Search

The carbonation of lime-treated soils that occurs during the short-term and long-term curing is not sufficiently explored in the domain of lime stabilization. The present study investigates the carbonation mechanism in lime-treated silty clay treated with two lime contents (4%, 8%) subjected to different curing periods (7, 90, 180, and 365 days). The cured samples were exposed to accelerated carbonation, and subsequent change in the unconfined compressive strength was compared with that of control samples tested under a nitrogen environment. The extent of carbonation was measured using phenolphthalein solution. X-ray diffraction technique and thermogravimetric analysis were used to analyze the reaction products resulted from carbonation. The morphology of carbonates and effects of carbonation on the pore structure were assessed using a scanning electron microscope and mercury intrusion porosimeter, respectively. Results show that carbonation has a deleterious effect on the performance of lime-treated clay. The strength of lime-treated soils upon carbonation decreased by 30% on average. The fabric structure of treated clay was found to vary with lime content and curing period, which determined the extent of carbonation. Decalcification of reaction products and cracking induced by the carbonation of residual lime contributed to the reduction in compressive strength of treated clay. The observed strength behavior of the carbonated samples is substantiated by quantifying the variation in pore structure characteristics.

Soil–lime interactions involve concomitant short-term and long-term alterations of the fine-grained soil resulting in the formation of a workable material bonded by various pozzolanic compounds. These pozzolanic compounds being cementitious in nature are expected to hold the soil particles together and bring long-term strength and stability to the soil–lime composites. However, the durability of cementitious phases formed due to pozzolanic reactions is highly subjective owing to the variations in the moisture and physiochemical factors like pH under diverse environmental conditions. The relative humidity and presence of atmospheric gases like carbon dioxide have a significant impact on the performance of the stabilized system. Carbonation of reaction products, as well as the effects of seasonal moisture fluctuations, can cause the decalcification of the cementitious phases and further degradation in the stabilized system. However, the type of reaction products and their chemical composition, which is a function of the mineralogy of the soil, will determine their durability in adverse conditions. The present study attempts to review the chemistry of reaction products formed in view of its inherent mineralogy. In addition, the degradation nature of the soil–lime composites under adverse conditions like moisture ingress and carbonation is evaluated for their long-term performance.