Search

Protonated hydrogen cyanide, HCNH$^{+}$, plays a fundamental role in astrochemistry because it is an intermediary in gas-phase ion-neutral reactions within cold molecular clouds. However, the impact of the environment on the chemistry of HCNH$^{+}$ remains poorly understood. With the IRAM-30 m and APEX-12 m observations, we report the first robust distribution of HCNH$^{+}$ in the Serpens filament and in Serpens South. Our data suggest that HCNH$^{+}$ is abundant in cold and quiescent regions, but is deficit in active star-forming regions. The observed HCNH$^{+}$ fractional abundances relative to H$_{2}$ range from $3.1\times 10^{-11}$ in protostellar cores to $5.9\times 10^{-10}$ in prestellar cores, and the HCNH$^{+}$ abundance generally decreases with increasing H$_{2}$ column density, which suggests that HCNH$^{+}$ coevolves with cloud cores. Our observations and modeling results suggest that the abundance of HCNH$^{+}$ in cold molecular clouds is strongly dependent on the H$_{2}$ number density. The decrease in the abundance of HCNH$^{+}$ is caused by the fact that its main precursors (e.g., HCN and HNC) undergo freeze-out as the number density of H$_{2}$ increases. However, current chemical models cannot explain other observed trends, such as the fact that the abundance of HCNH$^{+}$ shows an anti-correlation with that of HCN and HNC, but a positive correlation with that of N$_{2}$H$^{+}$ in the southern part of the Serpens South northern clump. This indicates that additional chemical pathways have to be invoked for the formation of HCNH$^{+}$ via molecules like N$_{2}$ in regions in which HCN and HNC freeze out. Both the fact that HCNH$^{+}$ is most abundant in molecular cores prior to gravitational collapse and the fact that low-$J$ HCNH$^{+}$ transitions have very low H$_{2}$ critical densities make this molecular ion an excellent probe of pristine molecular gas., Comment: 25 pages, 26 figures, accepted for publication in A&A

The Serpens filament, a prominent elongated structure in a relatively nearby molecular cloud, is believed to be at an early evolutionary stage, so studying its physical and chemical properties can shed light on filament formation and early evolution. The main goal is to address the physical and chemical properties as well as the dynamical state of the Serpens filament at a spatial resolution of $\sim$0.07 pc and a spectral resolution of $\lesssim$0.1~km~s$^{-1}$. We performed $^{13}$CO (1--0), C$^{18}$O (1--0), C$^{17}$O (1--0), $^{13}$CO (2--1), C$^{18}$O (2--1), and C$^{17}$O (2--1) imaging observations toward the Serpens filament with the Institut de Radioastronomie Millim{\'e}trique 30-m (IRAM-30 m) and Atacama Pathfinder EXperiment (APEX) telescopes. Widespread narrow $^{13}$CO (2--1) self-absorption is observed in this filament, causing the $^{13}$CO morphology to be different from the filamentary structure traced by C$^{18}$O and C$^{17}$O. Our excitation analysis suggests that the opacities of C$^{18}$O transitions become higher than unity in most regions, and this analysis confirms the presence of widespread CO depletion. Further we show that the local velocity gradients have a tendency to be perpendicular to the filament's long axis in the outskirts and parallel to the large-scale magnetic field direction. The magnitudes of the local velocity gradients decrease toward the filament's crest. The observed velocity structure can be a result of gravity-driven accretion flows. The isochronic evolutionary track of the C$^{18}$O freeze-out process indicates the filament is young with an age of $\lesssim$2 Myr. We propose that the Serpens filament is a newly-formed slightly-supercritical structure which appears to be actively accreting material from its ambient gas., Comment: 26 pages, 24 figures, 2 tables, accepted for publication in A&A; A 3D view of the C18O(2-1) cube can be found in https://gongyan2444.github.io/gallery.html