin settings. A puzzling feature is that many I-type granites show isotopic evidence for reworking of older supracrustal material, in conflict with the I-type designation. How the supracrustal component was incorporated by I-type magmas is a matter of deduction, particularly given difficulties in recognizing the putative infracrustal source region in the exposed geology. We report a case study of I-type granitic magma generation by hybridization between metasedimentary-derived partial melt and intercalated mafic granulite units during extraction of silicic magma from the lower crust in the Hidaka Metamorphic Belt (HMB), Japan (Hammerli et al., 2018). Isotopic data (Nd, Hf, O) obtained by microanalysis of accessory minerals in former melt networks (leucosomes) suggest that hybridization operates on a (sub-) grain scale, where repeated injections of externally derived melt attempt to approach local equilibrium with the host mafic granulites during transfer through complex melt pathways (see our figure 3; and also Hasalova et al. [2011] and references therein).

Paulsens is a mesothermal orogenic gold deposit located in the Wyloo Inlier on the southern margin of the Pilbara craton of Western Australia. Gold occurs in quartz-sulfide veins hosted within a folded and faulted gabbro dike, from which baddeleyite yields a U-Pb crystallization age of 2701 ± 11 Ma. Monazite and xenotime in the veins and from hydrothermally altered country rocks yield three distinct U-Pb dates of ca. 2400, 1730, and 1680 Ma. Textural relationships between euhedral xenotime and pyrite with rounded native gold inclusions from within the quartz-sulfide veins show that the primary gold mineralization was synchronous with xenotime crystallization at 2403 ± 5 Ma, and coeval with pervasive alteration of the host rocks, which yield monazite ages of 2398 ± 37 and 2403 ± 38 Ma. Regional-scale hydrothermal events at ca. 1730 and 1680 Ma are linked to the growth of monazite within phyllitic rocks at 1730 ± 28 and 1721 ± 32 Ma, carbonate veining at 1655 ± 37 Ma, and gold remobilization or introduction of new gold at 1680 ± 9 Ma. The ca. 2400 Ma age for mineralization and hydrothermal alteration does not correspond with any known deformation event in the region, indicating a significantly different and more complicated low-temperature tectonothermal evolution for the southern Pilbara region than previously recognized. The in situ secondary ion mass spectrometry dating of monazite and xenotime employed here will lead to better targeting of orogenic gold deposits in the northern Capricorn Orogen, and these techniques can be utilized for orogenic gold exploration worldwide.

The Proterozoic belts that occur along the margins of the West Australian Craton, as well as those in intraplate settings, generally share similar geological histories that suggest a common plate-margin driver for orogeny. However, the thermal drivers for intraplate orogenesis are more poorly understood. The Mutherbukin Tectonic Event records a protracted period of Mesoproterozoic reworking of the Capricorn Orogen and offers significant insight into both the tectonic drivers and heat sources of long-lived intraplate orogens. Mineral assemblages and tectonic fabrics related to this event occur within a 50 km-wide fault-bound corridor in the central part of the Gascoyne Province in Western Australia. This zone preserves a crustal profile, with greenschist facies rocks in the north grading to upper amphibolite facies rocks in the south. The P–T–t evolution of 13 samples from 10 localities across the Mutherbukin Zone is investigated using phase equilibria modelling integrated with in situ U–Pb monazite and zircon geochronology. Garnet chemistry from selected samples is used to further refine the P–T history and shows that the dominant events recorded in this zone are prolonged D1 transpression between c. 1,320 and 1,270 Ma, followed by D2 transtension from c. 1,210 to 1,170 Ma. Peak metamorphic conditions in the mid-crust reached >650°C and 4.4–7 kbar at c. 1,210–1,200 Ma. Most samples record a single clockwise P–T evolution during this event, although some samples might have experienced multiple perturbations. The heat source for metamorphism was primarily conductive heating of radiogenic mid- and upper crust, derived from earlier crustal differentiation events. This crust was thickened during D1 transpression, although the thermal effects persisted longer than the deformation event. Peak metamorphism was terminated by D2 transtension at c. 1,210 Ma, with subsequent cooling driven by thinning of the radiogenic crust. The coincidence of a sedimentary basin acting as a thermal lid and a highly radiogenic mid-crustal batholith restricted to the Mutherbukin Zone accounts for reworking being confined to a discrete crustal corridor. Our results show that radiogenic regions in the shallow to mid crust can elevate the thermal gradient and localize deformation, causing the crust to be more responsive to far-field stresses. The Mutherbukin Tectonic Event in the Capricorn Orogen was synchronous with numerous Mesoproterozoic events around the West Australian Craton, suggesting that thick cratonic roots play an important role in propagating stresses generated at distant plate boundaries.

The complex history of assemblage and disruption of continental plates surrounding the Atlantic Ocean is in part recorded by the distribution of detrital zircon ages entrained in continental sedimentary strata from Morocco (Central High Atlas and Argana basins) and Canada (Grand Manan Island, New Brunswick). Here we investigate detrital zircon from the latest Triassic (ca. 202 Ma) sedimentary strata directly underlying lava flows of the Central Atlantic magmatic province or interlayered within them. SHRIMP (Sensitive High-Resolution Ion MicroProbe) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry) U–Pb ages for zircon range from Paleozoic to Archean with a dominant Neoproterozoic peak, and significant amounts of ca. 2 Ga zircon. These ages suggest a prevailing West African (Gondwanan) provenance at all sampling sites. Notably, the Paleoproterozoic zircon population is particularly abundant in central Morocco, north of the High Atlas chain, suggesting the presence of Eburnean-aged rocks in this part of the country, which is consistent with recent geochronologic data from outcropping rocks. Minor amounts of late Mesoproterozoic and early Neoproterozoic zircon ages (ca. 1.1–0.9 Ga) in Moroccan samples are more difficult to interpret. A provenance from Avalonia or Amazonia, as proposed by previous studies is not supported by the age distributions observed here. An involvement of more distal source regions, possibly located in north-eastern Africa (Arabian Nubian Shield) would instead be possible. Paleozoic zircon ages are abundant in the Canadian sample, pointing to a significant contribution from Hercynian aged source rocks. Such a signal is nearly absent in the Moroccan samples, suggesting that zircon-bearing Hercynian granitic rocks of the Moroccan Meseta block were not yet outcropping at ca. 200 Ma. The only Moroccan samples that yield Paleozoic zircon ages are those interlayered within the CAMP lavas, suggesting an increased dismantling (i.e. uplift) of the Hercynian chain during emplacement of CAMP lava flows, combined with subsidence of the volcanic grabens.

Gold deposits are rare in upper-amphibolite to granulite facies environments. Known examples commonly attract debate about whether they formed under these conditions or instead represent metamorphosed, metasomatic, or superimposed (retrograde) mineralization. The Glenburgh gold deposit is located in the Paleoproterozoic upper-amphibolite to granulite facies Glenburgh Terrane in the southern Gascoyne Province of Western Australia. Gold at the Glenburgh deposit is free and disseminated within quartz–biotite–garnet gneiss, amphibolite, and (post-gold) quartz–chlorite veins. No clear association with a specific host lithology has been identified and mineralization does not have a visually distinct proximal alteration assemblage. The rocks hosting the deposit represent a distinct sedimentary package that was deposited, mineralized, buried, and metamorphosed, all during arc magmatism. Features within the internal structure of gold grains, such as high-purity gold veinlets, incoherent twinning, and low silver content, suggest the gold has been through post-depositional processes such as metamorphism and deformation. Abundant sulfide minerals are interpreted to have formed by sulfidation of the host rock contemporaneously with gold mineralization, and the presence of rounded sulfide inclusions within garnet porphyroblasts illustrates the presence of a sulfide phase prior to peak metamorphism. Geochronology of zircon and monazite constrains the timing of mineralization to be younger than c. 2035 Ma—the maximum depositional age of the metasedimentary host rocks—but older than c. 1991 Ma—the peak of M1 metamorphism during the Glenburgh Orogeny; these events were synchronous with arc magmatism. Rocks at the Glenburgh deposit were likely deposited in a fore-arc or accretionary wedge, a favourable setting for porphyry Cu–Mo–Au, epithermal Au, polymetallic (Sn, W) skarn, and orogenic Au mineralization. Phase equilibria modelling of a pelitic migmatite constrains peak P–T conditions to be 865–885 °C, 6.8–7.6 kbar, consistent with elevated thermal gradients within the arc, followed by conductive cooling of arc magmas. Partial melting during peak M1 metamorphism possible caused gold remobilization. The lack of an alteration assemblage further suggests that the alteration assemblage and mineralization were recrystallized during deformation and metamorphism. However, increases in Ca and K abundance and magnetic susceptibility decreases toward mineralization, suggesting that they may constitute ore vectors.

The Archean gneiss complex of the Saglek Block of Labrador is a part of the North Atlantic Craton, and is correlated with southern West Greenland, both being metamorphosed during a ca. 2.7 Ga event. The main component of the complex is the Eoarchean Uivak orthogneiss, which includes lenses of the Nulliak supracrustal assemblage. Both lithologies are cut by the mafic Saglek metadykes. The Uivak gneisses have been divided into Uivak I grey gneiss and Uivak II augen gneiss. The former underwent ca. 3.6 Ga high-T metamorphism prior to the intrusion of the latter. However, the exact age, nature, and extent of Uivak II gneiss are poorly understood. We present geochemical and geochronological results for both these orthogneisses to help refine the various hypotheses that have been proposed concerning the nature of their protoliths. Magmatic ages of 3746 ± 5 and 3717 ± 6 Ma are consistent with previous estimates for the age of Uivak I gneiss. Uivak II augen gneiss from Maidmonts Island, where there is a clear intrusive relationship between the Uivak II and Uivak I gneissic protoliths, has an age of 3325 ± 3 Ma. This is similar to an homogeneous grey gneiss from St. John’s Harbour, with an age of 3318 ± 5 Ma. Grey gneiss from Big Island is distinctively younger (3219 ± 7 Ma), and equivalent to the ca. 3.24 Ga Lister gneiss. Our study shows that granitic gneisses classified as Uivak II were emplaced 200–300 million years after ca. 3.6 Ga metamorphism and deformation of the Uivak I gneiss. The igneous protolith of Uivak II gneiss pre-dates the Lister gneiss by about 100 Ma. The Uivak I and Lister gneisses are geochemically similar, and are both Tonalite–Trondhjemite–Granodiorite (TTG) gneisses, whereas the Uivak II gneiss is a granitoid partially derived from pre-existing crust. We propose abandoning the term ‘Uivak II gneiss’, and renaming ca. 3.3 Ga granitoids, after the type locality, as Maidmonts gneiss. This restricts the term ‘Uivak gneiss’ to Eoarchean TTG gneisses and removes the necessity for subdividing them into Uivak I and II.

The presence of Pb oxide nanospheres in zircon from mylonites of the Ivrea-Verbano Zone (IVZ), Northern Italy is described for the first time. Isotopic dating of zircon reveals detrital cores with ages scattered from 960 to 320 Ma, and metamorphic rims with a mean age of 280 ± 4 Ma. Zircon crystals, derived from samples that contain pseudotachylite formed during seismic events, have planar fractures (PFs) and planar deformation bands (PDBs). The PDBs are associated with straight dislocation arrays in glide configuration. Detrital zircon cores have mottled diffraction contrast in TEM bright field images, indicative of irradiation damage and/or annealing in radiation damaged zircon. Lead oxide nanospheres up to 9 nm in diameter, as recognized in TEM, occur in detrital cores but not in metamorphic rims of the zircon. No relationship was observed between the nanospheres and PDBs or PFs. This is the first report of lead oxide nanospheres in zircon from a Phanerozoic metamorphic rock, as well as being the first observed case of such nanoinclusions being composed of Pb oxide, rather than native Pb. The formation of the nanospheres is attributed to high-temperature metamorphism, with subsequent seismic activity having little effect on distribution or preservation.

We summarize U–Pb age data for the Lutzow–Holm Complex (LHC) in East Antarctica and propose the following geological subdivisions based on protolith ages, along the coast of Dronning Maud Land from southwest to northeast: the Innhovde Suite (INH, 1070–1040 Ma) composed mainly of felsic orthogneiss; the Rundvagshetta Suite (RVG, 2520–2470 Ma), mostly felsic orthogneiss with minor mafic and metasedimentary gneisses; the Skallevikshalsen Suite (SKV, 1830–1790 Ma), felsic to mafic orthogneiss with abundant dolomitic marbles, calc-silicates and other metasediments; the Langhovde Suite (LHV, 1100–1050 Ma), mostly felsic orthogneiss with minor mafic and calc-silicate gneisses; the East Ongul Suite (EOG, 630 Ma), with various orthogneisses and metasediments; and the Akarui Suite (AKR, 970–800 Ma) with diverse orthogneisses and paragneisses. The oldest crustal components of the LHC lie in the southern part of Lutzow–Holm Bay, and consist of late Neoarchean and Paleoproterozoic protoliths to charnockites and enderbites that dominate the Rundvagshetta and Skallevikshalsen Suites. This older domain is surrounded by gneisses and granulites with late Mesoproterozoic to early Neoproterozoic protolith ages, including the Innhovde Suite and the Langhovde Suite. The Akarui Suite contains diverse orthogneisses with Neoproterozoic protoloiths, and the youngest unit is the East Ongul Suite with protolith ages of ~630 Ma. Cape Hinode, located geographically within the Akarui Suite, underwent high-grade metamorphism at ~960 Ma that is much older than that which produced the gneisses and granulites of the surrounding LHC (~600–520 Ma). Cape Hinode is therefore exotic, independent of the surrounding LHC, and defined as the “Hinode Block”. The boundaries proposed in this paper are largely consistent with those inferred from magnetic anomalies, gravity anomalies, and bedrock topographical data.

High-grade para- and orthogneissic rocks near the Chilka Lake granulite complex, northern part of the Eastern Ghats Belt show complex structural and petrological history. Based on field and petrographic characters, five (M 1 –M 5 ) metamorphic events could be identified. The earliest metamorphic event (M 1 ) produced amphibolite grade mineral assemblage which produced the peak granulite (M 2 ) assemblages at 900–950 °C, 8.5–9.0 kbar. The third metamorphic event caused decompression of the deeper crust up to 700–800 °C, 6.0–6.5 kbar. This was followed by cooling (M 4 ) and subsequent thermal overprinting (M 5 ). Fluid-composition during M 3 was dominated by high-density CO 2 and changed to low-density mixed CO 2 –H 2 O during the M 3 . Zircon U–Pb SHRIMP data suggest 781 ± 9 Ma age for M 3 event. Texturally constrained monazite U–Th–Pb EPMA data, on the other hand, yield a group age of 988 ± 23 Ma from grain interior, which can signifies the age of M 2 event. Few spots with younger dates in the range of 550–500 Ma are also noted. This interpretation changes the existing tectonothermal history of northern Eastern Ghats Belt. Our data show that the two adjacent crustal domains of the Eastern Ghats Belt show distinctly contrasting Neoproterozoic histories. While the central Domain 2 evolved through early anticlockwise P – T path culminating in ultrahigh temperature, the northern Domain 3 evolved through a clockwise P – T path. It appears that the Domain 3 was contiguous to East Antarctica and became part of the Eastern Ghats Belt during the assembly of Gondwana. The ca. 780 Ma decompression event in the northern Eastern Ghats Belt opens up new possibilities for interpreting the breakup of Rodinia.

In situ SHRIMP U-Pb dating of zirconolite in clinopyroxenite from the Cummins Range Carbonatite Complex, situated in the southern Halls Creek Orogen, Kimberley region, Western Australia, has provided a reliable 207Pb/206Pb age of emplacement of 1009 ± 16 Ma. Variably metamict and recrystallised zircons from co-magmatic carbonatites, including a megacryst ~1.5 cm long, gave a range of ages from ~1043–998 Ma, reflecting partial isotopic resetting during post-emplacement deformation and alteration. Monazite-(Ce) in a strongly foliated dolomite carbonatite produced U-Th-Pb dates ranging from ~900–590 Ma. Although the monazite-(Ce) data cannot give any definitive ages, they clearly reflect a long history of hydrothermal alteration/recrystallisation, over at least 300 million years. This is consistent with the apparent resetting of the Rb-Sr and K-Ar isotopic systems by a post-emplacement thermal event at ~900 Ma during the intracratonic Yampi Orogeny. The emplacement of the Cummins Range Carbonatite Complex probably resulted from the reactivation of a deep crustal structure within the Halls Creek Orogen during the amalgamation of Proterozoic Australia with Rodinia over the period ~1000–950 Ma. This may have allowed an alkaline carbonated silicate magma that was parental to the Cummins Range carbonatites, and generated by redox and/or decompression partial melting of the asthenospheric mantle, to ascend from the base of the continental lithosphere along the lithospheric discontinuity constituted by the southern edge of the Halls Creek Orogen. There is no evidence of a link between the emplacement of the Cummins Range Carbonatite Complex and mafic large igneous province magmatism indicative of mantle plume activity. Rather, patterns of Proterozoic alkaline magmatism in the Kimberley Craton may have been controlled by changing plate motions during the Nuna–Rodinia supercontinent cycles (~1200–800 Ma).

IODP Hole 1256D penetrates a complete section of upper oceanic crust spread from the East Pacific Rise at a full rate of up to 220 mm/yr. Here we present U Pb zircon data from Hole 1256D gabbroic rocks using isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and secondary ion mass spectrometry (SIMS). Three gabbro samples yielded Th-corrected weighted mean 206Pb/238U SIMS dates of 15.03 ± 0.14 Ma, 15.13 ± 0.35 Ma, and 15.23 ± 0.12 Ma. An ID-TIMS Th-corrected weighted mean 206Pb/238U date of 15.191 ± 0.040 Ma from the first of the three samples provides verification and refinement of the timing of magmatism. The U Pb dates agree with the predicted age of the crust based on marine magnetic anomalies, suggesting the gabbros most likely formed by intrusion and crystallization at or near the ridge axis. Zircons from two of the studied samples have anomalously high Th/U ratios, likely reflecting oxidation of U prior to or during zircon crystallization. The elevated ƒO2 of late stage melts in the axial melt lens may be related to progressive crystallization, assimilation of hydrothermally altered sheeted dikes and gabbros, and/or contamination of the melt lens by seawater derived saline brines.

The Saglek Block of Labrador comprises Eoarchean to Neoarchean lithologies, metamorphosed at high temperature at ca. 2.7 Ga. Here, we investigate the gneisses of Tigigakyuk Inlet, previously identified as the locality exposing the most ancient rocks in the Saglek Block. New geochronological and geochemical results reveal a multistage history. Precise magmatic emplacement ages of 3.75–3.71 Ga refine the age of the Uivak Gneiss. Zircon rims and neoblastic grains with low Th/U record metamorphism at ca. 3.6 and 2.8–2.7 Ga. Magmatism between these tectono-metamorphic events is recorded by the presence of meta-mafic dykes in the gneisses, gabbroic enclaves in ca. 2.7 Ga syn-tectonic granitoids, as well as by a ca. 3.56 Ga age for monzonitic gneiss in which metamorphic zircon is present as xenocrysts. Felsic (TTG) magmatism between ca. 3.75 Ga and 3.71 Ga, as well as metamorphism at both ca. 3.6 Ga and 2.8–2.7 Ga, is also recognised in the Itsaq Gneiss Complex of south West Greenland, and is restricted to the Faeringehavn Terrane. Our new data enable a more rigorous correlation between these formerly conjugate parts of the North Atlantic Craton.

This article proposes an improved approach to monazite dating by electron microprobe that includes a “monazite age reference correction” (MARC). During analysis, a set of differing monazite standard reference materials with established isotopic ages are measured at the start of the session. These measurements are used to test the analytical set-up and, if necessary, to calculate MARC factors that can be applied to monazite samples. The MARC is not intended as a way to correct systematic errors due to problems in set-up, but rather as a fine-scale adjustment for factors that cannot be readily assessed during single sessions. Long-term, multi-session calculation of MARC factors allows for precise monitoring of anomalous behavior among monazite age reference materials during individual sessions. The method can also assist in the identification of chemical inhomogeneity in monazite, such as that commonly produced by interaction with metasomatic fluids. A representative set of electron microprobe monazite age reference materials are presented, including two ‘reference monazites’ that are good examples of monazite with age disturbance induced by metasomatism. Additional modifications to analytic protocols are proposed, including a) corrections for count rate increases during long beam dwell times, and b) improved estimation of background values at line positions by accounting for the effect of mean atomic number.

The Saglek Block of coastal Labrador forms the western margin of the North Atlantic Craton, where Archean gneisses and granulites have been reworked during the Paleoproterozoic. Previous work has established that the block is a composite of Eoarchean to Mesoarchean protoliths metamorphosed to upper amphibolite and granulite facies at around 2.8–2.7 Ga. New in-situ microbeam dating of accessory minerals in granoblastic gneisses reveals a complex peak to post-peak thermal history. Zircon growth at ca. 3.7–3.6 Ga provides the age of formation of the tonalitic protoliths to the gneisses. Further zircon growth in syn-tectonic granitic gneiss and monazite growth in a variety of orthogneisses confirm peak metamorphic conditions at ca. 2.7 Ga, but also reveal high-temperature conditions at ca. 2.6 Ga and 2.5 Ga. The former is interpreted as the waning stages of the 2.7 Ga granulite event, whereas the latter is associated with a younger phase of granitic magmatism. In addition, apatite ages of ca. 2.2 Ga may represent either cooling associated with the 2.5 Ga event or a previously unrecognized greenschist-facies metamorphism event that predates the Torngat Orogeny.

A widely held hypothesis is that modern continental crust of an intermediate (i.e. andesitic) bulk composition forms at intra-oceanic arcs through subduction zone magmatism. However, there is a critical paradox in this hypothesis: to date, the dominant granitic rocks discovered in these arcs are tonalite, rocks that are significantly depleted in incompatible (i.e. magma-preferred) elements and do not geochemically and petrographically represent those of the continents. Here we describe the discovery of a submarine knoll, the Daisan–West Sumisu Knoll, situated in the rear-arc region of the intra-oceanic Izu–Bonin–Mariana Arc. Remotely-operated vehicle surveys reveal that this knoll is made up entirely of a 2.6 million year old porphyritic to equigranular granodiorite intrusion with a geochemical signature typical of continental crust. We present a model of granodiorite magma formation that involves partial remelting of enriched mafic rear-arc crust during the initial phase of back-arc rifting, which is supported by the preservation of relic cores inherited from initial rear-arc source rocks within magmatic zircon crystals. The strong extensional tectonic regime at the time of intrusion may have allowed the granodioritic magma to be emplaced at an extremely shallow level, with later erosion of sediment and volcanic covers exposing the internal plutonic body. These findings suggest that rear-arc regions could be the potential sites of continental crust formation in intra-oceanic convergent margins.

Rodingites occur in serpentine-matrix melange of the Nagasaki metamorphic rocks in Japan. Two types of rodingites can be distinguished on the basis of their mode of occurrence and mineralogical composition. One occurs as dikes, which contain a mineral assemblage of grossular, vesuvianite, diopside, apatite, titanite, and zircon. The other occurs as a block, which consists of zoisite, clinozoisite, diopside, chlorite, apatite, titanite, and zircon. The former type of rodingites posses two types of zircons: prismatic and porous. The prismatic zircons contain primary fluid inclusions indicating their crystallization in the presence of fluids. The porous zircons have extensive fractures filled by zircon, which are indicative of a hydrothermal origin. Both zircon types were thought to have formed under the influence of fluids. U–Pb ion probe analyses of prismatic zircons from the rodingites yield a weighted mean age of 108–105 Ma, suggesting the Early Cretaceous as the time of rodingitization in the subduction zone. Hafnium isotopic compositions of prismatic zircons are close to or overlap with the mid ocean ridge basalt (MORB) Hf isotopic ratio. This indicates that the fluid composition may have been reflected by the MORB composition during rodingitization. On the other hand, the low eHf values (11.8–18.9) of porous zircons suggest that they incorporate a small amount of Hf from fluid contaminated by subducted sediments. The rodingites are significantly enriched in Sr and depleted in large ion lithophile elements (LILE) (Cs, Rb, Ba). The fluid during rodingitization is able to extracts LILEs from the protolith of rodingites and adds Sr to the protolith of rodingites. The high field strength elements (HFSE) (Zr, Th, U, Nb, Ta) concentrations in the rodingites are similar to those of MORB, thus indicate their relatively immobile nature during rodingitization.

The Taishu Group, a marine formation with a thickness of >5400 m, crops out on Tsushima Island, located in the southwestern Japan Sea. The group, which is generally regarded as early Eocene to early Miocene in age, provides important information about the tectonic setting of the Japan Sea. In this study, we present new SHRIMP U–Pb dates for igneous zircons from the Kunehama Tuff, which is in the basal part of the Taishu Group, and the Oobaura Tuff, which is in the uppermost part of the group. Results show that the Taishu Group was deposited rapidly, during the short interval of 17.9–15.9 Ma (early–middle Miocene), and is equivalent to other early–middle Miocene strata found in the Japan Sea region. Our results provide new constraints on the geological history of the Japan Sea and its islands.

Zircons from two paragneisses (from Mount Sones and Dallwitz Nunatak) and one orthogneiss (from Gage Ridge) in the Tula Mountains, Napier Complex (East Antarctica) were analyzed for U-Pb age, oxygen isotopes, REEs and by scanning ion imaging. A large number of zircons from all samples are reversely discordant. Mount Sones zircons show an age range from 3.0 Ga to 2.5 Ga and underwent high-grade metamorphism at both ∼2.8 Ga and 2.5 Ga. Zircons from Dallwitz Nunatak record detrital ages between 3.5 Ga and 2.5 Ga. Zircons from Gage Ridge record multiple age groups, with concordant data between 3.6 Ga and 3.3 Ga and reversely discordant data that form a discrete ∼3.8 Ga population. All of the grains show evidence of Pb mobility during metamorphism. Ion imaging of zircons reveals Y and U zonation, characteristic of magmatic zircon, together with a micro-scale patchy distribution of 206Pb and 207Pb that does not correspond to either growth zonation or crystal imperfections. Some of these patches yield 207Pb/206Pb ages >4 Ga, whereas others yield ages younger than the magmatic crystallization age. Reversely discordant data are the result of ancient Pb mobilization, which is independent of the degree of metamictisation, oxygen isotope and REE content of the zircons. This mobilization can result in spurious ages and was most likely caused by polymetamorphism under anhydrous conditions; that is two high-grade events; one poorly defined at ∼2.8 Ga and the other ultra-high temperature (UHT) metamorphism at 2.5 Ga.

College of Geosciences, University of Tsukuba, Ibaraki 305-8572, Japan Faculty and Graduate School of Life and Environmental Sciences, University of Tsukuba, Ibaraki 305-8572, Japan Department of Geology, University of Johannesburg, Auckland Park 2006, South Africa Department of Earth Sciences, Chiba University, Chiba 263-8522, Japan Department of Applied Geology, Curtin University, Perth WA 6845, Australia

3 �AcademyofSciences,�InstituteofRockStructureandMechanics,�VHolesovickach�41,�182�09�Prague�8,�CzechRepublic * �Correspondingauthor The Bavarian Zone of the south-western Bohemian Massif is a late Variscan high heat-flow region, characterized by numerous granite intrusions and large amounts of LP-HT anatectic rocks, the latter comprising meta- and diatexites derived from sedimentary and igneous protoliths. Imaging and SIMS U-Pb dating of zircon from a distinctive type of hornblende-bearing diatexite, with a presumed igneous protolith, was done to gather information on both metamorphism and pre-anatectic crustal evolution. Zircon crystals have two phases of growth zoning, with oscillatory-zoned grains (visible through cathodoluminescence, CL, imaging) modified and surrounded by relatively uniform, high luminosity zircon. Analyses on oscillatory-zoned zircon yield an age of 344 ± 2 Ma (2σ), interpreted as the formation age of the igneous protolith. More luminescent overgrowths, interpreted as having formed during anatexis, were dated at 323 ± 3 Ma. Based on these dates, and on geochemical similarities, the protolith can be perfectly correlated with the high-K calc-alkaline Blatna suite of the Central Bohemian Plutonic Complex, c. 70 km to the north. This correlation strengthens tectonic models interpreting the Bavarian Zone as a reheated but integral constituent of the Variscan collisional crust of the Bohemian Massif, as opposed to an independent basement terrane assembled by late-Variscan orogenesis.

Sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon age dating was applied to several types of granulites and gneisses from the Lewisian Complex in South Harris, NW Scotland, to clarify the timing of Palaeoproterozoic tectono-thermal events. For comparison, monazite was dated using the chemical Th–U–total Pb isochron method (CHIME). The obtained U–Pb zircon age data were evaluated under the constrains of the modal amount of constituent minerals and whole-rock compositions of analysed samples, the zircon internal texture based on Th/U ratios, and the monazite CHIME ages. Zircons in three samples, characterised by zoned overgrowth rims, sector-zoned grains, and structureless high-U cores, yielded concordant ages of approximately 1900 Ma (1909 ± 3 Ma, 1899 ± 10, and 1888 ± 15 Ma, respectively). The age of 1899 ± 10 Ma, obtained from melanocratic granulite (garnet and kyanite/sillimanite: 76–91 vol.%), is interpreted to represent the timing of zircon crystallisation prior to the formation of restitic garnet and kyanite/sillimanite. Therefore, the age of ∼1900 Ma is proposed to represent the timing of early metamorphism, close to the thermal peak (M1). In the leucocratic gneiss (sample 93921-7), the age population at 1868 ± 35 Ma obtained from low-U and low-Th overgrowth rims represents a second stage of zircon growth from crystallising anatectic melt (M3), whereas the high-U cores represent the timing of zircon growth and recrystallisation prior to anatexis. Monazites from two leucocratic gneisses yield a relatively narrow range of CHIME ages: 1858 ± 7 Ma and 1840 ± 7 Ma. These ages probably represent the timing of zircon and monazite crystallisation from partial melt and resetting of the U–Th–Pb system. These results suggest that the timing of zircon formation was controlled by metamorphic processes, such as restite formation and crystallisation from partial melt.

The Bonin Ridge and trench slope preserves the geological record of subduction initiation and subsequent evolution of the Izu–Bonin–Mariana (IBM) arc. Diving and dredging in this region has revealed a bottom to top stratigraphy of: 1) mantle peridotite, 2) gabbroic rocks, 3) a sheeted dyke complex, 4) basaltic pillow lavas, 5) boninites and magnesian andesites, 6) tholeiites and calcalkaline arc lavas. This forearc stratigraphy is remarkably similar to that found in other IBM forearc localities and many ophiolites. Zircon U–Pb ages obtained here for gabbros are 51.6–51.7 Ma. The overlying basalts have 40Ar/39Ar ages of 48–52 Ma. A forearc basalt from the Mariana forearc near Guam produced a similar 40Ar/39Ar age of 51.1 Ma. The collective geochronology of igneous rocks from throughout the IBM system now indicates that the first basaltic magmatism at subduction initiation was produced by decompression melting of the mantle and took place at 51–52 Ma. The change to flux melting and boninitic volcanism took 2–4 m.y., and the change to flux melting in counterflowing mantle and “Normal” arc magmatism took 7–8 m.y. This evolution from subduction initiation to arc normalcy occurred nearly simultaneously along the entire length of the IBM subduction system. Mesozoic rocks found in the deep Bonin forearc suggest that the overriding plate at subduction initiation consisted of Mesozoic terranes and subduction preceded the opening of most or all of the Philippine Sea basins. The contemporaneousness of IBM forearc magmatism with the major change in plate motion in Western Pacific at ca. 50 Ma suggests that the two events are intimately linked.

Ion microprobe dating of zircon from meta-igneous samples of the Hitachi metamorphic terrane of eastern Japan yields Cambrian magmatic ages. Tuffaceous schist from the Nishidohira Formation contains ca 510 Ma zircon, overlapping in age with hornblende gneiss from the Tamadare Formation (ca 507 Ma), and meta-andesite (ca 507 Ma) and metaporphyry (ca 505 Ma) from the Akazawa Formation. The latter is unconformably overlain by the Carboniferous Daioin Formation, in which a granite boulder from metaconglomerate yields a magmatic age of ca 500 Ma. This date overlaps a previous estimate for granite that intrudes the Akazawa Formation. Intrusive, volcanic, and volcaniclastic lithologies are products of a Cambrian volcanic arc associated with a continental shelf, as demonstrated by the presence of arkose and conglomerate in the lowermost Nishidohira Formation. Granitic magmatism of Cambrian age is unknown elsewhere in Japan, except for a single locality in far western Japan with a similar geological context. Such magmatism is also unknown on the adjacent Asian continental margin, with the exception of the Khanka block in far northeastern China. A ‘great hiatus’ in the Paleozoic stratigraphy of the Sino–Korean block also exists in the Hitachi terrane between Cambrian volcanic arc rocks and Early Carboniferous conglomerate, and may indicate a common paleogeographic provenance.

We present zircon and monazite U-Pb data from ultrahigh-temperature (UHT) metamorphosed orthogneisses and paragneisses collected from key areas of the Eastern Ghats Belt, India. The results show contrasting tectonothermal histories in different isotopic domains of the Eastern Ghats Belt that were identified by previous workers. Of particular importance is the discovery of a ca. 1760 Ma event (concordia age) in the southern domain 1A, which is interpreted to be the age of an early UHT metamorphism event. This was followed by a second granulite-facies metamorphism event and partial melting at ca. 1600 Ma. This domain was presumably cratonized with India at around 1600 Ma. The record of the ca. 1760–1600 Ma events in domain 1A of the Eastern Ghats Belt allows us to speculate on modeling the Paleoproterozoic–Mesoproterozoic transcontinental correlation. The accretionary orogenic processes in the supercontinent Columbia encompassed Australia, Antarctica, Laurentia, and parts of India. The central part of Eastern Ghats Belt (isotopic domain 2), on the other hand, contains zircons showing inherited ages of ca. 1880–1700 Ma, with a concordant age group of ca. 1760 Ma. Moderately to strongly discordant ages in the time span of ca. 1600–1100 Ma in domain 2 are interpreted to be mixing ages as a result of strong overprint of a ca. 1030–900 Ma tectonothermal event(s) that affected this domain. An early UHT metamorphism event in this domain is inferred to have occurred at ca. 1030–990 Ma (chemical dating of included monazite grains). Zircon records the most pervasive tectonothermal event in this domain at ca. 980–900 Ma, which is correlative with the Rayner orogeny in East Antarctica as a part of the formation of Rodinia.

The Izu Peninsula, central Japan, is situated in a zone where the active intra-oceanic Izu–Bonin arc has been colliding end-on with the mainland Honshu arc for the past 15 million years. As a result of this arc–arc collision, parts of the submarine Izu–Bonin upper crustal sequences have been accreted and uplifted to form the Izu Peninsula, exposing seafloor volcaniclastic deposits, associated lava flows, and coeval intrusive bodies. Parts of this sequence have been subjected to extensive hydrothermal alteration, and these altered rocks have previously been interpreted as representative of hypothetical widespread Middle Miocene basement that presumably underlay northern Izu–Bonin arc volcanoes. New zircon U–Pb ages presented here, however, show that both fresh and altered volcanic sequences exposed in Izu Peninsula are broadly contemporaneous and were products of the same Late Miocene to Pleistocene magmatism. Geochemical characteristics of these sequences show them to have formed in the Izu–Bonin rear-arc environment, providing an unusual opportunity to investigate in detail the growth and architecture of a rear-arc region in an active intra-oceanic arc. Moreover, zircon ages from altered basal units of Kozushima and Niijima, Quaternary volcanic islands in the northern Izu–Bonin rear-arc, show that these islands rest on units only slightly older (

The Godzilla megamullion is the largest oceanic core complex (OCC) currently known, and is adjacent to the spreading center of the Parece Vela Basin (PVB), an extinct backarc basin in the Philippine Sea. The duration and termination of tectonomagmatic processes during OCC formation are poorly constrained, due to the weak geomagnetic anomalies in the region. Zircon U-Pb dating of gabbroic and leucocratic rocks from the Godzilla megamullion reveals that fault-induced spreading over the ∼125 km length of the OCC lasted for ∼4 m.y., with continuous magmatic accretion at the spreading axis. The latest magmatism constrains the cessation of PVB spreading to ca. 7.9 Ma or later, significantly younger than a previous estimate of ca. 12 Ma. The new ages show that backarc basin formation migrated to the present-day Mariana Trough soon after the cessation of spreading in the PVB.

We applied SHRIMP zircon U-Pb age dating to ultrahigh-temperature (UHT) sapphirine-bearing orthopyroxene garnet (SOG) granulite and biotite-hornblende (Bt-Hbl) gneiss in the Schirmacher Hills, East Antarctica. In the Bt-Hbl gneiss, concordant ages of and Ma were obtained from zircon overgrowth rims and zircon cores, with oscillatory and irregular zoning, respectively. The zircon overgrowth rims ( Ma) with low Th/U ratios from the Bt-Hbl gneiss are interpreted as having a metamorphic origin. Oscillatory-zoned and/or irregularly zoned zircon cores may have crystallized during an igneous event at Ma; 800-Ma igneous events have not previously been recognized in central Dronning Maud Land (DML) inland nunatak. Zircons in the SOG granulite yielded a concordant age of Ma, using analyses of sector-zoned and simple-zoned grains. These zircons have relatively high Th/U ratios with a narrow range, and they occur in association with garnet breaking down to form cordierite. The -Ma age obtained from these zir...

Integrated structural, petrological and geochronological study on a suite of granulites from the central part of the Eastern Ghats Belt (EGB), India unveils polyphase tectonothermal evolution. We document (a) M1 ultrahigh temperature (UHT) metamorphism (∼1000°C at 6.5–8.5 kbar) on an anticlockwise P–T trajectory simultaneously with early deformations D1–D2 involving partial melting, (b) cooling down to ∼ 800°C, 6 kbar that produced a variety of coronae/symplectites (M1R), (c) an unrelated compressional orogeny (D3) that produced deep crustal shears and mylonitic foliation (S3m) at low angles to D1–D2 structures and was associated with slight loading, and possible partial melt extraction under granulite facies condition (M2 ∼7 kbar, 850°C), and (d) localized retrogression (M3) in the presence of melt accompanying D4 deformation. This is the first record of the prograde P–T path of the superimposed granulite facies metamorphism in the EGB. U-Pb SHRIMP data of zircon preserves an inherited grain domain of ca. 1700 Ma (207Pb-206Pb age) that traces back the history of EGB with a lineage of the Mesoproterozoic supercontinent, Columbia. The UHT metamorphosed (peak M1 at ca. 1000 Ma) and subsequently cooled crustal segment (M1R) was subjected to strong tectonothermal reworking (M2) along a clockwise P–T path at 953 + 6 Ma (concordia age) that partially exhumed the rocks to mid-crustal levels. A later fluid-induced retrogressive event vis-a-vis melt crystallization occurred at ca. 900 Ma (207Pb-206Pb age). The post-peak evolution reveals striking similarities with those recorded in the rocks of the Rayner Complex of east Antarctica, thereby strengthening the notion of Indo-Antarctic correlation as part of Rodinia. Copyright © 2010 John Wiley & Sons, Ltd.

The Tanzawa plutonic complex (TPC), central Japan, is a suite of tonalitic-gabbroic plutons exposed in a globally unique arc-arc collision zone, where an active intraoceanic Izu-Bonin-Mariana (IBM) arc is colliding against the Honshu arc. The TPC has been widely accepted as an exposed middle crust section of the IBM arc, chiefly because of geochemical similarities between the TPC and IBM rocks and previously reported precollisional Miocene K-Ar ages. However, new zircon U-Pb ages show that the main pulse of TPC magmatism was syncollisional and that plutons were emplaced rapidly and cooled soon after Pliocene collision. Trace element compositions of TPC zircon show distinctively elevated Th/Nb ratios compared to zircon from other noncollisional IBM silicic plutonic rocks, indicating the involvement of continental sediments from the Honshu arc in their magma genesis.

Kyanite and andalusite are newly found in migmatized pelitic granulites from the Kerala Khondalite Belt, Southern India. Anhedral tiny grains of kyanite included within altered cordierite were interpreted as possible remnants of prograde metamorphism of the granulites within the kyanite stability field. Andalusite shows two distinct modes of occurrence; some are of magmatic origin and others are formed as partial replacement products of alkali-feldspar and plagioclase mainly in leucosomes. Our data put new constraints not only on the P-T path followed by the granulites but also on the correlation between the Gondwana fragments. The Kerala Khondalite Belt is closely correlated with the Southwestern Group (southwestern part of the Highland Complex) in Sri Lanka.