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3. Homolytic isomerization of di-n-butyl mercaptols of diethyl ketone and dipropyl ketone

Author

R. G. Petrova and T. D. Churkina

Subjects
chemistry.chemical_classification, Pentane, Heptane, chemistry.chemical_compound, Ketone, Chemistry, Dipropyl ketone, Organic chemistry, General Chemistry, Isomerization, Peroxide, Homolysis
Abstract

The rearrangement of the dibutyl mercaptols of diethyl ketone and dipropyl ketone under the influence of tert-butyl peroxide proceeds with a 1,2-migration of the butylthio group and leads to the respective formation of 2,3-bis(n-butylthio)pentane and 3,4-bis(n-butylthio)heptane.

Published
1975
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