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In this work, we report an innovative pump-probe based experimental set up, to study the melting, subsequent evaporation, plasma formation and redeposition in a thin film coated on a glass substrate under different ambient conditions and laser fluences. The ambient conditions restrict the expansion of the plasma plume. At high ambient pressure, plume expansion stops closer to the substrate and get re-deposited at the site of the ablation. This helps in the identification of multiple processes and their temporal evolutions during the melting, expansion and re-deposition stages. The ambient conditions affect the plasma plume formed upon ablation, thus modulating the transmission of probe laser pulses, which provides information about the plume dynamics. Further, the study offers valuable insights into the laser-based ablation of thin film coatings, which will have implications in in situ cleaning of view ports on large experimental facilities such as tokamaks and other systems e.g. coating units, pulsed laser deposition, Laser induced forward transfer, Laser surface structuring, etc.

Laser-induced breakdown spectroscopy (LIBS) is a well-established technique widely used in fundamental research and diverse practical fields. Polarization-resolved LIBS, a variant of this technique, aims to improve the sensitivity, which is a critical aspect in numerous scientific domains. In our recent work we demonstrated that the degree of polarization (DOP) in the emission depends on the spatial location and time in a nano second laser generated aluminium plasma1. Present study investigates the effect of polarized emission on the estimation of plasma parameters. The plasma parameters are estimated using the conventional spectroscopic methods such as Boltzmann plot and line intensity ratio for the estimation of electron temperature and Stark broadening for estimating the electron density. The estimated plasma temperature using Boltzmann plot method shows large errors in electron temperature for the locations where DOP is higher. However, the electron density estimated using the Stark width does not show such variation. The observed ambiguity in temperature estimation using the Boltzmann plot method appears to be a consequence of deviation from expected Maxwell Boltzmann distribution of population of the involved energy levels. These findings highlight the need of assessing the DOP of the plasma before selecting the polarization for PRLIBS or temperature estimation using Boltzmann plots in elemental analysis.