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Physical and compositional measurements are made at the ~ 7 km-long (~ 2200 years B.P.) Kings Bowl basaltic fissure system and surrounding lava field in order to further understand the interaction of fissure-fed lavas with phreatic explosive events. These assessments are intended to elucidate the cause and potential for hazards associated with phreatic phases that occur during basaltic fissure eruptions. In the present paper we focus on a general understanding of the geological history of the site. We utilize geospatial analysis of lava surfaces, lithologic and geochemical signatures of lava flows and explosively ejected blocks, and surveys via ground observation and remote sensing. Lithologic and geochemical signatures readily distinguish between Kings Bowl and underlying pre-Kings Bowl lava flows, both of which comprise phreatic ejecta from the Kings Bowl fissure. These basalt types, as well as neighboring lava flows from the contemporaneous Wapi lava field and the older Inferno Chasm vent and outflow channel, fall compositionally within the framework of eastern Snake River Plain olivine tholeiites. Total volume of lava in the Kings Bowl field is estimated to be ~ 0.0125 km3, compared to a previous estimate of 0.005 km3. The main (central) lava lake lost a total of ~ 0.0018 km3 of magma by either drain-back into the fissure system or breakout flows from breached levees. Phreatic explosions along the Kings Bowl fissure system occurred after magma supply was cut off, leading to fissure evacuation, and were triggered by magma withdrawal. The fissure system produced multiple phreatic explosions and the main pit is accompanied by others that occur as subordinate pits and linear blast corridors along the fissure. The drop in magma supply and the concomitant influx of groundwater were necessary processes that led to the formation of Kings Bowl and other pits along the fissure. A conceptual model is presented that has relevance to the broader range of low-volume, monogenetic basaltic fissure eruptions on Earth, the Moon and other planetary bodies.

We have measured the induced thermoluminescence (TL) properties of fifteen samples of basalts collected from the Big Island of Hawaii in order to continue our investigation into the possible utility of this technique as a chronometer. Previous studies of basalts from Idaho have suggested the induced TL of basalts increases with age. Meteorite data suggest two possible explanations for this observation which are that (1) the initial glassy or amorphous phases crystalize with time to produce feldspar, the mineral producing the TL signal, and (2) feldspars lose Fe as they equilibrate and since Fe is a quencher of TL this would cause an increase in TL. The old basalts from Kohala (> 100 ka), which are mostly alkali basalts, have TL sensitivities 10–100 times higher than the much younger tholeiites from Kilauea and Mauna Loa (

In order to find an additional quantitative way to estimate the petrographic type of unequilibrated ordinary chondrites (UOC), and one that can be used remotely in the study of asteroids, we have analyzed the near-infrared spectra of a suite of UOC observed falls. We obtained spectra from the RELAB database at Brown University and applied several methods for determining the amount of clinopyroxene (CPX) as a percentage of the total pyroxene in the meteorites. The presence of low-Ca CPX has long been known to be characteristic of little-metamorphosed ordinary chondrites. The methods we used were (1) naked-eye determination of the wavelength of the absorption features at ~1 μm and ~2 μm, (2) determination of the wavelengths of these features by fitting polynomial equations, and (3) determining the relative intensities of the CPX and OPX features after isolation by a curve fitting procedure. The measurements were then “calibrated” using data from the literature to obtain values for the amount of CPX in the total pyroxene. We find that there is an empirical relationship between the amount of CPX detected by these methods of spectrum analysis and the petrologic type. Petrologic type = + 4.402 – 0.019 × CPX % We explain this empirical relationship (1) as evidence that in pyroxene bearing rocks the spectrum of pyroxene dominates (this has been known in the 1970s), (2) that low-Ca CPX is so abundant in these meteorites (up to 40 vol%) that it is easily detected by reflectance spectroscopy, and (3) compositional effects caused by Ca and Fe in the pyroxenes partially cancel out or are small. We thus have a new method of quantitatively measuring the level of metamorphic alteration experienced by these important meteorites and of assigning them a petrologic type of 3.0 to 3.9. More importantly, unlike existing methods, this can be applied remotely so that chondritic asteroid surfaces (i.e. those of Q and S asteroids) can also be characterized in terms of their metamorphic history. As an example, (433) Eros and (25143) Itokawa were found to be types ~3.5 and ~3.4, respectively. We briefly discuss the implications of this for understanding the history of meteorites and asteroids.

In order to continue our investigation into the possible utility of induced thermoluminescence as a chronometer for volcanic activity we have measured the induced thermoluminescence properties of twenty-eight samples collected from the almost 3 km long Blue Dragon flow at Craters of the Moon National Monument and Preserve, Idaho. The properties of the samples are consistent with previous conclusions that the major mineral causing the luminescence is feldspar and that variation in the glow curves (light emitted as a function of heating temperature) is caused by variations in the thermal history of the samples. However, in nine of the 28 samples a there is a significant contribution to the TL signal from apatite. The induced thermoluminescence level along the flow is essentially constant, showing at most a factor of four decrease from beginning to the end (from ∼16 to ∼4, on a scale of the Dhajala meteorite = 1000), and this is not statistically significant. Thus sampling distance from the vent should not be a problem for the proposed TL dating method. However, there are details that might pose a problem for dating. (1) There is considerable (factor of 10 or so) scatter in the TL data due to the high heterogeneity of the samples. (2) There are abundant highly luminescent spherules which could explain some of the scatter; however, they are restricted to samples taken very close to the vent and could be screened from TL samples using cathodoluminescence, a microscopic means of identifying components producing the TL. (3) There is a factor of three increase in crystallization along the core (from ∼20 vol% to ∼60 vol%) but no factor of three increase in induced TL value. This is additionally problematic because crystallization is accompanied by a small decrease in anorthite content of the feldspar which should further increase induced TL values. While empirical data suggest that there is a weak correlation between induced TL and age for volcanics from Idaho and Hawaii, our detailed study of the Blue Dragon flow removes one complication for the dating method but reveals many details that need to be kept in mind as this possible dating method is explored. Most importantly, we need a method for reducing the scatter in induced TL displayed by samples from a single volcanic eruption.

Basaltic eruptive fissures of the Great Rift and surroundings on the eastern Snake River Plain of Idaho, USA, and selected volcanic features in Hawai’i, Iceland and northern Africa were surveyed for their relevancy as planetary analogs. Evaluated during field investigations and in satellite imagery for structures, physiography, and geologic setting, fissures were categorized into four broad types: (1) simple, monogenetic fissures with obvious volcanic constructs or deposits, (2) monogenetic fissures now obscured by low shields or relatively large cones, (3) polygenetic volcanic rift zones with multiple vents and deposits, and (4) compound regional fissure systems or dike swarms that comprise major rift zones or large volcanic terrains. Using this classification as an initial base, we surveyed imagery of volcanic features for likely fissure vents in two major geologic settings on the Moon: floor-fractured craters (FFCs) and mare and cryptomare provinces. Two major regions on Mars, the volcanic plains around Alba Mons and the greater Tharsis region, were also surveyed for fissure types and volcanic associations of fissure-like features. The planetary surveys suggest that the proposed classification provides a suitable analog starting point to interpret structures associated with fissure systems on the Moon and Mars. With few exceptions, our survey indicates that each of the studied terrains exhibits a dominant fissure type. Type 1 fissures, most with pyroclastic deposits, prevail in lunar FFCs and mare-like regions; whereas type 2 fissures are ubiquitous in the Tharsis region of Mars and a few exist on the Moon as low shields. Type 3 volcanic rift zones are not common on either the Moon or Mars, although they might become evident in future work on chemically evolved terrains. Type 4 fissures are inferred in mare terrains, often represented as the extensions of major linear rille networks or rimae, with possibly complex dike swarms that were buried beneath voluminous mare basalt lava flows. Likewise, numerous flood lavas on Mars are possibly associated with now-obscured or difficult to define type 4 fissure systems.

The “ponds” on asteroid (433) Eros are fine-grained deposits approximating flat (quasi-equipotential) surfaces with respect to local topographic depressions (e.g., craters) in spacecraft images. These ponds are discussed in the context of laboratory simulation experiments, crater-related ponded and pitted deposits observed on Mars and Vesta, terrestrial phreatic craters, and degassing features associated with eroded impact craters on Earth. While the details of formation of these features on Mars, Vesta and the Earth are thought to be different, they all include mechanisms that require the interactions between surface materials and volatiles (e.g., water vapor). Indeed, analogous features similar to the Eros ponds can be reproduced in the laboratory by the release of vapor (ice sublimation, water evaporation, or N2) through an unconsolidated regolith (independent of regolith composition). Eros is widely thought to be dry, but the discovery of exogenic water on Vesta, and recent arguments that subsurface water might be present in the inner asteroid belt suggest that endogenic water might also be present and serve as a source of the gases produced in the ponds. The amount of water required is comparable to the amount of water observed in little-metamorphosed ordinary chondrites (a few wt%). The primary morphologic characteristics of the Eros ponds can be explained in this model. The heat source for degassing could have been solar heating following transfer from a main belt orbit to a near Earth orbit. Although other hypotheses (e.g., electrostatic levitation, seismic shaking, and comminution of boulders) can account for most of the features of the ponds, recent observations regarding the role of volatiles on planetary surfaces, our laboratory experiments, and fluidization deposits on active comets suggests that degassing is a reasonable hypothesis to be considered and further tested for explaining the Eros ponds, and similar features on other bodies.

Perchlorate ( ClO 4 − ) and chlorate ( ClO 3 − ) are ubiquitous on Earth and ClO 4 − has also been found on Mars. These species can play important roles in geochemical processes such as oxidation of organic matter and as biological electron acceptors, and are also indicators of important photochemical reactions involving oxyanions; on Mars they could be relevant for human habitability both in terms of in situ resource utilization and potential human health effects. For the first time, we extracted, detected and quantified ClO 4 − and ClO 3 − in extraterrestrial, non-planetary samples: regolith and rock samples from the Moon, and two chondrite meteorites (Murchison and Fayetteville). Lunar samples were collected by astronauts during the Apollo program, and meteorite samples were recovered immediately after their fall. This fact, together with the heterogeneous distribution of ClO 4 − and ClO 3 − within some of the samples, and their relative abundance with respect to other soluble species (e.g., NO 3 − ) are consistent with an extraterrestrial origin of the oxychlorine species. Our results, combined with the previously reported widespread occurrence on Earth and Mars, indicate that ClO 4 − and ClO 3 − could be present throughout the Solar System.

A piece of the Sutter's Mill meteorite, fragment SM2-1d, has been examined using thermoluminescence techniques to better understand its thermal and metamorphic history. The sample had very weak but easily measureable natural and induced thermoluminescence (TL) signals; the signal-to-noise ratio was better than 10. The natural TL was restricted to the high-temperature regions of the glow curve suggesting that the meteorite had been heated to approximately 300 °C within the time it takes for the TL signal to recover from a heating event, probably within the last 105 years. It is possible that this reflects heating during release from the parent body, close passage by the Sun, or heating during atmospheric passage. Of these three options, the least likely is the first, but the other possibilities are equally likely. It seems that temperatures of approximately 300 °C reached 5 or 6 mm into the meteorite, so that all but one of the small Sutter's Mill stones have been heated. The Dhajala normalized induced TL signal for SM2-1d is comparable to that of type 3.0 chondrites and is unlike normal CM chondrites, the class it most closely resembles, which do not have detectable TL sensitivity. The shape of the induced TL curve is comparable to other low-type ordinary, CV, and CO chondrites, in that it has a broad hummocky structure, but does not resemble any of them in detail. This suggests that Sutter's Mill is a unique, low-petrographic–type (3.0) chondrite.

The Mg isotopic compositions of 47 well-characterized lunar samples, including mare basalts, highland rocks, regolith breccias, and mare and highland soils were measured to address the behavior of Mg isotopes during lunar magmatic differentiation, constrain the Mg isotopic composition of the Moon, and evaluate the degree of Mg isotopic fractionation between planetary bodies. The δ 26 Mg values range from −0.61 ± 0.03‰ to 0.02 ± 0.06‰ in 22 mare basalts, from −0.34 ± 0.04‰ to −0.18 ± 0.06‰ in 3 highland rocks, from −0.33 ± 0.05‰ to −0.14 ± 0.08‰ in 7 regolith breccias, from −0.23 ± 0.05‰ to −0.14 ± 0.07‰ in 6 highland soils, and from −0.41 ± 0.05‰ to −0.20 ± 0.09‰ in 9 mare soils. The limited Mg isotopic variation among bulk mare and highland soils and regolith breccias indicates negligible Mg isotope fractionation by lunar surface processes. By contrast, the large Mg isotopic fractionation between low-Ti and high-Ti basalts suggests the source heterogeneity produced during fractional crystallization of the lunar magma ocean, with ilmenite having lighter Mg isotopic compositions than olivine and pyroxene. Overall, the Moon has a weighted average Mg isotopic composition (δ 26 Mg = −0.26 ± 0.16‰) indistinguishable from the Earth (δ 26 Mg = −0.25 ± 0.07‰) and chondrites (δ 26 Mg = −0.28 ± 0.06‰), suggesting homogeneous Mg isotopic distribution in the solar system and the lack of Mg isotope fractionation during the Moon-forming giant impact.

In this interview, Dieter Stoffler (Fig. 1) describes how his interest in meteorites and impact craters dates from his Ph.D. studies at the University of Tubingen when it was learned that the Ries crater was formed by impact. A paper by Dieter's advisor, Wolf von Engelhardt, also triggered an interest in meteorites. After graduation, Dieter helped to establish a laboratory for high pressure mineralogy and he examined rocks from the Ries crater, which led to the concept of progressive shock metamorphism. The group also worked on newly returned Apollo samples and guided astronauts over the crater. A year at the NASA Ames Research Center taught Dieter about experimental impact research with a light-gas gun. After a few more years at Tubingen, Dieter obtained a professorship at the University of Munster where he created the Institute of Planetology, got involved in planning space missions including comet sample return, and continued high pressure mineralogy in collaboration with colleagues in Freiburg. Through several decades of research, Dieter and colleagues have documented the effects of shock on all the major rock-forming minerals and devised widely accepted schemes for the classification of shocked rocks. After the unification of Germany, Dieter became Director of the Natural History Museum in Berlin, during which he made much progress rebuilding the laboratories and the collections. Dieter also helped to create a museum and research center in the Ries crater. He received the Barringer Award of the Meteoritical Society in 1994 and several prestigious awards in Germany.

In this interview, Donald Burnett (Fig. 1) describes how he applied to the University of Chicago, with considerable support from his father, where he took classes from Harold Urey and was inspired by Ed Anders to pursue a career in nuclear chemistry and, later, cosmochemistry. As a graduate student at the University of California at Berkeley, Don learned to use charged-particle tracks as a detector for radioactive nuclei, a technique that he applied to a wide variety of problems over the next 20 years, including the neutron profile probe that was deployed on the Moon. After a one-year postdoc with William Fowler at the California Institute of Technology, he became involved with Jerry Wasserburg, who ultimately obtained a faculty position for him in the Geology Division. Since then, Don has worked on a number of fundamental problems in cosmochemistry, chronology of the solar system, the initial Pu/U abundance, fractionation of U and Pu in igneous processes, and elemental abundances. This last interest led him to advocate, propose, and lead the Genesis space mission to collect and return samples of the solar wind. The crash of the return capsule caused alarm, but some aspects of the mission were unaffected and others have been successfully handled, so that several major new results have been published: the lack of an SEP component in lunar samples, the Ne and Ar composition of the solar wind, and, most importantly, the oxygen and nitrogen isotopic composition of the Sun. Don received the Leonard Medal in 2012.

Early work on meteorite thermoluminescence (TL), influenced by pottery dating and dosimetry applications, demonstrated a relationship between natural thermoluminescence and (1) the orbital perihelion and (2) the terrestrial age (time since fall) of a meteorite. For 14 years natural TL measurements were routinely made on newly recovered Antarctic meteorites to help identify unusual thermal and radiation histories, and to sort them by terrestrial age and perihelion. Two examples of the value of such data are presented, an Antarctic meteorite that underwent a major orbit change prior to fall, and the collection mechanics of meteorites at the Lewis Cliff ice field. A second major area of focus for meteorite TL that has no non-meteorite heritage, is the use of their induced TL to provide an extraordinarily sensitive and quantitative means of exploring metamorphic intensity and palaeothermometry. While especially valuable for unequilibrated ordinary chondrites, these types of measurement have proved useful with virtually every major class of meteorite, asteroidal and planetary. The challenge now is to extend the technique to small particles, micrometeorites, interplanetary dust particles, and cometary particles.

Asteroid 2008 TC3 was characterized in a unique manner prior to impacting Earth's atmosphere, making its October 7, 2008, impact a suitable field test for or validating the application of high-fidelity re-entry modeling to asteroid entry. The accurate modeling of the behavior of 2008 TC3 during its entry in Earth's atmosphere requires detailed information about the thermophysical properties of the asteroid's meteoritic materials at temperatures ranging from room temperature up to the point of ablation (T ~ 1400 K). Here, we present measurements of the thermophysical properties up to these temperatures (in a 1 atm. pressure of argon) for two samples of the Almahata Sitta meteorites from asteroid 2008 TC3: a thick flat-faced ureilite suitably shaped for emissivity measurements and a thin flat-faced EL6 enstatite chondrite suitable for diffusivity measurements. Heat capacity was determined from the elemental composition and density from a 3-D laser scan of the sample. We find that the thermal conductivity of the enstatite chondrite material decreases more gradually as a function of temperature than expected, while the emissivity of the ureilitic material decreases at a rate of 9.5 × 10−5 K−1 above 770 K. The entry scenario is the result of the actual flight path being the boundary to the load the meteorite will be affected with when entering. An accurate heat load prediction depends on the thermophysical properties. Finally, based on these data, the breakup can be calculated accurately leading to a risk assessment for ground damage.

– We have obtained near-infrared spectra for near-Earth asteroids (NEA) and Main Belt asteroids by using NASA’s Infrared Telescope Facility. Most of the S complex classes of the Tholen-Bus-DeMeo scheme and the S(I)–S(VII) classes are represented. To help interpret the results, we examined visible/near-IR spectra for ordinary chondrites. The unequilibrated ordinary chondrites (UOC) spectra contain a 2.3 μm feature which is absent in the spectra of the equilibrated ordinary chondrites (EOC). On the basis of literature data and new spectra low-Ca clinopyroxenes, we suggest that the 2.3 μm in UOC is due to the presence of low-Ca clinopyroxene in the UOC which is absent in EOC. While this difference can be seen in the raw spectra, we confirmed this observation using a modified Gaussian model (MGM) for spectral analysis. Both the UOC and the EOC plot in the S(IV) field of the band area ratio plot for asteroids. We suggest that many or most S(IV) asteroids have material resembling UOC on their surfaces. An internally heated ordinary chondrite parent object would have EOC material at depth and UOC material on the surface. Cosmic ray exposure ages, and K-Ar ages for L chondrites, indicate that most EOC came from relatively few objects; however, the age distributions for UOC are unlike those of EOC. We suggest that while EOC come from the interiors of a limited number of S(IV) asteroids, the UOC come from the surfaces of a large number of S(IV) asteroids.

– In this interview, Dale Cruikshank (Fig. 1) explains how as an undergraduate at Iowa State University he was a summer student at Yerkes Observatory where he assisted Gerard Kuiper in work on his Photographic Lunar Atlas. Upon completing his degree, Dale went to graduate school at the University of Arizona with Kuiper where he worked on the IR spectroscopy of the lunar surface. After an eventful 1968 trip to Moscow via Prague, during which the Soviets invaded Czechoslovakia, Dale assumed a postdoc position with Vasili Moroz at the Sternberg Astronomical Institute and more observational IR astronomy. Upon returning to the United States and after a year at Arizona, Dale assumed a position at the University of Hawai’i that he held for 17 years. During this period Dale worked with others on thermal infrared determinations of the albedos of small bodies beyond the asteroid Main Belt, leading to the recognition that low-albedo material is prevalent in the outer solar system that made the first report of complex organic solids on a planetary body (Saturn’s satellite Iapetus). After moving to Ames Research Center, where he works currently, he continued this work and became involved in many outer solar system missions. Dale has served the community through his involvement in developing national policies for science-driven planetary exploration, being chair of the DPS 1990–1991 and secretary/treasurer for 1982–1985. He served as president of Commission 16 (Physics of Planets) of the IAU (2001–2003). He received the Kuiper prize in 2006. Figure 1. Dale P. Cruikshank. Download figure to PowerPoint

– Klaus Keil (Fig. 1) grew up in Jena and became interested in meteorites as a student of Fritz Heide. His research for his Dr. rer. nat. became known to Hans Suess who––with some difficulty––arranged for him to move to La Jolla, via Mainz, 6 months before the borders of East Germany were closed. In La Jolla, Klaus became familiar with the electron microprobe, which has remained a central tool in his research and, with Kurt Fredriksson, he confirmed the existence of Urey and Craig’s chemical H and L chondrite groups, and added a third group, the LL chondrites. Klaus then moved to NASA Ames where he established a microprobe laboratory, published his definitive paper on enstatite chondrites, and led in the development of the Si(Li) detector and the EDS method of analysis. After 5 years at Ames, Klaus became director of the Institute of Meteoritics at the University of New Mexico where he built up one of the leading meteorite research groups while working on a wide variety of projects, including chondrite groups, chondrules, differentiated meteorites, lunar samples, and Hawai’ian basalts. The basalt studies led to a love of Hawai’i and a move to the University of Hawai’i in 1990, where he has continued a wide variety of meteorite projects, notably the role of volcanism on asteroids. Klaus Keil has received honorary doctorates from Friedrich-Schiller University, Jena, and the University of New Mexico, Albuquerque. He was President of the Meteoritical Society in 1969–1970 and was awarded the Leonard Medal in 1988. Figure 1. Klaus Keil at the University of Hawai’i at Manoa, 2007. Download figure to PowerPoint

– John Wood (Fig. 1) was trained in Geology at Virginia Tech and M.I.T. To fulfill a minor subject requirement at M.I.T., he studied astronomy at Harvard, taking courses with Fred Whipple and others. Disappointed at how little was known in the 1950s about the origin of the earth, he seized an opportunity to study a set of thin sections of stony meteorites, on the understanding that these might shed light on the topic. This study became his Ph.D. thesis. He recognized that chondrites form a metamorphic sequence, and that idea proved surprisingly hard to sell. After brief service in the Army and a year at Cambridge University, John served for 3 years as a research associate with Ed Anders at the University of Chicago. He then returned to the Smithsonian Astrophysical Observatory in Cambridge, Massachusetts, where he spent the remainder of his career. At Chicago, he investigated the formation of the Widmanstatten structure, and found that the process informs us of the cooling rates of iron meteorites. Back in Cambridge, he collaborated with W. R. Van Schmus on a chondrite classification that incorporates metamorphic grade, and published on metal grains in chondrites, before becoming absorbed by preparations for the return of lunar samples by the Apollo astronauts. His group’s work on Apollo samples helped to establish the character of the lunar crust, and the need for a magma ocean to form it. Wood served as President of the Meteoritical Society in 1971–72 and received the Leonard Medal in 1978. Figure 1. John Wood. Download figure to PowerPoint

– In this interview, Joseph Goldstein (Fig. 1) recounts how he became interested in meteorites during his graduate studies working with Robert Ogilvie at MIT. By matching the Ni profiles observed across taenite fields in the Widmanstatten structure of iron meteorites with profiles he computed numerically he was able to determine cooling rates as the meteorites cooled through 650–400 °C. Upon graduating, he worked with a team of meteorite researchers led by Lou Walter at Goddard Space Flight Center where for 4 years he attempted to understand metallographic structures by reproducing them in the laboratory. Preferring an academic environment, Joe accepted a faculty position in the rapidly expanding metallurgy department at Lehigh University where he was responsible for their new electron microprobe. He soon became involved in studying the metal from lunar soils and identifying the metallic component from its characteristic iron and nickel compositions. Over the next two decades he refined these studies of Ni diffusion in iron meteorites, particularly the effect of phosphorus in the process, which resulted in superior Fe-Ni-P phase diagrams and improved cooling rates for the iron meteorites. After a period as vice president for research at Lehigh, in 1993 he moved to the University of Massachusetts to serve as dean of engineering, but during these administrative appointments Joe produced a steady stream of scientific results. Joe has served as Councilor, Treasurer, Vice President, and President of the Meteoritical Society. He received the Leonard Medal in 2005, the Sorby Award in 1999, and the Dumcumb Award for in 2008. Figure 1. Joseph Goldstein. Download figure to PowerPoint

– In this interview, Grenville Turner (Fig. 1) recounts how he became interested in meteorites during postdoctoral research with John Reynolds at the University of California, Berkeley, after completing a DPhil with Ken Mayne at the University of Oxford. At Berkeley, he worked on xenon isotopes with fellow students Bob Pepin and Craig Merrihue, but Reynolds’ insistence that they analyze all the inert gases in their samples meant that they also made important contributions to Ne isotope studies and potassium-argon dating leading to the Ar-Ar technique. In 1964, Grenville obtained a teaching position at the University of Sheffield where he developed his own laboratory for inert gas isotope measurements. After the return of samples from the Moon by the Apollo program, he became involved in determining the chronology of volcanism and major impacts on the Moon. In 1988, Grenville and his team moved to the University of Manchester as part of a national reorganization of earth science departments. During the post Apollo years, Grenville’s interest turned to the development of new instrumentation (resonance ionization mass spectrometry and the ion microprobe), and to problems in terrestrial isotope geochemistry, particularly the source of inert gases in fluid inclusions. He received the Leonard Medal of the Meteoritical Society in 1999, and he has also received awards from the Royal Society, the European Association of Geochemistry, and the Royal Astronomical Society. Figure 1. Grenville Turner. Download figure to PowerPoint

– Donald D. Bogard (Don, Fig. 1) became interested in meteorites after seeing the Fayetteville meteorite in an undergraduate astronomy class at the University of Arkansas. During his graduate studies with Paul Kuroda at Arkansas, Don helped discover the Xe decay products of 244Pu. After a postdoctoral period at Caltech, where he learned much from Jerry Wasserburg, Peter Eberhardt, Don Burnett, and Sam Epstein, Don became one of a number of young Ph.D. scientists hired by NASA’s Manned Spacecraft Center to set up the Lunar Receiving Laboratory (LRL) and to perform a preliminary examination of Apollo samples. In collaboration with Oliver Schaeffer (SUNY), Joseph Zahringer (Max Planck, Heidelberg), and Raymond Davis (Brookhaven National Laboratory), he built a gas analysis laboratory at JSC, and the noble gas portion of this laboratory remained operational until he retired in 2010. At NASA, Don worked on the lunar regolith, performed pioneering work on cosmic ray produced noble gas isotopes and Ar-Ar dating, the latter for important insights into the thermal and shock history of meteorites and lunar samples. During this work, he discovered that the trapped gases in SNC meteorites were very similar to those of the Martian atmosphere and thus established their Martian origin. Among Don’s many administrative accomplishments are helping to establish the Antarctic meteorite and cosmic dust processing programs at JSC and serving as a NASA-HQ discipline scientist, where he advanced peer review and helped create new programs. Don is a recipient of NASA’s Scientific Achievement and Exceptional Service Medals and the Meteoritical Society’s Leonard Medal. Figure 1. Donald Bogard. Download figure to PowerPoint

The thermoluminescence phenomenon has been used for pottery dating and radiation dosimetry for sixty years and for forty years has been applied to the study of meteorites, being successful in quantifying metamorphic histories and providing new insights into terrestrial age and orbits. Here we review some of the fundamental properties of thermoluminescence with particular focus on the study of small extraterrestrial particles. We suggest that natural TL data can be used to identify the burial and release history of cometary particles and that induced TL measurements can provide in-sights into the mineralogy of particles (even when largely amorphous) and the metamorphic history of those particles. We illustrate the use of TL to study small particles by describing recent studies on micrometeorites and 10–100 μm fragments taken from the matrix of a meteorite Semarkona which is type 3.0 ordinary chondrite.

Early work on meteorite thermoluminescence, influenced by pottery dating and dosimetry applications, demonstrated a relationship between natural thermoluminescence and (1) the orbital perihelion of a meteorite and (2) the terrestrial age (time since fall) of a meteorite. For 14 years natural TL measurements were routinely made on newly recovered Antarctic meteorites to help identify unusual thermal and radiation histories, and to sort them by terrestrial age and perihelion. Two examples of the value of such data are presented, an Antarctic meteorite that underwent a major orbit change prior to fall and the collection mechanics of meteorites at the Lewis Cliff collection site. A second major area of focus for meteorite TL, that has no non-meteorite heritage, is the use of their induced TL to provide an extraordinarily sensitive and quantitative means of exploring metamorphic intensity and palaeothermometry. While especially valuable for unequilibrated ordinary chondrites, these types of measurement have proved useful with virtually every major class of meteorite, asteroidal and planetary. The challenge now is to extend the technique to small particles, micrometeorites, interplanetary dust particles, and cometary particles.

– To understand the nature of C asteroid surfaces, which are often related to phyllosilicates and C chondrites, we report near-infrared spectra for a suite of phyllosilicates, heated to 100–1100 °C in 100 °C intervals, and compare the results for telescope IRTF spectra for 11 C asteroids. As C asteroids have relatively featureless spectra, we focus on “continuum plots” (1.0–1.75 μm slope against 1.8–2.5 μm slope). We compare the continuum plots of the 11 C asteroids and our heated phyllosilicates with literature data for C chondrites. The CI, CR, CK, and CV chondrite meteorites plot in the C asteroid field, whereas CM chondrites plot in a close but discrete field. All are well separated from the large phyllosilicate field. Heating kaolinite and montmorillonite to ≥700 °C moves their continua slopes into the C asteroid field, whereas chlorite and serpentine slopes move into the CM chondrite field. Water losses during heating are generally 10–15 wt% and were associated with a 20–70% albedo drop. Our data are consistent with surfaces of the C asteroids consisting of the dehydration products of montmorillonite whereas the CM chondrites are the dehydration products of serpentine and chlorite. The presence of opaque minerals and evaporites does not provide quantitative explanations for the difference in continua slopes of the phyllosilicates and C asteroids. The CM chondrites can also be linked to the C asteroids by heating. We suggest that the CM chondrites are interior samples, and the presence of a 3 μm feature in C asteroid spectra also indicates the excavation of material.

A large chondrule from Semarkona, the most primitive ordinary chondrite known, has been discovered to contain a record of mass transport during its formation. In most respects, it is a normal Type I, group A1, low-FeO chondrule that was produced by reduction and mass-loss during the unidentified flash-heating event that produced the chondrules, the most abundant structural component in primitive meteorites. We have previously measured elemental abundances and abundance profiles in this chondrule. We here report oxygen isotope ratio abundances and ratio abundance profiles. We have found that the mesostasis is zoned in oxygen isotope ratio, with the center of the chondrule containing isotopically heavier oxygen than the outer regions, the outer regions being volatile rich from the diffusion of volatiles into the chondrule during cooling. The δ17O values range from −2.0‰ to 9.9‰, while δ18O range from −1.9‰ to 9.6‰. More importantly, a plot of δ17O against δ18O has a slope of 1.1 ± 0.2 (1σ) and 0.88 ± 0.10 (1σ) when measured by two independent methods. Co-variation of δ17O with δ18O that does not follow mass-dependent fractionation has often been seen in primitive solar system materials and is usually ascribed to the mixing of different oxygen reservoirs. We argue that petrographic and compositional data indicate that this chondrule was completely melted at the time of its formation so that relic grains could not have survived. Furthermore, there is petrographic and compositional evidence that there was no aqueous alteration of this chondrule subsequent to its formation. Although it is possible to formulate a series of exchanges between the chondrule and external 16O-rich and 16O-poor reservoirs that may explain the detailed oxygen isotope systematics of this chondrule, such a sequence of events looks very contrived. We therefore hypothesize that reduction, devolatilization, and crystallization of the chondrule melt may have produced 16O-rich olivines and 16O-poor mesostasis plotting on a slope-one line as part of the chondrule-forming process in an analogous fashion to known chemical mass-independent isotopic fractionation mechanisms. During cooling, volatiles and oxygen near the terrestrial line in oxygen isotope composition produced the outer zone of volatile rich and 16O-rich mesostasis. The chondrule therefore not only retains a record of considerable mass transport accompanying formation, but also may indicate that the isotopes of oxygen underwent mass-independent fractionation during the process.

In order to explore the nature and history of micrometeorites, we have measured the thermoluminescence (TL) properties of four micrometeorites, three cosmic spherules, and one irregular scoriaceous particle, that we found in a survey of 17 micrometeorites. These micrometeorites have TL sensitivities ranging from 0.017 ± 0.002 to 0.087 ± 0.009 (on a scale normalized to 4 mg of the H3.9 chondrite Dhajala). The four micrometeorites have very similar TL peak temperatures and TL peak widths, and these distinguish them from CI, most CM, CV, CO, and ordinary chondrites. However, the TL properties of these micrometeorites closely resemble those of the unusual CM chondrite MacAlpine Hills (MAC) 87300 and terrestrial forsterites. Heating experiments on submillimeter chips of a CM chondrite and a H5 chondrite suggest that these TL properties are have not been significantly affected by atmospheric passage. Thus we suggest that there is no simple linkage between these micrometeorites and the established meteorite classes, and that forsterite is an important component of these micrometeorites, as it is in many primitive solar system materials.

To investigate the nature, origin, and history of the fine-grained matrix in Semarkona and develop techniques suitable for small samples, we have measured the induced thermoluminescence properties of six matrix samples 10 μm to 400 μm in size. The samples had TL sensitivities comparable with 4 mg of bulk samples of type 3.2-3.4 ordinary chondrites, which is very high relative to bulk Semarkona. The other induced TL properties of these samples, TL peak temperatures, and TL peak widths distinguish them from other ordinary chondrite samples where the TL is caused by feldspar. Cathodoluminescence images and other data suggest that the cause of the luminescence in the Semarkona fine-grained matrix is forsterite. In some respects the matrix TL data resemble that of Semarkona chondrules, in which the phosphor is forsterite and terrestrial forsterites from a variety of igneous and metamorphic environments. However, differences in the TL peak temperature versus TL peak width relationship between the matrix samples and the other forsterites suggest a fundamentally different formation mechanism. We also note that forsterite appears to be a major component in many primitive materials, such as nebulae, cometary dust, and Stardust particles.

10 pages, 6 figures, 5 tables, The fall of the Cali meteorite took place on 6 July 2007 at 16 h 32 ± 1 min local time (21 h 32 ± 1 min UTC). A daylight fireball was witnessed by hundreds of people in the Cauca Valley in Colombia from which 10 meteorite samples with a total mass of 478 g were recovered near 3°24.3'N, 76°30.6'W. The fireball trajectory and radiant have been reconstructed with moderate accuracy. From the computed radiant and from considering various plausible velocities, we obtained a range of orbital solutions that suggest that the Cali progenitor meteoroid probably originated in the main asteroid belt. Based on petrography, mineral chemistry, magnetic susceptibility, fhermoluminescence, and bulk chemistry, the Cali meteorite is classified as an H/L4 ordinary chondrite breccia, This work was partially supported by NASA Cosmochemistry grants NNH05AB65I to JNG and NNG06GF95G to AER and NASA Discovery Data Analysis grant NNX08G17G to DWGS. JMTR also thanks CSIC for a JAE-Doc research contract

We have studied the sublimation of ice and water vapor transport through various thicknesses of clay (

We have studied the effect of wind velocity on the sublimation rate of pure water ice under martian conditions. Measurements were made for wind velocities ranging from 0.7 to 11.4 m s −1 , a typical range observed by the meteorological instruments on the surface of Mars, and at − 15 ° C a value typical of the daily high temperature for most of the year at the Pathfinder landing site. At this temperature, and for a low-humidity environment (relative humidity around 1%) sublimation rates increase following a linear trend of equation E S = 0.68 + 0.025 V ( E S is the sublimation rate in mm h −1 and V is the wind speed in m s −1 ). In high relative humidity (30–35%) atmospheres, the effect of wind velocity is negligible, and the sublimation rate remains nearly constant at 0.33 ± 0.04 mm h −1 . Pure forced convection theory did not provide a satisfying description of the data in terms of the range of values and their wind speed dependency. Therefore, a new semi-empirical expression for the sublimation rate that combines free and forced convection was developed using analogy with heat transfer models. Using this expression, sublimation rates of ice as a function of wind velocity for any temperature can be calculated. In general, temperature is more important that wind speed and atmospheric humidity in determining the rate of sublimation of ice on Mars.

In order to advance our understanding of the long-term stability of subsurface ice, the diurnal martian water cycle, and implications for liquid water, we determined diffusion coefficients and adsorption kinetics for the water vapor produced by the sublimation of ice buried beneath various layers of fine-grained ( 1.56 ± 0.53 × 10 −4 , 2.05 ± 0.82 × 10 −4 , and 3.42 ± 1.36 × 10 −4 m 2 s −1 for the 52.6 ± 8.3 at 270 K for 39.0 ± 6.4 at 267 K for 63–125 μm, and 54.3 ± 9.3 at 266 K for 125–250 μm, resulting in surface areas of 2.6 ± 0.1 × 10 4 , 1.7 ± 0.3 × 10 4 , 1.5 ± 0.3 × 10 4 m 2 kg −1 , respectively. These results suggest that while diffusion is too rapid to explain the purported diurnal cycle in water content of the atmosphere, adsorption is efficient and rapid, and does provide an effective mechanism to explain such a cycle. The present diffusion data suggest that very thin, 10 h at ∼224 K, just above the freezing point of saturated CaCl2. Temperatures can remain above ∼224 K over most of the planet, which means that water, even as saturated brine, will sublimate before the freezing point is reached and liquid could be formed. On the other hand, 1 m ice layers below 1 m of fine-grained basaltic regolith at 235 K and 10 Pa of atmospheric water could last 600 to 1300 years. At deeper depths and lower temperatures, ice could last since the last major obliquity change 400,000 years ago.

Laboratory impact tests have been performed on experimental versions of a proposed robotic sample collector for extraterrestrial samples. The collector consists of a retractable aluminum ring containing an impregnable silicone compound that is pressed into the surface of the body to be sampled. As part of a comprehensive program to evaluate this idea, we have performed tests to determine if the samples embedded in the collector medium can survive the impact forces experienced during direct reentry, such as that of the recent Genesis sample return mission. For the present study, samples of sand, rock, glass, and chalk were subjected to decelerations of 1440–2880 g using drop tests. We found that even the most fragile samples, chosen to be representative of a wide range of the types of materials found on the surface of asteroids that have currently been studied, can withstand impacts of the intensity experienced by a sample return capsule during direct reentry.

Sample return from small solar system objects is playing an increasingly important part in solar system exploration. Critical to such missions is a robust, simple, and economic sample collector. We have developed a collector such as this for near-Earth asteroid sample return missions that we have termed the Touch-and-Go Impregnable Pad (TGIP). The collector utilizes a silicone substrate that is pushed into the dust and gravel surface layer of the asteroid. As part of a systematic evaluation of the TGIP, we have investigated the resilience of this substrate to ionizing radiations. Several miniature versions of the collector, containing typically ∼3 g of the collection substrate, were exposed to 0.564 MeV beta particles from a 90 Sr source and a 6 MeV electron beam in a linear accelerator to simulate the wide range of energies of solar and galactic ionizing radiation. Various radiation levels up to eight times greater than expected on a six-year asteroid mission (in the case of beta radiation) and 50 times greater than expected (in the case of the 6 MeV electron radiation) were administered to the substrate. After irradiation, the efficiency of the substrate in collecting samples of mock regolith was compared with that of collectors that had not been irradiated. No difference beyond experimental uncertainty was observed and we suggest that the operational TGIP will not be affected adversely by radiation doses expected during a typical six-year inner solar system mission.

Sample return is playing an increasingly important role in solar system exploration. Among the possible mission on the horizon, are sample return from asteroids, comets, the Moon and Mars. A collector initially intended for near-Earth asteroids is the touch-and-go-impregnable-pad (TGIP). Here we explore the effect of temperature on its collection capabilities. Temperatures expected on near-Earth asteroid mission targets range from −43 to 36 °C. Experiments were conducted at −75, −50, −25, 23, 65, and 105 °C. It was found that the mass of sample collected by the TGIP increased almost linearly to 23 °C and then leveled off at higher temperatures. We also found that the collector did not lose its ability to collect samples after being subjected to −75 °C temperatures (essentially frozen) and then thawed. These experiments have shown that the TGIP can operate effectively at temperatures expected on near-Earth asteroids, especially if collection is performed on the sunward side of the asteroid.

We report measurements of the evaporation rate of water under Mars-like conditions (CO2 atmosphere at 7 mbar and approximately 0 degrees C) in which small temperature oscillations about the freezing point repeatedly formed and removed a thin layer of ice. We found that the average evaporation at 2.7 +/- 0.5 degrees C without an ice layer (corrected for the difference in gravity on Earth and on Mars) was 1.24 +/- 0.12 mm/h, while at -2.1 +/- 0.3 degrees C with an ice layer the average evaporation rate was 0.84 +/- 0.08 mm/h. These values are in good agreement with those calculated for the evaporation of liquid water and ice when it is assumed that evaporation only depends on diffusion and buoyancy. Our findings suggest that such differences in evaporation rates are entirely due to the temperature difference and that the ice layer has little effect on evaporation rate. We infer that the formation of thin layers of ice on pools of water on Mars does not significantly increase the stability of water on the surface of Mars.

The surprisingly low S/Si ratio of Asteroid 433 Eros measured by the NEAR Shoemaker spacecraft probably reflects a surface depletion rather than a bulk property of the asteroid. The sulfur X-ray signal originates at a depth 10 μm in the regolith. The most efficient process for vaporizing minerals at the heliocentric distance of Eros are sputtering by solar wind ions and hypervelocity impacts. These are the same processes that account for the changes in optical properties of asteroids attributed to “space weathering” of lunar surface materials, although the relative importance of sputtering and impacts need not be the same for the Moon and asteroids. Troilite, FeS, which is the most important sulfide mineral in meteorites, and presumably on S-type asteroids like Eros, can be vaporized by much less energy than other major minerals, and will therefore be preferentially lost. Within 10 6 years either process can remove sulfide from the top 10–100 μm of regolith. Sulfur will be lost into space and some sulfur will migrate to deeper regolith layers. We also consider other possible mechanisms of surficial sulfur depletion, such as mineral segregation in the regolith and perhaps even incipient melting. Although we consider solar wind sputtering the most likely cause of the sulfur depletion on Eros, we cannot entirely rule out other processes as causes of the sulfur deficiency. Laboratory simulations of the relevant processes can address some of the open questions. Simulations will have to be carried out in such a way that potential sulfur loss processes as well as resurfacing can be studied simultaneously, requiring a large and complex environmental chamber.

The Hera mission is a proposed Discovery class mission to collect three samples from each of three near-Earth asteroids. Returned samples would have information on geological context and possibly stratigraphy, would provide fresh regolith, and conceivably samples that would not naturally reach the Earth. During the development of a simple touch-and-go sample collector, questions arose concerning the nature of the samples to be collected, their maximum science return, and the simplest engineering designs. This article reports the results of a small workshop convened to discuss this topic. It is argued that the maximum science return for the Hera samples would be obtained if asteroids of different major spectral classes were visited, samples were disturbed as little as possible during collection, and samples from the very surface were obtained. Surface samples would have the utmost value in interpreting links between asteroids and meteorites, would yield maximum information in solar exposure, would avoid planetary protection concerns, and would produce material not reaching Earth as meteorites. At the same time, they would be simpler to sample than subsurface samples. � 2004 COSPAR. Published by Elsevier Ltd. All rights reserved.

The NEAR mission was a spectacular rehearsal for one of the most exciting and scientifically rewarding missions of the next decade, sample return from near-Earth asteroids. A unique source of information about the early solar system, the formation of the planets, and the connection between stars and our Sun, are meteorites and asteroids. Yet, studies of both are hindered by a lack of unequivocal and detailed information linking the two. Meteorites are rock samples of unknown provenance. We have no information about the geological context of their source. They are also highly non-representative sampling of primitive solar system material because the terrestrial meteorite population is dominated by the ejecta of stochastic impacts and because the atmosphere filters out all but the toughest rocks. Without sample return, asteroids are not amenable to the depth and breadth of techniques available in the laboratory, yet the NEAR images indicate that there are many processes occurring on asteroids – or that could have occurred in the past – that we must understand if the meteorite data are ever to yield a clear image of early solar system processes. Technical developments of the last few years and the discovery of large numbers of NEAs mean that sample return is now within small mission capability. A team of about 20 scientists and engineers from all relevant subject fields are now assembling a mission called Hera. This paper reviews the mission as of fall 2002. 2004 COSPAR. Published by Elsevier Ltd. All rights reserved.

— The study of chondrules provides information about processes occurring in the early solar system. In order to ascertain to what extent these processes played a role in determining the properties of the enstatite chondrites, the physical and chemical properties of chondrules from three EL3 chondrites and three EH3 chondrites have been examined by optical, cathodoluminescence (CL), and electron microprobe techniques. Properties examined include size, texture, CL, and composition of both individual phases and bulk chondrules. The textures, distribution of textures, and composition of silicates of the EL3 chondrules resemble those of EH3 chondrules. However, the chondrules from the two classes differ in that (1) the size distribution of the EL chondrules is skewed to larger values than EH chondrules, (2) the enstatite in EL chondrules displays varying shades of red CL due to the presence of fine-grained sulfides and metal in the silicates, and (3) the mesostasis of EH chondrules is enriched in Na relative to that of EL chondrules. The similarities between the chondrules of the two classes suggest similar precursor materials, while the differences suggest that there was not a single reservoir of meteoritic chondrules, but that their origin was fairly local. The differences in the size distribution of chondrules in EH and EL chondrites may be explained by aerodynamic and gravitational sorting during accumulation of the meteoric material, while differences in CL and mesostasis properties may reflect differences in formation conditions and cooling rate following chondrule formation. We argue that our observations are consistent with the formation of enstatite chondrites in a thick dynamic regolith on their parent body.

The recently established Arkansas–Oklahoma Center for Space and Planetary Science has been given a large planetary simulation chamber by the Jet Propulsion Laboratory, Pasadena, California. When completely refurbished, the chamber will be dubbed Andromeda and it will enable conditions in space, on asteroids, on comet nuclei, and on Mars, to be reproduced on the meter-scale and surface and subsurface processes monitored using a range of analytical instruments. The following projects are currently planned for the facility. (1) Examination of the role of surface and subsurface processes on small bodies in the formation of meteorites. (2) Development of in situ sediment dating instrumentation for Mars. (3) Studies of the survivability of methanogenic microorganisms under conditions resembling the subsurface of Mars to test the feasibility of such species surviving on Mars and identify the characteristics of the species most likely to be present on Mars. (4) The nature of the biochemical “fingerprints” likely to have been left by live organisms on Mars from a study of degradation products of biologically related molecules. (5) Testing local resource utilization in spacecraft design. (6) Characterization of surface effects on reflectivity spectra for comparison with the data from spacecraft-borne instruments on Mars orbiters.

We review induced thermoluminescence (TL) data for 102 unequilibrated ordinary chondrites (UOCs), many data just published in abstracts, in order to identify particularly primitive UOCs and further explore TL systematics that may have implications for the history of the chondrites and their parent body. We have identified 11 UOCs of petrologic types 3.0-3.1: Adrar 003, Elephant Moraine (EET) 90066, EET 90161, Grosvenor Mountains (GRO) 95502, Lewis Cliff (LEW) 88477, Meteorite Hills (MET) 96503, Yamato (Y)-790787, Y-791324, Y-791558, Y-793565, and Y-793596. These samples represent an important new resource for researchers interested in the nature of primitive solar system materials. Previously reported trends in which TL sensitivity increases with TL peak temperature and TL peak width, which we interpret in terms of crystallization of feldspar in the ordered or disordered forms during metamorphism, are confirmed by the new data. Importantly, the present data strengthen the trend described earlier in which the mean level of metamorphism experienced by UOCs increases along the series LL, L and H. This suggests either different burial depths for the UOCs from each class, or formation at similar depths in regoliths of different thickness.

We measured cosmic ray products-noble gases, radionuclides, thermoluminescence, and nuclear tracks-and trace element contents and mineralogy of samples of three orthogonal and mutually intersecting cores (41-46 cm long) of a 101.6 kg Ghubara individual (1958,805) at The Natural History Museum, London. The xenoliths, like the host, have high concentrations of trapped solar gases and are heavily shocked. While contents of noble gases and degree of shock-loading in this individual and three others differ somewhat, the data indicate that Ghubara is a two-generation regolith breccia. Contents of cosmogenic 26Al and 10Be and low track densities indicate that the Ghubara individuals were located more than 15 cm below the surface of an 85 cm meteoroid. Because of its large size, Ghubara's cosmic ray exposure age is poorly defined to be 15-20 Ma from cosmogenic nuclides. Ghubara's terrestrial age, based on 14C data, is 2-3 ka. Not only is Ghubara the first known case of a 2-generation regolith breccia on the macro scale, it also has a complicated thermal and irradiation history.