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1. Synthesis and electronic properties of nitrogen-rich nanographene.

Author

Heim, Gavin P., Hirahara, Masanari, Dev, Vidhya M., and Agapie, Theodor

Subjects
POLYCYCLIC aromatic hydrocarbons, OPTICAL properties, METALS, ALKYNES, ELECTROCHEMISTRY
Abstract

A polycyclic aromatic hydrocarbon displaying twelve edge nitrogen centers for a 42 π-electron system is reported. This compound was synthesized via Sonogashira coupling of pyrimidine precursors, [2+2+2] cycloaddition of bis(aryl) alkynes, and anionic cyclodehydrogenation. Spectroscopy, electrochemistry, and computational results suggest a narrowing of the HOMO–LUMO gap compared to the N-free analogue. Metal coordination affects the optical properties of the extended π system. [ABSTRACT FROM AUTHOR]

Published
2024
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