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9 results on '"Di, Shuxia"'

5. Highly selectivity catalytic hydrogenation of acetylene on Al2O3 supported palladium-imidazolium based ionic liquid phase

Author

Xu, Yiqi, primary, Jiang, Yishu, additional, Xu, Hao, additional, Wang, Qingtao, additional, Huang, Weimin, additional, He, Haihua, additional, Zhai, Yuanyuan, additional, Di, Shuxia, additional, Guo, Lingling, additional, Xu, Xiaoliang, additional, Zhao, Jia, additional, Feng, Feng, additional, Zhang, Qunfeng, additional, and Li, Xiaonian, additional

Published
2018
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6. Carbon-supported perovskite-like CsCuCl3 nanoparticles: a highly active and cost-effective heterogeneous catalyst for the hydrochlorination of acetylene to vinyl chloride

Author

Zhai, Yuanyuan, primary, Zhao, Jia, additional, Di, Xiaoxia, additional, Di, Shuxia, additional, Wang, Bolin, additional, Yue, Yuxue, additional, Sheng, Gangfeng, additional, Lai, Huixia, additional, Guo, Lingling, additional, Wang, Hong, additional, and Li, Xiaonian, additional

Published
2018
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9. Carbon-supported perovskite-like CsCuCl3nanoparticles: a highly active and cost-effective heterogeneous catalyst for the hydrochlorination of acetylene to vinyl chlorideElectronic supplementary information (ESI) available. See DOI: 10.1039/c8cy00291f

Author

Zhai, Yuanyuan, Zhao, Jia, Di, Xiaoxia, Di, Shuxia, Wang, Bolin, Yue, Yuxue, Sheng, Gangfeng, Lai, Huixia, Guo, Lingling, Wang, Hong, and Li, Xiaonian

Abstract

Non-mercuric catalysts in acetylene hydrochlorination reaction have been gained much attention. Cu-based catalysts are low-cost, green and stable. However, their lower activity than that of mercury-based catalysts limits their practical applications. In this study, we report activated carbon-supported perovskite-like CsCuCl3nanoparticles as a catalyst for hydrochlorination of acetylene. Cu–Cs/AC with 1 wt% Cu content exhibits superior activity than pure Cu/AC and even Hg/AC. At the condition of 200 °C and 50 h−1industrial space velocity, C2H2conversion is maintained at 92% over 200 h. Our findings suggest that the low-cost Cu–Cs/AC catalyst can be envisioned as a viable alternative to commercial toxic HgCl2for acetylene hydrochlorination.

Published
2018
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